by | Sep 27, 2025
SDS
CHEMLINE ED77.9 S75 PART B BLACK
CHEMLINE CA, INC
1 PRODUCT AND COMPANY IDENTIFICATION
(310)764-0820
CHEMTREC 800.424.9300 (24 HOURS) CCN 4582
CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Supplier Details:
WWW.CHEMLINE.NET
(310)764-0822
Phone:
Emergency:
Web:
Fax:
2 HAZARDS IDENTIFICATION
Health, Acute toxicity, 4 Oral
Health, Skin sensitization, 1
Health, Carcinogenicity, 2
Environmental, Hazards to the aquatic environment – Chronic, 1
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: WARNING
GHS Hazard Pictograms:
GHS Hazard Statements:
H302 – Harmful if swallowed
H317 – May cause an allergic skin reaction
H351 – Suspected of causing cancer
H410 – Very toxic to aquatic life with long lasting effects
GHS Precautionary Statements:
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P261 – Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 – Wash … thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280b – Wear protective gloves/eye protection/face protection.
P281 – Use personal protective equipment as required.
P301 + P330 + P331 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or
shower].
P304 + P341 – IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308 + P313 – IF exposed or concerned: Get medical advice/ attention.
P314 – Get medical advice/attention if you feel unwell.
P333 + P313 – If skin irritation or rash occurs: Get medical advice/attention.
P363 – Wash contaminated clothing before reuse.
P391 – Collect spillage.
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:1 / 6
P405 – Store locked up.
P501 – Dispose of contents/ container to an approved waste disposal plant.
Route of Entry:
Target Organs:
Inhalation:
Skin Contact:
Eye Contact:
Eyes; Skin; Respiratory system;
Heating, spraying, foaming or otherwise mechanically dispersing operations way generate vapor
or aerosol concentrations sufficient to cause irritation or other adverse effects. Minimal respiratory
tract irritation may occur with exposure to a large amount of material.
Prolonged or repeated exposure can cause skin irritation or dermatitis in some individuals.
May cause watering of the eye and irritation of the conjunctiva.
Ingestion: May cause nausea or vomiting.
Eyes; Ingestion; Inhalation; Skin;
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Ingredients:
CAS# Chemical Name:
0
102093-68-5
104983-85-9
1333-86-4
%
60-90%
10-30%
0-7%
0-3%
Proprietary polyol blend
1,3-Benzenediamine, 4-methyl-2,6-
bis(methylthio)-
1,3-Benzenediamine, 2-methyl-4,6-
bis(methylthio)-
Carbon black
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility immediately.
Skin Contact:Remove all contaminated clothing and shoes. Wash skin with large quantities of water and soap. Wash
clothing before wearing again and clean shoes. If redness, itching or a burning sensation develops or
persists after the area is washed, consult a physician.
Eye Contact: Flush with large amounts of water for 15 minutes. Use fingers to assure that the eyelids are separated and
that the eye is being irrigated. Get immediate medical attention.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. This material is an
aspiration hazard. Never give anything by mouth to an unconscious person. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flash Point: >300 F
Flash Point Method: COC
Dry powder, foam, carbon dioxide. Use cold water spray to cool fire exposed containers to minimize risk of rupture. A solid
stream of water directed into hot burning liquid could cause frothing. If possible, contain fire run off.
6 ACCIDENTAL RELEASE MEASURES
Spill: Remove all sources of flames, heating elements, gas engines, etc. Emergency clean-up personnel should wear
chemical goggles, rubber or plastic gloves and clothing as required to protect against contact. Prevent spreading and
contamination of surface waters and drinking supplies. Notify local health officials and other appropriate agencies if such
contamination should occur.
Clean up: With adequate ventilation and appropriate personal protective equipment, cover the area with an inert absorbent
material such as clay or vermiculite and transfer to steel waste containers. Ventilate area to remove the remaining vapors.
7 HANDLING AND STORAGE
Handling Precautions: Do not smoke or use naked lights, open flames, space heaters or other ignition sources near
pouring, frothing or spraying operations. If contamination with isocyantes is suspected, do not
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:2 / 6
reseal containers. Special Emphasis for spray applications of mixed products containing
isocyanates: Inspect the application area for potential to expose other persons or for
overspray to drift onto buildings, vehicles or other property. When spraying building exteriors,
persons entering or exiting the building as well as those inside could be exposed to
polyisocyanates due to wind conditions, open windows or air intakes. Do not begin application
work until these potential problems have been corrected.
Storage Requirements: When stored between 60 -85 F in sealed containers, typical shelf life is 6 months or more
from the date of manufacture. Open containers must be handled properly to prevent moisture
pickup.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Proprietary polyol blend cas#:(0) [60-90%]
Contains no substance with occupational exposure limits
Carbon black cas#:(1333-86-4) [0-3%]
Components with workplace control parameters
TWA 3.5 mg/m3 USA. ACGIH Threshold Limit Values
(TLV)
Not classifiable as a human carcinogen
Engineering Controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Uses
requiring heating and/or spraying may require more agressive engineering controls or PPE.
Personal Protective
Equipment:
HMIS PP, X | Consult your supervisor for special instructions
Personal protective equipment
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate
use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole means of
protection, use a full-face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact with this
product. Dispose of contaminated gloves after use in accordance with applicable laws and
good laboratory practices. Wash and dry hands. Splash contact Material: Nitrile rubber
Minimum layer thickness: 0.4 mm Break through time: 120 min Material tested:Camatril (KCL
730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49
(0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of the
CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by
our customers. It should not be construed as offering an approval for any specific use
scenario.
Eye protection: Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:3 / 6
TWA 3.5 mg/m3 USA. OSHA – TABLE Z-1 Limits for
Air Contaminants – 1910.1000
TWA 3.5 mg/m3 USA. Occupational Exposure Limits
(OSHA) – Table Z-1 Limits for Air
Contaminants
TWA 3.5 mg/m3 USA. NIOSH Recommended
Exposure Limits
TWA 0.1 mg/m3 USA. NIOSH Recommended
Exposure Limits
Potential Occupational Carcinogen
Carbon black in presence of polycyclic aromatic hydrocarbons
(PAHs)
See Appendix C
See Appendix A
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pigmented liquid.
9.14 lbs/gal
>500 F
None Flammable
<1
Flash Point:
Vapor Density:
>200 F
>1
Spec Grav./Density:
Boiling Point:
Flammability:
Evap. Rate:
Physical State: Odor:Liquid Mild
10 STABILITY AND REACTIVITY
Reactivity: No specific data
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
No specific data
No specific data
Under normal storage conditions hazardous decomposition products should not be produced.
Will not occur.
11 TOXICOLOGICAL INFORMATION
Proprietary polyol blend cas#:(0) [60-90%]
Finished product has not been tested.
Carbon black cas#:(1333-86-4) [0-3%]
Information on toxicological effects
Acute toxicity:
LD50 Oral – rat – male and female – > 8,000 mg/kg (OECD Test Guideline 401)
Inhalation: no data available
LD50 Dermal – rabbit – > 3,000 mg/kg
Skin corrosion/irritation: Skin – rabbit Result: No skin irritation – 24 h (OECD Test Guideline 404)
Serious eye damage/eye irritation: Eyes – rabbit Result: No eye irritation (OECD Test Guideline 405)
Respiratory or skin sensitisation: – guinea pig Result: Did not cause sensitisation on laboratory animals. (OECD Test Guideline 406)
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:4 / 6
Germ cell mutagenicity: Ames test S. typhimurium Result: negative
Hamster ovary
DNA repair rat – female
Carcinogenicity:
Carcinogenicity – rat – Inhalation:
Tumorigenic:Carcinogenic by RTECS criteria. Lungs, Thorax, or Respiration:Tumors.
This product is or contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, or EPA
classification.
Limited evidence of carcinogenicity in animal studies
IARC: 2B – Group 2B: Possibly carcinogenic to humans (Carbon black)
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
OSHA.
Reproductive toxicity: no data available
Specific target organ toxicity – single exposure: no data available
Specific target organ toxicity – repeated exposure: no data available
Aspiration hazard: no data available
Additional Information:
RTECS: FF5800000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
12 ECOLOGICAL INFORMATION
Carbon black cas#:(1333-86-4) [0-3%]
Information on ecological effects
Toxicity:
Toxicity to fish LC50 – Danio rerio (zebra fish) – > 1,000 mg/l – 96 h.
Toxicity to daphnia and static test EC50 – Daphnia magna (Water flea) – > 5,600 mg/l – 24 h.
other aquatic (OECD Test Guideline 202) invertebrates
Toxicity to algae static test EC50 – Desmodesmus subspicatus (green algae) – > 10,000 mg/l -:
72 h (OECD Test Guideline 201)
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects: no data available
13 DISPOSAL CONSIDERATIONS
Disposal: Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical
additions, processing or otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal compliance are the
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:5 / 6
responsibility solely of the party generating the waste or deciding to discard or dispose of the material.
Do not allow material to enter sewers, a body of water, or contact the ground. Refer to RCRA 40 CFR 261, and/or any other
appropriate federal, state or local requirements for proper classification information.
14 TRANSPORT INFORMATION
DOT – Non DOT/Non RCRA regulated
IATA/IMDG/ICAO – Not dangerous goods
15 REGULATORY INFORMATION
[%] RQ (CAS#) Substance – Reg Codes
—————————————————————-
[10-30%] 1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- (102093-68-5) TSCA
[0-7%] 1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- (104983-85-9) TSCA
[0-3%] Carbon black (1333-86-4) IARC, MASS, OSHAWAC, PA, PROP65, TSCA, TXAIR
Regulatory Code Legend
—————————————————————-
IARC = IARC Carcinogen Risks
TSCA = Toxic Substances Control Act
MASS = MA Massachusetts Hazardous Substances List
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
PROP65 = CA Prop 65
TXAIR = TX Air Contaminants with Health Effects Screening Level
This product can expose you to chemicals including Carbon black (airborne, unbound particles of respirable size), which
is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov.
WARNING
16 OTHER INFORMATION
Disclaimer:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility
regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose(s).
Revision Date: 2/27/2019
Health = 1, Fire = 0, Reactivity = 0, Specific Hazard = None
Health = 1, Fire = 1, Physical Hazard = 0
X – Consult your supervisor for special instructions
NFPA:
HMIS III:
HMIS PPE:
0
1
None
1
0
X
1
0
Revision Date: 2/27/2019SDS Number: ED77.9-B-20000-S75 CA Page:6 / 6
by | Sep 27, 2025
SDS
CHEMLINE ED70.7 WHITE FASTCAST PART B
CHEMLINE CA, INC
1 PRODUCT AND COMPANY IDENTIFICATION
(310)764-0820
CHEMTREC 800.424.9300 (24 HOURS) CCN 4582
CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Supplier Details:
WWW.CHEMLINE.NET
(310)764-0822
Phone:
Emergency:
Web:
Fax:
2 HAZARDS IDENTIFICATION
Health, Skin sensitization, 1
Health, Skin corrosion/irritation, 2
Health, Serious Eye Damage/Eye Irritation, 2 A
Physical, Flammable Liquids, 3
Health, Specific target organ toxicity – Single exposure, 3
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: WARNING
GHS Hazard Pictograms:
GHS Hazard Statements:
H317 – May cause an allergic skin reaction
H315 – Causes skin irritation
H319 – Causes serious eye irritation
H226 – Flammable liquid and vapor
H336 – May cause drowsiness or dizziness
GHS Precautionary Statements:
P261 – Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P270 – Do not eat, drink or smoke when using this product.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P312 – IF SWALLOWED: Call a POISON CENTER/ doctor/ if you feel unwell.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P314 – Get medical advice/attention if you feel unwell.
