by | Sep 27, 2025
INDEX
243M-K
243M-K1
243M-K20
243M-K25
3M Glass Bubbles, Types K and S 07/20/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit there on.
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
SECTION 1: Identification
1.1. Product identifier
3M Glass Bubbles, Types K and S
Product Identification Numbers
70-0701-1952-7, 70-0701-8213-7, 70-0701-9409-0, 70-0701-9423-1, 70-0703-2625-4, 70-0703-2736-9, 70-0703-2737-7, 70-
0703-2749-2, 70-0703-2815-1, 70-0703-2816-9, 70-0703-3031-4, 70-0704-1615-4, 70-0704-1616-2, 70-0704-2949-6, 70-
0704-2950-4, 70-0704-2956-1, 70-0704-2959-5, 70-0704-2962-9, 70-0704-2966-0, 70-0704-2967-8, 70-0704-2968-6, 70-
0704-2971-0, 70-0704-5810-7, 70-0704-5811-5, 70-0704-5816-4, 70-0704-5822-2, 70-0704-5908-9, 70-0704-8401-2, 70-
0704-8402-0, 70-0704-8403-8, 70-0704-8404-6, 70-0704-8405-3, 70-0704-8406-1, 70-0704-8408-7, 70-0704-8409-5, 70-
0704-8410-3, 70-0704-8764-3, 70-0706-6017-3, 70-0707-4394-6, 98-0212-1022-8, 98-0212-1024-4, 98-0212-1025-1, 98-
0212-2726-3, 98-0212-2743-8, 98-0212-2744-6, 98-0212-2972-3, 98-0212-3053-1, 98-0212-3072-1, 98-0212-3206-5, 98-
0212-3207-3, 98-0212-3208-1, 98-0212-3210-7, 98-0212-3281-8, 98-0212-3315-4, 98-0212-3316-2, 98-0212-3317-0, 98-
0212-3320-4, 98-0212-3323-8, 98-0212-3351-9, 98-0212-3366-7, 98-0212-3389-9, 98-0212-3520-9, 98-0212-3522-5, 98-
0212-3532-4, 98-0212-3579-5, 98-0212-3587-8, 98-0212-3590-2, 98-0212-3591-0, 98-0212-3604-1, 98-0212-3622-3, 98-
0212-3640-5, 98-0213-3043-0, FJ-9600-0081-0, FJ-9600-0082-8, FJ-9600-0083-6, FS-9000-2572-7, FS-9000-2590-9, FS-
9100-0397-9, FS-9100-0398-7, FS-9100-0410-0, FS-9100-0411-8, FS-9100-0414-2, FS-9100-0437-3, FS-9100-0441-5, FS-
9100-0444-9, FS-9100-0746-7, FS-9100-0846-5, FS-9100-0882-0, FS-9100-1029-7, FS-9100-1313-5, FS-9100-1717-7, FS-
9100-1831-6, FS-9100-2037-9, FS-9100-2330-8, FS-9100-2363-9, FS-9100-2366-2, FS-9100-2395-1, FS-9100-2396-9, FS-
9100-2412-4, FS-9100-2438-9, FS-9100-2544-4, FS-9100-2590-7, FS-9100-2629-3, FS-9100-2708-5, FS-9100-2709-3, FS-
9100-2711-9, FS-9100-2984-2, FS-9100-3027-9, FS-9100-3028-7, FS-9100-3325-7, FS-9100-3346-3, FS-9100-3452-9, FS-
9100-3618-5, FS-9100-4083-1, FS-9100-4179-7, FS-9100-4216-7, FS-9100-4225-8, FS-9100-4227-4, FS-9100-4280-3, FS-
9100-4300-9, FS-9100-4311-6, FS-9100-4324-9, FS-9100-4360-3, FS-9100-4439-5, FS-9100-4472-6, FS-9100-4561-6, FS-
9100-5009-5, FS-9100-5010-3, FS-9100-5053-3, FS-9100-5065-7, FS-9100-5068-1, FS-9100-5121-8, FS-9100-5146-5, FS-
9100-5183-8, FS-9100-5184-6, FS-9100-5192-9, FS-9100-5194-5, FS-9100-5198-6, FS-9100-5199-4, FS-9100-5250-5, FS-
9100-5300-8, FS-9100-5304-0, FS-9100-5375-0, FS-9100-5392-5, FS-9100-5397-4, FS-9100-5415-4, H0-0021-5045-8, HB-
0040-8050-1, HB-0041-0069-7, HB-0041-8096-2, HB-0041-8898-1, HB-0041-8905-4, HB-0041-8906-2, HB-0041-8907-0,
HB-0041-8908-8, HB-0041-8909-6, HB-0041-8910-4, HB-0041-8911-2, HB-0041-8913-8, HB-0041-9053-2, HB-0041-
9054-0, HB-0041-9055-7, HB-0041-9074-8, HB-0041-9077-1, HB-0041-9124-1, HB-0041-9125-8, HB-0041-9126-6, HB-
0041-9127-4, HB-0041-9128-2, HB-0041-9131-6, HB-0041-9140-7, HB-0041-9142-3, HB-0041-9143-1, HB-0041-9146-4,
HB-0041-9147-2, HB-0041-9190-2, HB-0041-9193-6, HB-0041-9194-4, HB-0041-9234-8, HB-0042-0876-3, HB-0042-
0879-7, HB-0042-0881-3, HB-0042-0887-0, HB-0042-0888-8, HB-0042-3265-6, HB-0042-3909-9, HB-0042-4880-1, HB-
0042-7100-1, HB-0042-7135-7, HC-0006-2403-7, HC-0006-2404-5, HC-0006-2405-2, HC-0006-2406-0, HC-0006-2407-8,
HC-0006-2408-6, HC-0006-2409-4, HC-0006-2410-2, HC-0006-2411-0, HC-0006-2412-8, HC-0006-2413-6, HC-0006-
2414-4, HC-0006-2415-1, HC-0006-2416-9, HC-0006-2417-7, HC-0006-2418-5, HC-0006-2419-3, HC-0006-2420-1, HC-
0006-2421-9, HC-0006-2629-7, HC-0006-2630-5, HC-0006-2632-1, HC-0006-2633-9, HC-0006-2634-7, HC-0006-2635-4,
HC-0006-2636-2, HC-0006-2637-0, HC-0006-2638-8, HC-0006-2705-5, HC-0006-2706-3, HC-0006-2707-1, HC-0006-
3381-4, HC-0006-3389-7, HC-0006-3491-1, HC-0006-4572-7, JF-1000-4245-2, JF-1000-4246-0, JF-1000-4247-8, JF-1000-
4251-0, JF-1000-4252-8, JF-1000-4253-6, JF-1000-4254-4, JF-1000-4255-1, JF-1000-4257-7, JF-1000-4258-5, JF-1000-
4259-3, JF-1000-4261-9, JF-1000-4398-9, JF-1000-4422-7, JF-1000-4423-5, WF-6001-0106-8, WF-6001-0107-6, WF-6001-
0108-4, WF-6001-0109-2, WF-6001-0110-0, WF-6001-0111-8, WF-6001-0112-6, WF-6001-0113-4, WF-6001-0114-2, WF-
3M Glass Bubbles, Types K and S 07/20/15
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6001-0115-9, WF-6001-0116-7, WF-6001-0117-5, WF-6001-0118-3, WF-6001-0119-1, WF-6001-0120-9, WF-6001-0121-7,
WF-6001-0126-6, WF-6001-0127-4, WF-6001-0128-2, WF-6001-0129-0, WF-6001-0130-8, WF-6001-0131-6, WF-6001-
0132-4, WF-6001-0134-0, WF-6001-0135-7, WF-6001-0136-5, WF-6001-0137-3, WF-6001-0138-1, WF-6001-0148-0, WF-
6001-0150-6, WF-6001-0169-6, WF-6001-0170-4, WF-6001-1734-6, WF-6001-1814-6, WF-6009-0001-4, WF-6009-0002-2,
WF-6009-0003-0, WF-6009-0004-8, WF-6009-0005-5, WF-6009-0006-3, WF-6009-0007-1, WF-6009-0009-7, WF-6009-
0010-5, WF-6009-0017-0, WF-6009-0028-7, WF-6009-0029-5, WF-6009-0038-6, WF-6009-0039-4, WF-6009-0053-5, WF-
6009-0054-3, WF-6009-0055-0, WF-6009-0056-8, WF-6009-0057-6, WF-6009-0064-2, WF-6009-0065-9, WF-6009-0066-7,
WF-6009-0070-9, WF-6009-0077-4, WF-6009-0087-3, WF-6009-0091-5, WF-6009-0128-5, WF-6009-0162-4, WF-6009-
0163-2, WF-6009-0164-0, WF-6009-0210-1, WF-6009-0211-9, WF-6009-0366-1, WF-6009-0422-2, WF-6009-0423-0, WF-
6009-0473-5, WF-6009-0633-4, WF-6009-0634-2, WF-6009-0932-0, ZF-9100-1831-4
1.2. Recommended use and restrictions on use
Recommended use
Lightweight Filler
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Advanced Materials Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Soda Lime Borosilicate Glass 65997-17-3 97 – 100
Synthetic Amorphous Crystalline-Free Silica 7631-86-9 0 – 3
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Washwith soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place
in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of
collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
3M Glass Bubbles, Types K and S 07/20/15
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Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.Agency Limit type Additional Comments
Soda Lime Borosilicate Glass65997-17-3Manufacturer
determined
TWA(as dust):10 mg/m3
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Synthetic Amorphous Crystalline-
Free Silica
7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specificapplication, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Low density fine powder (< 100 microns)
Odor, Color, Grade: White odorless
Odor threshold Not Applicable
Melting point No Data Available
Boiling Point Not Applicable
Flash Point Not Applicable
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Evaporation rateNot Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density 0.1 -0.6 g/cm3
Specific Gravity 0.1 -0.6 [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility-non-water Not Applicable
Partition coefficient: n-octanol/ water Not Applicable
Autoignition temperature Not Applicable
Decomposition temperature Not Applicable
Viscosity Not Applicable
Volatile Organic Compounds Not Applicable
Percent volatile < 0.5 % weight
Softening point >=600 C
VOC Less H2O & Exempt Solvents Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
3M Glass Bubbles, Types K and S 07/20/15
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Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If acomponent is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRoute SpeciesValue
Soda Lime Borosilicate Glass Dermal LD50 estimated to be > 5,000 mg/kg
Soda Lime Borosilicate Glass Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Dermal Rabbit LD50 > 5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Synthetic Amorphous Crystalline-Free Silica IngestionRat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Synthetic Amorphous Crystalline-Free Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
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Soda Lime Borosilicate GlassIn VitroSome positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Soda Lime Borosilicate Glass InhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Soda Lime Borosilicate
Glass
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Synthetic Amorphous
Crystalline-Free Silica
Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this materia l and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
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Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill
properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classificationand packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and notthe packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -No Delayed Hazard -No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910 .1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
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emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health:0 Flammability:0 Physical Hazard:0 Personal Protection:X -See PPE section.
Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratingsare based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR P URPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com
by | Sep 27, 2025
by | Sep 27, 2025
3M Glass Bubbles, Types K and S 07/20/15
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Safety Data Sheet
Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit there on.
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
SECTION 1: Identification
1.1. Product identifier
3M Glass Bubbles, Types K and S
Product Identification Numbers
70-0701-1952-7, 70-0701-8213-7, 70-0701-9409-0, 70-0701-9423-1, 70-0703-2625-4, 70-0703-2736-9, 70-0703-2737-7, 70-
0703-2749-2, 70-0703-2815-1, 70-0703-2816-9, 70-0703-3031-4, 70-0704-1615-4, 70-0704-1616-2, 70-0704-2949-6, 70-
0704-2950-4, 70-0704-2956-1, 70-0704-2959-5, 70-0704-2962-9, 70-0704-2966-0, 70-0704-2967-8, 70-0704-2968-6, 70-
0704-2971-0, 70-0704-5810-7, 70-0704-5811-5, 70-0704-5816-4, 70-0704-5822-2, 70-0704-5908-9, 70-0704-8401-2, 70-
0704-8402-0, 70-0704-8403-8, 70-0704-8404-6, 70-0704-8405-3, 70-0704-8406-1, 70-0704-8408-7, 70-0704-8409-5, 70-
0704-8410-3, 70-0704-8764-3, 70-0706-6017-3, 70-0707-4394-6, 98-0212-1022-8, 98-0212-1024-4, 98-0212-1025-1, 98-
0212-2726-3, 98-0212-2743-8, 98-0212-2744-6, 98-0212-2972-3, 98-0212-3053-1, 98-0212-3072-1, 98-0212-3206-5, 98-
0212-3207-3, 98-0212-3208-1, 98-0212-3210-7, 98-0212-3281-8, 98-0212-3315-4, 98-0212-3316-2, 98-0212-3317-0, 98-
0212-3320-4, 98-0212-3323-8, 98-0212-3351-9, 98-0212-3366-7, 98-0212-3389-9, 98-0212-3520-9, 98-0212-3522-5, 98-
0212-3532-4, 98-0212-3579-5, 98-0212-3587-8, 98-0212-3590-2, 98-0212-3591-0, 98-0212-3604-1, 98-0212-3622-3, 98-
0212-3640-5, 98-0213-3043-0, FJ-9600-0081-0, FJ-9600-0082-8, FJ-9600-0083-6, FS-9000-2572-7, FS-9000-2590-9, FS-
9100-0397-9, FS-9100-0398-7, FS-9100-0410-0, FS-9100-0411-8, FS-9100-0414-2, FS-9100-0437-3, FS-9100-0441-5, FS-
9100-0444-9, FS-9100-0746-7, FS-9100-0846-5, FS-9100-0882-0, FS-9100-1029-7, FS-9100-1313-5, FS-9100-1717-7, FS-
9100-1831-6, FS-9100-2037-9, FS-9100-2330-8, FS-9100-2363-9, FS-9100-2366-2, FS-9100-2395-1, FS-9100-2396-9, FS-
9100-2412-4, FS-9100-2438-9, FS-9100-2544-4, FS-9100-2590-7, FS-9100-2629-3, FS-9100-2708-5, FS-9100-2709-3, FS-
9100-2711-9, FS-9100-2984-2, FS-9100-3027-9, FS-9100-3028-7, FS-9100-3325-7, FS-9100-3346-3, FS-9100-3452-9, FS-
9100-3618-5, FS-9100-4083-1, FS-9100-4179-7, FS-9100-4216-7, FS-9100-4225-8, FS-9100-4227-4, FS-9100-4280-3, FS-
9100-4300-9, FS-9100-4311-6, FS-9100-4324-9, FS-9100-4360-3, FS-9100-4439-5, FS-9100-4472-6, FS-9100-4561-6, FS-
9100-5009-5, FS-9100-5010-3, FS-9100-5053-3, FS-9100-5065-7, FS-9100-5068-1, FS-9100-5121-8, FS-9100-5146-5, FS-
9100-5183-8, FS-9100-5184-6, FS-9100-5192-9, FS-9100-5194-5, FS-9100-5198-6, FS-9100-5199-4, FS-9100-5250-5, FS-
9100-5300-8, FS-9100-5304-0, FS-9100-5375-0, FS-9100-5392-5, FS-9100-5397-4, FS-9100-5415-4, H0-0021-5045-8, HB-
0040-8050-1, HB-0041-0069-7, HB-0041-8096-2, HB-0041-8898-1, HB-0041-8905-4, HB-0041-8906-2, HB-0041-8907-0,
HB-0041-8908-8, HB-0041-8909-6, HB-0041-8910-4, HB-0041-8911-2, HB-0041-8913-8, HB-0041-9053-2, HB-0041-
9054-0, HB-0041-9055-7, HB-0041-9074-8, HB-0041-9077-1, HB-0041-9124-1, HB-0041-9125-8, HB-0041-9126-6, HB-
0041-9127-4, HB-0041-9128-2, HB-0041-9131-6, HB-0041-9140-7, HB-0041-9142-3, HB-0041-9143-1, HB-0041-9146-4,
HB-0041-9147-2, HB-0041-9190-2, HB-0041-9193-6, HB-0041-9194-4, HB-0041-9234-8, HB-0042-0876-3, HB-0042-
0879-7, HB-0042-0881-3, HB-0042-0887-0, HB-0042-0888-8, HB-0042-3265-6, HB-0042-3909-9, HB-0042-4880-1, HB-
0042-7100-1, HB-0042-7135-7, HC-0006-2403-7, HC-0006-2404-5, HC-0006-2405-2, HC-0006-2406-0, HC-0006-2407-8,
HC-0006-2408-6, HC-0006-2409-4, HC-0006-2410-2, HC-0006-2411-0, HC-0006-2412-8, HC-0006-2413-6, HC-0006-
2414-4, HC-0006-2415-1, HC-0006-2416-9, HC-0006-2417-7, HC-0006-2418-5, HC-0006-2419-3, HC-0006-2420-1, HC-
0006-2421-9, HC-0006-2629-7, HC-0006-2630-5, HC-0006-2632-1, HC-0006-2633-9, HC-0006-2634-7, HC-0006-2635-4,
HC-0006-2636-2, HC-0006-2637-0, HC-0006-2638-8, HC-0006-2705-5, HC-0006-2706-3, HC-0006-2707-1, HC-0006-
3381-4, HC-0006-3389-7, HC-0006-3491-1, HC-0006-4572-7, JF-1000-4245-2, JF-1000-4246-0, JF-1000-4247-8, JF-1000-
4251-0, JF-1000-4252-8, JF-1000-4253-6, JF-1000-4254-4, JF-1000-4255-1, JF-1000-4257-7, JF-1000-4258-5, JF-1000-
4259-3, JF-1000-4261-9, JF-1000-4398-9, JF-1000-4422-7, JF-1000-4423-5, WF-6001-0106-8, WF-6001-0107-6, WF-6001-
0108-4, WF-6001-0109-2, WF-6001-0110-0, WF-6001-0111-8, WF-6001-0112-6, WF-6001-0113-4, WF-6001-0114-2, WF-
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6001-0115-9, WF-6001-0116-7, WF-6001-0117-5, WF-6001-0118-3, WF-6001-0119-1, WF-6001-0120-9, WF-6001-0121-7,
WF-6001-0126-6, WF-6001-0127-4, WF-6001-0128-2, WF-6001-0129-0, WF-6001-0130-8, WF-6001-0131-6, WF-6001-
0132-4, WF-6001-0134-0, WF-6001-0135-7, WF-6001-0136-5, WF-6001-0137-3, WF-6001-0138-1, WF-6001-0148-0, WF-
6001-0150-6, WF-6001-0169-6, WF-6001-0170-4, WF-6001-1734-6, WF-6001-1814-6, WF-6009-0001-4, WF-6009-0002-2,
WF-6009-0003-0, WF-6009-0004-8, WF-6009-0005-5, WF-6009-0006-3, WF-6009-0007-1, WF-6009-0009-7, WF-6009-
0010-5, WF-6009-0017-0, WF-6009-0028-7, WF-6009-0029-5, WF-6009-0038-6, WF-6009-0039-4, WF-6009-0053-5, WF-
6009-0054-3, WF-6009-0055-0, WF-6009-0056-8, WF-6009-0057-6, WF-6009-0064-2, WF-6009-0065-9, WF-6009-0066-7,
WF-6009-0070-9, WF-6009-0077-4, WF-6009-0087-3, WF-6009-0091-5, WF-6009-0128-5, WF-6009-0162-4, WF-6009-
0163-2, WF-6009-0164-0, WF-6009-0210-1, WF-6009-0211-9, WF-6009-0366-1, WF-6009-0422-2, WF-6009-0423-0, WF-
6009-0473-5, WF-6009-0633-4, WF-6009-0634-2, WF-6009-0932-0, ZF-9100-1831-4
1.2. Recommended use and restrictions on use
Recommended use
Lightweight Filler
1.3. Supplier s details
MANUFACTURER: 3M
DIVISION: Advanced Materials Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)
1.4. Emergency telephone number
1-800-364-3577 or (651) 737-6501 (24 hours)
SECTION 2: Hazard identification
2.1. Hazard classification
Not classified as hazardous according to OSHA Hazard Communication Standard, 29 CFR 1910.1200.
