24F410-B_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… WEST SYSTEM

410 Microlight

Filler
APPLICABLE PRODUCT CODE S: ………………. 410, 410-2, 410-7 and 410-B
CHEMICAL FAMILY: ………………………………….. A blend of thermoplastic polymer microspheres and inorganic amorphous silicates.
INTENDED PRODUCT USES: ……………………… Thickening agent for liquid epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. 410-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 866-937-8797 or 989-684-7286 Non-transportation
www.westsystem.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Eye damage/irritation, Category 2A
Combustible dust

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H319 Causes serious eye irritation
May form combustible dust concentrations in the air

Precautionary Statements:
Prevention
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P332 + P313 If skin irritation occurs: Get medical attention/advice
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
Keep away from all ignition sources including heat, sparks and open flame.
Prevent dust accumulations to minimize explosion hazard.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Amorphous sodium borosilicate 50815-87-7 30-60
Thermoplastic copolymer 25214-39-5 30-60
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 5-10
Isobutane 75-28-5 1-5
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 1-5
Synthetic amorphous pyrogenic silica 112945-52-5 1-5

WEST SYSTEM

410 Microlight

Filler
Page 2 of 6 Last Revised: 03JAN22
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Excessive exposure may cause irritation and tearing.
RESPONSE: Flush with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician if symptoms develop
and persist.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: May cause skin irritation. RESPONSE: Wash with mild soap
and water. Consult a physician if effects occur and persist. No specific treatment is known or anticipated.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Excessive exposure may cause slight respiratory irritation.
RESPONSE: Remove to fresh air if symptoms develop and keep comfortable for breathing. Seek medical advice if symptoms develop and persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), water, or dry chemical. Fog or
mist is recommended if water is used. NON-SUITABLE: Avoid using high pressure media.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. May form combustible dust concentrations in the air. See Section 9 for
additional information. Combustion may result in the release of carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
formaldehyde, nitric acid and ammonia.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Dust may form an explosive mixture in the air, possibly resulting in a secondary explosion. Downwind personnel should be
evacuated.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Eliminate ignition sources. Use methods that avoid generating airborne
dust. Use a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Do not create a dust cloud by brushing or sweeping, or
using compressed air.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Contain spilled product to the extent practical and feasible.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 0 F (-17 C) / 95 F (35 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Keep container tightly closed in a dry, well-
ventilated place. Do not store directly in the sun or in conditions exceeding 95 F (35 C). Keep away from sources of ignition or heat. Avoid storing
near incompatible materials identified in Section 10.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid dust formation. Avoid breathing dust. Wash after handling. Provide
appropriate exhaust ventilation at points of operation where dust can be generated. Avoid using compressed air. Dust may form explosive mixture
with air. Take precautionary measures against static discharges. Metal parts of mixing and processing equipment should be earthed/grounded.
Dust deposits should not be allowed to accumulate on surfaces.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields, or goggles if necessary.

SKIN PROTECTION GUIDELINES: ……………………………………………. Liquid-proof gloves (such as neoprene or nitrile) should be used to prevent
skin irritation. Barrier creams can be used effectively.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with particulate filter, such as a N95 or greater, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.

WEST SYSTEM

410 Microlight

Filler
Page 3 of 6 Last Revised: 03JAN22
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Wash thoroughly after handling. Do not eat, drink or smoke when handling this product. Generally speaking, working cleanly and following
basic precautionary measures will greatly minimize the exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LI MITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Amorphous sodium borosilicate 50815-87-7 Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable
Thermoplastic copolymer 25214-39-5 No data available.
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available.
Isobutane 75-28-5 ACGIH TLV TWA 1000 ppm (central nervous
system)
NIOSH REL TWA 800 ppm; 1900 mg/m
3

Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 No data available.
Synthetic pyrogenic amorphous silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Powder, solid.
COLOR: ………………………………………………………………………………… Beige-tan.
ODOR: …………………………………………………………………………………… Slight.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 10.5
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. No data available
FLASH POINT: ……………………………………………………………………….. No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. No data available
BULK DENSITY………………………………………………………………………. No data available
VAPOR DENSITY (air = 1) ……………………………………………………….. No data available
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. Largely insoluble.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s

@ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. Not applicable.
EXPLOSIVE PROPERTIES: ……………………………………………………… Dust may form explosive mixtures in air. Explosive properties of this mixture
have not been measured. One or more of the components of this mixture have been identified as having the potential to form an explosive mixture
with air when suspended as a dust cloud.
Kst VALUE: ……………………………………………………………………………. No data available
MAXIMUM EXPLOSION PRESSURE (Pmax) ……………………………… No data available
MINIMUM IGNITION ENERGY (MIE): …………………………………………. No data available
MAXIMUM EXPLOSION CONCENTRATION (MEC): ……………………. No data available
DUST EXPLOSION CLASSIFICATION: ……………………………………… No data available

10. STABILITY AND REACTIVITY

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself.

INCOMPATIBILITIES: ……………………………………………………………… Strong oxidizing agents and acids. Contact with hydrofluoric acid will cause
the release of a toxic gas.

CONDITIONS TO AVOID: ………………………………………………………… Avoid settling dust collection and airborne dust formation. Avoid direct heat
or excessive sunlight.

DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
ammonia.

11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION

WEST SYSTEM

410 Microlight

Filler
Page 4 of 6 Last Revised: 03JAN22

Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Amorphous sodium borosilicate 50815-87-7 No data No data No data
Thermoplastic copolymer 25214-39-5 No data No data No data
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 >2000 mg/kg No data No data
Isobutane 75-28-5 No data No data No data
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 2169 mg/kg No data No data
Synthetic pyrogenic amorphous silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation. Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Does not meet criteria for skin sensitization.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Does not meet criteria for reproductive toxicity.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for mutagenicity.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity. Does not contain
components > 0.1% that are listed as a carcinogen by IARC, NTP or OSHA.

Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure
to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic
amorphous silica.

May contain trace amounts of acrylonitrile at levels <0.005% by weight. Acrylonitrile is listed by IARC as a Group 2B carcinogen, by NTP as a reasonably anticipated human carcinogen, and is specifically regulated by OSHA as a carcinogen. STOT (Single Exposure): .................................................................. Not classified. Does not meet STOT SE criteria. STOT (Repeated Exposure): ............................................................. Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity criteria. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Does not meet chronic aquatic toxicity criteria. PERSISTANCE AND BIODEGRADABI LITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Amorphous sodium borosilicate 50815-87-7 No data available. Thermoplastic copolymer 25214-39-5 No data available. Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available. Isobutane 75-28-5 No data available. Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 Acute Aquatic 3; Chronic Aquatic 3 Synthetic pyrogenic amorphous silica 112945-52-5 No data available. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. WEST SYSTEM 410 Microlight Filler Page 5 of 6 Last Revised: 03JAN22 Reclaim or reuse may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. MARINE POLLUTANT: ....................................................................... Not applicable. IMDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. EmS Number: .................................................................................... Not applicable. MARINE POLLUTANT ........................................................................ Not applicable. 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Data is not available for component CAS# 50815-87-7. South Korea KECI Data is not available for component CAS# 50815-87-7. China IECSC Data is not available for component CAS# 50815-87-7. Philippines PICCS Data is not available for component CAS# 50815-87-7. New Zealand NZIoC Data is not available for component CAS# 50815-87-7. US EPA TSCA Requirements: ........................................................... No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... Not regulated. Subject to Section 304 (RQ) ........................................................ Not regulated. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ Not regulated. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA Isobutane 75-28-5 PA, NJ, MA Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 PA, NJ Acrylonitrile WEST SYSTEM 410 Microlight Filler Page 6 of 6 Last Revised: 03JAN22 107-13-1 <0.005% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ December 9, 2019 SDS VERSION: .................................................................................. 410-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 1 FLAMMABILITY: 2 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 1 0 2

24F140-B_SDS.pdf

SAFETY DATA SHEET
Last Revised: 03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… WEST SYSTEM

410 Microlight

Filler
APPLICABLE PRODUCT CODE S: ………………. 410, 410-2, 410-7 and 410-B
CHEMICAL FAMILY: ………………………………….. A blend of thermoplastic polymer microspheres and inorganic amorphous silicates.
INTENDED PRODUCT USES: ……………………… Thickening agent for liquid epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. 410-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 866-937-8797 or 989-684-7286 Non-transportation
www.westsystem.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

Skin corrosion/irritation, Category 2
Eye damage/irritation, Category 2A
Combustible dust

Label Elements

Hazard Pictogram(s):

Signal Word:
WARNING

Hazard Statements:
H315 Causes skin irritation
H319 Causes serious eye irritation
May form combustible dust concentrations in the air

Precautionary Statements:
Prevention
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302 + P352 IF ON SKIN: Wash with plenty of soap and water
P332 + P313 If skin irritation occurs: Get medical attention/advice
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 If eye irritation persists: Get medical attention/advice.
Keep away from all ignition sources including heat, sparks and open flame.
Prevent dust accumulations to minimize explosion hazard.

Other Hazards
None known.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Amorphous sodium borosilicate 50815-87-7 30-60
Thermoplastic copolymer 25214-39-5 30-60
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 5-10
Isobutane 75-28-5 1-5
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 1-5
Synthetic amorphous pyrogenic silica 112945-52-5 1-5

WEST SYSTEM

410 Microlight

Filler
Page 2 of 6 Last Revised: 03JAN22
The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Excessive exposure may cause irritation and tearing.
RESPONSE: Flush with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician if symptoms develop
and persist.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: May cause skin irritation. RESPONSE: Wash with mild soap
and water. Consult a physician if effects occur and persist. No specific treatment is known or anticipated.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Excessive exposure may cause slight respiratory irritation.
RESPONSE: Remove to fresh air if symptoms develop and keep comfortable for breathing. Seek medical advice if symptoms develop and persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), water, or dry chemical. Fog or
mist is recommended if water is used. NON-SUITABLE: Avoid using high pressure media.

FIRE AND EXPLOSION HAZARDS: ………………………………………….. May form combustible dust concentrations in the air. See Section 9 for
additional information. Combustion may result in the release of carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
formaldehyde, nitric acid and ammonia.

SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment. Dust may form an explosive mixture in the air, possibly resulting in a secondary explosion. Downwind personnel should be
evacuated.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Eliminate ignition sources. Use methods that avoid generating airborne
dust. Use a vacuum with high efficiency particulate air (HEPA) filtration is recommended. Do not create a dust cloud by brushing or sweeping, or
using compressed air.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Contain spilled product to the extent practical and feasible.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 0 F (-17 C) / 95 F (35 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Keep container tightly closed in a dry, well-
ventilated place. Do not store directly in the sun or in conditions exceeding 95 F (35 C). Keep away from sources of ignition or heat. Avoid storing
near incompatible materials identified in Section 10.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid dust formation. Avoid breathing dust. Wash after handling. Provide
appropriate exhaust ventilation at points of operation where dust can be generated. Avoid using compressed air. Dust may form explosive mixture
with air. Take precautionary measures against static discharges. Metal parts of mixing and processing equipment should be earthed/grounded.
Dust deposits should not be allowed to accumulate on surfaces.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: ……………………………………………………. Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields, or goggles if necessary.

SKIN PROTECTION GUIDELINES: ……………………………………………. Liquid-proof gloves (such as neoprene or nitrile) should be used to prevent
skin irritation. Barrier creams can be used effectively.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with particulate filter, such as a N95 or greater, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.

WEST SYSTEM

410 Microlight

Filler
Page 3 of 6 Last Revised: 03JAN22
ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Wash thoroughly after handling. Do not eat, drink or smoke when handling this product. Generally speaking, working cleanly and following
basic precautionary measures will greatly minimize the exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LI MITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Amorphous sodium borosilicate 50815-87-7 Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable
Thermoplastic copolymer 25214-39-5 No data available.
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available.
Isobutane 75-28-5 ACGIH TLV TWA 1000 ppm (central nervous
system)
NIOSH REL TWA 800 ppm; 1900 mg/m
3

Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 No data available.
Synthetic pyrogenic amorphous silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Powder, solid.
COLOR: ………………………………………………………………………………… Beige-tan.
ODOR: …………………………………………………………………………………… Slight.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. 10.5
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. No data available
FLASH POINT: ……………………………………………………………………….. No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. No data available
BULK DENSITY………………………………………………………………………. No data available
VAPOR DENSITY (air = 1) ……………………………………………………….. No data available
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. Largely insoluble.
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data available (mm
2
/s

@ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. Not applicable.
EXPLOSIVE PROPERTIES: ……………………………………………………… Dust may form explosive mixtures in air. Explosive properties of this mixture
have not been measured. One or more of the components of this mixture have been identified as having the potential to form an explosive mixture
with air when suspended as a dust cloud.
Kst VALUE: ……………………………………………………………………………. No data available
MAXIMUM EXPLOSION PRESSURE (Pmax) ……………………………… No data available
MINIMUM IGNITION ENERGY (MIE): …………………………………………. No data available
MAXIMUM EXPLOSION CONCENTRATION (MEC): ……………………. No data available
DUST EXPLOSION CLASSIFICATION: ……………………………………… No data available

10. STABILITY AND REACTIVITY

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself.

INCOMPATIBILITIES: ……………………………………………………………… Strong oxidizing agents and acids. Contact with hydrofluoric acid will cause
the release of a toxic gas.

CONDITIONS TO AVOID: ………………………………………………………… Avoid settling dust collection and airborne dust formation. Avoid direct heat
or excessive sunlight.

DECOMPOSITION PRODUCTS: ……………………………………………….. Carbon monoxide, carbon dioxide, hydrogen chloride, nitrogen oxides,
ammonia.

11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION

WEST SYSTEM

410 Microlight

Filler
Page 4 of 6 Last Revised: 03JAN22

Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Amorphous sodium borosilicate 50815-87-7 No data No data No data
Thermoplastic copolymer 25214-39-5 No data No data No data
Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 >2000 mg/kg No data No data
Isobutane 75-28-5 No data No data No data
Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 2169 mg/kg No data No data
Synthetic pyrogenic amorphous silica 112945-52-5 >5000 mg/kg >2000 mg/kg No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Causes skin irritation. Category 2.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Causes serious eye irritation. Category 2A.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Does not meet criteria for skin sensitization.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Does not meet criteria for reproductive toxicity.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for mutagenicity.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity. Does not contain
components > 0.1% that are listed as a carcinogen by IARC, NTP or OSHA.

Synthetic amorphous silica: No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure
to synthetic amorphous silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic
amorphous silica.

May contain trace amounts of acrylonitrile at levels <0.005% by weight. Acrylonitrile is listed by IARC as a Group 2B carcinogen, by NTP as a reasonably anticipated human carcinogen, and is specifically regulated by OSHA as a carcinogen. STOT (Single Exposure): .................................................................. Not classified. Does not meet STOT SE criteria. STOT (Repeated Exposure): ............................................................. Not classified. Does not meet STOT RE criteria. ASPIRATION HAZARD : ..................................................................... Not classified. Does not meet aspiration toxicity criteria. OTHER HEALTH HAZARD INFORMATION : ...................................... None known. 12. ECOLOGICAL INFORMATION ACUTE AQUATIC TOXICITY :............................................................. No specific test data available for the mixture. Calculated Estimate: Does not meet acute aquatic toxicity criteria. CHRONIC AQUATIC TOXICITY : ........................................................ No specific test data available for the mixture. Calculated Estimate: Does not meet chronic aquatic toxicity criteria. PERSISTANCE AND BIODEGRADABI LITY: ..................................... No specific test data available for the mixture. MOBILITY IN SOIL: ............................................................................ No specific test data available for the mixture. ADDITIONAL ECOTOXICITY INFORMATION : ................................... Prevent release to the environment, sewers and natural waters. Ingredient CAS# Ecotoxicity Classification Information Amorphous sodium borosilicate 50815-87-7 No data available. Thermoplastic copolymer 25214-39-5 No data available. Formaldehyde polymer with 1,3-dimethylbenzene 26139-75-3 No data available. Isobutane 75-28-5 No data available. Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 Acute Aquatic 3; Chronic Aquatic 3 Synthetic pyrogenic amorphous silica 112945-52-5 No data available. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: ........................................................... Evaluation of this product using RCRA criteria shows that it is not a hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal methods. WEST SYSTEM 410 Microlight Filler Page 5 of 6 Last Revised: 03JAN22 Reclaim or reuse may be preferred methods when conducted in accordance with federal, state and local regulations. 14. TRANSPORTATION INFORMATION US DOT UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. CANADA TDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. ICAO/IATA UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. MARINE POLLUTANT: ....................................................................... Not applicable. IMDG UN NUMBER: ..................................................................................... Not regulated. SHIPPING NAME: ............................................................................... Not applicable. TECHNICAL SHIPPING NAME: .......................................................... Not applicable. HAZARD CLASS: ................................................................................ Not applicable. PACKING GROUP: ............................................................................. Not applicable. EmS Number: .................................................................................... Not applicable. MARINE POLLUTANT ........................................................................ Not applicable. 15. REGULATORY INFORMATION COUNTRY INVENTORY LIST STATUS United States TSCA All ingredients are listed or otherwise compliant. Europe EINECS or ELINCS All ingredients are listed or otherwise compliant. Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant. Australia AICS All ingredients are listed or otherwise compliant. Japan ENCS Data is not available for component CAS# 50815-87-7. South Korea KECI Data is not available for component CAS# 50815-87-7. China IECSC Data is not available for component CAS# 50815-87-7. Philippines PICCS Data is not available for component CAS# 50815-87-7. New Zealand NZIoC Data is not available for component CAS# 50815-87-7. US EPA TSCA Requirements: ........................................................... No data available. Canada WHMIS Confidential Business Information (CBI): .............. No data available. US EPA SARA TITLE III Reporting and Notification Requirements: Subject to Section 302 (TPQ) ..................................................... Not regulated. Subject to Section 304 (RQ) ........................................................ Not regulated. Subject to Section 311 or 312 ..................................................... Refer to the health and physical classifications in section 2. Subject to Section 313 ................................................................ Not regulated. STATE REGULATORY INFORMATION: Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the appropriate state agency. COMPONENT NAME /CAS NUMBER STATE CODE Amorphous silica 7631-86-9 or 112945-52-5 PA, NJ, MA Isobutane 75-28-5 PA, NJ, MA Tris-2, 4, 6-(dimethylaminomethyl) phenol 90-72-2 PA, NJ Acrylonitrile WEST SYSTEM 410 Microlight Filler Page 6 of 6 Last Revised: 03JAN22 107-13-1 <0.005% PA, NJ, MA, 1 CA 1. These substances are known to the state of California to cause cancer or reproductive harm, or both. 16. OTHER INFORMATION REASON FOR ISSUE:........................................................................ Approval date change. PREPARED BY: ................................................................................. Gougeon Brothers, Inc. SDS CONTACT: ................................................................................. safety@gougeon.com TITLE: ................................................................................................ Health, Safety & Environmental Manager APPROVAL DATE: ............................................................................ January 3, 2022 SUPERSEDES DATE: ........................................................................ December 9, 2019 SDS VERSION: .................................................................................. 410-2022a OTHER HAZARD INFORMATION AND RATING SYSTEMS : HMIS RATING NFPA 704 CODES HEALTH: 1 FLAMMABILITY: 2 PHYSICAL HAZARD: 0 PERSONAL PROTECTION: Approximate HMIS and NFPA Risk Ratings Legend: 0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers, Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or reliance upon these data. 1 0 2

24COTTON_SDS.pdf

INTERNATIONAL FIBER
CORPORATION
This Safety Data Sheet was prepared to comply with Globally Harmonized System of Classification
and Labelling of Chemicals (GHS)
SAFETY DATA SHEET
1 – IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the substance or preparation:
Product Names: Cotton Flock
Product grade: W200 Cotton Flock
Company/undertaking identification: International Fiber Corporation
50 Bridge Street
North Tonawanda, New York 14120, USA
Phone : + 716-693-4040 Fax : + 716-693-3528
Email : info@ifcfiber.com
Website: http://www. ifcfiber.com
Emergency telephone: + 716-693-4040
2 – HAZARDS IDENTIFICATION
This product is not classified as hazardous or flammable. Refer to the recommendations regarding the other products
present on the site
Preparation classification: None known
3 – COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous substances present on their own:
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100%
pure state)
This product contains no hazardous substance in this category
Other substances representing a hazard: None
Substances present at a concentration below the minimum danger threshold:
No known substance in this category present.
Other substances with occupational exposure limits:
INDEX CAS EC NAME
9004-34-6 232-674-9 CELLULOSE
4-FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing in an unconscious person.
In the event of exposure by inhalation:
In the event of inhalation, move patient to the open air. Keep warm and at rest. Medical attention may be required if per-
sistent irritation occurs.
In the event of contact with eyes:
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
Refer the patient to an ophthalmologist, in particular if there is any redness, pain or visual impairment

24COTTONA_SDS.pdf

GRS Fibers for Life.