P330 – Rinse mouth.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P391 – Collect spillage.
P501 – Dispose of contents/container to a licensed waste disposal services provider.
Route of Entry:
Target Organs:
Inhalation:
Eyes; Skin; Respiratory system;
Heating, spraying, foaming or otherwise mechanically dispersing operations way generate vapor
Eyes; Ingestion; Inhalation; Skin;
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:1 / 7
Skin Contact:
Eye Contact:
or aerosol concentrations sufficient to cause irritation or other adverse effects. Minimal respiratory
tract irritation may occur with exposure to a large amount of material.
Prolonged or repeated exposure can cause skin irritation or dermatitis in some individuals.
May cause watering of the eye and irritation of the conjunctiva.
Ingestion: May cause nausea or vomiting.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Ingredients
CAS# Chemical Name
0
102-60-3
68551-17-7
%
60-80%
20-40%
0-20%
Proprietary polyol blend
2-Propanol, 1,1′,1”,1”’-
(1,2-
ethanediyldinitrilo)tetraki
s-
Alkanes, C10-13-iso-
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility immediately.
Skin Contact:Remove all contaminated clothing and shoes. Wash skin with large quantities of water and soap. Wash
clothing before wearing again and clean shoes. If redness, itching or a burning sensation develops or
persists after the area is washed, consult a physician.
Eye Contact: Flush with large amounts of water for 15 minutes. Use fingers to assure that the eyelids are separated and
that the eye is being irrigated. Get immediate medical attention.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. This material is an
aspiration hazard. Never give anything by mouth to an unconscious person. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flash Point: >200 F
Flash Point Method: COC
Dry powder, foam, carbon dioxide. Use cold water spray to cool fire exposed containers to minimize risk of rupture. A solid
stream of water directed into hot burning liquid could cause frothing. If possible, contain fire run off.
6 ACCIDENTAL RELEASE MEASURES
Spill: Remove all sources of flames, heating elements, gas engines, etc. Emergency clean-up personnel should wear
chemical goggles, rubber or plastic gloves and clothing as required to protect against contact. Prevent spreading and
contamination of surface waters and drinking supplies. Notify local health officials and other appropriate agencies if such
contamination should occur.
Clean up: With adequate ventilation and appropriate personal protective equipment, cover the area with an inert absorbent
material such as clay or vermiculite and transfer to steel waste containers. Ventilate area to remove the remaining vapors.
7 HANDLING AND STORAGE
Handling Precautions: Do not smoke or use naked lights, open flames, space heaters or other ignition sources near
pouring, frothing or spraying operations. If contamination with isocyantes is suspected, do not
reseal containers. Special Emphasis for spray applications of mixed products containing
isocyanates: Inspect the application area for potential to expose other persons or for
overspray to drift onto buildings, vehicles or other property. When spraying building exteriors,
persons entering or exiting the building as well as those inside could be exposed to
polyisocyanates due to wind conditions, open windows or air intakes. Do not begin application
work until these potential problems have been corrected.
Storage Requirements: When stored between 60 -85 F in sealed containers, typical shelf life is 6 months or more
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:2 / 7
from the date of manufacture. Open containers must be handled properly to prevent moisture
pickup.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Proprietary polyol blend cas#:(0) [60-80%]
Contains no substance with occupational exposure limits
2-Propanol, 1,1′,1”,1”’-(1,2-ethanediyldinitrilo)tetrakis- cas#:(102-60-3) [20-40%]
Alkanes, C10-13-iso- cas#:(68551-17-7) [0-20%]
Engineering Controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Uses
requiring heating and/or spraying may require more agressive engineering controls or PPE.
Personal Protective
Equipment:
HMIS PP, X | Consult your supervisor for special instructions
Personal protective equipment
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate
use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole means of
protection, use a full-face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact with this
product. Dispose of contaminated gloves after use in accordance with applicable laws and
good laboratory practices. Wash and dry hands. Splash contact Material: Nitrile rubber
Minimum layer thickness: 0.4 mm Break through time: 120 min Material tested:Camatril (KCL
730 / Aldrich Z677442, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49
(0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of the
CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by
our customers. It should not be construed as offering an approval for any specific use
scenario.
Eye protection: Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Non-Pigmented liquid.
Physical State: Odor:Liquid Mild
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:3 / 7
8.29 lbs/gal
None Flammable
<1
Flash Point:
Vapor Density:
>200 F
>1
Spec Grav./Density:
Flammability:
Evap. Rate:
10 STABILITY AND REACTIVITY
Reactivity: No specific data
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
No specific data
No specific data
Under normal storage conditions hazardous decomposition products should not be produced.
Will not occur.
11 TOXICOLOGICAL INFORMATION
Proprietary polyol blend cas#:(0) [60-80%]
Finished product has not been tested.
2-Propanol, 1,1′,1”,1”’-(1,2-ethanediyldinitrilo)tetrakis- cas#:(102-60-3) [20-40%]
Information on toxicological effects
Acute toxicity:
Oral LD50 no data available
Inhalation LC50
Dermal LD50
Other information on acute toxicity
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitisation: May cause allergic skin reaction.
Germ cell mutagenicity: no data available
Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible
or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.
Reproductive toxicity: no data available
Teratogenicity: no data available
Specific target organ toxicity – single exposure (Globally Harmonized System):
no data available
Specific target organ toxicity – repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be
harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:4 / 7
irritation.
Synergistic effects: no data available
Additional Information:
RTECS: UB5604000
Alkanes, C10-13-iso- cas#:(68551-17-7) [0-20%]
Information on toxicological effects
Acute toxicity:
Oral LD50 no data available
Inhalation LC50
Dermal LD50
Other information on acute toxicity
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitization: no data available
Germ cell mutagenicity: no data available
Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible
or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.
Reproductive toxicity: no data available
Teratogenicity: no data available
Specific target organ toxicity – single exposure (Globally Harmonized System):
Inhalation – May cause respiratory irritation.
Specific target organ toxicity – repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be
harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye
irritation.
Signs and Symptoms of Exposure: Nausea, Headache, Vomiting, To the best of our knowledge, the chemical,
physical, and toxicological properties have not been thoroughly investigated.
Synergistic effects: no data available
Additional Information:
RTECS: Not available
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:5 / 7
12 ECOLOGICAL INFORMATION
2-Propanol, 1,1′,1”,1”’-(1,2-ethanediyldinitrilo)tetrakis- cas#:(102-60-3) [20-40%]
Information on ecological effects
Toxicity: no data available
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available
Other adverse effects: no data available
Alkanes, C10-13-iso- cas#:(68551-17-7) [0-20%]
Information on ecological effects
Toxicity: no data available
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available
Other adverse effects: no data available
13 DISPOSAL CONSIDERATIONS
Disposal: Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical
additions, processing or otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal compliance are the
responsibility solely of the party generating the waste or deciding to discard or dispose of the material.
Do not allow material to enter sewers, a body of water, or contact the ground. Refer to RCRA 40 CFR 261, and/or any other
appropriate federal, state or local requirements for proper classification information.
14 TRANSPORT INFORMATION
DOT – Non DOT/Non RCRA regulated
IATA/IMDG/ICAO – Not dangerous goods
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:6 / 7
15 REGULATORY INFORMATION
Component (CAS#) [%] – CODES
—————————————————————-
Proprietary polyol blend (0) [60-80%] IARC
2-Propanol, 1,1′,1”,1”’-(1,2-ethanediyldinitrilo)tetrakis- (102-60-3) [20-40%] TSCA
Alkanes, C10-13-iso- (68551-17-7) [0-20%] TSCA
Regulatory CODE Descriptions
—————————————————————-
IARC = IARC Carcinogen Risks
TSCA = Toxic Substances Control Act
16 OTHER INFORMATION
Disclaimer:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility
regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose(s).
Health = 1, Fire = 2, Reactivity = 0, Specific Hazard = None
Health = 1, Fire = 2, Physical Hazard = 0
X – Consult your supervisor for special instructions
NFPA:
HMIS III:
HMIS PPE:
2
1
None
1
0
X
2
0
Revision Date: 4/17/2017SDS Number: ED70.7 PART B 30000 Page:7 / 7
by | Sep 27, 2025
SDS
CHEMLINE ED70.7 WHITE FASTCAST PART A
CHEMLINE CA, INC
1 PRODUCT AND COMPANY IDENTIFICATION
(310)764-0820
CHEMTREC 800.424.9300 (24 HOURS) CCN 4582
CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Supplier Details:
WWW.CHEMLINE.NET
(310)764-0822
Phone:
Emergency:
Web:
Fax:
2 HAZARDS IDENTIFICATION
Health, Respiratory or skin sensitization, 1 Respiratory
Health, Respiratory or skin sensitization, 1 Skin
Health, Skin corrosion/irritation, 2
Health, Carcinogenicity, 2
Health, Serious Eye Damage/Eye Irritation, 2 A
Health, Specific target organ toxicity – Single exposure, 3
Health, Acute toxicity, 5 Oral
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
GHS Signal Word: DANGER
GHS Hazard Pictograms:
GHS Hazard Statements:
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled
H317 – May cause an allergic skin reaction
H315 – Causes skin irritation
H351 – Suspected of causing cancer.
H319 – Causes serious eye irritation
H336 – May cause drowsiness or dizziness
H303 – May be harmful if swallowed
GHS Precautionary Statements:
P260 – Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P280 – Wear protective gloves.
P284 – Wear respiratory protection.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 – Immediately call a POISON CENTER or doctor/ physician.
Route of Entry:
Target Organs:
Inhalation:
Respiratory system; Skin; Eyes;
At room temperature, MDI vapors are minimal due to low vapor pressure. However, heating,
spraying, foaming, or otherwise mechanically dispersing (drumming, venting or pumping)
operations may generate vapor or aerosol concentrations sufficient to cause irritation or other
adverse effects. Excessive exposure may cause irritation of the eyes, upper respiratory tract and
Eyes; Ingestion; Inhalation; Skin;
Classification of the Substance or Mixture
GHS Label Elements, Including Precautionary Statements
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:1 / 7
Skin Contact:
Eye Contact:
lungs. Severe overexposure may lead to pulmonary edema. May cause respiratory sensitization
with asthma-like symptoms in susceptible individuals. MDI concentrations below the exposure
guidelines may cause allergic respiratory reactions in individuals already sensitized. Symptoms
may include coughing, dryness of throat, headache, nausea, difficult breathing and a feeling of
tightness in the chest. Effects may be delayed. Impaired lung function (decreased ventilator
capacity) has been associated with overexposure to isocyanates
Chronic: As a result of previous repeated overexposures or a single large dose, certain individuals
develop isocyanate sensitization (chemical asthma) or tissue injury in the upper respiratory tract.
