by | Sep 27, 2025
Page 1 of 7
SAFETY DATA SHEET :
o :
OB Date Issued : 10/10/2017
Ooo SDS No: F-140 REV 1 PARTA
& Date Revised : 12/16/2020
ENTERPRISES Revision No : 1
F-140 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-140 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc, CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2, HAZARDS IDENTIFICATION 3
GUS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
332: Harmful if inhaled: .
H315: Causes skin irritation.
H319: Causes serious eye irritation,
334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory imitation.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
264: Wash thoroughly after handling.
by | Sep 27, 2025
Safety Data Sheet
F 13-3004 A
Safety Data Sheet dated: 2/22/2024 – version 4
Date of first edition: 2/20/2024 E T E C O INC.
POLYURETHANE SPECIALIST
1, IDENTIFICATION
Product identifier
Mixture identification:
Trade name: F 13-3004
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use: N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company: ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable: info@etecoinc.com
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Acute toxicity (inhalation), Category 4 Harmful if inhaled.
Skin irritation, Category 2 Causes skin irritation.
Eye irritation, Category 24 Causes serious eye irritation.
Respiratory Sensitization, Category 1 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Skin Sensitization, Category 1 May cause an allergic skin reaction.
Specific target organ toxicity following single exposure, May cause respiratory irritation.
Category 3
Specific target organ toxicity following repeated exposure, May cause damage to organs through prolonged or repeated
Category 2 exposure.
Acute aquatic hazard, category 2 Toxic to aquatic life
Label elements
Hazard pictograms and Signal Word
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
Date 2/22/2024 Production Name F 13-3004 A Pagen. 1 of 9
by | Sep 27, 2025
‘ Page 1 of 5
SAFETY DATA SHEET
@
,. @ Date Issued : 10/04/2017
Go SDS No: F-126 REV 1 PARTB
@ Date Revised : 11/12/2020
ENTERPRISES Revision No : 1
F-126 REV 1 PART B
1, PRODUCT AND COMPANY IDENTIFICATION :!
PRODUCT NAME: F-126 REV | PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BIB Enterprises, Inc, CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2, HAZARDS IDENTIFICATION ae
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Aquatic Toxicity, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
– GHS LABEL
Health hazard Exclamation.
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation,
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
11373: May cause damage to organs through prolonged or repeated exposure.
H401; Toxic to aquatic life.
412: Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS,
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264; Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P305+P35 14+-P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 10/04/2017
SDS No : F-126 REV 1 PART A
Date Revised : 11/12/2020
Revision No : 1
F-126 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-126 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyurethane prepolymer 40 – 70Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 30 – 60474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
Page 1 of 5
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Polyurethane prepolymer
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Toluene diisocyanate
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA 0.005 -
STEL0.02 -
NIOSH REL
TWA - -
STEL - -
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
Page 2 of 5
F-126 REV 1 PART A
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: 0.35
FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slightly with water
SPECIFIC GRAVITY: 1.014 (water=1) at 25 C (77 F)
VISCOSITY #1: 630 Centipoise at 25 C (77 F)
(VOC): < 3.6 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: None Known
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, alcohols, and oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and
linear
> 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
Page 3 of 5
F-126 REV 1 PART A
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status IARC Status
Toluene diisocyanate 2 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Toluene diisocyanate < 0.1 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene diisocyanate < 0.126471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
Page 4 of 5
F-126 REV 1 PART A
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Toluene diisocyanate < 0.1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 11/12/2020
REVISION SUMMARY: This SDS replaces the 10/04/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
F-126 REV 1 PART A
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 10/04/2017
SDS No : F-126 REV 1 PARTA
Date Revised : 11/12/2020
ENTERPRISES Revision No : |
F-126 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-126 REV | PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24HR. EMERGENCY TELEPHONE NUMBERS
BIB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS
Polyurethane prepolymer 40-70] Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
26471-6258
4, FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5, FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
by | Sep 27, 2025
Page 1 of 6
SAFETY DATA SHEET
e
Loe) Date Issued : 04/27/2017
O’s e SDS No : F-125 REV 1 PART A
@ Date Revised : 05/05/2020
ENTERPRISES Revision No : 1
F-125 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-125 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2, HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Polyurethane prepolymer 40-70
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
Toluene diisocyanate 2471-625
4, FIRST AID MEASURES
EYES: Immediately flush with plenty of water. A fier initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water, Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam,
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
by | Sep 27, 2025
Page 1 ore
SAFETY DATA SHEET
@
6,6, @ Date Issued : 04/27/2017
O’e’ SDS No: F-125 REV 1 PARTA
@ Date Revised : 05/05/2020
ENTERPRISES Revision No : 1
F-125 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION bic iy a Os Nai ee SR
PRODUCT NAME: F- 125 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc, CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone; (714) 734-8450
2. HAZARDS IDENTIFICATION ~- Ne : : ecko
GHS CLASSIFICATIONS
This product does not meet the criteria for classification,
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS |… 3. Ei S $ Sree ee
Chemical Name
Polyurethane prepolymer 40-70
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 4749 19-59-0
Toluene diisocyanate 26471-62-5| –
4. FIRST AID MEASURES PRETO as ge ate + ; SPE Dea
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops:
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIREFIGHTING MEASURES HGR EE ee RE Ve OA Sena
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
by | Sep 27, 2025
Pee ag SHORE A POLYURETHANES
@ Dedicated to QUALITY, SERVICE, SAFETY, and INNOVATION
ENTERPRISES
An 150-9001 Certified company
F-116 REV 1 A/B Jf
15 SHORE A POLYURETHANE ELASTOMER
RoHS
BJB s F-1 Series , with its 3 to 10 minutes of work time, addresses the need for shorter processing times and higher part
production. These 5 to 95 Shore A products exhibit excellent physical properties and easily process at room temperature. You’ll
also find the easy mix ratio to be extremely convenient. F-116 REV 1 can be cartridge-dispensed with our CPE handheld dispense
equipment. For longer work times consider our M Series or L Series of elastomers.
