by | Sep 27, 2025
: : Page 1 of 5
) ot
| SAFETY DATA SHEET
co
. o.+ & Date Issued : 10/24/2017
He SDS No: F-115 REV 1 PART A
&
@ Date Revised : 12/08/2020
ENTERPRISES Revision No : 1
F-115 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION 6:
PRODUCT NAME: F-115 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc, CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
[etemical Name ee cas
Polyurethane prepolymer :
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
Toluene diisocyanate 26471-62-5
4, FIRST AID MEASURES :
EYES: Immediately flush with plenty of water, After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothin, ‘g. Get medical advice/attention if irritation or rash
develops, Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person,
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours,
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam,
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Donot *
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area, Clean-up should only be performed by trained personnel. People dealing with a major
by | Sep 27, 2025
SAFETY DATA SHEET
@
Lae) Date Issued : 10/24/2017:
O’s’w SDS No: F-115 REV 1 PARTA
Date Revised : 12/08/2020
ENTERPRISES Revision No: 1
F-115 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION eo eC a TL ee ee |
PRODUCT NAME: F-115 REV | PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION : x : }
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS ie 4
Chemical Name CAS
Polyurethane prepolymer Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
Toluene diisocyanate 26471-62-5
4. FIRST AID MEASURES i
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5, FIRE FIGHTING MEASURES #2260 2009005 0 8 i 8 ot ROLE og Ee 2″ BERR PEE
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
_6. ACCIDENTAL RELEASE MEASURES RRM MRS eee ae ate emer ne eee |
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 6/4/2014
MSDS No : F-105 PART B
Date-Revised : 8/19/2014
Revision No : 1
F-105 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see on this label).
P332+P313: If skin irritation occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
Page 1 of 6
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber liquid with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 – 100Proprietary
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 10 – 3068515-49-1
Diethyltoluenediamine (DETDA) 1 – 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
Page 2 of 6
F-105 PART B
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
Page 3 of 6
F-105 PART B
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.14
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.001 (water=1) at 25 C (77 F)
VISCOSITY: 670 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 1.410 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
IRRITATION: Causes eye and skin irritation.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
Page 4 of 6
F-105 PART B
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 10 – 30Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
Page 5 of 6
F-105 PART B
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 6/4/2014 MSDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
F-105 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 10/24/2017
SDS No : F-105 REV 1 PART A
Date Revised : 12/08/2020
Revision No : 1
F-105 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 60 – 100474919-59-0
Polyurethane prepolymer 15 – 40Proprietary
Toluene diisocyanate < 0.126471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
Page 1 of 5
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Polyurethane prepolymer
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Toluene diisocyanate
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA 0.005 -
STEL0.02 -
NIOSH REL
TWA - -
STEL - -
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Page 2 of 5
F-105 REV 1 PART A
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slightly with water
SPECIFIC GRAVITY: 0.985 (water=1) at 25 C (77 F)
VISCOSITY #1: 440 Centipoise at 25 C (77 F)
(VOC): < 4 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, alcohols, and oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and
linear
> 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Polyurethane prepolymer No data available No data available No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Page 3 of 5
F-105 REV 1 PART A
Chemical Name NTP Status IARC Status
Toluene diisocyanate 2 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Toluene diisocyanate < 0.1 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene diisocyanate < 0.126471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
Page 4 of 5
F-105 REV 1 PART A
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Toluene diisocyanate < 0.1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 12/08/2020
REVISION SUMMARY: This SDS replaces the 10/24/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
F-105 REV 1 PART A
SAFETY DATA SHEET
Date Issued : 10/24/2017
SDS No : F-105 REV 1 PART B
Date Revised : 12/08/2020
Revision No : 1
F-105 REV 1 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 REV 1 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 3
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
H412: Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
Disposal:
Page 1 of 5
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 - 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 15 - 40474919-59-0
Diethylmethylbenzenediamine 1 - 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
F-105 REV 1 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Polyether polyol mixture
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Diethylmethylbenzenediamine
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Pale amber
pH: No data available
FLASH POINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
Page 3 of 5
F-105 REV 1 PART B
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 0.996 (water=1) at 25 C (77 F)
VISCOSITY #1: 550 Centipoise at 25 C (77 F)
(VOC): < 1.7 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyether polyol mixture No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear> 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Diethylmethylbenzenediamine > 500 mg/kg Rat> 2000 mg/kg Rat No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
Page 4 of 5
F-105 REV 1 PART B
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No. 68479-98-1) which is subject to TSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm.