Animal tests indicate skin contact alone may also lead to allergic respiratory reaction. These
effects may be permanent. Any person developing asthmatic reaction or other sensitization should
be removed from further exposure
Product is a skin sensitizer. Causes irritation with symptoms of reddening, itching and swelling.
Prolonged or repeated exposure can cause skin irritation, reddening, dermatitis, and in some
individuals, sensitization. Skin contact may result in allergic skin reactions or respiratory
sensitization, but is not expected to result in absorption of amounts sufficient to cause other
adverse effects. May stain skin. Cured material is difficult to remove.
As a liquid, vapor, aerosol or dust, may cause irritation, inflammation, and/or damage to sensitive
eye tissue. Symptoms include reddening, tearing, stinging and swelling. May cause corneal injury.
Prolonged contact may cause conjunctivitis.
Ingestion: Single dose oral toxicity is considered to be extremely low. Can result in irritation and corrosive
action in the mouth, stomach tissue and digestive tract. Symptoms can include nausea, vomiting,
sore throat, abdominal pain and diarrhea. Ingestion is not an applicable route of entry for intended
use.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Ingredients
CAS# Chemical Name
26447-40-5
101-68-8
39310-05-9
%
45-65%
40-60%
15-35%
Benzene, 1,1′-
methylenebis[isocyanato-
4,4′-Methylenediphenyl
diisocyanate
Benzene, 1,1′-
methylenebis[isocyanato-,
homopolymer
4 FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to a medical facility immediately.
Skin Contact:Wash off in flowing warm water or shower with soap. Remove and wash contaminated clothing and discard
contaminated shoes. For severe exposure, get under safety shower after removing clothing, then seek
medical attention. If redness, itching or a burning sensation develops or persists after the area is washed,
consult a physician.
Eye Contact: Flush with large amounts of water for 15 minutes. Materials containing MDI may react with the moisture in
the eye forming a thick material that is difficult to remove. Get immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Give 1-2 cups of milk or water to drink. Never give anything by mouth to an
unconscious person. Seek medical attention.
5 FIRE FIGHTING MEASURES
Flammability: OSHA – none; DOT – none
Flash Point: 460 F
Burning Rate: N/A
Flash Point Method: PMCC
Autoignition Temp: NDA
LEL: N/A
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:2 / 7
UEL: N/A
Use dry chemical, foam, carbon dioxide, foam or water spray for large fires. The reaction between water and hot isocyanate
may be vigorous. If possible, contain fire run-off water.
Protective Equipment: Wear positive-pressure self-contained breathing apparatus with full face mask and full protective
clothing.
Unusual Hazards: At temperatures greater than 400 F, polymeric MDI can polymerize and decompose which will cause
pressure build-up in closed containers. Explosive rupture is possible. Water contamination will produce carbon dioxide. Do not
reseal contaminated containers as pressure buildup may rupture the containers. Downwind personnel must be evacuated.
Fire Degradation Products: Isocyanate vapor and mist, carbon dioxide, carbon monoxide, nitrogen oxides and traces of
hydrogen cyanide.
6 ACCIDENTAL RELEASE MEASURES
Spill: Evacuate and isolate spill area. Remove any ignition sources. With adequate ventilation and appropriate personal
protective equipment, cover the area with an inert absorbent material such as clay or vermiculite and transfer to metal waste
containers. Move container to a well ventilated area (outside), but do not seal the container with the isocyanate mixture.
Larger quantities of liquid may be transferred directly to drums for disposal. Decontaminate or discard all clean-up equipment.
NOTE: ISOCYANATES WILL REACT WITH WATER AND GENERATE CARBON DIOXIDE. THIS COULD RESULT IN THE
RUPTURE OF ANY CLOSED CONTAINERS.
Clean up: The area should then be flushed with a decontamination solution. The decontamination solution is a 5-10% mixture
of sodium carbonate and 0.5% liquid detergent in water solution or a 3-8% concentrated ammonium hydroxide and 0.5%
liquid detergent in water. Use 10 parts decontamination solution to 1 part spilled material. If the ammonium hydroxide solution
is used, ammonia will be evolved as a vapor. Use caution to avoid exposure to high concentrations of ammonia. Allow to
stand for 48 hours letting evolved carbon dioxide escape.
7 HANDLING AND STORAGE
Handling Precautions: Handling: Use personal protective equipment when transferring material to or from drums,
totes or other containers. The reaction of polyols and isocyanates generates heat. Contact of
the reacting materials with skin or eyes can cause irritiation and may be difficult to remove
from the affected areas. Do not smoke or use naked lights, open flames, space heaters, or
other ignition sources near pouring, frothing or spraying operations.
Special Emphasis for Spray Applications: Inspect the application area from the potential to
expose other persons or for overspray to drift onto buildings, vehicles or other property. When
spraying building exteriors, persons entering or exiting the building as well as those inside
could be exposed to polyisocyanates due to wind conditions, open windows or air intakes. Do
not begin application work until these potential problems have been corrected.
Storage Requirements: Storage: When stored between 15 and 30 C (60 and 85 F) in dry place in tightly sealed
containers, typical shelf life is 6 months or more from the date of manufacture. Consult
technical data sheet for shelf life requirements affecting performance quality. Should freezing
occur, the material must be thawed thoroughly and mixed until uniform. Opened containers
must be handled properly to prevent moisture pickup. Do not reseal if contamination is
suspected.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: MDI has a low vapor pressure at room temperature. Monitoring is required to determine
engineering controls. Uses requiring heating and/or spraying may require more agressive
engineering controls or PPE. Eyewash and safety showers should be available.
Personal Protective
Equipment:
HMIS PP, X | Consult your supervisor for special instructions
Personal protective equipment
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate
use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as
a backup to engineering controls. If the respirator is the sole means of protection, use a full-
face supplied air respirator. Use respirators and components tested and approved under
appropriate government standards such as NIOSH (US) or CEN (EU).
Hand protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching gloves outer surface) to avoid skin contact with this
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:3 / 7
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [40-60%]
Components with workplace control parameters
TWA 0.0050 ppm USA. ACGIH Threshold Limit Values (TLV)
Respiratory sensitization
C 0.02 ppm USA. OSHA – TABLE Z-1 Limits for Air Contaminants –
0.2 mg/m3 1910.1000
C 0.02 ppm USA. Occupational Exposure Limits (OSHA) – Table Z- 1
0.2 mg/m3 Limits for Air Contaminants
The value in mg/m3 is approximate. Ceiling limit is to be determined from breathing-zone air
samples.
TWA 0.0050 ppm USA. NIOSH Recommended Exposure Limits
0.05 mg/m3
10 minute ceiling value
C 0.2 ppm USA. NIOSH Recommended Exposure Limits
0.2 mg/m3
10 minute ceiling value
product. Dispose of contaminated gloves after use in accordance with applicable laws and
good laboratory practices. Wash and dry hands.
Eye protection: Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection: Complete suit protecting against chemicals, The type of protective
equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace.
Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands before breaks and
immediately after handling the product.
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Non-pigmented liquid.
Molecular Formula:N/A9.56 lb/gallon
approx. 400 cps
>354 F
None
<1
Solubility:
Percent Volatile:
Freezing/Melting Pt.:
Flash Point:
Vapor Density:
Auto-Ignition Temp:
Not soluble in water; REACTS with
water releasing carbon dioxide.
0%
60 F
>460 F
>1
NDA
Spec Grav./Density:
Viscosity:
Boiling Point:
Flammability:
Evap. Rate:
Physical State: Odor:Liquid musty
10 STABILITY AND REACTIVITY
Chemical Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Polyisocyanates are highly reactive chemicals that should be handled and stored in a way to
avoid many common substances, including water and moisture. Product is stable under
normal conditions.
Moisture and/or water. High temperatures, sparks, flame and temperature above 350 F.
Water; strong bases; alcohols; amines; metal compounds;
By fire or excessive heat: carbon monoxide, carbon dioxide, oxides of nitrogen, traces of
hydrogen cyanide, ammonia and MDI vapors. Excess gas may rupture containers.
May occur with incompatible reactants, especially strong bases, water or temperatures over
320 F (50 C).
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:4 / 7
11 TOXICOLOGICAL INFORMATION
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [40-60%]
Information on toxicological effects
Acute toxicity:
Oral LD50 LD50 Oral – rat – 4,700 mg/kg
Inhalation LC50 Dermal LD50 no data available
Other information on acute toxicity
Skin corrosion/irritation: Serious eye damage/eye irritation:
Eyes – rabbit – Moderate eye irritation
Respiratory or skin sensitization: no data available
May cause allergic respiratory and skin reactions
Germ cell mutagenicity: Laboratory experiments have shown mutagenic effects.
Genotoxicity in vitro – Human – lymphocyte Sister chromatid exchange
Genotoxicity in vivo – rat – Inhalation DNA damage
Carcinogenicity:
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA
classification.
Limited evidence of carcinogenicity in animal studies
IARC: 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Diphenylmethane-4,4- diisocyanate)
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by
NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by
OSHA.
Reproductive toxicity: Reproductive toxicity – rat – Inhalation:
Maternal Effects: Other effects. Specific Developmental Abnormalities: Musculoskeletal system.
no data available
Teratogenicity: no data available
Specific target organ toxicity – single exposure (Globally Harmonized System):
May cause respiratory irritation.
Specific target organ toxicity – repeated exposure (Globally Harmonized System):
no data available
Aspiration hazard: no data available
Potential health effects: Inhalation May be fatal if inhaled. Causes respiratory tract irritation. Ingestion May be harmful if swallowed. Skin
May be harmful if absorbed through skin. Causes skin irritation. Eyes Causes eye irritation.
Signs and Symptoms of Exposure: Cough, Shortness of breath, Headache, Nausea, Vomiting, Pulmonary edema. Effects may be delayed.
Synergistic effects: no data available
Additional Information:
RTECS: NQ9350000
12 ECOLOGICAL INFORMATION
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:5 / 7
4,4′-Methylenediphenyl diisocyanate cas#:(101-68-8) [40-60%]
Information on ecological effects
Toxicity:
Toxicity to daphnia EC50 – Daphnia magna (Water flea) – 0.35 mg/l – 24 h.
and other aquatic invertebrates
Persistence and degradability: no data available
Bioaccumulative potential: no data available
Mobility in soil: no data available
PBT and vPvB assessment: no data available
Other adverse effects: Do not empty into drains.
no data available
13 DISPOSAL CONSIDERATIONS
Disposal: Any disposal practice must be in compliance with all federal, state and local laws and regulations. Chemical
additions, processing or otherwise altering this material may make the waste management information presented in this
MSDS incomplete, inaccurate or otherwise inappropriate. Waste characterization and disposal compliance are the
responsibility solely of the party generating the waste or deciding to discard or dispose of the material.
Do not allow material to enter sewers, a body of water, or contact the ground. Refer to RCRA 40 CFR 261, and/or any other
appropriate federal, state or local requirements for proper classification information.