2.2. Label elements
Signal word
Not applicable.
Symbols
Not applicable.
Pictograms
Not applicable.
2.3. Hazards not otherwise classified
None.
SECTION 3: Composition/information on ingredients
Ingredient C.A.S. No. % by Wt
Soda Lime Borosilicate Glass 65997-17-3 97 – 100
Synthetic Amorphous Crystalline-Free Silica 7631-86-9 0 – 3
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
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Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Washwith soap and water. If signs/symptoms develop, get medical attention.
Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Suitable extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising fromthe substance or mixture
None inherent in this product.
5.3. Special protective actions for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Use wet sweeping compound or water to avoid dusting. Sweep up. Place
in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of
collected material as soon as possible.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
For industrial or professional use only. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when
using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
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Occupational exposure limits
If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
IngredientC.A.S. No.Agency Limit type Additional Comments
Soda Lime Borosilicate Glass65997-17-3Manufacturer
determined
TWA(as dust):10 mg/m3
SILICA, AMORPHOUS 7631-86-9OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Synthetic Amorphous Crystalline-
Free Silica
7631-86-9CMRG TWA(as respirable dust):3
mg/m3
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA : United States Department of Labor -Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to belowrelevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety Glasses with side shields
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for particulates
For questions about suitability for a specificapplication, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Low density fine powder (< 100 microns)
Odor, Color, Grade: White odorless
Odor threshold Not Applicable
Melting point No Data Available
Boiling Point Not Applicable
Flash Point Not Applicable
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Evaporation rateNot Applicable
Flammability (solid, gas) Not Classified
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Not Applicable
Vapor Density Not Applicable
Density 0.1 -0.6 g/cm3
Specific Gravity 0.1 -0.6 [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility-non-water Not Applicable
Partition coefficient: n-octanol/ water Not Applicable
Autoignition temperature Not Applicable
Decomposition temperature Not Applicable
Viscosity Not Applicable
Volatile Organic Compounds Not Applicable
Percent volatile < 0.5 % weight
Softening point >=600 C
VOC Less H2O & Exempt Solvents Not Applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
This material is considered to be non reactive under normal use conditions.
10.2. Chemical stability
Stable.
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
Substance Condition
None known. Not Specified
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material cla ssification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1. Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
3M Glass Bubbles, Types K and S 07/20/15
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Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing,nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin Contact:
Mechanical Skin irritation: Signs/symptoms may include abrasion, redness, pain, and itching.
Eye Contact:
Mechanical eye irritation: Signs/symptoms may include pain, redness, tearing and corneal abrasion.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Toxicological Data
If acomponent is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
NameRoute SpeciesValue
Soda Lime Borosilicate Glass Dermal LD50 estimated to be > 5,000 mg/kg
Soda Lime Borosilicate Glass Ingestion LD50 estimated to be 2,000 -5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Dermal Rabbit LD50 > 5,000 mg/kg
Synthetic Amorphous Crystalline-Free Silica Inhalation-
Dust/Mist
(4 hours)
Rat LC50 > 0.691 mg/l
Synthetic Amorphous Crystalline-Free Silica IngestionRat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Serious Eye Damage/Irritation
Name SpeciesValue
Soda Lime Borosilicate Glass Professio
nal
judgeme
nt
No significant irritation
Synthetic Amorphous Crystalline-Free Silica Rabbit No significant irritation
Skin Sensitization
Name SpeciesValue
Synthetic Amorphous Crystalline-Free Silica Human
and
animal
Not sensitizing
Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.
Germ Cell Mutagenicity
Name Route Value
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Soda Lime Borosilicate GlassIn VitroSome positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica In VitroNot mutagenic
Carcinogenicity
Name Route SpeciesValue
Soda Lime Borosilicate Glass InhalationMultiple
animal
species
Some positive data exist, but the data are not
sufficient for classification
Synthetic Amorphous Crystalline-Free Silica Not
Specified
Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value SpeciesTest Result Exposure
Duration
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to female reproductionRat NOAEL 509
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
Synthetic Amorphous Crystalline-Free
Silica
IngestionNot toxic to development Rat NOAEL 1,350
mg/kg/day
during
organogenesi
s
Target Organ(s)
Specific Target Organ Toxicity -single exposure
For the component/components, either no data are currently available or the data are not sufficient for classification.
Specific Target Organ Toxicity -repeated exposure
Name Route Target Organ(s) Value SpeciesTest Result Exposure
Duration
Soda Lime Borosilicate
Glass
Inhalationrespiratory systemSome positive data exist, but the
data are not sufficient for
classification
Human NOAEL not
available
occupational
exposure
Synthetic Amorphous
Crystalline-Free Silica
Inhalationrespiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational
exposure
Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this materia l and/or its components.
SECTION 12: Ecological information
Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information onthis material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.
SECTION 13: Disposal considerations
13.1. Disposal methods
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Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in
a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill
properly designed for industrial waste.
EPA Hazardous Waste Number (RCRA): Not regulated
SECTION 14: Transport Information
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classificationand packaging. 3M
transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of
applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information
applies only to transportation classification and notthe packaging, labeling, or marking requirements. The original 3M
package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet
applicable regulatory requirements.
SECTION 15: Regulatory information
15.1. US Federal Regulations
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard -No Pressure Hazard -No Reactivity Hazard -No Immediate Hazard -No Delayed Hazard -No
15.2. State Regulations
Contact 3M for more information.
15.3. Chemical Inventories
The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain
restrictions may apply. Contact the selling division for additional information.
This product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.
Contact 3M for more information.
15.4. International Regulations
Contact 3M for more information.
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910 .1200.
SECTION 16: Other information
NFPA Hazard Classification
Health: 0 Flammability: 0 Instability: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
3M Glass Bubbles, Types K and S 07/20/15
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emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.
HMIS Hazard Classification
Health:0 Flammability:0 Physical Hazard:0 Personal Protection:X -See PPE section.
Hazardous Material Identification System (HMIS III) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratingsare based on the inherent properties of the material under expected conditions of normal use
and are not intended for use in emergency situations. HMIS III ratings are to be used with a fully implemented HMIS III
program. HMIS is a registered mark of the American Coatings Association (ACA).
Document Group:10-4852-9 Version Number: 122.06
Issue Date: 07/20/15 Supercedes Date: 03/09/15
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR P URPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M
3MUSA SDSs are available at www.3M.com
by | Sep 27, 2025
Poly-Fair T27 R
Liquid.
SAFETY DATA SHEET
GHS product identifier
Product type
Section 1. Identification
:
:
Supplier’s details :
Poly-Fair T27 R
Relevant identified uses of the substance or mixture and uses advised against
Resins.
Identified uses
Scott Bader ATC,
2400 Canadian Street
Drummondville, Que
Canada, J2C 7W3
Tel: +1 819 477 1752
SB –
Canada
Emergency telephone
number (with hours of
operation)
:
SDS@scottbader.com:e-mail address of person
responsible for this SDS
+1 215 207 0061 (NCEC, Geographic) 24h
+1 866 928 0789 (NCEC, Toll free) 24h
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SKIN SENSITIZATION – Category 1
TOXIC TO REPRODUCTION (Fertility) – Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs) –
Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :H226 – Flammable liquid and vapor.
H332 – Harmful if inhaled.
H319 – Causes serious eye irritation.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H361 – Suspected of damaging fertility.
H335 – May cause respiratory irritation.
H372 – Causes damage to organs through prolonged or repeated exposure. (hearing
organs)
Hazard pictograms :
Precautionary statements
GHS label elements
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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Poly-Fair T27 R
Section 2. Hazards identification
Prevention :P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P241 – Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P233 – Keep container tightly closed.
P271 – Use only outdoors or in a well-ventilated area.
P260 – Do not breathe vapor.
P270 – Do not eat, drink or smoke when using this product.
P264 – Wash hands thoroughly after handling.
P272 (OSHA) – Contaminated work clothing must not be allowed out of the workplace.
Response :P314 – Get medical attention if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical attention.
P304 + P340 + P312 – IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or physician if you feel unwell.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
P302 + P352 + P363 – IF ON SKIN: Wash with plenty of soap and water. Wash
contaminated clothing before reuse.
P333 + P313 – If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical attention.
Storage :P405 – Store locked up.
P403 – Store in a well-ventilated place.
P235 – Keep cool.
Disposal :P501 – Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
styrene 34.939 100-42-5
Benzene, ethenyl-, polymer with 1,3-butadiene <2.0797 9003-55-8
dimethyl glutarate <1.3645 1119-40-0
cobalt bis(2-ethylhexanoate) 0.22559 136-52-7
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Not available.
CAS number :Not applicable.
Substance/mixture
Product code :CF027E00
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
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Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
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Section 4. First aid measures
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Specific treatments :No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
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Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill :
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Avoid exposure - obtain special instructions before use. Avoid
exposure during pregnancy. Do not handle until all safety precautions have been read
and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist.
Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
TWA: 85 mg/m 8 hours.
STEL: 40 ppm 15 minutes.
STEL: 170 mg/m 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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Section 8. Exposure controls/personal protection
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
cobalt bis(2-ethylhexanoate) ACGIH TLV (United States, 3/2016).
TWA: 0.02 mg/m , (as Co) 8 hours.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid. [Paste.]
Not available.
SolventOdor
pH
PinkColor
Not available.
Not available.Odor threshold
:
:
:
:
:
:
Appearance
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Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1 to 1.1
Not available.
Not available.
Not available.
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Viscosity Kinematic (40 C (104 F)): >0.4 cm
2
/s (>40 cSt)
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
Boiling point :Not available.