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 12/08/2020
REVISION SUMMARY: This SDS replaces the 10/24/2017 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
F-105 REV 1 PART B
by | Sep 27, 2025
Page 1 of 5
SAFETY DATA SHEET
Date Issued : 10/24/2017
SDS No : F-105 REV 1 PART A
Date Revised : 12/08/2020
ENTERPRISES Revision No : 1
F-105 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
1,2-Cyclohexanedicarboxylic acid, 1,2-dinony] ester, branched and linear 60- 100} 474919-59-0
Polyurthane prepolymer
Toluene diisocyanate 26471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES,
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
by | Sep 27, 2025
Page 1 of 5
SAFETY DATA SHEET
. Date Issued : 10/24/2017
SDS No: F-105 REV 1 PARTA
Date Revised : 12/08/2020
ENTERPRISES Revision No : 1
F-105 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 60- 100] 474919-59-0
Polyurethane prepolymer
Toluene diisocyanate 26471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 6/4/2014
MSDS No : F-105 PART A
F-105 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale yellow liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher
temperatures.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyurethane prepolymer 30 – 60Proprietary
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 6068515-49-1
Phosphoric Acid, Triethyl Ester 1 – 5 78-40-0
Toluene-2,6-diisocyanate < 0.039 91-08-7
Toluene-2,4-diisocyanate < 0.039584-84-9
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
Page 1 of 6
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and phosphorus oxides.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 6
F-105 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyurethane prepolymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
Phosphoric Acid, Triethyl Ester
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Toluene-2,6-diisocyanate
TWA NE NE 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
Toluene-2,4-diisocyanate
TWA 0.02 0.14 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: Nil
FLASHPOINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: < 1 mmHg at 21 C (70 F)
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Reacts slightly with water
Page 3 of 6
F-105 PART A
SPECIFIC GRAVITY: 1.003 (water=1) at 25 C (77 F)
VISCOSITY: 500 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and phosphorus
oxides.
INCOMPATIBLE MATERIALS: Water, alcohols, oxidizers, acids and alkalis.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyurethane prepolymer Not Established Not Established Not Established
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
Phosphoric Acid, Triethyl Ester 1165 mg/kg Not Established 8.82 mg/l (4 h)
Toluene-2,6-diisocyanate > 5000 mg/kg > 4000 mg/kg > 480 mg/kg
Toluene-2,4-diisocyanate > 5000 mg/kg > 4000 mg/kg > 480 mg/kg
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Toluene-2,6-diisocyanate 2 2B
Toluene-2,4-diisocyanate 2 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
Page 4 of 6
F-105 PART A
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None Known
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Toluene-2,6-diisocyanate < 0.039100 lbs.
Toluene-2,4-diisocyanate < 0.039100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene-2,6-diisocyanate < 0.03991-08-7
Toluene-2,4-diisocyanate < 0.039584-84-9
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 - 60Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
Page 5 of 6
F-105 PART A
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child's mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
F-105 PART A
SAFETY DATA SHEET
Date Issued : 6/4/2014
MSDS No : F-105 PART B
Date-Revised : 8/19/2014
Revision No : 1
F-105 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-105 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see on this label).