14 TRANSPORT INFORMATION
DOT – Non DOT/non RCRA regulated
IATA/IMDG/ICAO – Not dangerous goods
15 REGULATORY INFORMATION
Component (CAS#) [%] – CODES
—————————————————————-
Benzene, 1,1′-methylenebis[isocyanato- (26447-40-5) [45-65%] TSCA
RQ(5000LBS), 4,4′-Methylenediphenyl diisocyanate (101-68-8) [40-60%] CERCLA, HAP, IARC, MASS, NJHS, OSHAWAC,
PA, SARA313, TSCA, TXAIR
Benzene, 1,1′-methylenebis[isocyanato-, homopolymer (39310-05-9) [15-35%] TSCA
Regulatory CODE Descriptions
—————————————————————-
RQ = Reportable Quantity
TSCA = Toxic Substances Control Act
CERCLA = Superfund clean up substance
HAP = Hazardous Air Pollutants
IARC = IARC Carcinogen Risks
MASS = MA Massachusetts Hazardous Substances List
NJHS = NJ Right-to-Know Hazardous Substances
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:6 / 7
SARA313 = SARA 313 Title III Toxic Chemicals
TXAIR = TX Air Contaminants with Health Effects Screening Level
16 OTHER INFORMATION
Disclaimer:
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no
representations as to the accuracy or completeness of the information contained herein, and assume no responsibility
regarding the suitability of this information for the user’s intended purposes or for the consequences of its use. Each individual
should make a determination as to the suitability of the information for their particular purpose(s).
Health = 2, Fire = 1, Reactivity = 1, Specific Hazard = None
Health = 2, Fire = 1, Physical Hazard = 1
X – Consult your supervisor for special instructions
NFPA:
HMIS III:
HMIS PPE:
1
2
None
2
1
X
1
1
Revision Date: 4/24/2018SDS Number: ED70.7 PART A 30000 CA Page:7 / 7
by | Sep 27, 2025
~
1
PRODUCT NAME: SPL T6010 A DATE: 6/01/19
MSDS NUMBER: SPL T6010 A SUPERSEDES MSDS: 6/01/15
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER: TRANSPORTATION EMERGENCY CALL CHEMTREC:
Eteco, Inc. 800 424 9300
1000 South Linwood Ave. MEDICAL EMERGENCY INFORMATION:
Santa Ana, CA 92705 800 328 8501
Phone: 714 480 1370
PRODUCT IDENTIFICATION NUMBER: SPL T6010 A
CHEMICAL FAMILY: AROMATIC ISOCYANATE
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Pale Yellow Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m%, the highest dose tested. This is well above
the recommended TLV of Sppb (0.05 mg/m ). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
by | Sep 27, 2025
y) uw
Safety Data Sheet
SPL-H 5070 A
Safety Data Sheet dated: 8/10/2023 – version 2
Date of first edition: 7/17/2023 = T [= C Oo me.
POLYURETHANE SPECIALIST
1, IDENTIFICATION
Product identifier
Mixture identification:
Trade name: SPL-H 5070 A
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use: N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company: ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable: N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2, HAZARD(S) IDENTIFICATION
Classification of the chemical
Skin irritation, Category 2 Causes skin irritation.
Eye irritation, Category 2A Causes serious eye irritation.
Respiratory Sensitization, Category 1 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Skin Sensitization, Category 18 May cause an allergic skin reaction.
Carcinogenicity, Category 2 Suspected of causing cancer.
Specific target organ toxicity following single exposure, May cause respiratory irritation.
Category 3
Specific target organ toxicity following repeated exposure, May cause damage to organs through prolonged or repeated
Category 2 exposure.
Acute toxicity (inhalation), Category 4 Harmful if inhaled.
Label elements
Hazard pictograms and Signal Word
ob
Danger
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
332 Harmful if inhaled.
334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
Date 8/10/2023 Production Name SPL-H 5070 A Pagen. 1 of 9
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: SPL H 4070 B REVISED DATE: June 01, 2021
MSDS NUMBER: SPL H 4070 B SUPERSEDES MSDS: June 01, 2018
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCTION IDENTIFICATION NUMBER: SPL H 4070 B
CHEMICAL FAMILY: POLYETHER POLYOL BLEND
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical State: Liquid
Potential Acute Heath Effects:
Eyes Corrosive to eyes.
Skin Corrosive to skin on contact. Skin contact may produce burns.
Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking or shortness of breath.
Ingestion May cause burns to mouth, throat and stomach.
GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards.
GHS Label Elements:
Hazard Pictograms
Signal Word: Warning
Hazard statement: Causes serious eye irritation
Precautionary statements: Wear eye protection, protective clothing, protective gloves. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
SECTION 3: COMPOSITION AND INFORMATION ON IGREDIENTS
MATERIAL OR COMPONENT
CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 40-80 %
DIETHYLTOLUENE DIAMINE (DETDA) 68479-98-1 0-10 %
GLYCOLS Mixture 0-20 %
TRIETHYLENE DIAMINE 280-57-9 0-2%
2
*Occupational Exposure Limit(s), if available, are listed in Section 8.
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention
immediately.
Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified
personnel may administer oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if
necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours as
delayed pulmonary edema may develop.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >212 F Closed Cup
Auto Ignition Temp: Not available.
Flammable Limits: Not available.
Products of Combustion:
Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen,
amines, possibly other irritating gases.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire):
Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
See Safety Data Sheet section 8 Personal Protective Equipment
Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container.
3
Large Spill and Leak Corrosive liquid. Toxic liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water
spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate
all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
SECTION 7: HANDLING AND STORAGE
Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in case of insufficient ventilation or where operational procedures
demand it. For guidance on engineering control measures refer to publications such as the ACGIH
current edition of Industrial Ventilation, a manual of Recommended Practice.
Personal Protection
Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield.
Body and Hands Full chemical suit. Gloves.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Personal Protection in case of a Large Spill
Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots.
Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
Ethylene Glycol ACGIH TLV (United States)
CEIL: 100mg/m
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Beige Slight Odor
BOILING POINT ( F/ C) Not determined
MELTING POINT ( F/ C) Not determined
SPECIFIC GRAVITY ( WATER = 1) 1.08
BULK DENSITY 8.27 lb/gal
pH OF UNDILUTED PRODUCT Not determined
VAPOR PRESSURE (MM Hg.) Not determined
VAPOR DENSITY (AIR-1) >1
VISCOSITY 700-1100 cps @ 25 C
PERCENT (%) VOC 0
4
SOLUBILITY IN WATER Soluble
SECTION 10: STABILITY AND REACTIVITY
Stability and Reactivity This product is stable.
Conditions of Stability Avoid moisture to protect product quality.
Incompatibility with Various Substances
Slightly reactive to reactive with oxidizing agents, alkalis.
Hazardous Decomposition Products
Thermal decomposition products are toxic and may include oxides of carbon and
nitrogen, amines, possibly other irritating gases.
Hazardous Polymerization Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
No applicable data for this section.
SECTION 12I: ECOLOGICAL INFORMATION
No applicable data for this section.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems.
Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a
scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or
crushed to prevent reuse.
Material for disposal should be placed in appropriated sealed containers to avoid potential human and
environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal
contractor and environmental agency for relevant laws and regulations. Under the US, Resource
Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at
the time of disposal, whether the product meets relevant waste classification and to assure proper
disposal.
SECTION 14: TRANSPORT INFORMATION
Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
DOT Classification Non Regulated
TDG Classification Non Regulated
IMO/IMDG Classification Non Regulated
ICAO/IATA Classification Non Regulated
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
5
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification
Class: Corrosive material
TSCA 8(b) inventory: All ingredients Listed.
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
Ethylene Glycol (CAS# 107-21-1) Reportable Quantity (RQ) 5000 lbs.
Any spill or release above the RC must be reported to the National Response Center (800-424-8802)
SARA 313 toxic chemical notification and release reporting: Ethylene Glycol 6%
State Regulations California prop 65: No ingredients listed.
Canadian Regulations
This product has been classified in accordance with the hazard criteria of the CPR
(Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2A: Material causing other toxic effects (Very Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL/NDSL Not all Ingredients Listed.
SECTION 16: OTHER INFORMATION
Causes respiratory tract, eye and skin burns.
Harmful if inhaled.
May be harmful if swallowed.
Contains material, which may cause birth defects based on animal data.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 3 Health: 3
Fire Hazard: 1 Fire Hazard: 1
Reactivity: 0 Reactivity: 0
Notice to Reader
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANT Y, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOUL D BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
6
Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be
determined by the user and made known to handlers, processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APPROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: SPL H4070 A DATE: June 1, 2021
MSDS NUMBER: SPL H4070 A SUPERSEDES MSDS: June 1, 2018
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCT IDENTIFICATION NUMBER: SPL H4070 A
CHEMICAL FAMILY: AROMATIC ISOCYANATE
SECTION 2: HAZARD IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Pale Yellow Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNES S, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG -TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTA CT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALA TION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m
3
, the highest dose tested. This is well above
the recommended TLV of 5ppb (0.05 mg/m
3
). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
2
Aggravated Medical Conditions:
Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-
specific bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates.
GHS Label Elements:
Hazard pictograms
Signal Word: Danger
Hazard statement: Harmful if inhaled. Causes skin and eye irritation.
May Cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
SECTION 3: HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 25-45 %
4,4 DIPHENYLMETHANE DIISOCYANATE 101-68-8 <50%
MODIFIED MDI 26447-40-5 <10%
*Occupational Exposure Limit(s) if available, are listed in section 8.
SECTION 4: FIRST AID MEASURES
Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get immediate medical attention.
Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water.
If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has
demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water.
Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical
attention.
Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim
is unconscious or having convulsions. Get immediate medical attention.
NOTES TO PHYSICIANS : There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive
therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.
Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is
recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a
minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased,
recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as
having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >110 C, Closed Cup.
Autoignition: >600 C.
Flammable Limits: Not available.
Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
3
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks
and static discharge or combustible materials.
Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be
used to avoid inhalation of the product.
Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed
containers. This reaction accelerates at higher temperatures.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages
should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further
leakage, spillage or entry into drains.
Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth
or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area
with
Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly
dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is
reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15).
Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium
hydroxide). Follow the precautions on the supplier s material safety data sheets when preparing and using solution.
Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums.
Do not tighten the bungs. Mixing with wet earth is also effective, but slower.
SECTION 7: HANDLING AND STORAGE
Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that
the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly
because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for
details.)
Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from
moisture. Due to reaction with water, producing CO -gas, a hazardous build-up of pressure could result if contaminated
containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be
resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or
galvanized surfaces.
Ideal storage temperature is 16-38 C (60-100 F).
Keep stocks of decontaminant (see Section 6) readily available.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For
guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial
Ventilation, a manual of Recommended Practice .
4
Personal Protection
Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield.
Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl
rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be
selected and used in accordance with Guidelines for the Selection of Chemical Protective Clothing published by ACGIH.
Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH
positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges
and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has
been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134).
Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing
apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Product Name Exposure Limits
4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m (8-hour, 40 hours/week)
OSHA PEL Ceiling Limit 0.20 mg/m
NIOSH REL/TWA 0.05 mg/m (10-hour, 40 hours/week)
NIOSH REL/CEILING 0.20 mg/m (10-minutes)
Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with
respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic
Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their
suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that
caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized
individuals.