Flammability (solid, gas):Not available.
Lower and upper explosive
(flammable) limits
:Not available.
Burning rate Not applicable.:
Burning time :Not applicable.
SADT Not available.:
Decomposition temperature:Not available.
Aerosol product
Solubility in water :Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Dermal Rat >2000 mg/kg –
LD50 Oral Rat 2650 mg/kg –
dimethyl glutarate LD50 Dermal Rabbit >5000 mg/kg –
LD50 Oral Rat >5000 mg/kg –
cobalt bis(2-ethylhexanoate)LD50 Dermal Rabbit >5 g/kg –
LD50 Oral Rat >2000 mg/kg –
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
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Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
styrene Eyes – Mild irritant Human – 50 parts per
million
–
Eyes – Moderate irritantRabbit – 24 hours 100
milligrams
–
Eyes – Severe irritantRabbit – 100
milligrams
–
Skin – Mild irritant Rabbit – 500
milligrams
–
Skin – Moderate irritantRabbit – 100 Percent-
Benzene, ethenyl-, polymer
with 1,3-butadiene
Eyes – Mild irritant Rabbit – 24 hours 500
milligrams
–
dimethyl glutarate Eyes – Moderate irritantRabbit – 0.1 Mililiters-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Name Category
Name Category
styrene Category 1 Inhalation hearing organs
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD – Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Classification
styrene – 2B Reasonably anticipated to be a human carcinogen.
Benzene, ethenyl-, polymer
with 1,3-butadiene
– 3 –
cobalt bis(2-ethylhexanoate)- 2B Reasonably anticipated to be a human carcinogen.
Product/ingredient name NTPIARCOSHA
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Section 11. Toxicological information
styrene Chronic NOAEL Dermal Rat 615 mg/kg –
Chronic NOAEL Inhalation
Gas.
Rat 20 ppm 8 hours
Product/ingredient name Result Species Dose Exposure
Causes damage to organs through prolonged or repeated exposure. Once sensitized, a
severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :Suspected of damaging fertility.
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 7943.1 mg/kg
Inhalation (gases) 7096.2 ppm
Inhalation (vapors) 30.23 mg/l
Route ATE value
Acute toxicity estimates
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
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Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
dimethyl glutarate 0.49 – low
cobalt bis(2-ethylhexanoate)- 15600 high
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene – – Readily
cobalt bis(2-ethylhexanoate)- – Not readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae – Pseudokirchneriella
subcapitata
72 hours
Acute EC50 33 mg/l Fresh water Algae – Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia – Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans – Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish – Pimephales promelas 96 hours
Chronic NOEC 1.01 mg/l Daphnia 21 days
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
Resin solution RESIN
SOLUTION
Resin solution
UN1866UN1866 UN1866
DOT
Classification
IMDG IATA
UN number
UN proper
shipping name
TDG
Classification
UN1866
RESIN
SOLUTION
ADR/RID
UN1866
RESIN
SOLUTION
Mexico
Classification
UN1866
RESINA,
SOLUCIONES
DE
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Section 14. Transport information
3
III
3
III
3
III
Reportable
quantity 2862.
1 lbs / 1299.4
kg [326.92 gal /
1237.5 L].
Package sizes
shipped in
quantities less
than the
product
reportable
quantity are
not subject to
the RQ
(reportable
quantity)
transportation
requirements.
Limited
quantity Yes.
Packaging
instruction
Exceptions:
150. Non-bulk:
173. Bulk: 242.
Quantity
limitation
Passenger
aircraft/rail: 60
L. Cargo
aircraft: 220 L.
Special
provisions B1,
B52, IB3, T2,
TP1
Emergency
schedules F-E,
_S-E_
Special
provisions
223, 955
Quantity
limitation
Passenger and
Cargo Aircraft:
60 L.
Packaging
instructions:
355. Cargo
Aircraft Only:
220 L.
Packaging
instructions:
366. Limited
Quantities –
Passenger
Aircraft: 10 L.
Packaging
instructions:
Y344.
Special
provisions A3
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No. No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
3
III
No.
Product
classified as
per the
following
sections of the
Transportation
of Dangerous
Goods
Regulations: 2.
18-2.19 (Class
3).
Explosive
Limit and
Limited
Quantity Index
5
Passenger
Carrying
Road or Rail
Index 60
3
III
No.
Hazard
identification
number 30
Limited
quantity 5 L
Special
provisions
640E
Tunnel code
(D/E)
3
III
No.
Special
provisions 223
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Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS
GLASS
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
styrene 100-42-5 34.939
cobalt bis(2-ethylhexanoate) 136-52-7 0.22559
styrene 100-42-5 34.939
cobalt bis(2-ethylhexanoate) 136-52-7 0.22559
Form R – Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112
(b) Hazardous Air
Pollutants (HAPs)
:Listed
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
DEA List I Chemicals
(Precursor Chemicals)
:Not listed
DEA List II Chemicals
(Essential Chemicals)
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
COBALT compounds
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; COBALT COMPOUNDS
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification :Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
styrene 34.939 Yes. No. No. Yes. Yes.
Benzene, ethenyl-, polymer with 1,
3-butadiene
<2.0797 No. No. No. Yes. No.
dimethyl glutarate <1.3645 No. No. No. Yes. No.
cobalt bis(2-ethylhexanoate) 0.22559 No. No. No. Yes. Yes.
Name % Fire
hazard
Sudden
release of
pressure
Reactive Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
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Section 15. Regulatory information
WARNING: This product contains a chemical known to the State of California to cause cancer. WARNING: This product
contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
styrene Yes. No. - -
1,4-naphthoquinone Yes. No. - -
ethanediol No. Yes. - -
Ingredient name Cancer Reproductive No significant risk
level
Maximum
acceptable dosage
level
International regulations
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventoryNot determined
Section 16. Other information
Hazardous Material Information System (U.S.A.)
3
3
0
0
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/2/2015 Version:1.21 13/14
Poly-Fair T27 R
Section 16. Other information
1/8/2019
History
Date of printing
Date of issue/Date of
revision
Version
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References :Not available.
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
1/8/2019
12/2/2015
1.21
Date of issue/Date of revision :1/8/2019 Date of previous issue :12/2/2015 Version:1.21 14/14
by | Sep 27, 2025
AS Ze
Adhesive Systems, Inc. Page 1/9
A Division Of Royal Adhesives & Sealants LLC. Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/09/2016 Revision Number 1 Revision Date 11/09/2016
1 Identification
Product identifier
+ Trade name: RP Series, SI Series, FS Series, HT Series, MG Series – Adhesives
+ Relevant identified uses of the substance or mixture, Adhesive
+ Details of the supplier of the safety data sheet
– Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
* Information department: Environment protection department.
– Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
7 2 Hazard(s) identification
i Twteation of the substance or mixture
<= = =GHs07
Skin Irrit. 2. H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
Skin Sens. | H317 May cause an allergic skin reaction.
STOT SE 3 H335 May cause respiratory irritation.
Flam. Lig. 4 H227 Combustible liquid.
Label elements
+ GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
* Hazard pictograms
GHS07
+ Signal word Warning
Hazard statements
Combustible liquid.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
May cause respiratory irritation.
Precautionary statements
Keep away from flames and hot surfaces. No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray
(Contd. on page 2)
by | Sep 27, 2025
1
Safety Data Sheet
ES99 Aerosol and Canister
Section 1. Product Description
Product Name: EverStrong ES99 Adhesive Aerosol and Canister
Recommended Use: Vacuum Infusion Molding Adhesive
Manufacturer: NewStar Adhesives Inc, 31 Silver Hill Road, Weston, MA 02493
Information Contact: PH 855-497-0700 FX 770-607-3637
Emergency Contact: 800-424-9300 (CHEMTREC- Transportation Spill Response 24 hours )
Section 2. Hazard Identification
Classification in accordance with OSHA Standard 29CFR 1910.1200
DANGER
Highly flammable liquid and vapor. Pressurized Container: May burst if heated. Causes serious eye irritation.
May cause respiratory irritation, drowsiness or dizziness. May cause damage to organs through prolonged or
repeated exposure. Causes skin irritation.
GHS Classification:
Flammable Gas (Category 1)
Eye Irritation (Category 2)
Skin Irritation ( Category 2)
Specific target organ toxicity (Category 3)
Aspiration hazard (Category 1)
PRECAUTIONARY STATEMENTS:
1. Keep away from heat sparks/open flames/hot surfaces–No Smoking.
2. Avoid breathing dust/fumes/gas/mist/vapors/spray.
3. Wash thoroughly after handling.
4. Use only outdoors or in well ventilated areas.
5. Wear protective gloves/protective clothing/eye protection.
6. If swallowed, immediately call Poison Center or doctor/physician .
7. Do Not Induce Vomiting.
8. If on skin, wash with plenty of soap and water.
9. If inhaled call Poison Center or doctor/physician if you feel unwell.
10. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do. Continue rinsing. If eye irritation persists get medical advice/attention.
11. Take off contaminated clothing before reuse.
12. Store in a well ventilated place.
13. Protect from sunlight.
14. In case of fire, use dry chemicals, CO2 or appropriate foam.
15. Dispose of contents/containers in accordance with local/regional/national/international
regulation.
2
Section 3. Composition/ Information on Ingredients
C.A.S.
Chemical Name Number %
Methyl Acetate 79-20-9 20-30%
Heptane 142-82-5 10-15%
Dimethyl Ether 115-10-6 15-25%
Hydrocarbon Propellants 68476- 86-9 15-25%
Section 4. First Aid Measures
Skin Contact: Wash with plenty of water. Wash contaminated clothing after use.
Inhalation: Remove person to fresh air and keep comfortable for breathing. If respiratory irritation, dizziness,
nausea or unconsciousness occurs, seek medical assistance. If breathing has stopped, give artificial
respiration.
Eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing.
Ingestion: Immediately call a POISON CENTER or doctor/physician if you feel unwell. If exposed or if you feel
unwell get medical advice/attention.
Section 5. Firefighting Procedures
Extinguishing Media: Use dry chemical, CO2 or appropriate foam.