P332+P313: If skin irritation occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
Page 1 of 6
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber liquid with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. Causes eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 - 100Proprietary
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 10 - 3068515-49-1
Diethyltoluenediamine (DETDA) 1 - 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
Page 2 of 6
F-105 PART B
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
Page 3 of 6
F-105 PART B
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.14
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.001 (water=1) at 25 C (77 F)
VISCOSITY: 670 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 1.410 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
IRRITATION: Causes eye and skin irritation.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
Page 4 of 6
F-105 PART B
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 10 – 30Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
Page 5 of 6
F-105 PART B
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 6/4/2014 MSDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
F-105 PART B
by | Sep 27, 2025
1. IDENTIFICATION
Product identifier
Product Name Insulfoam EPS, Platinum (GPS), R-Tech
Other means of identification
Product Code INSULFOAM
Synonyms Type XI, I, VIII, II, IX, XIV and XV, Molded Expanded Polystyrene (MEPS), Treated,
R-Tech, Platinum (Graphite Polystyrene), with or without Polypropylene, Polyethylene, or
Polyester films
Recommended use of the chemical and restrictions on use
Recommended Use Insulation
Uses advised against No information available
Details of the supplier of the safety data sheet
Emergency telephone number
Company Phone Number 800-486-1278
Emergency Telephone US and Canada only (toll-free) : 3E Company – 1-866-519-4752 (access code 334832)
US/Canada, all other countries: 3E Company – +1-760-476-3962 (access code 334832)
Mexico (additional contact option): 3E Company – +52 55 41696225 (Code 334832)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200) and Canadian Workplace Hazardous Material Information System (WHMIS)
Label elements
Emergency Overview
Precautionary Statements – Prevention
Not applicable
Precautionary Statements – Response
Not applicable
Hazards not otherwise classified (HNOC)
Not applicable
_____________________________________________________________________________________________
Page 1 / 7
Manufacturer Address
Insulfoam, a division of Carlisle Construction Materials
19727 57th Avenue
Puyallup, WA 98375
SAFETY DATA SHEET
Not classified
Issue Date 16-Jun-2023
Hazard statements
None
Revision Date 16-Jun-2023 Version 1
Appearance Foam sheet Physical state Solid Odor Slight
by | Sep 27, 2025
1. IDENTIFICATION
Product identifier
Product Name Insulfoam EPS, Platinum (GPS), R-Tech
Other means of identification
Product Code INSULFOAM
Synonyms Type XI, I, VIII, II, IX, XIV and XV, Molded Expanded Polystyrene (MEPS), Treated,
R-Tech, Platinum (Graphite Polystyrene), with or without Polypropylene, Polyethylene, or
Polyester films
Recommended use of the chemical and restrictions on use
Recommended Use Insulation
Uses advised against No information available
Details of the supplier of the safety data sheet
Emergency telephone number
Company Phone Number 800-486-1278
Emergency Telephone US and Canada only (toll-free) : 3E Company – 1-866-519-4752 (access code 334832)
US/Canada, all other countries: 3E Company – +1-760-476-3962 (access code 334832)
Mexico (additional contact option): 3E Company – +52 55 41696225 (Code 334832)
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This article doesn’t contain hazardous substances or mixtures intended to be released under normal or reasonably foreseeable
conditions of use This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200) and Canadian Workplace Hazardous Material Information System (WHMIS)
Label elements
Emergency Overview
Precautionary Statements – Prevention
Not applicable
Precautionary Statements – Response
Not applicable
Hazards not otherwise classified (HNOC)
Not applicable
_____________________________________________________________________________________________
Page 1 / 7
Manufacturer Address
Insulfoam, a division of Carlisle Construction Materials
19727 57th Avenue
Puyallup, WA 98375
SAFETY DATA SHEET
Not classified
Issue Date 16-Jun-2023
Hazard statements
None
Revision Date 16-Jun-2023 Version 1
Appearance Foam sheet Physical state Solid Odor Slight
by | Sep 27, 2025
SDS
CHEMLINE ED77.9 S75 PART A NEUTRAL
CHEMLINE CA, INC
1 PRODUCT AND COMPANY IDENTIFICATION
(310)764-0820
CHEMTREC 800.424.9300 (24 HOURS) CCN 4582
CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Supplier Details:
WWW.CHEMLINE.NET
(310)764-0822
Phone:
Emergency:
Web:
Fax:
2 HAZARDS IDENTIFICATION
Health, Acute toxicity, 4 Oral
Health, Skin corrosion/irritation, 2
Health, Respiratory or skin sensitization, 1 Skin
Health, Serious Eye Damage/Eye Irritation, 2 A
Health, Respiratory or skin sensitization, 1 Respiratory
Health, Specific target organ toxicity – Single exposure, 3
Health, Carcinogenicity, 2
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: DANGER
GHS Hazard Pictograms:
GHS Hazard Statements:
H302 – Harmful if swallowed
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled
H336 – May cause drowsiness or dizziness
H351 – Suspected of causing cancer
GHS Precautionary Statements:
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P284 – Wear respiratory protection.