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Pale Yellow Liquid Slightly Musty
BOILING POINT ( C) >300 C
MELTING POINT ( F/ C) Not available
SPECIFIC GRAVITY ( WATER = 1) 1.07 gr/ml
BULK DENSITY 9.0 lb/gal
pH Not applicable
VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25 C
VAPOR DENSITY (AIR-1) 8.5
VISCOSITY 900-1300 cps @ 25 C
PERCENT (%) VOC 0%
FLASH POINTS >110 C (230 F) Closed Cup
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at room temperature.
Incompatibility with various Substances: Reactive with moisture.
Conditions of Instability: Avoid high temperatures. Avoid freezing.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary
amines and metal compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
5
Toxicity to Animals: LD50 Rat Oral: >5000mg/kg
LD50 Rabbit Dermal: >5000 mg/kg
Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or
aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include
irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty
in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive
response to even minimal concentrations of MDI may develop in sensitized persons.
Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited
evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the
need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance
work.
Eye Contact: The vapor, aerosol, and liquid are irritant.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is
considered practically non-toxic by ingestion.
Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE)
Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not
regulated as carcinogens by OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects: There is no substantial evidence of mutagenic potential.
Reproductive Effects: No adverse reproductive effects are anticipated.
Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at
doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not
maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined
limits.
Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to
atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m . No adverse effects were
observed at 0.2 mg/m . At the 1mg/m concentration, minimal nasal and lung irritant effect were seen. Only at the top
concentration (6.0 mg/m ) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant
pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m group. MDI administration to rats in this study did not
change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung
tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In
the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely
that tumor formation will occur.
There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli)
> 100ml/l.
Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise
based on consideration of the production and use of the substance.
Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable
solids.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information: The generation of waste should be avoided or minimized wherever possible.
6
Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous
waste under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The
treated waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never
be poured down drains, sewers or waterways.
Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed.
SECTION 14: TRANSPORT INFORMATION
For major spills call Chemtrec (800-424-9300).
DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of
4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl
Diisocyanate), 9, NA3082, PGlll, RQ.
TDG Classification: Not regulated.
IMO/IMDG Classification: Not regulated.
ICAO/IATA Classification: Not regulated.
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification: Class: Toxic
Class: Irritating substance.
Class: Sensitizing substance.
TSCA 8(b) inventory: All Ingredients Listed
EPCRA Section 313 (40 CFR 372)
Diisocyanate Compounds (Category Code N120) 73.18%
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act): 4,4-
Methylene diphenyl diisocyanate (CAS 101-68-8) has 5000 lb. RQ (reportable quantity). Any spills or releases above the
RQ must be reported to the National Response Center (800-424-8802). This product does not contain nor is it
manufactured with ozone depleting substances.
State Regulations: California prop. 65: No ingredients listed.
Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled
Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA: DSL/NDSL: All Ingredients Listed.
SECTION 16: OTHER INFORMATION
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE
HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EY E AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
7
Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity: 1
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date
of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND
RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRI BED IN THIS
PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing
circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers,
processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
Trademark of The Dow Chemical Company (“Dow”) or an affiliated
company of Dow
Page 1 of 17
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: FROTH-PAK 60REF 1.75 HFC Insulating Foam
Sealant
Issue Date: 04/10/2015
Print Date: 06/11/2015
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK 60REF 1.75 HFC Insulating Foam Sealant
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. Component(s) for the manufacture of urethane polymers. We
recommend that you use this product in a manner consistent with the listed use. If your intended use is
not consistent with the stated use, please contact your sales or technical service representative.
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number: 800-258-2436
SDSQuestion@dow.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Reproductive toxicity – Category 2
Label elements
Hazard pictograms
Product name: FROTH-PAK 60REF 1.75 HFC Insulating Foam
Sealant
Issue Date: 04/10/2015
Page 2 of 17
Signal word: WARNING!
Hazards
Suspected of damaging fertility or the unborn child.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Use personal protective equipment as required.
Response
IF exposed or concerned: Get medical advice/ attention.
Storage
Store locked up.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
no data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Construction and composite applications
This product is a mixture.
Component CASRN Concentration
1,1,1,2-Tetrafluoroethane 811-97-2 >= 10.0 – <= 30.0 %
Glycerol propylene oxide polymer 25791-96-2 >= 10.0 – <= 30.0 %
Polyester polyol, aromatic Not available >= 10.0 – <= 30.0 %
Sucrose , propylene oxide 9049-71-2 >= 10.0 – <= 30.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 10.0 – <= 30.0 %
1,1,1,3,3 - Pentafluoropropane 460-73-1 >= 1.0 – <= 10.0 %
Product name: FROTH-PAK 60REF 1.75 HFC Insulating Foam
Sealant
Issue Date: 04/10/2015
Page 3 of 17
Triethyl phosphate 78-40-0 >= 1.0 – <= 5.0 %
Ethylene glycol 107-21-1 > 0.1 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Wash off with plenty of water.
Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. This material is a
cholinesterase inhibitor. Treat symptomatically. In case of severe acute poisoning, use antidote
immediately after establishing an open airway and respiration. Atropine, only by injection, is the
preferable antidote. Oximes, such as 2-PAM/protopam, may be therapeutic if used early; however,
use only in conjunction with atropine. Attempt seizure control with diazepam 5-10 mg (adults)
intravenous over 2-3 minutes. Repeat every 5-10 minutes as needed. Monitor for hypotension,
respiratory depression, and need for intubation. Consider second agent if seizures persist after 30
mg. If seizures persist or recur administer phenobarbital 600-1200 mg (adults) intravenous diluted in
60 ml 0.9% saline given at 25-50 mg/minute. Evaluate for hypoxia, dysrhythmia, electrolyte
disturbance, hypoglycemia (treat adults with dextrose 100 mg intravenous). If exposed, plasma and
red blood cell cholinesterase tests may indicate significance of exposure (baseline data are useful).
Exposure may increase myocardial irritability . Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
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5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire situation.
Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption may occur
upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
Accidental Release Measures and the Ecological Information sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Spilled material may cause a slipping
hazard. Use appropriate safety equipment. For additional information, refer to Section 8, Exposure
Controls and Personal Protection. Keep personnel out of confined or poorly ventilated areas. Keep
upwind of spill. Ventilate area of leak or spill. Confined space entry procedures must be followed
before entering the area. Refer to section 7, Handling, for additional precautionary measures.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
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containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Wash thoroughly
after handling. Keep container closed. Use only with adequate ventilation. This material is
hygroscopic in nature. Contents under pressure. Do not puncture or incinerate container. Do not
enter confined spaces unless adequately ventilated. See Section 8, EXPOSURE CONTROLS AND
PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Store under cover in a dry, clean, cool, well ventilated place away from
sunlight. Blowing agent may migrate from product and accumulate in some storage situations.
Storage stability
Storage temperature: Storage Period:
24 C (75 F) 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
1,1,1,2-Tetrafluoroethane US WEEL TWA 1,000 ppm
1,1,1,3,3 -
Pentafluoropropane
US WEEL TWA 300 ppm
Triethyl phosphate US WEEL TWA 7.45 mg/m3
Ethylene glycol Dow IHG TWA 50 mg/m3
Dow IHG STEL 100 mg/m3
ACGIH C Aerosol only 100 mg/m3
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material when prolonged or
frequently repeated contact could occur. Examples of preferred glove barrier
materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol
laminate ( EVAL ). Polyvinyl alcohol ( PVA ). Styrene/butadiene rubber. Viton.
Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber
( latex ). Polyvinyl chloride ( PVC or vinyl ). NOTICE: The selection of a specific
glove for a particular application and duration of use in a workplace should also take
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into account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Wear clean, body-covering clothing.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, use an approved respirator. When respiratory protection is
required, use an approved positive-pressure self-contained breathing apparatus or positive-
pressure airline with auxiliary self-contained air supply. For emergency conditions, use an
approved positive-pressure self-contained breathing apparatus. In confined or poorly
ventilated areas, use an approved self-contained breathing apparatus or positive pressure air
line with auxiliary self-contained air supply.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Liquid.
Color Yellow
Odor Characteristic
Odor Threshold No test data available
pH Not applicable
Melting point/range No test data available
Freezing point No test data available
Boiling point (760 mmHg) No test data available
Flash point closed cup > 100 C ( > 212 F) Estimated.
Evaporation Rate (Butyl Acetate
= 1)
No test data available
Flammability (solid, gas) Not applicable to liquids
Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure
Not applicable
Relative Vapor Density (air = 1)
No test data available
Relative Density (water = 1) 1.18 Calculated.
Water solubility No test data available
Partition coefficient: n-
octanol/water
no data available
Auto-ignition temperature No test data available
Decomposition temperature No test data available
Kinematic Viscosity 2,240 cSt
ASTM D4878
Explosive properties Not explosive
Oxidizing properties No
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Issue Date: 04/10/2015
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Molecular weight
no data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: no data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Will not occur by itself.
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
11. TOXICOLOGICAL INFORMATION
Toxicological information on this product or its components appear in this section when such data is
available.
Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. Signs and symptoms of excessive exposure may include: May cause
lacrimation (tears). Salivation. Convulsions. Tremors. Increased activity (hyperactivity).
As product: Single dose oral LD50 has not been determined.
LD50, Rat, > 2,000 mg/kg Estimated.
Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
LD50, Rabbit, > 2,000 mg/kg Estimated.
Acute inhalation toxicity
Prolonged excessive exposure may cause adverse effects. In confined or poorly ventilated
areas, vapor can easily accumulate and can cause unconsciousness and death due to
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displacement of oxygen. May cause respiratory irritation and central nervous system
depression. Excessive exposure may increase sensitivity to epinephrine and increase
myocardial irritability (irregular heartbeats). Symptoms of excessive exposure may be
anesthetic or narcotic effects; dizziness and drowsiness may be observed.
As product: The LC50 has not been determined.
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight eye irritation.
May cause slight temporary corneal injury.
Sensitization
For skin sensitization:
No relevant data found.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Contains a component which is reported to be a weak organophosphate-type cholinesterase inhibitor.
Contains component(s) which have been reported to cause effects on the following organs in animals:
Heart.
Liver.
Carcinogenicity
No relevant data found.
Teratogenicity
Contains component(s) which, in laboratory animals, have been toxic to the fetus at doses nontoxic to
the mother. Contains component(s) which, in laboratory animals, have been toxic to the fetus only at
doses toxic to the mother.
Reproductive toxicity
In animal studies on component(s), effects on reproduction were seen only at doses that produced
significant toxicity to the parent animals.
Mutagenicity
Genetic toxicity studies on tested components were predominantly negative. Contains component(s)
which were negative in some animal genetic toxicity studies and positive in others.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
COMPONENTS INFLUENCING TOXICOLOGY:
1,1,1,2-Tetrafluoroethane
Acute inhalation toxicity
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LC50, Rat, 4 Hour, vapour, > 1,500 mg/l
Glycerol propylene oxide polymer
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not
likely to be hazardous. Vapor from heated material or mist may cause respiratory irritation.