Firefighting Methods and Protection: Firefighters should wear full protective equipment and NIOSH approved
self contained breathing apparatus
Fire and/or Explosion Hazards: Vapors may travel back to ignition source. Containers exposed to heat may
explode.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide.
Further Information: Containers exposed to high heat from fire or other sources may build pressure and
explode. Liquid and vapors are extremely flammable. Use water spray to cool unopened containers.
Section 6. Accidental Release Measures
Personal Precautions: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
Environmental Precautions: Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up: Cover with commercially available nonflammable inorganic absorbent material. Mix
in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Collect waste and dispose of in accordance with all applicable local, state and federal regulations .
3
SECTION 7. Handling and Storage
Handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
breathing vapors. Use personal protection equipment as required. In case of inadequate ventilation wear
respiratory protection. Do not eat, drink or smoke when using this product. Wash contaminated clothing and
skin after use.
Storage: Store in a well ventilated space. Protect from direct sunlight. Do not expose to temperatures
exceeding 50 C/122 F.
SECTION 8. Protection Information
Hazardous Component Authority Type Limit
Methyl Acetate ACGIH TWA 200 ppm
Methyl Acetate ACGIH STEL 250 ppm
Methyl Acetate OSHA TWA 200 ppm
Methyl Acetate OSHA STEL 250 ppm
Heptane ACGIH TWA 400 ppm
Heptane ACGIH STEL 500 ppm
Heptane OSHA TWA 400 ppm
Heptane OSHA STEL, Vacated 500 ppm
Dimethyl Ether AIHA TWA 1000 ppm
Dimethyl Ether CMRG TWA 1000 ppm
Hydrocarbon Propellants ACGIH TWA 1000 ppm
Hydrocarbon Prop ellants OSHA TWA 1000 ppm
SOURCES OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
CMRG: Chemical Manufacturer Recommended Guideline
EPA: Environmental Protection Agency
IARC: International Agency for the Research on Cancer
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
WEEL Workplace Environmental Exposure Level
Control Parameters
Engineering Measures: Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment (PPE):
Eyes/Face: Safety goggles or safety glasses with ide shields .
Skin: Protective gloves such as Viton, PVA or equivalent and impervious clothing.
Respiratory: In operations where exposure limits are exceeded, use a NIOSH approved
respirator suitable for the specific work conditions.
Hygiene: Avoid contact with skin, eyes and clothing. Wash promptly with soap and water
if skin becomes contaminated. Remove and wash contaminated clothing after
use. Do not eat, drink or smoke when using.
4
SECTION 9. Physical Data
Odor, Color: Organic solvent odor, clear or blue in color
Boiling point: Not Determined
Vapor Pressure Not Determined
Vapor Density Not Determined
Specific Gravity .70-.74 g/cc
Solubility in Water: Negligible
Volatile Organic Compounds: <55% by weight
Flash Point -156 F (-104 C)
LEL 1.8
UEL 18
SECTION 10. Stability and Reactivity
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Keep away from open flames, hot surfaces, static electricity and sources of ignition.
Incompatible Materials: None known.
Hazardous Polymerization: Will not occur.
Hazardous By-Products: Combustion may result in formation of aldehydes, hydrocarbons, carbon monoxide
and carbon dioxide.
SECTION 11. Toxicological Information
Typical Routes of Entry: Inhalation, skin absorption, eye contact
Reproductive toxicity: No data
Mutagenicity: No data
STOT-single exposure: No data
STOT-repeat exposure: No data
Aspiration Hazard: No data
Acute Toxicity: No data
Irritation: No data
Corrosivity: No data
Sensitisation: No data
Chronic Toxicity/ Carcinogenicity:
There is no data indicating this mixture contains any chemicals which can cause cancer.
SECTION 12. Ecological Data
Overview: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife.
Mobility: No data
Persistence: No data
SECTION 13. Disposal Considerations
Waste Disposal Method:
Dispose of only by a permitted hazardous waste TSD facility in accordance with all local, state and federal regulations.
5
SECTION 14. Transportation Information
REGULATION DESCRIPTION
DOT
Proper Shipping Name Liquified Gas, Flammable, N.O.S.(Contains Heptane )
Hazard Class 2.1
UN # UN3161
Packing Group None
Label DOT Flammable Gas 2 red diamond
SECTION 15. Regulatory Information
311/312 Hazard Categories:
Fire Hazard Yes;
Pressure Hazard Yes;
Reactivity Hazard No;
Immediate Hazard Yes;
Delayed Hazard Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part
372 (EPCRA):
Ingredient C.A.S. Number % by Wt.
None
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. Number Classification
None
US-TSCA:
All hazardous components are on TSCA.
WHMIS:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
HMIS Hazard Rating
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
Health: 2
Flammability: 4
Reactivity: 0
Special Hazard: None
SECTION 16. Other Information
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. NEWSTAR
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. The user is
responsible for determining whether the NEWSTAR product is fit for a particular purpose and suitable for users method of
use or application, given the variety of factors that can affect the use and application of a NEWSTAR product, many of
which are solely within the user s knowledge and control. It is essential that the user evaluate the NEWSTAR product to
determine whether it is fit for a particular purpose and suitable for users method of use or application.
SDS Issue Date: May 12, 2016
Supersedes: May 21, 2015
by | Sep 27, 2025
1
Safety Data Sheet
ES99 Aerosol and Canister
Section 1. Product Description
Product Name: EverStrong ES99 Adhesive Aerosol and Canister
Recommended Use: Vacuum Infusion Molding Adhesive
Manufacturer: NewStar Adhesives Inc, 31 Silver Hill Road, Weston, MA 02493
Information Contact: PH 855-497-0700 FX 770-607-3637
Emergency Contact: 800-424-9300 (CHEMTREC- Transportation Spill Response 24 hours )
Section 2. Hazard Identification
Classification in accordance with OSHA Standard 29CFR 1910.1200
DANGER
Highly flammable liquid and vapor. Pressurized Container: May burst if heated. Causes serious eye irritation.
May cause respiratory irritation, drowsiness or dizziness. May cause damage to organs through prolonged or
repeated exposure. Causes skin irritation.
GHS Classification:
Flammable Gas (Category 1)
Eye Irritation (Category 2)
Skin Irritation ( Category 2)
Specific target organ toxicity (Category 3)
Aspiration hazard (Category 1)
PRECAUTIONARY STATEMENTS:
1. Keep away from heat sparks/open flames/hot surfaces–No Smoking.
2. Avoid breathing dust/fumes/gas/mist/vapors/spray.
3. Wash thoroughly after handling.
4. Use only outdoors or in well ventilated areas.
5. Wear protective gloves/protective clothing/eye protection.
6. If swallowed, immediately call Poison Center or doctor/physician .
7. Do Not Induce Vomiting.
8. If on skin, wash with plenty of soap and water.
9. If inhaled call Poison Center or doctor/physician if you feel unwell.
10. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do. Continue rinsing. If eye irritation persists get medical advice/attention.
11. Take off contaminated clothing before reuse.
12. Store in a well ventilated place.
13. Protect from sunlight.
14. In case of fire, use dry chemicals, CO2 or appropriate foam.
15. Dispose of contents/containers in accordance with local/regional/national/international
regulation.
2
Section 3. Composition/ Information on Ingredients
C.A.S.
Chemical Name Number %
Methyl Acetate 79-20-9 20-30%
Heptane 142-82-5 10-15%
Dimethyl Ether 115-10-6 15-25%
Hydrocarbon Propellants 68476- 86-9 15-25%
Section 4. First Aid Measures
Skin Contact: Wash with plenty of water. Wash contaminated clothing after use.
Inhalation: Remove person to fresh air and keep comfortable for breathing. If respiratory irritation, dizziness,
nausea or unconsciousness occurs, seek medical assistance. If breathing has stopped, give artificial
respiration.
Eyes: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing.
Ingestion: Immediately call a POISON CENTER or doctor/physician if you feel unwell. If exposed or if you feel
unwell get medical advice/attention.
Section 5. Firefighting Procedures
Extinguishing Media: Use dry chemical, CO2 or appropriate foam.
Firefighting Methods and Protection: Firefighters should wear full protective equipment and NIOSH approved
self contained breathing apparatus
Fire and/or Explosion Hazards: Vapors may travel back to ignition source. Containers exposed to heat may
explode.
Hazardous Combustion Products: Carbon dioxide, carbon monoxide.
Further Information: Containers exposed to high heat from fire or other sources may build pressure and
explode. Liquid and vapors are extremely flammable. Use water spray to cool unopened containers.
Section 6. Accidental Release Measures
Personal Precautions: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Remove all sources of ignition. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
Environmental Precautions: Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up: Cover with commercially available nonflammable inorganic absorbent material. Mix
in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Collect waste and dispose of in accordance with all applicable local, state and federal regulations .
3
SECTION 7. Handling and Storage
Handling: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoid
breathing vapors. Use personal protection equipment as required. In case of inadequate ventilation wear
respiratory protection. Do not eat, drink or smoke when using this product. Wash contaminated clothing and
skin after use.
Storage: Store in a well ventilated space. Protect from direct sunlight. Do not expose to temperatures
exceeding 50 C/122 F.
SECTION 8. Protection Information
Hazardous Component Authority Type Limit
Methyl Acetate ACGIH TWA 200 ppm
Methyl Acetate ACGIH STEL 250 ppm
Methyl Acetate OSHA TWA 200 ppm
Methyl Acetate OSHA STEL 250 ppm
Heptane ACGIH TWA 400 ppm
Heptane ACGIH STEL 500 ppm
Heptane OSHA TWA 400 ppm
Heptane OSHA STEL, Vacated 500 ppm
Dimethyl Ether AIHA TWA 1000 ppm
Dimethyl Ether CMRG TWA 1000 ppm
Hydrocarbon Propellants ACGIH TWA 1000 ppm
Hydrocarbon Prop ellants OSHA TWA 1000 ppm
SOURCES OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
CMRG: Chemical Manufacturer Recommended Guideline
EPA: Environmental Protection Agency
IARC: International Agency for the Research on Cancer
NIOSH: National Institute for Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
WEEL Workplace Environmental Exposure Level
Control Parameters
Engineering Measures: Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment (PPE):
Eyes/Face: Safety goggles or safety glasses with ide shields .