Safety Data Sheet

19798 8 2/16/2023 10:25:45
AM

Section 1- Identification- White Cotton Flock

Description: Cotton Flock (White)

Applicable to: White Cotton Flock, W200 White Cotton Flock, W200Z White Cotton Flock,

W200SW White Cotton Flock, W230 White Cotton Flock, W245B White
Cotton Flock, W260 White Cotton Flock, 50 CWC Chopped White Cotton

Supplier: J. Rettenmaier USA Schoolcraft, MI 49087

Phone: 269-679-2340

Recommended Use: Professional use as an Industrial ingredient

Restrictions on Use: None

Section 2- Hazard(s) Identification

GHS Pictogram: N/A

Warning: May form combustible dust concentrations in air.

HMIS Rating: Health- 0; Reactivity- 0; Flammability- 1; Personal Protection- E

NFPA Rating: Health- 0: Flammability- 1; Reactivity- 0; Special- None

The material does not require registration in accordance with REACH, Annex IV and V.

Section 3- Composition/Information on Ingredients

Cotton is a naturally occurring fibrous plant

CAS Number: Does Not Apply

EC- Number (EINECS/ELINCS): Does Not Apply

Dangerous Ingredients: None

Section 4- First Aid Measures

General: When symptoms persist or if in doubt, seek
immediate professional medical advice.

Chronic exposure may lead to dermatitis or
respiratory sensitization.

Following Inhalation: May irritate respiratory system. Persons with
respiratory problems should avoid breathing dust. Use
NIOSH approved respiratory mask for nuisance dust.
For overexposure- remove to fresh air

Skin contact: For broken or sensitive skin wear protective gloves.
Wash dust from skin with soap and water.

Eye Contact: May irritate eyes. Wear protective glasses or goggles.
Carefully and thoroughly flush from eyes with eye bath
or water.

Ingestion: First aid measures normally not required for incidental

Disclaimer: To the best of our knowledge, the information contained herein is accurate and reliable as of the date of publication.

However, we do not assume any liability whatsoever for the accuracy and completeness of the above information.

J. RETTENMAIER USA LP 16369 US Highway 131 Phone: +1 269679 2340 www.jrsusa.com

Schoolcraft, Michigan 49087 (USA) _info@jrsusa.com

24CALSULPH_SDS.pdf

Safety Data Sheet
PMC Revision date:
January 1, 2023
1
1. IDENTIFICATION
Product Name: PMC
Synonyms: Gypsum, Calcium Sulfate Dihydrate ( CaSO
4 2H2O) SP, SPT, CWS, LP#2 Manufacturer: Performance Minerals Corp
10220 Wicker Ave Ste 4
Saint John, IN 46373
www.performancemineralscorp.com
Telephone Number: 1-800-847-3637
2.HAZARD IDENTIFICATION
Warning
May cause respiratory irritation
Prolonged inhalation of airborne dust can produce scar tissue in the lungs. The condition may not be
reversible.
Handling and Storage: Use general room or local exhaust ventilation. Wear MSHA/NIOSH approved dust
mask where dust levels exceed the threshold limit value (TLV) while handling the product. This product
is for manufacturing purposes only.
Potential Health Effects:
Inhalation (acute): Exposure to dust generated during the handling or use of the product may
cause temporary irritation to eyes, skin, nose, throat, and upper respiratory
tract. Persons subjected to large amounts of this dust will be forced to leave
area because of nuisance conditions such as coughing, sneezing, and nasal
irritation. Labored breathing may occur after excessive inhalation. If
respiratory symptoms persist, consult a physician.

Safety Data Sheet

PMC Revision date:
January 1, 2020

2

Inhalation (chronic): Exposures to respirable crystalline silica are not expected during the normal
use of this product. Prolonged and repeated exposure to airborne free
respirable crystalline silica can result in lung disease (i.e., silicosis) and/or
lung cancer. The development of silicosis may increase the risks of additional
health effects. The risk of developing silicosis is dependent upon the
exposure intensity and duration.

Eye Contact: Dust can cause temporary mechanical irritation of eyes. If burning, redness,
itching, pain or other symptoms persist or develop, consult a physician.

Skin Contact: None known

Ingestion: None known

3. COMPOSITION
Chemical Name % by weight CAS#
Gypsum >95 13397-24-5
Crystalline Silica .01-1 14808-60-7

4. FIRST AID MEASURES
Inhalation: Remove to fresh air. Leave the area of exposure and remain away until coughing
and other symptoms subside. Other measures are usually not necessary,
however if conditions warrant, contact a physician.

Eyes: In case of contact, do not rub or scratch eyes. To prevent mechanical irritation,
flush thoroughly with water for 15 minutes. If irritation persists, consult a
physician.

Skin: Wash with mild soap and water. If irritation persists, consult a physician.

Ingestion: This product is not intended to be ingested or eaten. If gastric disturbance
occurs, contact a physician.

Most Important Symptoms: Eye and respiratory irritation due to exposure to dust.

Immediate Medical Attention
/Special Treatment: No immediate medical attention anticipated. Treatment should
be directed at the control of symptoms and the clinical condition.

5. FIRE FIGHTING MEASURES
Extinguishing Media: Water or use extinguishing media appropriate for surrounding fire.

Specific Hazards: None known

Safety Data Sheet

PMC Revision date:
January 1, 2020

3

Protective equipment/
Precautions: Wear appropriate personal protective equipment. See Section 8

6. ACCIDENTAL RELEASE MEASURES
Containment: No special precautions. Wear appropriate personal protective equipment. See
Section 8

Clean- up: Use normal clean up procedures. No special precautions.

Disposal: Follow all local, state, provincial and federal regulations. Prevent discharge of
large releases directly into sewers or surface waters.

7. HANDLING AND STORAGE
Safe Handling: Avoid dust contact with eyes and skin. Wear the appropriate eye and skin protection against dust (See section 8). Minimize dust generation and accumulation. Avoid breathing dust.

Safe Storage: Store in a cool, dry, ventilated area away from sources of heat, moisture and
incompatibilities (See section 10).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
WT% TLV (mg/m3) PEL (mg/m3)
Gypsum >95 10 15(T)/5(R)
Crystalline Silica .01-1 0.025(R) 0.1(R)
(T) Total (R) Respirable

Engineering Controls: Provide ventilation sufficient to control airborne dust levels. If user
operations generate airborne dust, use ventilation to keep dust
concentrations below permissible exposure limits. Where general
ventilation is inadequate, use process enclosures, local exhaust ventilation,
or other engineering controls to control dust levels below permissible
exposure limits.

Personal Protective Equipment:

Specific Respiratory
Protection: Wear a NIOSH/MSHA approved respirator equipped with particulate
cartridges when dusty in poorly ventilated areas, and if TLV is exceeded.
A respiratory program that meets OSHA s 29 CFR 1910-134 and ANSI
Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator s use. If engineering controls are not possible, wear
a properly fitted NIOSH/MSHA-approved particulate respirator.

Safety Data Sheet

PMC Revision date:
January 1, 2020

4

Specific Eye/Face
Protection: Wear eye protection, safety glasses or goggles, to avoid possible eye
contact.
Specific Skin
Protection: Wear gloves and protective clothing to prevent repeated or prolonged
skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White to off-white

Odor: Low to no odor

Odor Threshold: Not determined

pH at 25 C: 7

Melting Point: Not applicable

Freezing Point: Not applicable

Boiling Point: Not applicable

Flash Point: Not determined

Upper/ lower flammability limits: Not determined

Vapor Pressure/density: Not applicable

Specific Gravity: 2.32 (Gypsum)

Solubility in water: 0.2 g/100g (Gypsum)

Partition coefficient: Not determined

Auto-ignition temp: Not determined

Decomposition temp: 2642 F/1450 C

Viscosity: Not applicable

Particle Size: Varies

Bulk Density: 45-150 lb/ft
3
/ 0.7-2.5 kg/m
3

Molecular Weight: 172 g/mole

Safety Data Sheet

PMC Revision date:
January 1, 2020

5

VOC Content: Zero g/l

Percent Volatile: Zero

10. STABILITY AND REACTIVITY
Chemical Stability: Stable
Conditions to Avoid: Contact with incompatibles (see below)

Incompatibility: None known

Hazardous
Polymerization: None Known

11. TOXICOLOGICAL INFORMATION
Likely routes of exposure & symptoms:

Eyes: Exposure to dust may cause irritation

Skin: Exposure to dust may cause dryness and irritation

Ingestion: No adverse effects expected for normal, incidental ingestion

Inhalation: Exposure to dust may cause irritation in nose, throat and lungs

Chronic Health Effects: This product contains trace a mounts of crystalline silica. Prolonged or
repeated inhalation of respirable crystalline silica can cause silicosis, as
serious lung disease.
Respiratory or Skin
Sensitization: This material is not known to cause sensitization

Carcinogenicity: This product is not listed as carcinogenic by OSHA, IARC, NTP, ACGIH, or the EU
Directives. This product may contain trace amounts of crystalline silica quartz
which is listed by IARC as Carcinogenic to Humans (Group 1) and Known to
be a Human Carcinogen by NTP.

Reproductive Toxicity: No data available

12. ECOLOGICAL INFORMATION
This product has no known affect on ecology. Toxicity studies of gypsum performed with fish, aquatic
invertebrates and aquatic plants showed no toxic effects.
13. DISPOSAL CONSIDERATIONS
Dispose of material in accordance with federal, state and local regulations. Prevent discharge directly
into sewers or surface waters. Consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Safety Data Sheet

PMC Revision date:
January 1, 2020

6

14. TRANSPORT INFORMATION
This product is not classified as a hazardous material under US DOT or Canadian TDG regulations.