The LC50 has not been determined.
Polyester polyol, aromatic
Acute inhalation toxicity
The LC50 has not been determined.
Sucrose , propylene oxide
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility; single exposure is not
likely to be hazardous. Vapor from heated material or mist may cause respiratory irritation.
Typical for this family of materials. No deaths occurred following exposure to a saturated
atmosphere.
Tris(1-chloro-2-propyl) phosphate
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 7 mg/l
1,1,1,3,3 – Pentafluoropropane
Acute inhalation toxicity
LC50, Rat, 4 Hour, vapour, 1,096 mg/l
Triethyl phosphate
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 2.35 mg/l No deaths occurred at this concentration.
Ethylene glycol
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility. With good ventilation,
single exposure is not expected to cause adverse effects. If material is heated or areas are
poorly ventilated, vapor/mist may accumulate and cause respiratory irritation and symptoms
such as headache and nausea.
LC50, Rat, male and female, 6 Hour, dust/mist, > 2.5 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicological information on this product or its components appear in this section when such data
is available.
Toxicity
1,1,1,2-Tetrafluoroethane
Acute toxicity to fish
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Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, 450 mg/l
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 980 mg/l
Toxicity to bacteria
EC50, Pseudomonas putida, static test, 6 Hour, Growth inhibition, > 730 mg/l
Glycerol propylene oxide polymer
Acute toxicity to fish
For this family of materials:
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, mortality, >= 10 mg/l
LOEC, Daphnia magna (Water flea), semi-static test, 21 d, mortality, > 10 mg/l
Polyester polyol, aromatic
Acute toxicity to fish
No relevant data found.
Sucrose , propylene oxide
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Danio rerio (zebra fish), static test, 96 Hour, 6,310 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 9,890 mg/l, OECD Test Guideline
202 or Equivalent
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, mortality, >= 10 mg/l
LOEC, Daphnia magna (Water flea), semi-static test, 21 d, mortality, > 10 mg/l
Tris(1-chloro-2-propyl) phosphate
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent
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Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l
LOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, > 32 mg/l
1,1,1,3,3 – Pentafluoropropane
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, > 100 mg/l
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, > 100 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Selenastrum capricornutum (green algae), static test, 72 Hour, Growth rate, > 118 mg/l
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 14 d, mortality, 29 mg/l
Triethyl phosphate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Leuciscus idus (Golden orfe), static test, 48 Hour, 2,140 mg/l, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/l, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 900 mg/l,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/l, OECD 209 Test
Ethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), static test, 96 Hour, 72,860 mg/l, Other
guidelines
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, > 100 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
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ErC50, Pseudokirchneriella subcapitata (green algae), 96 Hour, Growth rate inhibition, 6,500 –
13,000 mg/l, Other guidelines
Toxicity to bacteria
EC50, activated sludge, 30 min, 225 mg/l, OECD 209 Test
Persistence and degradability
1,1,1,2-Tetrafluoroethane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 4 %
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Theoretical Oxygen Demand: 0.47 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 1,700 d
Method: Estimated.
Glycerol propylene oxide polymer
Biodegradability: For this family of materials: Based on stringent OECD test guidelines, this
material cannot be considered as readily biodegradable; however, these results do not
necessarily mean that the material is not biodegradable under environmental conditions.
Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for
inherent biodegradability).
Polyester polyol, aromatic
Biodegradability: No relevant data found.
Sucrose , propylene oxide
Biodegradability: Based on information for a similar material: Material is inherently
biodegradable (reaches > 20% biodegradation in OECD test(s) for inherent biodegradability).
Tris(1-chloro-2-propyl) phosphate
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Not applicable
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 302A or Equivalent
Theoretical Oxygen Demand: 1.17 mg/mg
Photodegradation
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Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 0.24 d
Method: Estimated.
1,1,1,3,3 – Pentafluoropropane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 8 %
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Theoretical Oxygen Demand: 0.60 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 360 d
Method: Estimated.
Triethyl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
Ethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD
test(s) for inherent biodegradability).
10-day Window: Pass
Biodegradation: 90 – 100 %
Exposure time: 10 d
Method: OECD Test Guideline 301A or Equivalent
10-day Window: Not applicable
Biodegradation: 90 %
Exposure time: 1 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.29 mg/mg
Bioaccumulative potential
Bioaccumulation: No data available.
Mobility in soil
1,1,1,2-Tetrafluoroethane
Potential for mobility in soil is high (Koc between 50 and 150).
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Partition coefficient(Koc): 97 Estimated.
Glycerol propylene oxide polymer
No relevant data found.
Polyester polyol, aromatic
No relevant data found.
Sucrose , propylene oxide
No relevant data found.
Tris(1-chloro-2-propyl) phosphate
Potential for mobility in soil is slight (Koc between 2000 and 5000).
Partition coefficient(Koc): 1300 Estimated.
1,1,1,3,3 – Pentafluoropropane
Potential for mobility in soil is medium (Koc between 150 and 500).
Partition coefficient(Koc): 280 Estimated.
Triethyl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry s constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient(Koc): 48 Estimated.
Ethylene glycol
Given its very low Henry s constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient(Koc): 1 Estimated.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PR ACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USIN G THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRO DUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Co mposition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred opti ons include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
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Proper shipping name Chemical under pressure, n.o.s.
UN number UN 3500
Class 2.2
Packing group
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S.
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.
UN number UN 3500
Class 2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard
This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard
Chronic Health Hazard
Sudden Release of Pressure Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
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Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
1,4-Dioxane 123-91-1
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
WARNING: This product contains a chemical(s) known to the State of California to cause cancer.
Components CASRN
1,4-Dioxane 123-91-1
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
:
16. OTHER INFORMATION
Product Literature
Additional information on this product may be obtained by calling your sales or customer service
contact.
Hazard Rating System
NFPA
Health Fire Reactivity
2 1 0
Revision
Identification Number: 101194191 / A001 / Issue Date: 04/10/2015 / Version: 6.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
C Ceiling limit
Dow IHG Dow Industrial Hygiene Guideline
STEL Short term exposure limit
TWA Time weighted average
US WEEL USA. Workplace Environmental Exposure Level s (WEEL)
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or rec ipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
Product name: FROTH-PAK 60REF 1.75 HFC Insulating Foam
Sealant
Issue Date: 04/10/2015
Page 17 of 17
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer s/user s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer s/user s duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
by | Sep 27, 2025
Trademark of The Dow Chemical Company (“Dow”) or an affiliated
company of Dow
Page 1 of 15
SAFETY DATA SHEET
THE DOW CHEMICAL COMPANY
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Print Date: 06/11/2015
THE DOW CHEMICAL COMPANY encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam Sealant
Recommended use of the chemical and restrictions on use
Identified uses: Component(s) for the manufacture of urethane polymers.
COMPANY IDENTIFICATION
THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND MI 48674-0000
UNITED STATES
Customer Information Number: 800-258-2436
SDSQuestion@dow.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard
29CFR 1910.1200.
Acute toxicity – Category 4 – Inhalation
Skin irritation – Category 2
Eye irritation – Category 2B
Respiratory sensitisation – Category 1
Skin sensitisation – Category 1
Carcinogenicity – Category 2
Specific target organ toxicity – single exposure – Category 3
Specific target organ toxicity – repeated exposure – Category 2 – Inhalation
Label elements
Hazard pictograms
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 2 of 15
Signal word: DANGER!
Hazards
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
Suspected of causing cancer.
May cause damage to organs (Respiratory system) through prolonged or repeated exposure if
inhaled.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves.
Use personal protective equipment as required.
In case of inadequate ventilation wear respiratory protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
no data available
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 3 of 15
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature: Construction and composite applications
This product is a mixture.
Component CASRN Concentration
Diphenylmethane Diisocyanate, isomers and
homologues
9016-87-9 >= 60.0 – <= 100.0 %
4,4 -Methylenediphenyl diisocyanate 101-68-8 30.0 - 60.0 %
1,1,1,2-Tetrafluoroethane 811-97-2 >= 5.0 – <= 10.0 %
Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
4. FIRST AID MEASURES
Description of first aid measures
General advice: First Aid responders should pay attention to self-protection and use the
recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.
Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed: Aside from the information found
under Description of first aid measures (above) and Indication of immediate medical attention and
special treatment needed (below), any additional important symptoms and effects are described in
Section 11: Toxicology Information.
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 4 of 15
Indication of any immediate medical attention and special treatment needed
Notes to physician: Excessive exposure may aggravate preexisting asthma and other respiratory
disorders (e.g. emphysema, bronchitis, reactive airways dysfunction syndrome). Maintain adequate
ventilation and oxygenation of the patient. May cause respiratory sensitization or asthma-like
symptoms. Bronchodilators, expectorants and antitussives may be of help. Treat bronchospasm with
inhaled beta2 agonist and oral or parenteral corticosteroids. Respiratory symptoms, including
pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-48
hours for signs of respiratory distress. If you are sensitized to diisocyanates, consult your physician
regarding working with other respiratory irritants or sensitizers. Exposure may increase myocardial
irritability . Do not administer sympathomimetic drugs such as epinephrine unless absolutely
necessary. Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: no data available
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen fluoride.
Hydrogen cyanide. Carbon monoxide. Carbon dioxide.
Unusual Fire and Explosion Hazards: Product reacts with water. Reaction may produce heat and/or
gases. This reaction may be violent. Container may rupture from gas generation in a fire situation.
Vaporizes quickly at room temperature. Vapors are heavier than air and may travel a long distance
and accumulate in low lying areas. Dense smoke is emitted when burned without sufficient oxygen.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Fight fire from protected location or safe distance. Consider the use of unmanned hose holders or
monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound from
venting safety device or discoloration of the container. Do not use direct water stream. May spread
fire. Move container from fire area if this is possible without hazard. Use water spray to cool fire-
exposed containers and fire-affected zone until fire is out.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 5 of 15
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of low areas.
Keep personnel out of confined or poorly ventilated areas. Keep upwind of spill. Spilled material may
cause a slipping hazard. Ventilate area of leak or spill. Confined space entry procedures must be
followed before entering the area. If available, use foam to smother or suppress. Refer to section 7,
Handling, for additional precautionary measures. See Section 10 for more specific information. Use
appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and
Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Vermiculite. Sand. Clay. Do NOT use absorbent materials such
as: Cement powder (Note: may generate heat). Collect in suitable and properly labeled open
containers. Do not place in sealed containers. Suitable containers include: Metal drums. Plastic
drums. Polylined fiber pacs. Wash the spill site with large quantities of water. Attempt to neutralize
by adding suitable decontaminant solution: Formulation 1: sodium carbonate 5 - 10%; liquid detergent
0.2 - 2%; water to make up to 100%, OR Formulation 2: concentrated ammonia solution 3 - 8%; liquid
detergent 0.2 - 2%; water to make up to 100%. If ammonia is used, use good ventilation to prevent
vapor exposure. Contact your supplier for clean-up assistance. See Section 13, Disposal
Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes, skin, and clothing. Avoid prolonged or
repeated contact with skin. Avoid breathing vapor. Use with adequate ventilation. Wash thoroughly
after handling. Keep container tightly closed. Do not enter confined spaces unless adequately
ventilated. See Section 8, EXPOSURE CONTROLS AND PERSONAL PROTE CTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Store in a dry place. Protect from atmospheric moisture. Do not store
product contaminated with water to prevent potential hazardous reaction. See Section 10 for more
specific information. Additional storage and handling information on this product may be obtained by
calling your sales or customer service contact.