Skin: Protective gloves such as Viton, PVA or equivalent and impervious clothing.
Respiratory: In operations where exposure limits are exceeded, use a NIOSH approved
respirator suitable for the specific work conditions.
Hygiene: Avoid contact with skin, eyes and clothing. Wash promptly with soap and water
if skin becomes contaminated. Remove and wash contaminated clothing after
use. Do not eat, drink or smoke when using.
4
SECTION 9. Physical Data
Odor, Color: Organic solvent odor, clear or blue in color
Boiling point: Not Determined
Vapor Pressure Not Determined
Vapor Density Not Determined
Specific Gravity .70-.74 g/cc
Solubility in Water: Negligible
Volatile Organic Compounds: <55% by weight
Flash Point -156 F (-104 C)
LEL 1.8
UEL 18
SECTION 10. Stability and Reactivity
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Keep away from open flames, hot surfaces, static electricity and sources of ignition.
Incompatible Materials: None known.
Hazardous Polymerization: Will not occur.
Hazardous By-Products: Combustion may result in formation of aldehydes, hydrocarbons, carbon monoxide
and carbon dioxide.
SECTION 11. Toxicological Information
Typical Routes of Entry: Inhalation, skin absorption, eye contact
Reproductive toxicity: No data
Mutagenicity: No data
STOT-single exposure: No data
STOT-repeat exposure: No data
Aspiration Hazard: No data
Acute Toxicity: No data
Irritation: No data
Corrosivity: No data
Sensitisation: No data
Chronic Toxicity/ Carcinogenicity:
There is no data indicating this mixture contains any chemicals which can cause cancer.
SECTION 12. Ecological Data
Overview: Moderate ecological hazard. This product may be dangerous to plants and/or wildlife.
Mobility: No data
Persistence: No data
SECTION 13. Disposal Considerations
Waste Disposal Method:
Dispose of only by a permitted hazardous waste TSD facility in accordance with all local, state and federal regulations.
5
SECTION 14. Transportation Information
REGULATION DESCRIPTION
DOT
Proper Shipping Name Liquified Gas, Flammable, N.O.S.(Contains Heptane )
Hazard Class 2.1
UN # UN3161
Packing Group None
Label DOT Flammable Gas 2 red diamond
SECTION 15. Regulatory Information
311/312 Hazard Categories:
Fire Hazard Yes;
Pressure Hazard Yes;
Reactivity Hazard No;
Immediate Hazard Yes;
Delayed Hazard Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part
372 (EPCRA):
Ingredient C.A.S. Number % by Wt.
None
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. Number Classification
None
US-TSCA:
All hazardous components are on TSCA.
WHMIS:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
HMIS Hazard Rating
0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme
Health: 2
Flammability: 4
Reactivity: 0
Special Hazard: None
SECTION 16. Other Information
DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. NEWSTAR
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. The user is
responsible for determining whether the NEWSTAR product is fit for a particular purpose and suitable for users method of
use or application, given the variety of factors that can affect the use and application of a NEWSTAR product, many of
which are solely within the user s knowledge and control. It is essential that the user evaluate the NEWSTAR product to
determine whether it is fit for a particular purpose and suitable for users method of use or application.
SDS Issue Date: May 12, 2016
Supersedes: May 21, 2015
by | Sep 27, 2025
Page 1/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/18/2016 Revision Date 11/18/2016Revision Number 1
43.0
* 1 Identification
Product identifier
Trade name: Quick-Tac 2 (Liquid)
Relevant identified uses of the substance or mixture.
Adhesive
Activator
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) USA
Page 2/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/18/2016 Revision Date 11/18/2016Revision Number 1
Trade name: Quick-Tac 2 (Liquid)
(Contd. of page 1)
43.0
Hazard pictograms
GHS02GHS06GHS07GHS08
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Toxic if swallowed, in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
Call a POISON CENTER/doctor.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Rinse mouth.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
(Contd. on page 3)
USA
Page 3/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/18/2016 Revision Date 11/18/2016Revision Number 1
Trade name: Quick-Tac 2 (Liquid)
(Contd. of page 2)
43.0
HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
0
Health = 2
Fire = 3
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
67-64-1 acetone 50-100%
99-97-8 N,N-dimethyl-p-toluidine 1.0%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
Rinse mouth with water.
Seek medical treatment.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
USA
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Prevent seepage into sewage system, workpits and cellars.
Inform respective authorities in case of seepage into water course or sewage system.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep container closed when not in use.
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Store as flammable liquid.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
67-64-1 acetone
PEL Long-term value: 2400 mg/m , 1000 ppm
(Contd. on page 5)
USA
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REL Long-term value: 590 mg/m , 250 ppm
TLV Short-term value: 1187 mg/m , 500 ppm
Long-term value: 594 mg/m , 250 ppm
BEI
99-97-8 N,N-dimethyl-p-toluidine
WEEL Long-term value: 0.5 ppm
Ingredients with biological limit values:
67-64-1 acetone
BEI 50 mg/L
Medium: urine
Time: end of shift
Parameter: Acetone (nonspecific)
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Face shield over protective glasses or goggles.
Safety glasses with side shields.
Tightly sealed goggles
Body protection:Protective work clothing
USA
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* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Clear, light amber
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point: Undetermined.
Boiling point: 55 C (131 F)
Flash point: -17 C (1 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 465 C (869 F)
Decomposition temperature: Not determined.
Auto igniting: 465C (869.0F)
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Flammable limits:
Lower: 2.6 Vol %
Upper: 13.0 Vol %
Vapor pressure at 20 C (68 F):245.3 hPa (184 mm Hg)
Specific gravity at 20 C (68 F):0.791 g/cm (6.601 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined
Solubility in / Miscibility with
Water: Miscible
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: Not available
Solids content: Not available
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsForms explosive gas mixture with air.
(Contd. on page 7)
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Conditions to avoid
Heat, flames, sparks.
Exposure to high temperatures.
Direct sunlight
Incompatible materials:
Reacts with oxidizing agents.
Reacts with reducing agents.
Reacts with alkalis (bases)
Acetone reacts violently with phosphorous oxychloride.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
67-64-1 acetone
Oral LD50 5800 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
Primary irritant effect:
on the skin:May irritate the skin.
on the eye:
Irritating effect.
Vapors may be irritating to the eyes.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 8)
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vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1090
UN proper shipping name
DOT Acetone
IMDG, IATA ACETONE
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 1090 ACETONE, 3, II
USA
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
99-97-8 N,N-dimethyl-p-toluidine
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
New Jersey Right-to-Know List:
67-64-1 acetone
New Jersey Special Hazardous Substance List:
67-64-1 acetone F3
Pennsylvania Right-to-Know List:
67-64-1 acetone
Pennsylvania Special Hazardous Substance List:
67-64-1 acetone E
Cancerogenity categories
EPA (Environmental Protection Agency)
67-64-1 acetone I
TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
(Contd. on page 10)
USA
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Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:11/18/2016
Date of preparation / last revision11/18/2016 / –
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Acute Tox. 3: Acute toxicity Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
USA
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* 1 Identification
Product identifier
Trade name: Quick-Tac 2 (Liquid)
Relevant identified uses of the substance or mixture.
Adhesive
Activator
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Adhesive Systems, Inc.
A Division of Royal Adhesives & Sealants, LLC
9411 Corsair Road
Frankfort, Illinois 60423
Phone Number: 800-552-0299
Information department:Environment protection department.
Emergency telephone number:
ChemTrec: Day or Night within USA and Canada: 1-800-424-9300.
Outside USA and Canada: +1 703-527-3887 (collect calls accepted)
* 2 Hazard(s) identification
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 Health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 2) USA
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Hazard pictograms
GHS02GHS06GHS07GHS08
Signal wordDanger
Hazard statements
Highly flammable liquid and vapor.
Toxic if swallowed, in contact with skin or if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves / eye protection / face protection.
Wear protective gloves / protective clothing.
Ground/bond container and receiving equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see on this label).
Call a POISON CENTER/doctor.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Rinse mouth.
In case of fire: Use for extinction: CO2, powder or water spray.
Take off immediately all contaminated clothing and wash it before reuse.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 – 4)
2
3
0
Health = 2
Fire = 3
Reactivity = 0
(Contd. on page 3)
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HMIS-ratings (scale 0 – 4)
HEALTH
FIRE
PHYSICAL HAZARD
2
3
0
Health = 2
Fire = 3
Physical Hazard = 0
Other hazards
Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
* 3 Composition/information on ingredients
Chemical characterization: Mixtures
Description:Mixture
Hazardous components:
67-64-1 acetone 50-100%
99-97-8 N,N-dimethyl-p-toluidine 1.0%
* 4 First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:
Rinse mouth with water.
Seek medical treatment.
Information for doctor:
Most important symptoms and effects, both acute and delayedNo further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
* 5 Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixtureNo further relevant information available.
Advice for firefighters
Firefighters use standard protective equipment including flame retardant coat, helmet with face shield, gloves,
rubber boots, and in enclosed spaces, SCBA.
Protective equipment:Protective clothing and respiratory protective device.
USA
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* 6 Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Prevent seepage into sewage system, workpits and cellars.
Inform respective authorities in case of seepage into water course or sewage system.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste in accordance with federal state and local regulations.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
* 7 Handling and storage
Handling:
Precautions for safe handling
Open and handle receptacle with care.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Keep container closed when not in use.
Keep ignition sources away – Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:Store in a cool location away from direct heat.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Store as flammable liquid.
Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Specific end use(s)No further relevant information available.