15. REGULATORY INFORMATION
CERCLA Hazardous Substance: Not listed

SARA Toxic Chemical (40 CFR 355): Not listed

SARA Section302 Extremely Hazardous Substance ( 40 CFR 355): Not listed

SARA 311/312: Not listed

SARA Section 313 Toxic Chemical Reporting Requirements: None

Threshold Planning Quantity (TPQ): Not listed

RCRA Hazardous Waste Classification (40 CFR 261): Not classified

EPA Toxic Substances Control Act (TSCA) Status: All components of this product are
listed on the TSCA

California Proposition 65: Airborne crystalline silica particulates of respirable size
are known to the State of California to cause cancer

NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0

HMIS Ratings: Health: 1 Fire: 0 Reactivity: 0 Personal Protection: A

OSHA Specifically Regulated Substance (29 CFR 1910): Not listed

OSHA Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Listed

MSHA: Not listed

Canada DSL: Listed

Canadian WHMIS Classification: D2A, Materials causing other toxic effects

Canada CPR: This product has been classified in accordance with the hazard criteria of the CPR
of Canada and this SDS contains all the required information.

Ontario Regulations: Refer to Regulation 845: Designated Substances – Silica

Safety Data Sheet

PMC Revision date:
January 1, 2020

7

16. OTHER INFORMATION
List of GHS H316: Causes mild skin irritation
Hazard H320: Causes eye irritation
Statements: H350: May cause cancer by inhalation
H372: Causes damage to lungs through prolonged or repeated exposure by
inhalation

List of GHS P201: Obtain special instructions before use
Precautionary P202: Do not handle until all safety precautions have been read and understood
Statements: P260: Do not breathe dust
P264: Wash hands thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P281: Use personal protective equipment as required

Abbreviations

ANSI American National Standards Institute
ACGIH American Conference of Governmental Industrial Hygienists
CAA Clean Air Act
CAS Chemical Abstracts Service (Registry Number)
CERCLA Comprehensive Environmental Response, Compensation and Liability Act
CFR Code of Federal Regulations
DOT United States Department of Transportation
DSL Canadian Domestic Substances List
EPA United States Environmental Protections Agency
EPCRA Emergency Planning & Community Right-to-know Act
HMIS Hazardous Materials Identification System
IARC International Agency of Research of Cancer
MSHA Mine Safety and Health Administration
NDSL Canadian Non-Domestic Substances List
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
OSHA Occupational Health and Safety Administration
PEL Permissible Exposure Limit
PPE Personal Protection Equipment
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorizations Act of 1986
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
UN/NA# United Nations/North America number
WHMIS Workplace Hazardous Material Information Sheet
The information contained in this document applies to this specific material as supplied. It may not be
valid for this material if it is used in combination with any other materials. It is the user s responsibility
to satisfy oneself as to the suitability and completeness of this information for his/her own particular
use.

Safety Data Sheet

PMC Revision date:
January 1, 2020

8

24BJO0930Q_SDS.pdf

Page 1 of 5

SAFETY DATA SHEET

Document ID : SDSCLP-03 Issue Date : 03 April 20 15
Revision : 4 Supersedes date : 26 March 2015

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMP ANY

1.1

Identification of product
Product Name
Trade Name
Chemical name
Manufacturer product ID

: Phenolic microspheres
: PHENOSET microspheres
: Phenol formaldehyde polymer, cured
: BJO-0930, BJO-0840, EPO-0360, SPO-0620

1.2

Use of product
Functional filler for composites

1.3

Company Identification
MALAYAN ADHESIVES & CHEMICALS SDN. BHD.
No. 9, Jalan Utas 15/7, 40200 Shah Alam,
Selangor Darul Ehsan, MALAYSIA

Importer/Distributor:

Tel: +603-5566 1188
Fax:+603-5566 1122
1.4 Emergency telephone
+603-5566 1188

2. HAZARDS IDENTIFICATION
Not classified as hazardous for use/supply

Dust may cause irritation, experienced as stinging with excessive blinking and tear production.
Material may contain trace amount (<0.2%) of free formaldehyde, which is listed by IARC, NTP and OSHA as a carcinogen. There should be minimal risk when adequate ventilation is used due to the very low formaldehyde concentration. Page 2 of 5 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS no. EC no. Weight % Risk phrases Hazard Statements Fully polymerized phenolic resin, inert NA NA >99.8 None None
Formaldehyde* 50-00-0 200-001-8 <0.2 R45, R68, R23/24/25, R34, R43 H350, H341, H331, H311, H301, H314, H317 Note*: Material is not considered hazardous in the classification of product as its concentration is below concentration cut-off point Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under REACH article 7(1). 4. FIRST AID MEASURES Skin contact: Remove contaminated clothing. Wash skin with soap and water. Obtain medical attention if irritation persists. Wash clothing before reuse. Eye contact: Immediately flush eyes with water and continue for several minutes. Obtain medical attention if discomfort persists. Inhalation: If signs and symptoms develop, remove person to fresh air. If signs or symptoms persist, obtain medical attention. Ingestion: Do not induce vomiting unless instructed to do so by medical personnel. Unless unconscious, give victim lots of water. Obtain medical attention. Notes to physician: There is no specific antidote. Treatment or overexposure should be directed at the control of the symptoms and the clinical condition of the patient 5. FIRE-FIGHTING MEASURES Suitable Extinguishing media: Apply alcohol type or all-purpose type foams by manufacturers recommended techniques for large fires. Use carbon monoxide or dry chemical media for small fires. Do not direct a solid stream of water or foam into burning molten material; this may cause spattering and spread of fire. Extinguishing media to be avoided: None Unusual fire and explosion hazards: Avoid dispersion of dust in air to reduce potential of dust ignition / explosion. Special protective equipment for fire fighters: Use self-contained breathing apparatus and protective coating. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Wear suitable protective clothing. Methods for cleaning up: Ventilate with fresh air. Collect as much of the spilled material as possible. Use wet sweeping or water to avoid dusting. Collect and place in a closed container. Dispose as approved by your State Regulations. Page 3 of 5 7. HANDLING AND STORAGE 7.1 Handling General precaution: For industrial and professional use only. Avoid dispersion of dust in air. Electrically bond and ground equipment. Avoid sparks and flame under dust conditions. Use with adequate ventilation. Ventilation: Special, local ventilation is recommended in areas where containers are opened and their containers are discharged or in any areas where dusting conditions may occur. Other precaution {Caution] May undergo spontaneous smouldering if stored or heated in bulk above 35 o C under conditions allowing air ingress to the product. Store package material in a cool, well-ventilated area. Do not store in the sun. Do not dry in package use special drying instructions as below. Microspheres will undergo oxidation at elevated temperatures. Due to the microspheres excellent insulating characteristics, the internal temperature of the mass can increase to the point where spontaneous ignition and smouldering can occur. The temperature at which this occurs is a function of the geometry, amount of material being heated and available oxygen. Smouldering appears as a soft glow similar to burning charcoal. Drying instructions for the Phenoset microspheres: To reduce the moisture content of this product to less than 4%, dry a two-inch layer of the product at a maximum temperature of 75 o C for 24 hours. To prevent oven or product contamination, the metal drying tray should be covered with a cloth that will allow the product moisture to evaporate. 7.2 Storage Keep container closed. 7.3 Specific use (s) For industrial and professional use only. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Exposure limit values . No exposure limit has been established. 8.2 8.2.1 Exposure controls Occupational exposure controls Respiratory protection: Hand protection : Eye protection : Other protective equipment: Dust respirator, if dusting occurs General working gloves are acceptable. Safety glasses Eye bath and safety shower. Adequate ventilation . 8.2.2 Environmental exposure controls None established. Page 4 of 5 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red brown, fine powder Odour: Odourless Molecular weight: >10,000, Fully cured C-stage
Relative density: 0.20 0.80
Self-ignition temperature: 500
o
C (ASTM D1929)
Boiling point: Does not boil
Melting point: Does not melt
Solubility: Not soluble in water

10. STABILITY AND REACTIVITY
General : Stable
Conditions to avoid: None known
Materials to avoid: Strong acids and base, halogens , acyl halides
Hazardous decomposition products: Carbon monoxide, car bon dioxide, formaldehyde and phenol
derivatives upon decomposition.
Hazardous polymerisation: Will not occur.
11. TOXICOLOGICAL INFORMATION

Effects from inhalation:
Upper respiratory tract irritation signs/symptoms may include sneezing, cough, and nasal discharge.

Effects from ingestion:
Gastrointestinal irritation.

Effects from skin contact:
Mechanical skin irritation. May result in itching.

Effects from eye contact:
Mechanical eye irritation. Signs and symptoms may include pain, redness and tears.

Significant data with possible relevance to human health
Formaldehyde has been shown to cause cancer in laboratory animals and mutations in a variety of in-vitro
test systems. The relevance of these findings for human is unknown. Formaldehyde is listed as a
carcinogen by IARC, NTP and OSHA.

12. ECOLOGICAL INFORMATION
Ecotoxicity: None known.
Mobility: Does not dissolve in water.
Persistence and degradability: Not determined.
Bioaccumulative potential: Unknown.

13. DISPOSAL CONSIDERATIONS

Dispose off in accordance with appropriate National and local regulations.

Page 5 of 5
14. TRANSPORT INFORMATION
UN Number, ADR/RID:
IMDG/ICAO:
MONT-BLANC:
Not restricted for transportation.
Not restricted for transportation.
Not restricted for transportation.
15. REGULATORY INFORMATION
Label Elements [Regulations (EC) No. 1272/2008]
None Not classified as hazardous
Inventory Listed In:
China IECSC, EU EINECS, US TSCA, Canada DSL, Japan ENCS, Korea KECL, Taiwan NECI,
Philippine PICCS, Australia AICS, New Zealand NZIoC
16. OTHER INFORMATION
Text of R phrases referred to under headings 3
R45 May cause cancer
R68 Possible risk of irreversible effects
R23/24/25 Toxic by inhalation, in contact and if s wallowed
R34 Causes burns
R43 May cause sensitization by skin contact
H317 May cause an allergic skin reaction

Text of H phrases referred to under headings 3
H350 May cause cancer
H341 Suspected of causing genetic defects
H331 Toxic if inhaled
H311 Toxic in contact with skin
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction

Product category:
Phenoset microspheres is an article fulfilling the exemption of substance registration requirements under
REACH article 7(1).