Storage stability
Storage temperature: Storage Period:
15 - 27 C (59 - 81 F) 6 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure limits are listed below, if they exist.
Component Regulation Type of listing Value/Notation
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 6 of 15
4,4 -Methylenediphenyl
diisocyanate
ACGIH TWA 0.005 ppm
OSHA Z-1 C 0.2 mg/m3 0.02 ppm
1,1,1,2-Tetrafluoroethane US WEEL TWA 1,000 ppm
Exposure controls
Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilationto control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in
areas with poor ventilation.
Individual protection measures
Eye/face protection: Use chemical goggles.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Butyl rubber. Polyethylene. Chlorinated
polyethylene. Ethyl vinyl alcohol laminate ( EVAL ). Examples of acceptable glove
barrier materials include: Viton. Neoprene. Polyvinyl chloride ( PVC or vinyl ).
Nitrile/butadiene rubber ( nitrile or NBR ). NOTICE: The selection of a specific glove
for a particular application and duration of use in a workplace should also take into
account all relevant workplace factors such as, but not limited to: Other chemicals
which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure
guideline. When atmospheric levels may exceed the exposure guideline, use an approved air-
purifying respirator equipped with an organic vapor sorbent and a particle filter. For situations
where the atmospheric levels may exceed the level for which an air-purifying respirator is
effective, use a positive-pressure air-supplying respirator (air line or self-contained breathing
apparatus). For emergency response or for situations where the atmospheric level is
unknown, use an approved positive-pressure self-contained breathing apparatus or positive-
pressure air line with auxiliary self-contained air supply. In confined or poorly ventilated areas,
use an approved self-contained breathing apparatus or positive pressure air line with auxiliary
self-contained air supply.
The following should be effective types of air-purifying respirators: Organic vapor cartridge
with a particulate pre-filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state liquid
Color Brown
Odor Musty
Odor Threshold No test data available
pH Not applicable
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 7 of 15
Melting point/range
No test data available
Freezing point No test data available
Boiling point (760 mmHg) No test data available
Flash point closed cup Not applicable, Gas
Evaporation Rate (Butyl Acetate
= 1)
No test data available
Flammability (solid, gas) No
Lower explosion limit No test data available
Upper explosion limit No test data available
Vapor Pressure 225 lb/in2
at 54 C (129 F) Container is under pressure.
Relative Vapor Density (air = 1)
No test data available
Relative Density (water = 1) 1.24
at 25 C (77 F) / 25 C Estimated.
Water solubility insoluble, reacts, evolution of CO2
Partition coefficient: n-
octanol/water
no data available
Auto-ignition temperature No test data available
Decomposition temperature No test data available
Kinematic Viscosity No test data available
Explosive properties Not explosive
Oxidizing properties No
Molecular weight No test data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: no data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Can occur.
Conditions to avoid: Elevated temperatures can cause container to vent and/or rupture. Exposure to
elevated temperatures can cause product to decompose. Generation of gas during decomposition
can cause pressure in closed systems. Pressure build-up can be rapid. Avoid moisture. Material
reacts slowly with water, releasing carbon dioxide which can cause pressure buildup and rupture of
closed containers. Elevated temperatures accelerate this reaction.
Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Ammonia. Bases. Metal
compounds. Strong oxidizers. Diisocyanates react with many materials and the rate of reaction
increases with temperature as well as increased contact; these reactions can become violent. Contact
is increased by stirring or if the other material mixes with the diisocyanate. Diisocyanates are not
soluble in water and sink to the bottom, but react slowly at the interface. The reaction forms carbon
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 8 of 15
dioxide gas and a layer of solid polyurea. Reaction with water will generate carbon dioxide and heat.
Avoid unintended contact with polyols. The reaction of polyols and isocyanates generate heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Toxic gases are released during decomposition.
11. TOXICOLOGICAL INFORMATION
Toxicological information on this product or its components appear in this section when such data is
available.
Acute toxicity
Acute oral toxicity
Low toxicity if swallowed. Small amounts swallowed incidentally as a result of normal
handling operations are not likely to cause injury; however, swallowing larger amounts may
cause injury. Observations in animals include: Gastrointestinal irritation.
As product: Single dose oral LD50 has not been determined.
LD50, Rat, > 2,000 mg/kg Estimated.
Acute dermal toxicity
Prolonged skin contact is unlikely to result in absorption of harmful amounts.
As product: The dermal LD50 has not been determined.
LD50, Rabbit, > 2,000 mg/kg Estimated.
Acute inhalation toxicity
In confined or poorly ventilated areas, vapor can easily accumulate and can cause
unconsciousness and death due to displacement of oxygen. Excessive exposure may cause
irritation to upper respiratory tract (nose and throat) and lungs. May cause pulmonary edema
(fluid in the lungs.) Effects may be delayed. Decreased lung function has been associated
with overexposure to isocyanates. Excessive exposure may increase sensitivity to
epinephrine and increase myocardial irritability (irregular heartbeats). May cause central
nervous system effects. Symptoms of excessive exposure may be anesthetic or narcotic
effects; dizziness and drowsiness may be observed.
As product: The LC50 has not been determined.
Skin corrosion/irritation
Prolonged contact may cause skin irritation with local redness.
May stain skin.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight temporary corneal injury.
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
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Issue Date: 04/10/2015
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May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in the chest.
Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Teratogenicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother. Contains component(s) which did not cause birth
defects in animals; other fetal effects occurred only at doses toxic to the mother.
Reproductive toxicity
No relevant data found.
Mutagenicity
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other
in vitro studies were negative. Animal mutagenicity studies were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
COMPONENTS INFLUENCING TOXICOLOGY:
Diphenylmethane Diisocyanate, isomers and homologues
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l
For similar material(s): 2,4 -Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4
Hour, Aerosol, 0.31 mg/l
For similar material(s): 4,4 -Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1
Hour, Aerosol, 2.24 mg/l
4,4 -Methylenediphenyl diisocyanate
Acute inhalation toxicity
LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l
1,1,1,2-Tetrafluoroethane
Acute inhalation toxicity
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
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Issue Date: 04/10/2015
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LC50, Rat, 4 Hour, vapour, > 1,500 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicological information on this product or its components appear in this section when such data
is available.
Toxicity
Diphenylmethane Diisocyanate, isomers and homologues
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
4,4 -Methylenediphenyl diisocyanate
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
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Issue Date: 04/10/2015
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Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
1,1,1,2-Tetrafluoroethane
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), semi-static test, 96 Hour, 450 mg/l
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 980 mg/l
Toxicity to bacteria
EC50, Pseudomonas putida, static test, 6 Hour, Growth inhibition, > 730 mg/l
Persistence and degradability
Diphenylmethane Diisocyanate, isomers and homologues
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
4,4 -Methylenediphenyl diisocyanate
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
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Issue Date: 04/10/2015
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Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
1,1,1,2-Tetrafluoroethane
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability.
10-day Window: Fail
Biodegradation: 4 %
Exposure time: 28 d
Method: OECD Test Guideline 301D or Equivalent
Theoretical Oxygen Demand: 0.47 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitizer: OH radicals
Atmospheric half-life: 1,700 d
Method: Estimated.
Bioaccumulative potential
Diphenylmethane Diisocyanate, isomers and homologues
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
4,4 -Methylenediphenyl diisocyanate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
1,1,1,2-Tetrafluoroethane
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 1.68 Estimated.
Mobility in soil
Diphenylmethane Diisocyanate, isomers and homologues
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
4,4 -Methylenediphenyl diisocyanate
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
1,1,1,2-Tetrafluoroethane
Potential for mobility in soil is high (Koc between 50 and 150).
Partition coefficient(Koc): 97 Estimated.
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
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Issue Date: 04/10/2015
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13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PR ACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USIN G THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRO DUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Co mposition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred opti ons include sending to a licensed,
permitted: Incinerator or other thermal destruction device. As a service to its customers, Dow can
provide names of information resources to help identify waste management companies and other
facilities which recycle, reprocess or manage chemicals or plastics, and that manage used drums.
Telephone Dow s Customer Information Group at 1-800-258-2436 or 1-989-832-1556 (U.S.), or 1-800-
331-6451 (Canada) for further details.
14. TRANSPORT INFORMATION
DOT
Proper shipping name Chemical under pressure, n.o.s.(FLUORINATED
HYDROCARBONS )
UN number UN 3500
Class 2.2
Packing group
Reportable Quantity MDI
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S. (FLUORINATED
HYDROCARBONS )
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(FLUORINATED
HYDROCARBONS )
UN number UN 3500
Class 2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 14 of 15
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
OSHA Hazard Communication Standard
This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard,
29 CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Acute Health Hazard
Chronic Health Hazard
Sudden Release of Pressure Hazard
Reactivity Hazard
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Components CASRN
4,4 -Methylenediphenyl diisocyanate 101-68-8
Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9
Pennsylvania Worker and Community Right-To-Know Act:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Components CASRN
Diphenylmethane Diisocyanate, isomers and
homologues
9016-87-9
4,4 -Methylenediphenyl diisocyanate 101-68-8
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances knownto the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
:
Product name: FROTH-PAK AF 60gal REF HFC ISO Spray Foam
Sealant
Issue Date: 04/10/2015
Page 15 of 15
16. OTHER INFORMATION
Revision
Identification Number: 101194148 / A001 / Issue Date: 04/10/2015 / Version: 7.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
C Ceiling
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
TWA 8-hour, time-weighted average
US WEEL USA. Workplace Environmental Exposure Level s (WEEL)
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
THE DOW CHEMICAL COMPANY urges each customer or rec ipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer s/user s responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer s/user s duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
by | Sep 27, 2025
Trademark of The Dow Chemical Company or an affiliate. DuPont Oval
Logo trademark of affiliates of DuPont de Nemours,Inc
Page 1 of 23
SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Print Date: 06/29/2021
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray Foam Sealant
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Specific target organ toxicity – repeated exposure – Category 2 – Oral
Simple Asphyxiant
Label elements
Hazard pictograms
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 2 of 23
Signal word: WARNING!
Hazards
Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed.
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF exposed or concerned: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
Wash contaminated clothing before reuse.
Storage
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Component CASRN Concentration
2-Ethylhexanoic acid potassium salt 3164-85-0 >= 1.0 – <= 10.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 10.0 – <= 30.0 %
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 3 of 23
Triethyl phosphate 78-40-0 >= 1.0 – <= 10.0 %
trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >= 10.0 – <= 30.0 %
Polyethylene glycol 25322-68-3 >= 1.0 – < 10.0 %
Polyester polyol Not available >= 20.0 – <= 80.0 %
Diethylene glycol 111-46-6 >= 1.0 – < 10.0 %
Dimethylbis((1-oxoneodecyl)oxy)stannane 68928-76-7 >= 0.25 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove contaminated clothing immediately. Immediately wash skin with soap and
plenty of water. Suitable emergency safety shower facility should be available in work area.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reuse. In the case of skin irritation or allergic reactions see a physician.