P305+351+338 – IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and
easy to do. Continue rinsing.
P310 – Immediately call a POISON CENTER or doctor/physician.
Route of Entry:
Target Organs:
Inhalation:
Respiratory system; Skin; Eyes;
At room temperature, MDI vapors are minimal due to low vapor pressure. May cause respiratory
sensitization with asthma-like symptoms in susceptable individuals. Impaired lung function has
been associated with overesposure to isocyanates. MDI concentrations below the exposure
guidelines may cause allergic respiratory reactions in indiviuals already sensitized. Heating,
Eyes; Ingestion; Inhalation; Skin;
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
Revision Date: 2/27/2019SDS Number: ED77.9-A-30000-S75 CA Page:1 / 8
Skin Contact:
Eye Contact:
spraying, foaming or otherwise mechanically dispersing operations way generate vapor or aerosol
concentrations sufficient to cause irritation or other adverse effects.
Prolonged or repeated exposure can cause skin irritation, reddening, dermatitis and in some cases
sensitization. Skin contact may result in allergic reactions or respiratory sensitization, but it is not
expected to result in absorption of amounts sufficient to cause other adverse effects. May stain
skin.
As a liquid or dust, may cause irritation, inflammation, and/or damage to sensitive eye tissue.
Symptoms include watering or discomfort of the eyes. Corneal injury is unlikely. As a liquid or dust,
may cause irritation, inflammation, and/or damage to sensitive eye tissue. Symptoms include
watering or discomfort of the eyes. Corneal injury is unlikely.
Ingestion: Single dose oral exposure is low. Can result in irritation and corrosive action in the mouth, throat
and digestive tract.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Ingredients:
CAS# Chemical Name:
0
101-68-8
9016-87-9
26447-40-5
39310-05-9
%
0-55%
25-65%
20-40%
10-30%
0-11%
Proprietary Polyisocyanate
Prepolymer
4,4′-Methylenediphenyl diisocyanate
Isocyanic acid,
polymethylenepolyphenylene ester
Benzene, 1,1′-
methylenebis[isocyanato-
Benzene, 1,1′-
methylenebis[isocyanato-,
homopolymer
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility immediately. Get
immediate medical attention.
Skin Contact:Wash off in flowing warm water or shower with soap. Remove and wash contaminated clothing. Properly
dispose of any articles that cannot be decontaminated, like leather belts. If redness, burning or itching
develops or persists after the area has been washed, consult a physician.
Eye Contact: Flush with large amounts of water for 15 minutes. Materials containing MDI may react with the moisture in
the eye forming a thick material that is difficult to remove. Get immediate medical attention.
Ingestion: Do not induce vomiting or give liquids unless directed to do so by medical personnel. Never give anything
by mouth to an unconscious person. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flammability: OSHA – none; DOT – none
Flash Point: >250 F
Burning Rate: N/A
Flash Point Method: COC
Autoignition Temp: N/A
LEL: N/A
UEL: N/A
Use dry chemical, foam, carbon dioxide, or halogenated agents. If water is used, use very large quantities. The reaction
between water and hot isocyanate may be vigorous. If possible, contain fire run-off water.