* 8 Exposure controls/personal protection
Additional information about design of technical systems:No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
67-64-1 acetone
PEL Long-term value: 2400 mg/m , 1000 ppm
(Contd. on page 5)
USA
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REL Long-term value: 590 mg/m , 250 ppm
TLV Short-term value: 1187 mg/m , 500 ppm
Long-term value: 594 mg/m , 250 ppm
BEI
99-97-8 N,N-dimethyl-p-toluidine
WEEL Long-term value: 0.5 ppm
Ingredients with biological limit values:
67-64-1 acetone
BEI 50 mg/L
Medium: urine
Time: end of shift
Parameter: Acetone (nonspecific)
Additional information:The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment (see listings below)
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
Use approved respiratory protection equipment when airborne exposure is excessive. Consult the respirator
manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use
limitations specified by the manufacturer.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Material of gloves
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Face shield over protective glasses or goggles.
Safety glasses with side shields.
Tightly sealed goggles
Body protection:Protective work clothing
USA
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* 9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Color: Clear, light amber
Odor: Characteristic
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point: Undetermined.
Boiling point: 55 C (131 F)
Flash point: -17 C (1 F)
Flammability (solid, gaseous):Not applicable.
Ignition temperature: 465 C (869 F)
Decomposition temperature: Not determined.
Auto igniting: 465C (869.0F)
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Flammable limits:
Lower: 2.6 Vol %
Upper: 13.0 Vol %
Vapor pressure at 20 C (68 F):245.3 hPa (184 mm Hg)
Specific gravity at 20 C (68 F):0.791 g/cm (6.601 lbs/gal)
Relative density Not determined.
Vapor density Not determined.
Evaporation rate Not determined
Solubility in / Miscibility with
Water: Miscible
Partition coefficient (n-octanol/water):Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: Not available
Solids content: Not available
Other information No further relevant information available.
* 10 Stability and reactivity
ReactivityNo further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications.
Possibility of hazardous reactionsForms explosive gas mixture with air.
(Contd. on page 7)
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Conditions to avoid
Heat, flames, sparks.
Exposure to high temperatures.
Direct sunlight
Incompatible materials:
Reacts with oxidizing agents.
Reacts with reducing agents.
Reacts with alkalis (bases)
Acetone reacts violently with phosphorous oxychloride.
Hazardous decomposition products:Carbon monoxide and carbon dioxide
* 11 Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
67-64-1 acetone
Oral LD50 5800 mg/kg (rat)
Dermal LD50 20000 mg/kg (rabbit)
Primary irritant effect:
on the skin:May irritate the skin.
on the eye:
Irritating effect.
Vapors may be irritating to the eyes.
Sensitization:No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
* 12 Ecological information
Toxicity
Aquatic toxicity:No further relevant information available.
Persistence and degradabilityNo further relevant information available.
Behavior in environmental systems:
Bioaccumulative potentialNo further relevant information available.
Mobility in soilNo further relevant information available.
Additional ecological information:
General notes:At present there are no ecotoxicological assessments.
Results of PBT and vPvB assessment
PBT:Not applicable.
(Contd. on page 8)
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vPvB:Not applicable.
Other adverse effectsNo further relevant information available.
* 13 Disposal considerations
Waste treatment methods
Recommendation:Must be specially treated adhering to official regulations.
Uncleaned packagings:
Recommendation:Disposal must be made according to official regulations.
* 14 Transport information
UN-Number
DOT, IMDG, IATA UN1090
UN proper shipping name
DOT Acetone
IMDG, IATA ACETONE
Transport hazard class(es)
DOT
Class 3 Flammable liquids
Label 3
IMDG, IATA
Class 3 Flammable liquids
Label 3
Packing group
DOT, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable liquids
Danger code (Kemler): 33
EMS Number: F-E,S-D
Stowage Category E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN “Model Regulation”: UN 1090 ACETONE, 3, II
USA
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* 15 Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
Proposition 65
Chemicals known to cause cancer:
99-97-8 N,N-dimethyl-p-toluidine
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
(DSL) Canada Dosmestic Substance List
All components of this product are on the DSL(Canada Domestic Substance list) or are exempt from DSL
requirements.
New Jersey Right-to-Know List:
67-64-1 acetone
New Jersey Special Hazardous Substance List:
67-64-1 acetone F3
Pennsylvania Right-to-Know List:
67-64-1 acetone
Pennsylvania Special Hazardous Substance List:
67-64-1 acetone E
Cancerogenity categories
EPA (Environmental Protection Agency)
67-64-1 acetone I
TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
National regulations:
Water hazard class:Water hazard class 1 (Self-assessment): slightly hazardous for water.
(Contd. on page 10)
USA
Page 10/10
Safety Data Sheet
acc. to OSHA HCS
Printing Date 11/18/2016 Revision Date 11/18/2016Revision Number 1
Trade name: Quick-Tac 2 (Liquid)
(Contd. of page 9)
43.0
Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
* 16 Other information
Although the information and recommendations set forth in this SDS are presented in good faith and are believed
to be correct as of the date of this SDS, Royal Adhesives & Sealants makes no representations as to the
completeness or accuracy thereof. Information is supplied on the condition that the persons receiving and using it
will make their own determination as to the suitability for their purpose prior to use. In no event will Royal
Adhesives & Sealants or any affiliate thereof be responsible for damages of any nature whatsoever resulting from
the use or reliance on the information set forth in the SDS.
Department issuing SDS:Environment protection department.
Creation Date:11/18/2016
Date of preparation / last revision11/18/2016 / –
Abbreviations and acronyms:
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BEI: Biological Exposure Limit
Flam. Liq. 2: Flammable liquids Category 2
Acute Tox. 3: Acute toxicity Category 3
Skin Irrit. 2: Skin corrosion/irritation Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A
STOT SE 3: Specific target organ toxicity (single exposure) Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2
USA
by | Sep 27, 2025
COR-Grip Cmpd
Unsaturated Polyester Resin Compound
Liquid.
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
:
:
Supplier’s details :INTERPLASTIC CORPORATION
1225 Willow Lake Boulevard
St. Paul, MN 55110-5145
651.481.6860
COR-Grip Cmpd
Relevant identified uses of the substance or mixture and uses advised against
Product code :PA-160-PMMN
Industrial applications.
CHEMTREC 24-Hour Emergency Telephone
US and Canada 800.424.9300
Outside US and Canada +1 703.741.5970
Section 2. Hazards identification
FLAMMABLE LIQUIDS – Category 3
ACUTE TOXICITY (inhalation) – Category 4
SKIN IRRITATION – Category 2
EYE IRRITATION – Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) – Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
respiratory system) – Category 1
Classification of the
substance or mixture
:
Signal word :Danger
Hazard statements :Flammable liquid and vapor.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
May cause respiratory irritation.
Causes damage to organs through prolonged or repeated exposure. (hearing organs,
respiratory system)
Hazard pictograms :
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 13.4%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 45.5%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 23%
OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
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COR-Grip Cmpd PA-160-PMMN
Section 2. Hazards identification
Prevention :Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Do
not eat, drink or smoke when using this product. Wash hands thoroughly after handling.
Response :Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage :Store in a well-ventilated place. Keep cool. Store containers in a safe place.
Disposal :Dispose of contents and container in accordance with all local, regional, national and
international regulations. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Hazards not otherwise
classified
:None known.
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:Unsaturated Polyester Resin Compound
Substance/mixture :
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Any concentration shown as exact is based on formula.
VOC content is listed in Section 9.
Environmental composition is shown in Section 15.
styrene <= 23.0 100-42-5
talc (none asbestiform) <= 15.0 14807-96-6
Man-made mineral fibers <= 10.0 65997-17-3
Ingredient name % CAS number
Section 4. First aid measures
Eye contact :
Description of necessary first aid measures
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention. Buffered baby shampoo will aid in removal of resin.
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COR-Grip Cmpd PA-160-PMMN
Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention following
exposure or if feeling unwell. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Remove contaminated clothing and shoes. Flush contaminated skin with plenty of
water. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact
Inhalation
Ingestion :
:
:
Protection of first-aiders:No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments :No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical, CO , water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill :
Small spill :
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders:If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations (see Section 13). Dispose
of via a licensed waste disposal contractor. Contaminated absorbent material may pose
the same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal. Wear appropriate respiratory protection.
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Absorb with an inert material and transfer the spilled material and absorbent to an
appropriate waste disposal container. Wear appropriate respirator when ventilation is
inadequate. Wear eye/face protection.
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Section 6. Accidental release measures
Wear protective clothing and eye or face protection:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Do not store above the following temperature: 38 C (100.4 F). Store in accordance with
local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate all ignition
sources. Separate from oxidizing materials. Keep container tightly closed and sealed
until ready for use. Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination. See Section 10 for incompatible
materials before handling or use. Store containers in a safe place.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8). Do not breathe
vapor or mist. Do not ingest. Avoid contact with eyes, skin and clothing. Use only with
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do
not enter storage areas and confined spaces unless adequately ventilated. Keep in the
original container or an approved alternative made from a compatible material, kept
tightly closed when not in use. Store and use away from heat, sparks, open flame or
any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Take precautionary
measures against electrostatic discharges. Empty containers retain product residue
and can be hazardous. Do not reuse container.
:
Precautions for safe handling
styrene ACGIH TLV (United States, 3/2019).
TWA: 20 ppm 8 hours.
STEL: 40 ppm 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 50 ppm 8 hours.
TWA: 215 mg/m 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
OSHA PEL Z2 (United States, 2/2013).
TWA: 100 ppm 8 hours.
CEIL: 200 ppm
AMP: 600 ppm 5 minutes.
NIOSH REL (United States, 10/2016).
TWA: 50 ppm 10 hours.
TWA: 215 mg/m 10 hours.
STEL: 100 ppm 15 minutes.
STEL: 425 mg/m 15 minutes.
talc (none asbestiform) OSHA PEL 1989 (United States, 3/1989).
TWA: 2 mg/m 8 hours. Form: Respirable dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Control parameters
Occupational exposure limits
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COR-Grip Cmpd PA-160-PMMN
Section 8. Exposure controls/personal protection
NIOSH REL (United States, 10/2016).