Text on Label:
CAUTION! May undergo spontaneous smouldering if stored or heated in bulk above 35C under conditions
allowing air ingress to the product.
Store in cool, well-ventilated area.
Do not store in the sun
Do not dry in package refer special drying instructions.
FOR INDUSTRIAL USE ONLY

Recommended usage and restrictions:
Please consult the product and/or applications information bulletins for this product.

Disclaimer
The information contains herein is correct to the best of our knowledge. We disclaim any liability as to the
recommendations or completeness of the information. The final evaluation on the fitness of use lies on the
user digression. All material has hidden hazards and should be used with extreme care. Even though
various hazards had been listed herein, we do not warranty that those are the only existing hazards.

Revision Date: 03 April 2015
Revision Summary: Section 3 classification of formaldehyde.
Section 16 Text of R- and H-phrases

2440610_SDS.pdf

SAFETY DATA SHEET
03JAN22

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: ……………………………………… WEST SYSTEM

406 Colloidal Silica
APPLICABLE PRODUCT CODE S: ………………. 406, 406-2, 406-7, 406-B.
CHEMICAL FAMILY: ………………………………….. Synthetic amorphous pyrogenic silica.
INTENDED PRODUCT USES: ……………………… Thickening agent for liquid epoxy resins.
PRODUCT RESTRICTIONS: ……………………….. None identified.
SDS VERSION: …………………………………………. 406-2022a

MANUFACTURER: EMERGENCY TELEPHONE NUMBERS (24 HRS):
Gougeon Brothers, Inc. Transportation
100 Patterson Ave. CHEMTREC: ……………….. 800-424-9300 (U.S.)
Bay City, MI 48706, U.S.A. 703-527-3887 (International)
Phone: 866-937-8797 or 989-684-7286 Non-transportation
www.westsystem.com Poison Hotline: …………….. 800-222-1222

2. HAZARDS IDENTIFICATION

Classification of Substance or Mixture

None

Label Elements

Hazard Pictogram(s):
None

Signal Word:
None

Hazard Statements:
None

Precautionary Statements:
None

Other Hazards
Handling and conveyance of material may create static electrical charge. Earth/ground handling and processing equipment to prevent
against static discharge.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS

INGREDIENT NAME CAS # CONCENTRATION (%)
Synthetic amorphous pyrogenic silica 112945-52-5 80-100

The exact chemical identity and/or exact percentage (concentration) of each ingredient may be held as confidential business information
(CBI). Any ingredient not disclosed in this section may have been determined not to be hazardous to health or the environment, or it may
be present at a level below its disclosure threshold.

4. FIRST AID MEASURES

FIRST AID FOR EYES ……………………………………………………………… SYMPTOMS: Excessive exposure may cause irritation and tearing.
RESPONSE: Flush with water for at least 15 minutes. Remove contact lenses if present and easy to do. Consult a physician as a precautionary
measure if symptoms develop and persist.

FIRST AID FOR SKIN ………………………………………………………………. SYMPTOMS: May cause skin dryness or slight irritation. RESPONSE:
Wash with mild soap and water. Consult a physician if effects occur and persist.

FIRST AID FOR INHALATION…………………………………………………… SYMPTOMS: Excessive exposure may cause coughing, respiratory
irritation or shortness of breath due to temporary lung overload. RESPONSE: Remove to fresh air if symptoms develop and keep comfortable for
breathing. Seek medical advice is symptoms persist.

FIRST AID FOR INGESTION …………………………………………………….. SYMPTOMS: No acute adverse health effects expected from amounts
ingested under normal conditions of use. RESPONSE: Seek medical attention if a significant amount is ingested.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: ………………………………………………………… SUITABLE: Foam, carbon dioxide (CO2), water, or dry chemical. Fog or
mist is recommended if water is used. NON-SUITABLE: Avoid using high pressure media.

WEST SYSTEM

406 Colloidal Silica
Page 2 of 5 Last Revised: 03JAN22

FIRE AND EXPLOSION HAZARDS: ………………………………………….. This product will not support combustion. Will not form combustible dust
concentrations in the air.
SPECIAL FIRE FIGHTING PROCEDURES: ………………………………… Wear a self-contained breathing apparatus and complete full-body personal
protective equipment.

6. ACCIDENTAL RELEASE MEASURES

EMERGENCY PROCEDURES : …………………………………………………. Keep unnecessary and unprotected personnel from entering area. Use
appropriate safety and personal protective equipment as indicated in Section 8.

MITIGATION AND CLEAN UP PROCEDURES: …………………………… Use methods that avoid generating airborne dust. Use a vacuum with high
efficiency particulate air (HEPA) filtration is recommended. Avoid creating a dust cloud by brushing or sweeping, or using compressed air.

ENVIRONMENTAL PRECAUTIONS: ………………………………………….. Contain spilled product to the extent practical and feasible.

7. HANDLING AND STORAGE

STORAGE TEMPERATURE (min./max.): …………………………………… 0 F (-17 C) / 100 F (38 C)

STORAGE: …………………………………………………………………………….. Store in cool, dry place. Store in sealed containers to prevent moisture
absorption or absorption of other volatile materials.

HANDLING PRECAUTIONS: ……………………………………………………. Avoid dust formation. Avoid breathing dust. Wash after handling. Provide
appropriate exhaust ventilation at points of operation where dust can be generated. Avoid using compressed air. Take precautionary measures
against static discharges. Metal parts of mixing and processing equipment should be earthed/grounded.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

ENGINEERING CONTROLS: . Use with adequate general ventilation and/or local ventilation to keep
exposures below established limits.

EYE PROTECTION GUIDELINES: …………………………………………….. Safety glasses with side shields, or goggles if necessary.

SKIN PROTECTION GUIDELINES: ……………………………………………. Gloves or a barrier cream may be useful to help prevent skin from drying.

RESPIRATORY PROTECTION GUIDELINES: …………………………….. When ventilation cannot be made adequate enough to keep exposures
below established limits, use a NIOSH approved respirator with particulate filter, such as a N95 or greater, depending on specific workplace
conditions. Consult with your respirator and cartridge supplier to ensure proper selection of respirator and cartridge based on ingredients listed in
Section 3 and specific workplace conditions. Use and select a respirator according the guidelines established in OSHA 1910.134 or other
applicable respiratory protection standard.

ADDITIONAL PROTECTIVE MEASURES: ………………………………….. Practice good caution and personal cleanliness to avoid skin and eye
contact. Wash thoroughly after handling. Generally speaking, working cleanly and following basic precautionary measures will greatly minimize the
exposure to this product under normal use conditions.

OCCUPATIONAL EXPOSURE LIMITS: ……………………………………… Exposure limits may not be established for this product as a whole. For
established exposure limits of specific ingredients in this product, or other available exposure limit information, refer to the table below.

Ingredient Name CAS# Exposure Limit Information
Synthetic amorphous pyrogenic silica 112945-52-5 Amorphous silica: OSHA PEL 6 mg/m
3

Dust and PNOS: ACGIH 10mg/m
3
, TWA,
Inhalable; 3 mg/m
3
, TWA, Respirable; OSHA
PEL 15 mg/m
3
, TWA, total dust; 5 mg/m
3
, TWA,
Respirable

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL FORM: ………………………………………………………………….. Powder, solid.
COLOR: ………………………………………………………………………………… White.
ODOR: …………………………………………………………………………………… None.
ODOR THRESHOLD: ………………………………………………………………. No data available
pH …………………………………………………………………………………………. No data available
MELTING POINT / FREEZING POINT ………………………………………… No data available
BOILING POINT (760mm/Hg): ………………………………………………….. No data available
FLASH POINT: ……………………………………………………………………….. No data available
AUTO IGNITION TEMPERATURE ……………………………………………… No data available
LOWER EXPLOSIVE LIMIT (LEL) ……………………………………………… No data available
UPPER EXPLOSIVE LIMIT (UEL) ……………………………………………… No data available
VAPOR PRESSURE ………………………………………………………………… No data available
SPECIFIC GRAVITY/DENSITY (water = 1)………………………………….. 2.2
BULK DENSITY………………………………………………………………………. No data available

WEST SYSTEM

406 Colloidal Silica
Page 3 of 5 Last Revised: 03JAN22
VAPOR DENSITY (air = 1) ……………………………………………………….. No data available
EVAPORATIOIN RATE (Butyl Acetate = 1) ………………………………… No data available
WATER SOLUBILITY (% BY WT.) …………………………………………….. Only slightly soluble
PARTITION COEFFICIENT, n-OCTANOL/WATER (log Pow) ………… No data available
KINEMATIC VISCOSITY: …………………………………………………………. No data (mm
2
/s

@ 20

C)
DECOMPOSITION TEMPERATURE : …………………………………………. No data available.
% VOLATILE BY WEIGHT: ………………………………………………………. Not applicable.
EXPLOSIVE PROPERTIES: ……………………………………………………… Not applicable. This product will not support combustion.
Kst VALUE: ……………………………………………………………………………. No data available
MAXIMUM EXPLOSION PRESSURE (Pmax) ……………………………… No data available
MINIMUM IGNITION ENERGY (MIE): …………………………………………. No data available
MAXIMUM EXPLOSION CONCENTRATION (MEC): ……………………. No data available
DUST EXPLOSION CLASSIFICATION: ……………………………………… No data available

10. STABILITY AND REACTIVITY

STABILITY: ……………………………………………………………………………. Product is stable at normal temperatures and pressures.

REACTIVITY/HAZARDOUS REACTIONS: ………………………………….. Product will not react by itself.

INCOMPATIBILITIES: ……………………………………………………………… None known.

CONDITIONS TO AVOID: ………………………………………………………… Avoid excessive airborne dust formation.

DECOMPOSITION PRODUCTS: ……………………………………………….. None known.