Protective Equipment: Wear positive-pressure self-contained breathing apparatus with full face mask and full protective
clothing.
Unusual Hazards: At temperatures greater than 400 F, polymeric MDI can polymerize and decompose which will cause
pressure build-up in closed containers. Explosive rupture is possible. Water contamination will produce carbon dioxide. Do not
reseal contaminated containers as pressure buildup may rupture the containers. Downwind personnel must be evacuated.
Fire Degradation Products: Isocyanate vapor and mist, carbon dioxide, carbon monoxide, nitrogen oxides and traces of
hydrogen cyanide.
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6 ACCIDENTAL RELEASE MEASURES
Spill: Evacuate spill area. With adequate ventilation and appropriate personal protective equipment, cover the area with an
inert absorbent material such as clay or vermiculite and transfer to metal waste containers. Move container to a well ventilated
area (outside), but do not seal the container with the isocyanate mixture. Larger quantities of liquid may be transferred directly
to drums for disposal. Decontaminate or discard all clean-up equipment.
NOTE: ISOCYANATES WILL REACT WITH WATER AND GENERATE CARBON DIOXIDE. THIS COULD RESULT IN THE
RUPTURE OF ANY CLOSED CONTAINERS.
Clean up: The area should then be flushed with a decontamination solution. The decontamination solution is a 5-10% mixture
of sodium carbonate and 0.5% liquid detergent in water solution or a 3-8% concentrated ammonium hydroxide and 0.5%
liquid detergent in water. Use 10 parts decontamination solution to 1 part spilled material.
If the ammonium hydroxide solution is used, ammonia will be evolved as a vapor. Use caution to avoid exposure to high
concentrations of ammonia. Allow spill clean up to vent for 48 hours letting evolved carbon dioxide to escape.
7 HANDLING AND STORAGE
Handling Precautions: Handling: Use personal protective equipment when transferring material to or from drums,
totes or other containers. The reaction of polyols and isocyanates generates heat. Contact of
the reacting materials with skin or eyes can cause irritiation and may be difficult to remove
from the affected areas. Immediately wash affected areas with plenty of water and seek
medical attention. In addition, such contact increases the risk of exposure to isocyanate
vapors. Do not smoke or use naked lights, open flames, space heaters, or other ignition
sources near pouring, frothing or spraying operations.
Special Emphasis for Spray Applications: Inspect the application area from the potential to
expose other persons or for overspray to drift onto buildings, vehicles or other property. When
spraying building exteriors, persons entering or exiting the building as well as those inside
could be exposed to polyisocyanates due to wind conditions, open windows or air intakes. Do
not begin application work until these potential problems have been corrected.
Storage Requirements: When stored between 60 -85 F in sealed containers, typical shelf life is 6 months or more
from the date of manufacture. Consult technical data sheet for shelf life requirements affecting
performance quality. Should freezing occur, the material must be thawed completely and
mixed until uniform. Opened containers must be handled properly to prevent moisture pickup.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: MDI has a low vapor pressure at room temperature. General/local ventilation typically control
vapor levels very adequately. Uses requiring heating and/or spraying may require more
agressive engineering controls or PPE. Monitoring is required to determine engineering
controls.
Personal Protective
Equipment:
HMIS PP, X | Consult your supervisor for special instructions
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate
use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as
a backup to engineering controls. If the respirator is the sole means of protection, use a full-
face supplied air respirator. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact with this
product. Dispose of contaminated gloves after use in accordance with applicable laws and
good laboratory practices. Wash and dry hands.
Eye protection: Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks and
immediately after handling the product.