TWA: 2 mg/m 10 hours. Form: Respirable fraction
ACGIH TLV (United States, 3/2019).
TWA: 2 mg/m 8 hours. Form: Respirable fraction
Man-made mineral fibers NIOSH REL (United States, 10/2016).
TWA: 3 f/cc 10 hours. Form: Fibers of spec length
TWA: 3 f/cc 10 hours.
TWA: 5 mg/m 10 hours. Form: Total
ACGIH TLV (United States, 3/2019).
TWA: 5 mg/m 8 hours. Form: Inhalable fraction
TWA: 1 f/cc 8 hours. Form: Respirable fibers: length greater than 5
uM; aspect ratio equal to or greater than 3:1 as determined by the
membrane filter method at 400-450X magnification (4-mm objective)
phase contrast illumination.
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Environmental exposure
controls
:Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures :
Individual protection measures
Skin protection
Other skin protection :Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
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COR-Grip Cmpd PA-160-PMMN
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.9 to 1.3
3.6 [Air = 1]
0.67 kPa (5 mm Hg) [room temperature]
Not available.
Sweetish.Odor
pH
Tan. [Light]Color
Evaporation rate <1 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: 31 C (87.8 F)
Not available.
Not applicable.
Viscosity Not available.
0.1 ppmOdor threshold
Partition coefficient: n-
octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point :145 C (293 F)
Lower and upper explosive
(flammable) limits
:Lower: 0.9%
Upper: 6.8%
Solubility in water :Not applicable.
VOC content :23.6 % (w/w) As shipped, including monomers and additives.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials:
oxidizing materials
:
:
:
Incompatible materials :
Possibility of hazardous
reactions
:Hazardous reactions or instability may occur under certain conditions of storage or use.
Reactivity :No specific test data related to reactivity available for this product or its ingredients.
Polymerization may occur under certain conditions of storage and use. Keep away from
heat and flame. Keep away from oxidizing agents.
Reactive or incompatible with the following materials: acids and alkalis.
Incompatible with alkali metals. Incompatible with some alkalis. Incompatible with some
strong acids.
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Section 11. Toxicological information
Acute toxicity
styrene LC50 Inhalation Gas. Rat 2770 ppm 4 hours
LC50 Inhalation Vapor Rat 11800 mg/m 4 hours
LD50 Oral Rat 2650 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
Not available.
Conclusion/Summary :
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
styrene Eyes - Mild irritant Human - 50 ppm -
Eyes - Moderate irritantRabbit - 24 hours 100
mg
-
Eyes - Severe irritantRabbit - 100 mg -
Skin - Mild irritant Rabbit - 500 mg -
Skin - Moderate irritantRabbit - 100 % -
talc (none asbestiform) Skin - Mild irritant Human - 72 hours 300
ug I
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
styrene Category 3 Not applicable.Respiratory tract
irritation
Man-made mineral fibers Category 3 Not applicable.Respiratory tract
irritation
Name Category Route of
exposure
Target organs
Information on toxicological effects
Classification
styrene - 2A Reasonably anticipated to be a human carcinogen.
talc (none asbestiform) - 3 -
Man-made mineral fibers - 3 -
Product/ingredient name NTPIARCOSHA
Styrene manufacturers have determined that the weight of evidence for the
carcinogenicity of this substance does not meet the criteria for classification.
In 2018, styrene was listed by IARC as a probable carcinogen to humans (Group 2A)
based on hazard assessment data. The United States NTP listed styrene as reasonably
anticipated to be a human carcinogen based on "limited evidence" from studies in
humans, "sufficient evidence" from studies in experimental animals, and supporting
data on mechanisms of carcinogenesis. The significance of these results for humans
has not been established through risk assessment.
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COR-Grip Cmpd PA-160-PMMN
Section 11. Toxicological information
Not available.
Information on the likely
routes of exposure
Inhalation :Harmful if inhaled. May cause respiratory irritation.
No known significant effects or critical hazards.:Ingestion
Skin contact :Causes skin irritation.
Causes serious eye irritation.:Eye contact
Causes damage to organs through prolonged or repeated exposure.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact :Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (repeated exposure)
Name Category
styrene Category 1 Inhalation hearing organs
talc (none asbestiform) Category 1 Inhalation Not determined
Man-made mineral fibers Category 1 Not determinedrespiratory system
Aspiration hazard
Name Result
styrene ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
:Not available.
Potential acute health effects
Potential immediate
effects
:Not available.
Short term exposure
Potential delayed effects:Not available.
Potential immediate
effects
:Not available.
Long term exposure
Potential delayed effects:Not available.
A study of long term effects of workers exposed to styrene levels in the range of 25-35 ppm for an 8-hour TWA indicated
a possible mild hearing loss.
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Section 11. Toxicological information
No known significant effects or critical hazards.Teratogenicity :
Developmental effects :No known significant effects or critical hazards.
Fertility effects :No known significant effects or critical hazards.
Numerical measures of toxicity
Oral 9039.7 mg/kg
Inhalation (gases) 9492.5 ppm
Inhalation (vapors) 40.44 mg/l
Route ATE value
Acute toxicity estimates
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects :No known significant effects or critical hazards.
Product/ingredient name
styrene 0.35 13.49 low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
styrene - - Readily
Toxicity
styrene Acute EC50 1400 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
72 hours
Acute EC50 720 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Acute EC50 4700 g/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 52 mg/l Marine water Crustaceans - Artemia salina48 hours
Acute LC50 4020 g/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 63 g/l Fresh water Algae - Pseudokirchneriella
subcapitata
96 hours
Product/ingredient name SpeciesResult Exposure
Persistence and degradability
styrene OECD 70 % - Readily - 28 days - -
Product/ingredient name Test DoseResult Inoculum
Soil/water partition
coefficient (KOC)
:Not available.
Mobility in soil
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Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
RESIN
SOLUTION
3
III
RESIN
SOLUTION
3
III
RESIN
SOLUTION
UN1866
3
III
UN1866 UN1866
Reportable quantity 4452.7 lbs / 2021.5 kg [485.48 gal / 1837.8 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
DOT
Classification
IMDGIATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No. No.No.
Transport within user s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:Not available.
:
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
Mexico
Classification
UN1866
RESIN
SOLUTION
3
III
No.
DOT Classification
TDG Classification
:
:
TDG
Classification
UN1866
RESIN
SOLUTION
3
III
No.
Date of issue/Date of revision :11/30/2020 Date of previous issue :3/18/2020 Version:3 11/14
COR-Grip Cmpd PA-160-PMMN
Section 15. Regulatory information
U.S. Federal regulations
The following components are listed: STYRENE; PHENYLETHYLENE; FIBROUS GLASS;
MAGNESITE DUST; TALC; SOAPSTONE
Clean Water Act (CWA) 311: styrene; propionic acid
Massachusetts
:
:
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Styrene
-Methyl styrene
Ethylene Glycol
Silica, crystalline
Form R - Reporting
requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b)
Hazardous Air Pollutants
(HAPs)
:
Clean Air Act Section 602
Class I Substances
:Not listed
Clean Air Act Section 602
Class II Substances
:Not listed
New York :The following components are listed: Styrene
New Jersey :The following components are listed: STYRENE MONOMER; BENZENE, ETHENYL-;
MAGNESITE; CARBONIC ACID, MAGNESIUM SALT (1:1); SOAPSTONE;
ISOPROPENYL BENZENE; alpha-METHYLSTYRENE
Pennsylvania :The following components are listed: BENZENE, ETHENYL-; TALC; SOAPSTONE DUST
State regulations
TSCA 8(a) PAIR: N,N-dimethylaniline
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
SARA 302/304
SARA 304 RQ :625000 lbs / 283750 kg [68144.4 gal / 257954.5 L]
1,4-dihydroxybenzene <0.1 Yes.500 / 10000- 100 -
Composition/information on ingredients
Name % EHS(lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312
Classification :FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs, respiratory
system) - Category 1
:The following components are listed. For more information go to www.P65Warnings.ca.gov.
styrene 100-42-5 <= 23.0
styrene 100-42-5 22.46
Any concentration shown as exact is based on formula.
Listed
If components are "Listed", and additional information is required, contact Supplier
using email in Section 16.
Date of issue/Date of revision :11/30/2020 Date of previous issue :3/18/2020 Version:3 12/14
COR-Grip Cmpd PA-160-PMMN
Section 15. Regulatory information
Inventory list
Australia :Not determined.
Canada :All components are listed or exempted.
China :All components are listed or exempted.
Europe :Not determined.
Japan :Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
Republic of Korea :All components are listed or exempted.
Malaysia :Not determined.
New Zealand :All components are listed or exempted.
Philippines :Not determined.
Taiwan :All components are listed or exempted.
Turkey :Not determined.
United States :All components are listed or exempted.
Thailand :Not determined.
Viet Nam :All components are listed or exempted.
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
3
1
1
3
2
*
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS
ratings are to be used with a fully implemented HMIS program. HMIS is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS
Personal Protective Equipment (PPE) codes, consult the HMIS Implementation Manual.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
Date of issue/Date of revision :11/30/2020 Date of previous issue :3/18/2020 Version:3 13/14
COR-Grip Cmpd PA-160-PMMN
Section 16. Other information
11/30/2020
History
Date of printing
Date of issue/Date of
revision
Version
Prepared by
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
Notice to reader
Date of previous issue
:
:
:
:
:
Indicates information that has changed from previously issued version.
References :
Key to abbreviations :ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
11/30/2020
3/18/2020
3
Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN IRRITATION - Category 2 Calculation method
EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (hearing organs,
respiratory system) - Category 1
Calculation method
Health, Safety and Environmental Department
For questions about the
SDS, contact
:iasafety@ip-corporation.com
29 CFR 1910.1200 Hazard Communication Standard, March 2012
CCR Title 27 Division 4 Office of Environmental Health Hazard Assessment (California
Prop. 65)
American Composites Manufacturers Association
Styrene Information and Research Center
New form 08-2018
Date of issue/Date of revision :11/30/2020 Date of previous issue :3/18/2020 Version:3 14/14