11. TOXICOLOGICAL AND HAZARD ENDPOINT INFORMATION

Component Name CAS# LD50 Oral LD50 Dermal LC50 Inhalation
Synthetic amorphous pyrogenic silica 112945-52-5 >5000 mg/kg
OECD 401
>2000 mg/kg
OECD 402
No data

ACUTE TOXICITY: ………………………………………………………………….. No specific toxicity data exists for this mixture. Classification is
based on acute toxicity estimation methods using ingredient data.
Oral: ……………………………………………………………………….. Not classified. Does not meet acute oral toxicity criteria.
Dermal: …………………………………………………………………… Not classified. Does not meet acute dermal toxicity criteria.
Inhalation:………………………………………………………………… Not classified. Does not meet acute inhalation toxicity criteria.

SKIN CORROSION / IRRITATION: …………………………………………….. Not classified. Does not meet criteria for skin corrosion/irritation.

SERIOUS EYE DAMAGE / IRRITATION :…………………………………….. Not classified. Does not meet criteria for skin eye
damage/irritation, OECD 405. High dust concentrations may cause mechanical irritation.

RESPIRATORY SENSITIZATION : ……………………………………………… Not classified. Does not meet criteria for respiratory sensitizer.

SKIN SENSITIZATION:…………………………………………………………….. Not classified. Does not meet criteria for skin sensitization.

REPRODUCTIVE TOXICITY : …………………………………………………….. Not classified. Does not meet criteria for reproductive toxicity.

MUTAGENICITY: …………………………………………………………………….. Not classified. Does not meet criteria for mutagenicity.

CARCINOGENICITY: ……………………………………………………………….. Not classified. Does not meet criteria for carcinogenicity.

No evidence of carcinogenicity was observed in multiple animal species following repeated oral or inhalation exposure to synthetic amorphous
silica. Similarly, epidemiology studies show no evidence of carcinogenicity in workers who manufacture synthetic amorphous silica.

STOT (Single Exposure): ………………………………………………………… Not classified. Does not meet STOT SE criteria.

STOT (Repeated Exposure): ……………………………………………………. Not classified. Does not meet STOT RE criteria.

Repeated dose toxicity: oral (rat), 13 weeks, LOEL = 1.3 mg/m
3
based on mild reversible effects in the lungs. Repeated dose toxicity: inhalation
(rat), 90 days, LOEL = 1 mg/m3 based on reversible effects in the lungs and effects in the nasal cavity.

ASPIRATION HAZARD : …………………………………………………………… Not classified. Does not meet aspiration toxicity criteria.

OTHER HEALTH HAZARD INFORMATION : ……………………………….. While product does not meet the classification of a respiratory
irritant, excessive inhalation exposure can irritate the respiratory tract. Temporary lung overload can cause coughing and shortness of
breath.

12. ECOLOGICAL INFORMATION

ACUTE AQUATIC TOXICITY :……………………………………………………. Not classified. Does not meet acute aquatic toxicity criteria.

WEST SYSTEM

406 Colloidal Silica
Page 4 of 5 Last Revised: 03JAN22
Fish (brachydanio rerio) LC50 96h = >10,000 mg/L (OECD 203). No acute toxicity to daphnia with EL and EL50 ranging from >1000
10,000 mg/L (OECD 202).

CHRONIC AQUATIC TOXICITY : ……………………………………………….. No specific test data available.

PERSISTANCE AND BIOD EGRADABILITY: ………………………………. Not applicable to inorganic substances.

MOBILITY IN SOIL: …………………………………………………………………. No specific test data available for the mixture.

ADDITIONAL ECOTOXICITY INFORMATION : …………………………….. Prevent release to the environment, sewers and natural waters.

Ingredient CAS# Ecotoxicity Classification
Information
Synthetic amorphous pyrogenic silica 112945-52-5 Not classified.

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: ………………………………………………….. Evaluation of this product using RCRA criteria shows that it is not a
hazardous waste, either by listing or characteristics, in its purchased form. It is the responsibility of the user to determine proper disposal
methods.

Recycle (fuel blending) or reclaim may be preferred methods when conducted in accordance with federal, state and local regulations.

14. TRANSPORTATION INFORMATION

US DOT
UN NUMBER: …………………………………………………………………………. Not regulated.
SHIPPING NAME: ……………………………………………………………………. Not applicable.
TECHNICAL SHIPPING NAME: …………………………………………………. Not applicable.
HAZARD CLASS: …………………………………………………………………….. Not applicable.
PACKING GROUP: ………………………………………………………………….. Not applicable.

CANADA TDG
UN NUMBER: …………………………………………………………………………. Not regulated.
SHIPPING NAME: ……………………………………………………………………. Not applicable.
TECHNICAL SHIPPING NAME: …………………………………………………. Not applicable.
HAZARD CLASS: …………………………………………………………………….. Not applicable.
PACKING GROUP: ………………………………………………………………….. Not applicable.

ICAO/IATA
UN NUMBER: …………………………………………………………………………. Not regulated.
SHIPPING NAME: ……………………………………………………………………. Not applicable.
TECHNICAL SHIPPING NAME: …………………………………………………. Not applicable.
HAZARD CLASS: …………………………………………………………………….. Not applicable.
PACKING GROUP: ………………………………………………………………….. Not applicable.
MARINE POLLUTANT: …………………………………………………………….. Not applicable.

IMDG
UN NUMBER: …………………………………………………………………………. Not regulated.
SHIPPING NAME: ……………………………………………………………………. Not applicable.
TECHNICAL SHIPPING NAME: …………………………………………………. Not applicable.
HAZARD CLASS: …………………………………………………………………….. Not applicable.
PACKING GROUP: ………………………………………………………………….. Not applicable.
EmS Number: ………………………………………………………………………… Not applicable.
MARINE POLLUTANT ……………………………………………………………… Not applicable.

15. REGULATORY INFORMATION

COUNTRY INVENTORY LIST STATUS
United States TSCA All ingredients are listed or otherwise compliant.
Europe EINECS or ELINCS All ingredients are listed or otherwise compliant.
Canada CEPA (DSL/NDSL) All ingredients are listed or otherwise compliant.
Australia AICS All ingredients are listed or otherwise compliant.
Japan ENCS All ingredients are listed or otherwise compliant.
South Korea KECI All ingredients are listed or otherwise compliant.
China IECSC All ingredients are listed or otherwise compliant.
Philippines PICCS All ingredients are listed or otherwise compliant.
New Zealand NZIoC All ingredients are listed or otherwise compliant.

US EPA TSCA Requirements: ………………………………………………….. No data available.

Canada WHMIS Confidential Business Information (CBI): ………….. No data available.

WEST SYSTEM

406 Colloidal Silica
Page 5 of 5 Last Revised: 03JAN22

US EPA SARA TITLE III Reporting and Notification Requirements:
Subject to Section 302 (TPQ) …………………………………………….. Not regulated.
Subject to Section 304 (RQ) ……………………………………………….. Not regulated.
Subject to Section 311 or 312 …………………………………………….. Not regulated.
Subject to Section 313 ………………………………………………………. Not regulated.

STATE REGULATORY INFORMATION:
Chemicals listed below may be specifically regulated by individual states. For details on state regulatory requirements you should contact the
appropriate state agency.

COMPONENT NAM E
/CAS NUMBER STATE CODE
Amorphous silica
7631-86-9 or 112945-52-5 PA, NJ, MA

16. OTHER INFORMATION

REASON FOR ISSUE:……………………………………………………………… Approval date change.
PREPARED BY: ……………………………………………………………………… Gougeon Brothers, Inc.
SDS CONTACT: ……………………………………………………………………… safety@gougeon.com
TITLE: …………………………………………………………………………………… Health, Safety & Environmental Manager
APPROVAL DATE: …………………………………………………………………. January 3, 2022
SUPERSEDES DATE: ……………………………………………………………… January 15, 2019
SDS VERSION: ………………………………………………………………………. 406-2022a

OTHER HAZARD INFORMATION AND RATING SYSTEMS :

HMIS RATING NFPA 704 CODES

HEALTH: 0
FLAMMABILITY: 1
PHYSICAL HAZARD: 0
PERSONAL PROTECTION:

Approximate HMIS and NFPA Risk Ratings Legend:
0 = Low or None; 1 = Slight; 2 = Moderate; 3 = Serious; 4 = Severe

Information in this document is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Gougeon Brothers,
Inc. The data on this sheet is related only to the specific material designated herein. Gougeon Brothers, Inc. assumes no legal responsibility for use or
reliance upon these data.
0 0
1