Revision Date: 2/27/2019SDS Number: ED77.9-A-30000-S75 CA Page:3 / 8
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [25-65%]
Components with workplace control parameters
TWA 0.0050 ppm USA. ACGIH Threshold Limit Values (TLV)
Respiratory sensitization
C 0.02 ppm USA. OSHA – TABLE Z-1 Limits for Air Contaminants –
0.2 mg/m3 1910.1000
C 0.02 ppm USA. Occupational Exposure Limits (OSHA) – Table Z- 1
0.2 mg/m3 Limits for Air Contaminants
The value in mg/m3 is approximate. Ceiling limit is to be determined from breathing-zone air
samples.
TWA 0.0050 ppm USA. NIOSH Recommended Exposure Limits
0.05 mg/m3
10 minute ceiling value
C 0.2 ppm USA. NIOSH Recommended Exposure Limits
0.2 mg/m3
10 minute ceiling value
Isocyanic acid, polymethylenepolyphenylene ester cas#:(9016-87-9) [20-40%]
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Non-pigmented liquid.
9.8 lbs/gal
>350 F
None
<1
Solubility:
Percent Volatile:
Flash Point:
Vapor Density:
Auto-Ignition Temp:
Not soluble in water, REACTS.
By volume <1% By weight <1%
>250 F
>1
NDA
Spec Grav./Density:
Boiling Point:
Flammability:
Evap. Rate:
Physical State: Odor:Liquid Mild
10 STABILITY AND REACTIVITY
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Stability: Polyisocyanates are highly reactive chemicals and should be handled and stored in
a way to avoid exposure to many common substances, including water and moisture. Material
is stable when stored in sealed containers under normal conditions. Avoid extended exposure
over 110 F (45 C).
Reactivity: Reacts with water, acids, bases, alcohols, metal compounds. The reaction with
water is very slow under 120 F (50 C), but is accelerated at higher temperatures and in the
presence of alkalis, tertiary amines and metal compounds. Some reactions can be vigorous or
even violent.
Moisture and/or water. High temperatures, sparks, flame and extended exposure over 110 F
(45 C).
Acids; Alcohols; Bases; Metal compounds; Water;
Carbon dioxide; Excess gas may rupture containers.
May occur with incompatible reactants, especially strong bases, water or temperatures over
320 F (50 C).
11 TOXICOLOGICAL INFORMATION
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [25-65%]
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Information on toxicological effects
Acute toxicity:
Oral LD50 LD50 Oral – rat – 4,700 mg/kg
Inhalation LC50 Dermal LD50 no data available
Other information on acute toxicity
Skin corrosion/irritation: Serious eye damage/eye irritation:
Eyes – rabbit – Moderate eye irritation
Respiratory or skin sensitization: no data available
May cause allergic respiratory and skin reactions
Germ cell mutagenicity: Laboratory experiments have shown mutagenic effects.
Genotoxicity in vitro – Human – lymphocyte Sister chromatid exchange
Genotoxicity in vivo – rat – Inhalation DNA damage
Carcinogenicity:
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA
classification.
Limited evidence of carcinogenicity in animal studies
IARC: 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Diphenylmethane-4,4- diisocyanate)
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
OSHA.
Reproductive toxicity: Reproductive toxicity – rat – Inhalation:
Maternal Effects: Other effects. Specific Developmental Abnormalities: Musculoskeletal system.
no data available
Teratogenicity: no data available
Specific target organ toxicity – single exposure (Globally Harmonized System):
May cause respiratory irritation.
Specific target organ toxicity – repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation May be fatal if inhaled. Causes respiratory tract irritation. Ingestion May be harmful if swallowed. Skin
May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes eye irritation.
Signs and Symptoms of Exposure: Cough, Shortness of breath, Headache, Nausea, Vomiting, Pulmonary edema. Effects may be delayed.