e RoHS/REACH Compliant e Easy to Pigment e High Tensile & Tear Strength
e Special Effects & Props * Medical Training Models e Mercury/Phthalate Free
PHYSICAL PROPERTIES ee
Hardness, Shore A 1545
Canal TBS 1017
Cubic Inches per Pound 27.62
Color/Appearance Translucent Pale Amber
Tensile Strength (psi) 600
Tensile Modulus (psi) 70
Elongation (%) 1,220
Tear Strength (pli) 65
Shrinkage (in/in) linear _ ASTM D2566 @ 1 depth 0.001*
Dielectric Constant, 1 MHz ASTM D150-87 5.334
Dissipation Factor, 1 MHz 0.0452
*Note: Reported physical properties are based on test specimens cured 1-3 hours at room temperature then 16 hours at 160 F (71 C).
*Shrink test specimens are cured for 24 hours at room temperature and then 16 hours at 160 F (71 C).
HANDLING PROPERTIES Part B
Mix Ratio by weight 100
Mix Ratio by volume (cartridge dispense friendly) 99
Specific Gravity @ 77 F (25 C) 1.04
Color Pale Amber
Viscosity (cps) @ 77 F (25 C) Brookfield 4,100
Mixed Viscosity (cps) @ 77 F (25 C) Brookfield 1,200
Work Time, 100g mass @ 77 F (25 C) 4-5 minutes
Gel Time 8 9 minutes
Demold Time @ 77 F (25 C) 1-2 hours
Properties above are typical and not for specifications.
F-116 REV 1 A/B Page | of 2 Date: 12/03/2020
For more information call BJB Enterprises, Inc. (714) 734-8450 Fax (714) 734-8929
www.bjbenterprises.com
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 10/24/2017
SDS No : F-115 REV 1 PART B
Date Revised : 12/08/2020
Revision No : 1
F-115 REV 1 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-115 REV 1 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Aquatic Toxicity, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Page 1 of 5
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 80 – 100Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 1 – 5102093-68-5
Diethylmethylbenzenediamine 0.5 – 1.568479-98-1
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- < 0.5104983-85-9
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 5
F-115 REV 1 PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Pale amber
pH: No data available
PERCENT VOLATILE: 0.01
FLASH POINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.01 (water=1) at 25 C (77 F)
VISCOSITY #1: 1100 Centipoise at 25 C (77 F)
(VOC): < 0.11 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
Page 3 of 5
F-115 REV 1 PART B
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
Diethylmethylbenzenediamine > 500 mg/kg Rat > 2000 mg/kg Rat No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
NOTES: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid
release to the environment.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
Page 4 of 5
F-115 REV 1 PART B
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No. 68479-98-1) which is subject to TSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product does not contain any chemicals which are known to the State of California to cause cancer,
birth defects or other reproductive harm.
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 12/08/2020
REVISION SUMMARY: This SDS replaces the 10/24/2017 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
F-115 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 10/24/2017
SDS No : F-115 REV 1 PART A
Date Revised : 12/08/2020
Revision No : 1
F-115 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: F-115 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyurethane prepolymer 30 – 60Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 30 – 60474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
Page 1 of 5
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Polyurethane prepolymer
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Toluene diisocyanate
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA 0.005 -
STEL0.02 -
NIOSH REL
TWA - -
STEL - -
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
Page 2 of 5
F-115 REV 1 PART A
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: 0.27
FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slightly with water
SPECIFIC GRAVITY: 0.999 (water=1) at 25 C (77 F)
VISCOSITY #1: 1150 Centipoise at 25 C (77 F)
(VOC): < 2.7 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, alcohols, and oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and
linear
> 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
Page 3 of 5
F-115 REV 1 PART A
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status IARC Status
Toluene diisocyanate 2 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Toluene diisocyanate < 0.1 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene diisocyanate < 0.126471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
Page 4 of 5
F-115 REV 1 PART A
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Toluene diisocyanate < 0.1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 12/08/2020
REVISION SUMMARY: This SDS replaces the 10/24/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
F-115 REV 1 PART A