Eye contact: In case of contact, immediately flush eye with plenty of water. Suitable emergency eye
wash facility should be available in work area.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. If breathing is
difficult, oxygen should be administered by qualified personnel. Treatment of exposure should be
directed at the control of symptoms and the clinical condition of the patient.
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 4 of 23
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption
may occur upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or
poorly ventilated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate
area of leak or spill. Confined space entry procedures must be followed before entering the area.
Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 5 of 23
containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
50 C (122 F) See Section 10 for more specific information.
Storage stability
Storage Period: 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Triethyl phosphate US WEEL TWA 7.45 mg/m3
trans-1-Chloro-3,3,3-
trifluoropropene
US WEEL TWA 800 ppm
Polyethylene glycol US WEEL TWA aerosol 10 mg/m3
Diethylene glycol US WEEL TWA 10 mg/m3
Dimethylbis((1-
oxoneodecyl)oxy)stannane
OSHA Z-1 TWA 0.1 mg/m3 , Tin
ACGIH TWA 0.1 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
ACGIH STEL 0.2 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
CAL PEL PEL 0.1 mg/m3 , Tin
Further information: S: Skin
CAL PEL STEL 0.2 mg/m3 , Tin
Further information: S: Skin
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 6 of 23
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields). Where contact with the liquid is likely,
chemical goggles are recommended.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove
barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Liquefied gas
Color yellow
Odor No information available.
Odor Threshold No data available
pH No data available
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) No data available
Flash point > 200 C ( > 392 F)
Evaporation Rate (Butyl Acetate
= 1)
Not available
Flammability (solid, gas) Not applicable to liquids Not expected to form explosive dust-
air mixtures.
Lower explosion limit Not applicable
Upper explosion limit Not applicable
Vapor Pressure No data available
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) No data available
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 7 of 23
Water solubility Not applicable
Partition coefficient: n-
octanol/water
No data available
Auto-ignition temperature No data available
Decomposition temperature No test data available
Kinematic Viscosity No data available
Explosive properties Not applicableNot explosive
Oxidizing properties No data available
Molecular weight No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Will not occur by itself.
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Product test data not available. Refer to component data.
Acute dermal toxicity
Product test data not available. Refer to component data.
Acute inhalation toxicity
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 8 of 23
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product test data not available. Refer to component data.
Mutagenicity
Product test data not available. Refer to component data.
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCI NG TOXICOLOGY:
2-Ethylhexanoic acid potassium salt
Acute oral toxicity
Based on information for a similar material: LD50, Rat, female, 2,043 mg/kg OECD Test
Guideline 401
Acute dermal toxicity
Based on information for a similar material: LD50, Rabbit, > 2,000 mg/kg OECD Test
Guideline 402 No deaths occurred at this concentration.
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated
material may cause respiratory irritation. Prolonged excessive exposure to mist may cause
adverse effects.
LC50, Rat, 4 Hour, vapour, > 0.14 mg/l No deaths occurred following exposure to a saturated
atmosphere.
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
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Skin corrosion/irritation
Brief contact may cause moderate skin irritation with local redness.
Effects may be slow to heal.
Serious eye damage/eye irritation
May cause severe eye irritation.
May cause corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
For similar active ingredient(s).
In animals, effects have been reported on the following organs:
Liver.
Carcinogenicity
No relevant data found.
Teratogenicity
For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the
mother. Did not cause birth defects in laboratory animals.
Reproductive toxicity
For similar material(s): In laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals.
Mutagenicity
For similar material(s): In vitro genetic toxicity studies were negative. Animal genetic toxicity
studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Tris(1-chloro-2-propyl) phosphate
Acute oral toxicity
LD50, Rat, male and female, >1,000 mg/kg
Acute dermal toxicity
LD50, Rabbit, > 5,000 mg/kg
Acute inhalation toxicity
No deaths occurred at this concentration. LC50, Rat, 4 Hour, dust/mist, > 7 mg/l
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
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Foam Sealant
Issue Date: 02/23/2021
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Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No data available.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
No relevant data found.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Triethyl phosphate
Acute oral toxicity
LD50, Rat, 1,131 mg/kg
Acute dermal toxicity
LD50, Guinea pig, > 21,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 2.35 mg/l No deaths occurred at this concentration.
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
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Foam Sealant
Issue Date: 02/23/2021
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No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Triethyl phosphate is considered to be a weak cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination,
muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils,
blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
In vitro genetic toxicity studies were predominantly negative. Animal genetic toxicity studies
were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
trans-1-Chloro-3,3,3-trifluoropropene
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
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Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
This material was not mutagenic in an Ames bacterial assay.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Polyethylene glycol
Acute oral toxicity
Typical for this family of materials. LD50, Rat, > 10,000 mg/kg Estimated.
Acute dermal toxicity
Typical for this family of materials. LD50, Rabbit, > 20,000 mg/kg
Acute inhalation toxicity
Typical for this family of materials. LC50, Rat, 6 Hour, dust/mist, > 2.5 mg/l No deaths
occurred at this concentration.
Skin corrosion/irritation
Prolonged exposure not likely to cause significant skin irritation.
May cause more severe response if skin is abraded (scratched or cut).
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
For this family of materials:
Did not cause allergic skin reactions when tested in humans.
For this family of materials, sensitization studies done in guinea pigs have been negative.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Recent findings of kidney failure and death in burn patients, as well as some studies using
animal burn models, suggest that polyethylene glycol may have been a factor.
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Foam Sealant
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The use of topical applications containing this material may not be appropriate in severely
burned patients.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
Polyethylene glycols did not cause cancer in long-term animal studies.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Diethylene glycol
Acute oral toxicity
In humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. Ingestion of quantities (approximately 65 mL (2 oz.) for diethylene
glycol or 100 mL (3 oz.) for ethylene glycol) has caused death in humans. May cause nausea
and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney
failure. LD50, Rat, male, 19,600 mg/kg
Lethal Dose, Human, adult, 2 Ounces Estimated.
Acute dermal toxicity
LD50, Rabbit, 13,330 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 4.6 mg/l The LC50 value is greater than the Maximum
Attainable Concentration. No deaths occurred at this concentration.
Skin corrosion/irritation
Prolonged contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
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The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to
pose a carcinogenic risk to man.
Teratogenicity
Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic,
high doses in animals. Other animal studies have not reproduced birth defects even at much
higher doses that caused severe maternal toxicity.
Reproductive toxicity
Diethylene glycol did not interfere with reproduction in animal studies except at very high
doses.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
No aspiration toxicity classification
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute oral toxicity
LD50, Rat, 892 mg/kg
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact may cause skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Has caused allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
No relevant data found.
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Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
Not mutagenic in Ames Test
Aspiration Hazard
No aspiration toxicity classification
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
2-Ethylhexanoic acid potassium salt
Acute toxicity to fish
Based on information for a similar material:
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
Tris(1-chloro-2-propyl) phosphate
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l
Triethyl phosphate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
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LC50, Leuciscus idus (Golden orfe), static test, 48 Hour, 2,140 mg/l, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/l, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 900 mg/l,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/l, OECD 209 Test
trans-1-Chloro-3,3,3-trifluoropropene
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/l, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, 115 mg/l
Polyethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), static test, 96 Hour, > 10,000 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Skeletonema costatum (marine diatom), 72 Hour, Growth rate, > 100 mg/l
Diethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 75,200 mg/l,
OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 24 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
Based on data from similar materials
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EC50, Selenastrum capricornutum (green algae), 96 Hour, 6,500 – 13,000 mg/l
Toxicity to bacteria
EC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic toxicity to fish
Based on data from similar materials
NOEC, Pimephales promelas (fathead minnow), 7 d, 15,380 mg/l
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, > 15,000 mg/l
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute toxicity to aquatic invertebrates
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 7.6 mg/l, OECD Test Guideline
201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1.2 mg/l, OECD Test
Guideline 201
Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mg/l
Persistence and degradability
2-Ethylhexanoic acid potassium salt
Biodegradability: Based on information for a similar material: Material is expected to be
readily biodegradable. Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
Tris(1-chloro-2-propyl) phosphate
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability. Material is ultimately biodegradable
(reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Not applicable
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 302A or Equivalent
Theoretical Oxygen Demand: 1.17 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
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Atmospheric half-life: 0.24 d
Method: Estimated.
Triethyl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
trans-1-Chloro-3,3,3-trifluoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Polyethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 85 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 1.67 mg/mg
Diethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 90 – 100 %
Exposure time: 20 d
Method: OECD Test Guideline 301A or Equivalent
10-day Window: Not applicable
Biodegradation: 82 – 98 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Theoretical Oxygen Demand: 1.51 mg/mg
Dimethylbis((1-oxoneodecyl)oxy)stannane
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301B or Equivalent
Bioaccumulative potential
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2-Ethylhexanoic acid potassium salt
Bioaccumulation: Based on information for a similar material: Bioconcentration potential is
low (BCF < 100 or Log Pow < 3).
Tris(1-chloro-2-propyl) phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 2.59 Measured
Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured
Triethyl phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.80 Measured
trans-1-Chloro-3,3,3-trifluoropropene
Bioaccumulation: No relevant data found.
Polyethylene glycol
Partition coefficient: n-octanol/water(log Pow): -0.698 Pow: 0.2 at 30 C
Diethylene glycol
Bioaccumulation: Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 C
Bioconcentration factor (BCF): 100 Fish Measured
Dimethylbis((1-oxoneodecyl)oxy)stannane
Partition coefficient: n-octanol/water(log Pow): 5.503
Mobility in soil
2-Ethylhexanoic acid potassium salt
Based on information for a similar material:
Potential for mobility in soil is very high (Koc between 0 and 50).
Tris(1-chloro-2-propyl) phosphate
Potential for mobility in soil is slight (Koc between 2000 and 5000).
Partition coefficient (Koc): 1300 Estimated.
Triethyl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): 48 Estimated.
trans-1-Chloro-3,3,3-trifluoropropene
No relevant data found.
Polyethylene glycol
No relevant data found.
Diethylene glycol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
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Partition coefficient (Koc): < 1 Estimated.
Dimethylbis((1-oxoneodecyl)oxy)stannane
No relevant data found.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
Proper shipping name Chemical under pressure, n.o.s.(Inert Gases)
UN number UN 3500
Class 2.2
Packing group
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S. (Inert Gases)
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(Inert Gases)
UN number UN 3500
Class 2.2
Packing group
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This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Reproductive toxicity
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, a nd Liability Act of 1980 (CERCLA)
Section 103
This material does not contain any components with a CERCLA RQ.
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Diethylene glycol 111-46-6
California Prop. 65
This product contains a chemical that is at or below California Propositions 65 s "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
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Health Flammability
Physical
Hazard
2* 1 3
* = Chronic Effects (See Hazards Identification)
Revision
Identification Number: 12069390 / A749 / Issue Date: 02/23/2021 / Version: 1.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
PEL Permissible exposure limit
STEL Short-term exposure limit
TWA 8-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
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UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