Synergistic effects: no data available
Additional Information:
RTECS: NQ9350000
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Isocyanic acid, polymethylenepolyphenylene ester cas#:(9016-87-9) [20-40%]
Information on toxicological effects
Acute toxicity:
Oral LD50 no data available
Inhalation LC50 LC50 Inhalation – rat – 4 h – 0.49 mg/l
Dermal LD50
Other information on acute toxicity
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitisation: May cause allergic respiratory and skin reactions
Germ cell mutagenicity: no data available
Carcinogenicity:
IARC: 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Isocyanic acid, polymethylenepolyphenylene ester)
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
OSHA.
Reproductive toxicity: no data available
Teratogenicity: no data available
Specific target organ toxicity – single exposure (Globally Harmonized System):
Inhalation – May cause respiratory irritation.
Specific target organ toxicity – repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation May be fatal if inhaled. Causes respiratory tract irritation. Ingestion Harmful if swallowed. Skin Harmful if
absorbed through skin. Causes skin irritation. Eyes Causes eye irritation.
Signs and Symptoms of Exposure: salivary gland obstruction, allergic dermatitis, respiratory difficulties, bronchoconstriction, To the best of
our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Synergistic effects: no data available
Additional Information:
RTECS: Not available
12 ECOLOGICAL INFORMATION
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [25-65%]
Information on ecological effects
Toxicity:
Toxicity to daphnia EC50 – Daphnia magna (Water flea) – 0.35 mg/l – 24 h.
and other aquatic invertebrates
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Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available
Other adverse effects: Do not empty into drains.
no data available
Isocyanic acid, polymethylenepolyphenylene ester cas#:(9016-87-9) [20-40%]
Information on ecological effects
Toxicity: no data available
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available
Other adverse effects: no data available
13 DISPOSAL CONSIDERATIONS
{rtf1ansideff0{fonttbl{f0fnilfcharset0 Arial;}}
viewkind4uc1pardlang1033fs20 Disposal: Any disposal practice must be in compliance with all federal, state and local laws and
regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in
this MSDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal compliance are the responsibility solely
of the party generating the waste or deciding to discard or dispose of the material.
par Do not allow material to enter sewers, a body of water, or contact the ground. Refer to RCRA 40 CFR 261, and/or any other
appropriate federal, state or local requirements for proper classification information.
par
par }
14 TRANSPORT INFORMATION
Non DOT/RCRA regulated
IATA/IMDG/ICAO – Not dangerous goods
15 REGULATORY INFORMATION
[%] RQ (CAS#) Substance – Reg Codes
—————————————————————-
[25-65%] RQ(5000LBS), 4,4′-Methylenediphenyl diisocyanate (101-68-8) CERCLA, HAP, IARC, MASS, NJHS, OSHAWAC,
PA, SARA313, TSCA, TXAIR
[20-40%] Isocyanic acid, polymethylenepolyphenylene ester (9016-87-9) IARC, SARA313, TSCA
[10-30%] Benzene, 1,1′-methylenebis[isocyanato- (26447-40-5) TSCA
[0-11%] Benzene, 1,1′-methylenebis[isocyanato-, homopolymer (39310-05-9) TSCA
This product does not contain chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm.
Revision Date: 2/27/2019SDS Number: ED77.9-A-30000-S75 CA Page:7 / 8
Regulatory Code Legend
—————————————————————-
RQ = Reportable Quantity
CERCLA = Superfund clean up substance
HAP = Hazardous Air Pollutants
IARC = IARC Carcinogen Risks
MASS = MA Massachusetts Hazardous Substances List
NJHS = NJ Right-to-Know Hazardous Substances
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
SARA313 = SARA 313 Title III Toxic Chemicals
TSCA = Toxic Substances Control Act
TXAIR = TX Air Contaminants with Health Effects Screening Level
16 OTHER INFORMATION
Disclaimer:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility
regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose(s).
Revision Date: 2/27/2019
Health = 2, Fire = 1, Reactivity = 1, Specific Hazard = None
Health = 2, Fire = 1, Physical Hazard = 1
X – Consult your supervisor for special instructions
NFPA:
HMIS III:
HMIS PPE:
1
2
None
2
1
X
1
1
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