243MK-15_SDS.pdf

INDEX

243MK
243MK-1
243MK-15
243MK1H-G

3M Glass Bubbles, Types K and S 07/20/15
__________________________________________________________________________________________
Page 1 of 9
Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit there on.
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
SECTION 1: Identification
1.1. Product identifier
3M Glass Bubbles, Types K and S
Product Identification Numbers
70-0701-1952-7, 70-0701-8213-7, 70-0701-9409-0, 70-0701-9423-1, 70-0703-2625-4, 70-0703-2736-9, 70-0703-2737-7, 70-
0703-2749-2, 70-0703-2815-1, 70-0703-2816-9, 70-0703-3031-4, 70-0704-1615-4, 70-0704-1616-2, 70-0704-2949-6, 70-
0704-2950-4, 70-0704-2956-1, 70-0704-2959-5, 70-0704-2962-9, 70-0704-2966-0, 70-0704-2967-8, 70-0704-2968-6, 70-
0704-2971-0, 70-0704-5810-7, 70-0704-5811-5, 70-0704-5816-4, 70-0704-5822-2, 70-0704-5908-9, 70-0704-8401-2, 70-
0704-8402-0, 70-0704-8403-8, 70-0704-8404-6, 70-0704-8405-3, 70-0704-8406-1, 70-0704-8408-7, 70-0704-8409-5, 70-
0704-8410-3, 70-0704-8764-3, 70-0706-6017-3, 70-0707-4394-6, 98-0212-1022-8, 98-0212-1024-4, 98-0212-1025-1, 98-
0212-2726-3, 98-0212-2743-8, 98-0212-2744-6, 98-0212-2972-3, 98-0212-3053-1, 98-0212-3072-1, 98-0212-3206-5, 98-
0212-3207-3, 98-0212-3208-1, 98-0212-3210-7, 98-0212-3281-8, 98-0212-3315-4, 98-0212-3316-2, 98-0212-3317-0, 98-
0212-3320-4, 98-0212-3323-8, 98-0212-3351-9, 98-0212-3366-7, 98-0212-3389-9, 98-0212-3520-9, 98-0212-3522-5, 98-
0212-3532-4, 98-0212-3579-5, 98-0212-3587-8, 98-0212-3590-2, 98-0212-3591-0, 98-0212-3604-1, 98-0212-3622-3, 98-
0212-3640-5, 98-0213-3043-0, FJ-9600-0081-0, FJ-9600-0082-8, FJ-9600-0083-6, FS-9000-2572-7, FS-9000-2590-9, FS-
9100-0397-9, FS-9100-0398-7, FS-9100-0410-0, FS-9100-0411-8, FS-9100-0414-2, FS-9100-0437-3, FS-9100-0441-5, FS-
9100-0444-9, FS-9100-0746-7, FS-9100-0846-5, FS-9100-0882-0, FS-9100-1029-7, FS-9100-1313-5, FS-9100-1717-7, FS-
9100-1831-6, FS-9100-2037-9, FS-9100-2330-8, FS-9100-2363-9, FS-9100-2366-2, FS-9100-2395-1, FS-9100-2396-9, FS-
9100-2412-4, FS-9100-2438-9, FS-9100-2544-4, FS-9100-2590-7, FS-9100-2629-3, FS-9100-2708-5, FS-9100-2709-3, FS-
9100-2711-9, FS-9100-2984-2, FS-9100-3027-9, FS-9100-3028-7, FS-9100-3325-7, FS-9100-3346-3, FS-9100-3452-9, FS-
9100-3618-5, FS-9100-4083-1, FS-9100-4179-7, FS-9100-4216-7, FS-9100-4225-8, FS-9100-4227-4, FS-9100-4280-3, FS-
9100-4300-9, FS-9100-4311-6, FS-9100-4324-9, FS-9100-4360-3, FS-9100-4439-5, FS-9100-4472-6, FS-9100-4561-6, FS-
9100-5009-5, FS-9100-5010-3, FS-9100-5053-3, FS-9100-5065-7, FS-9100-5068-1, FS-9100-5121-8, FS-9100-5146-5, FS-
9100-5183-8, FS-9100-5184-6, FS-9100-5192-9, FS-9100-5194-5, FS-9100-5198-6, FS-9100-5199-4, FS-9100-5250-5, FS-
9100-5300-8, FS-9100-5304-0, FS-9100-5375-0, FS-9100-5392-5, FS-9100-5397-4, FS-9100-5415-4, H0-0021-5045-8, HB-
0040-8050-1, HB-0041-0069-7, HB-0041-8096-2, HB-0041-8898-1, HB-0041-8905-4, HB-0041-8906-2, HB-0041-8907-0,
HB-0041-8908-8, HB-0041-8909-6, HB-0041-8910-4, HB-0041-8911-2, HB-0041-8913-8, HB-0041-9053-2, HB-0041-
9054-0, HB-0041-9055-7, HB-0041-9074-8, HB-0041-9077-1, HB-0041-9124-1, HB-0041-9125-8, HB-0041-9126-6, HB-
0041-9127-4, HB-0041-9128-2, HB-0041-9131-6, HB-0041-9140-7, HB-0041-9142-3, HB-0041-9143-1, HB-0041-9146-4,
HB-0041-9147-2, HB-0041-9190-2, HB-0041-9193-6, HB-0041-9194-4, HB-0041-9234-8, HB-0042-0876-3, HB-0042-
0879-7, HB-0042-0881-3, HB-0042-0887-0, HB-0042-0888-8, HB-0042-3265-6, HB-0042-3909-9, HB-0042-4880-1, HB-
0042-7100-1, HB-0042-7135-7, HC-0006-2403-7, HC-0006-2404-5, HC-0006-2405-2, HC-0006-2406-0, HC-0006-2407-8,
HC-0006-2408-6, HC-0006-2409-4, HC-0006-2410-2, HC-0006-2411-0, HC-0006-2412-8, HC-0006-2413-6, HC-0006-
2414-4, HC-0006-2415-1, HC-0006-2416-9, HC-0006-2417-7, HC-0006-2418-5, HC-0006-2419-3, HC-0006-2420-1, HC-
0006-2421-9, HC-0006-2629-7, HC-0006-2630-5, HC-0006-2632-1, HC-0006-2633-9, HC-0006-2634-7, HC-0006-2635-4,
HC-0006-2636-2, HC-0006-2637-0, HC-0006-2638-8, HC-0006-2705-5, HC-0006-2706-3, HC-0006-2707-1, HC-0006-
3381-4, HC-0006-3389-7, HC-0006-3491-1, HC-0006-4572-7, JF-1000-4245-2, JF-1000-4246-0, JF-1000-4247-8, JF-1000-
4251-0, JF-1000-4252-8, JF-1000-4253-6, JF-1000-4254-4, JF-1000-4255-1, JF-1000-4257-7, JF-1000-4258-5, JF-1000-
4259-3, JF-1000-4261-9, JF-1000-4398-9, JF-1000-4422-7, JF-1000-4423-5, WF-6001-0106-8, WF-6001-0107-6, WF-6001-
0108-4, WF-6001-0109-2, WF-6001-0110-0, WF-6001-0111-8, WF-6001-0112-6, WF-6001-0113-4, WF-6001-0114-2, WF-

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6001-0115-9, WF-6001-0116-7, WF-6001-0117-5, WF-6001-0118-3, WF-6001-0119-1, WF-6001-0120-9, WF-6001-0121-7,
WF-6001-0126-6, WF-6001-0127-4, WF-6001-0128-2, WF-6001-0129-0, WF-6001-0130-8, WF-6001-0131-6, WF-6001-
0132-4, WF-6001-0134-0, WF-6001-0135-7, WF-6001-0136-5, WF-6001-0137-3, WF-6001-0138-1, WF-6001-0148-0, WF-
6001-0150-6, WF-6001-0169-6, WF-6001-0170-4, WF-6001-1734-6, WF-6001-1814-6, WF-6009-0001-4, WF-6009-0002-2,
WF-6009-0003-0, WF-6009-0004-8, WF-6009-0005-5, WF-6009-0006-3, WF-6009-0007-1, WF-6009-0009-7, WF-6009-
0010-5, WF-6009-0017-0, WF-6009-0028-7, WF-6009-0029-5, WF-6009-0038-6, WF-6009-0039-4, WF-6009-0053-5, WF-
6009-0054-3, WF-6009-0055-0, WF-6009-0056-8, WF-6009-0057-6, WF-6009-0064-2, WF-6009-0065-9, WF-6009-0066-7,
WF-6009-0070-9, WF-6009-0077-4, WF-6009-0087-3, WF-6009-0091-5, WF-6009-0128-5, WF-6009-0162-4, WF-6009-
0163-2, WF-6009-0164-0, WF-6009-0210-1, WF-6009-0211-9, WF-6009-0366-1, WF-6009-0422-2, WF-6009-0423-0, WF-
6009-0473-5, WF-6009-0633-4, WF-6009-0634-2, WF-6009-0932-0, ZF-9100-1831-4
1.2. Recommended use and restrictions on use
Recommended use
Lightweight Filler
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Advanced Materials Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Soda Lime Borosilicate Glass 65997-17-3 97 – 100
Synthetic Amorphous Crystalline-Free Silica 7631-86-9 0 – 3
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:

3M Glass Bubbles, Types K and S 07/20/15
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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Washwith soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place
in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of
collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

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Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.Agency Limit type Additional Comments
Soda Lime Borosilicate Glass65997-17-3Manufacturer
determined
TWA(as dust):10 mg/m3
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Synthetic Amorphous Crystalline-
Free Silica
7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specificapplication, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Low density fine powder (< 100 microns) Odor, Color, Grade: White odorless Odor threshold Not Applicable Melting point No Data Available Boiling Point Not Applicable Flash Point Not Applicable 3M Glass Bubbles, Types K and S 07/20/15 __________________________________________________________________________________________ Page 5 of 9 Evaporation rateNot Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 0.1 -0.6 g/cm3 Specific Gravity 0.1 -0.6 [Ref Std: WATER=1] Solubility in Water Negligible Solubility-non-water Not Applicable Partition coefficient: n-octanol/ water Not Applicable Autoignition temperature Not Applicable Decomposition temperature Not Applicable Viscosity Not Applicable Volatile Organic Compounds Not Applicable Percent volatile < 0.5 % weight Softening point >=600 C
VOC Less H2O & Exempt Solvents Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.

10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:

3M Glass Bubbles, Types K and S 07/20/15
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Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If acomponent is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRoute SpeciesValue
Soda Lime Borosilicate Glass Dermal LD50 estimated to be > 5,000 mg/kg
Soda Lime Borosilicate Glass Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Dermal Rabbit LD50 > 5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Synthetic Amorphous Crystalline-Free Silica IngestionRat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Synthetic Amorphous Crystalline-Free Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value

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Soda Lime Borosilicate GlassIn VitroSome positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Soda Lime Borosilicate Glass InhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Soda Lime Borosilicate
Glass
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Synthetic Amorphous
Crystalline-Free Silica
Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this materia l and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods

3M Glass Bubbles, Types K and S 07/20/15
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Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill
properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classificationand packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and notthe packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -No Delayed Hazard -No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910 .1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

3M Glass Bubbles, Types K and S 07/20/15
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emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification
Health:0 Flammability:0 Physical Hazard:0 Personal Protection:X -See PPE section.
Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratingsare based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR P URPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com

243M-K25_SDS.pdf

INDEX

243M-K
243M-K1
243M-K20
243M-K25

3M Glass Bubbles, Types K and S 07/20/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit there on.
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
SECTION 1: Identification
1.1. Product identifier
3M Glass Bubbles, Types K and S
Product Identification Numbers
70-0701-1952-7, 70-0701-8213-7, 70-0701-9409-0, 70-0701-9423-1, 70-0703-2625-4, 70-0703-2736-9, 70-0703-2737-7, 70-
0703-2749-2, 70-0703-2815-1, 70-0703-2816-9, 70-0703-3031-4, 70-0704-1615-4, 70-0704-1616-2, 70-0704-2949-6, 70-
0704-2950-4, 70-0704-2956-1, 70-0704-2959-5, 70-0704-2962-9, 70-0704-2966-0, 70-0704-2967-8, 70-0704-2968-6, 70-
0704-2971-0, 70-0704-5810-7, 70-0704-5811-5, 70-0704-5816-4, 70-0704-5822-2, 70-0704-5908-9, 70-0704-8401-2, 70-
0704-8402-0, 70-0704-8403-8, 70-0704-8404-6, 70-0704-8405-3, 70-0704-8406-1, 70-0704-8408-7, 70-0704-8409-5, 70-
0704-8410-3, 70-0704-8764-3, 70-0706-6017-3, 70-0707-4394-6, 98-0212-1022-8, 98-0212-1024-4, 98-0212-1025-1, 98-
0212-2726-3, 98-0212-2743-8, 98-0212-2744-6, 98-0212-2972-3, 98-0212-3053-1, 98-0212-3072-1, 98-0212-3206-5, 98-
0212-3207-3, 98-0212-3208-1, 98-0212-3210-7, 98-0212-3281-8, 98-0212-3315-4, 98-0212-3316-2, 98-0212-3317-0, 98-
0212-3320-4, 98-0212-3323-8, 98-0212-3351-9, 98-0212-3366-7, 98-0212-3389-9, 98-0212-3520-9, 98-0212-3522-5, 98-
0212-3532-4, 98-0212-3579-5, 98-0212-3587-8, 98-0212-3590-2, 98-0212-3591-0, 98-0212-3604-1, 98-0212-3622-3, 98-
0212-3640-5, 98-0213-3043-0, FJ-9600-0081-0, FJ-9600-0082-8, FJ-9600-0083-6, FS-9000-2572-7, FS-9000-2590-9, FS-
9100-0397-9, FS-9100-0398-7, FS-9100-0410-0, FS-9100-0411-8, FS-9100-0414-2, FS-9100-0437-3, FS-9100-0441-5, FS-
9100-0444-9, FS-9100-0746-7, FS-9100-0846-5, FS-9100-0882-0, FS-9100-1029-7, FS-9100-1313-5, FS-9100-1717-7, FS-
9100-1831-6, FS-9100-2037-9, FS-9100-2330-8, FS-9100-2363-9, FS-9100-2366-2, FS-9100-2395-1, FS-9100-2396-9, FS-
9100-2412-4, FS-9100-2438-9, FS-9100-2544-4, FS-9100-2590-7, FS-9100-2629-3, FS-9100-2708-5, FS-9100-2709-3, FS-
9100-2711-9, FS-9100-2984-2, FS-9100-3027-9, FS-9100-3028-7, FS-9100-3325-7, FS-9100-3346-3, FS-9100-3452-9, FS-
9100-3618-5, FS-9100-4083-1, FS-9100-4179-7, FS-9100-4216-7, FS-9100-4225-8, FS-9100-4227-4, FS-9100-4280-3, FS-
9100-4300-9, FS-9100-4311-6, FS-9100-4324-9, FS-9100-4360-3, FS-9100-4439-5, FS-9100-4472-6, FS-9100-4561-6, FS-
9100-5009-5, FS-9100-5010-3, FS-9100-5053-3, FS-9100-5065-7, FS-9100-5068-1, FS-9100-5121-8, FS-9100-5146-5, FS-
9100-5183-8, FS-9100-5184-6, FS-9100-5192-9, FS-9100-5194-5, FS-9100-5198-6, FS-9100-5199-4, FS-9100-5250-5, FS-
9100-5300-8, FS-9100-5304-0, FS-9100-5375-0, FS-9100-5392-5, FS-9100-5397-4, FS-9100-5415-4, H0-0021-5045-8, HB-
0040-8050-1, HB-0041-0069-7, HB-0041-8096-2, HB-0041-8898-1, HB-0041-8905-4, HB-0041-8906-2, HB-0041-8907-0,
HB-0041-8908-8, HB-0041-8909-6, HB-0041-8910-4, HB-0041-8911-2, HB-0041-8913-8, HB-0041-9053-2, HB-0041-
9054-0, HB-0041-9055-7, HB-0041-9074-8, HB-0041-9077-1, HB-0041-9124-1, HB-0041-9125-8, HB-0041-9126-6, HB-
0041-9127-4, HB-0041-9128-2, HB-0041-9131-6, HB-0041-9140-7, HB-0041-9142-3, HB-0041-9143-1, HB-0041-9146-4,
HB-0041-9147-2, HB-0041-9190-2, HB-0041-9193-6, HB-0041-9194-4, HB-0041-9234-8, HB-0042-0876-3, HB-0042-
0879-7, HB-0042-0881-3, HB-0042-0887-0, HB-0042-0888-8, HB-0042-3265-6, HB-0042-3909-9, HB-0042-4880-1, HB-
0042-7100-1, HB-0042-7135-7, HC-0006-2403-7, HC-0006-2404-5, HC-0006-2405-2, HC-0006-2406-0, HC-0006-2407-8,
HC-0006-2408-6, HC-0006-2409-4, HC-0006-2410-2, HC-0006-2411-0, HC-0006-2412-8, HC-0006-2413-6, HC-0006-
2414-4, HC-0006-2415-1, HC-0006-2416-9, HC-0006-2417-7, HC-0006-2418-5, HC-0006-2419-3, HC-0006-2420-1, HC-
0006-2421-9, HC-0006-2629-7, HC-0006-2630-5, HC-0006-2632-1, HC-0006-2633-9, HC-0006-2634-7, HC-0006-2635-4,
HC-0006-2636-2, HC-0006-2637-0, HC-0006-2638-8, HC-0006-2705-5, HC-0006-2706-3, HC-0006-2707-1, HC-0006-
3381-4, HC-0006-3389-7, HC-0006-3491-1, HC-0006-4572-7, JF-1000-4245-2, JF-1000-4246-0, JF-1000-4247-8, JF-1000-
4251-0, JF-1000-4252-8, JF-1000-4253-6, JF-1000-4254-4, JF-1000-4255-1, JF-1000-4257-7, JF-1000-4258-5, JF-1000-
4259-3, JF-1000-4261-9, JF-1000-4398-9, JF-1000-4422-7, JF-1000-4423-5, WF-6001-0106-8, WF-6001-0107-6, WF-6001-
0108-4, WF-6001-0109-2, WF-6001-0110-0, WF-6001-0111-8, WF-6001-0112-6, WF-6001-0113-4, WF-6001-0114-2, WF-

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6001-0115-9, WF-6001-0116-7, WF-6001-0117-5, WF-6001-0118-3, WF-6001-0119-1, WF-6001-0120-9, WF-6001-0121-7,
WF-6001-0126-6, WF-6001-0127-4, WF-6001-0128-2, WF-6001-0129-0, WF-6001-0130-8, WF-6001-0131-6, WF-6001-
0132-4, WF-6001-0134-0, WF-6001-0135-7, WF-6001-0136-5, WF-6001-0137-3, WF-6001-0138-1, WF-6001-0148-0, WF-
6001-0150-6, WF-6001-0169-6, WF-6001-0170-4, WF-6001-1734-6, WF-6001-1814-6, WF-6009-0001-4, WF-6009-0002-2,
WF-6009-0003-0, WF-6009-0004-8, WF-6009-0005-5, WF-6009-0006-3, WF-6009-0007-1, WF-6009-0009-7, WF-6009-
0010-5, WF-6009-0017-0, WF-6009-0028-7, WF-6009-0029-5, WF-6009-0038-6, WF-6009-0039-4, WF-6009-0053-5, WF-
6009-0054-3, WF-6009-0055-0, WF-6009-0056-8, WF-6009-0057-6, WF-6009-0064-2, WF-6009-0065-9, WF-6009-0066-7,
WF-6009-0070-9, WF-6009-0077-4, WF-6009-0087-3, WF-6009-0091-5, WF-6009-0128-5, WF-6009-0162-4, WF-6009-
0163-2, WF-6009-0164-0, WF-6009-0210-1, WF-6009-0211-9, WF-6009-0366-1, WF-6009-0422-2, WF-6009-0423-0, WF-
6009-0473-5, WF-6009-0633-4, WF-6009-0634-2, WF-6009-0932-0, ZF-9100-1831-4
1.2. Recommended use and restrictions on use
Recommended use
Lightweight Filler
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Advanced Materials Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Soda Lime Borosilicate Glass 65997-17-3 97 – 100
Synthetic Amorphous Crystalline-Free Silica 7631-86-9 0 – 3
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:

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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Washwith soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place
in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of
collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

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Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.Agency Limit type Additional Comments
Soda Lime Borosilicate Glass65997-17-3Manufacturer
determined
TWA(as dust):10 mg/m3
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Synthetic Amorphous Crystalline-
Free Silica
7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specificapplication, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Low density fine powder (< 100 microns) Odor, Color, Grade: White odorless Odor threshold Not Applicable Melting point No Data Available Boiling Point Not Applicable Flash Point Not Applicable 3M Glass Bubbles, Types K and S 07/20/15 __________________________________________________________________________________________ Page 5 of 9 Evaporation rateNot Applicable Flammability (solid, gas) Not Classified Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 0.1 -0.6 g/cm3 Specific Gravity 0.1 -0.6 [Ref Std: WATER=1] Solubility in Water Negligible Solubility-non-water Not Applicable Partition coefficient: n-octanol/ water Not Applicable Autoignition temperature Not Applicable Decomposition temperature Not Applicable Viscosity Not Applicable Volatile Organic Compounds Not Applicable Percent volatile < 0.5 % weight Softening point >=600 C
VOC Less H2O & Exempt Solvents Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.

10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:

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Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If acomponent is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRoute SpeciesValue
Soda Lime Borosilicate Glass Dermal LD50 estimated to be > 5,000 mg/kg
Soda Lime Borosilicate Glass Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Dermal Rabbit LD50 > 5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Synthetic Amorphous Crystalline-Free Silica IngestionRat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Synthetic Amorphous Crystalline-Free Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value

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Soda Lime Borosilicate GlassIn VitroSome positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Soda Lime Borosilicate Glass InhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Soda Lime Borosilicate
Glass
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Synthetic Amorphous
Crystalline-Free Silica
Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this materia l and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods

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Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill
properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classificationand packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and notthe packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -No Delayed Hazard -No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910 .1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

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emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification
Health:0 Flammability:0 Physical Hazard:0 Personal Protection:X -See PPE section.
Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratingsare based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR P URPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com