by | Sep 27, 2025
INDEX
25NA
25NA150148
25NA150548
25NA151548
25NA157548
25NA202048
25NA202410
25NA202548
25NA205048
25NA207548
25NA241248
25NA241548
COOSA BLUEWATER PRODUCT LINES
COOSA NAUTICAL PRODUCT LINES
SAFETY DATA SHEET
Revision Date: 7/31/2015 Page 1/5
Section 1: Product and Company Identification
Product Identifier:
Trade Name: Bluewater 26, Bluewater 20, Nautical 24, Nautical 20, Nautical 15
Article Number:
CAS Number:
EC Number:
Index Number:
Formula:
Synonyms: Fiberglass Reinforced Polyurethane Foam
Intended Use of the Product
Use of the substance/mixture: plywood or wood replacement
Name, Address, and Telephone of the Responsible Party
Coosa Composites, LLC
105 Pardue Road
Pelham, AL 35124
205-663-3225
Emergency Telephone
205-663-3225
Section 2: Hazards Identification
Classification of the substance or mixture
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Label Elements
GHS Label elements
The substance is classified and labeled according to the Globally Harmonized Systems (GHS)
Hazard pictograms
GHS07
Signal word: Warning
Hazard-determining components of labeling: polyurethane foam/ fiberglass
Hazard Statements
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 2/5
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources – No smoking
P261 Avoid breathing dust/fume/gas/mist/vapours/mist
P262 Do not get in eyes, on skin, or on clothing
P264 Wash ..thoroughly after handling
P284 [In case of inadequate ventilation] wear respiratory protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. If present and easy to
do. Continue rinsing
P303+361+353 IF ON SKIN (or hair) take off immediately all contaminated clothing . Rinse skin with water/shower
P361 Take off immediately all contaminated clothing
Classification Systems: NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme
NFPA ratings (scale 0 -4)
Health = 1
Fire =1
Reactivity=0
HMIS ratings (scale 0 – 4)
1 Health = 1
1 Fire =1
0 Reactivity=0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable
vPvB: Not applicable
Section 3 Composition / Information on ingredients
Chemical characterization: Substances
Cas No. Description
9010-69-9 Polyurethane foam
Glass fibers (Nuisance particles. Non-Respirable
A glass fibers (continuous filament non-Respirable)
Woven fiberglass fabric (continuous filament non Respirable)
Identification numbers
EC Numbers
Index Numbers
SVHC
Section 4: First-Aid Measures
Description of first aid measures
General Advice: Remove contaminated clothing
If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention. If glass fibers
become imbedded, seek medical attention
If in eyes: In case of contact with eyes, rinse immediately for at least 15 minutes with plenty of water. If eye irritation persist
seek medical attention.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 3/5
Section 5: Fire-Fighting Measures
Suitable extinguishing media: Water, carbon dioxide, foam
Hazards during firefighting: If product is heated above decomposition temperature, toxic vapors will be released. By
products of combustion would be CO, CO2, hydrogen cyanide, carbon particulate, hydrogen, and glass fibers.
Protective equipment for firefighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out
gear.
Section 6: Accidental Release Measures
Cleanup: Place into suitable container for disposal (see SDS Section 13- Disposal Considerations)
Section7: Handling and Storage
Handling: Wear protective clothing, gloves, and eye protection
Protection against fire and explosion: No explosion proofing necessary
Storage: Avoid deposition of dust. No special precautions necessary
Storage Stability: No data available
Section 8: Exposure Controls and Personal Protection
Advice on system design: Provide local exhaust ventilation to control dust
Personal protective equipment
Respiratory protection:
Wear NIOSH-certified 95 mask (or better) where adequate ventilation cannot be guaranteed, especially if cutting,
sanding, and/or grinding
Hand protection: Working gloves
Eye protection:
Eye protection as appropriate for method of cutting, sanding and/or grinding
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wear protective clothing, gloves, and eye protection.
Wash soiled clothing immediately.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 4/5
Section 9: Physical and Chemical Properties
Appearance:
Form: Solid
Odor: Odorless Odor threshold: not applicable
Color: Gray
pH value: not applicable
Melting Point:
Boiling Point:
Flash Point:
Flammability: If exposed directly to flame
Ignition temperature: 400 F
Auto igniting: May auto ignite in temperatures over 1,000 F
Danger of explosion: Explosion may occur in areas of high concentration of airborne dust
Miscibility with water: Not Soluble
Section 10: Stability and Reactivity
Conditions to avoid:
>300 Fahrenheit
Avoid extreme heat. Avoid all sources of ignition: heat, sparks, and open flame
Hazardous reactions:
The product is chemically stable
Decomposition products:
Polyurethane:
Hazardous decomposition products: carbon monoxide, carbon dioxide, hydrogen cyanide, ether, esters, ketones
Glass Fibers:
Fiberglass alone will not burn, but smoking of the binder/sizing content of the product may occur in temperature of the
environment exceeding +400 F. These same ingredients will release carbon monoxide and carbon dioxide in a sustained fire
situation. Additional trace ingredient releases can occur under similar circumstances but cannot be predicted as they may
vary in each situation.
Thermal decomposition:
Will decompose to a liquid at high temperatures whilst burning
Corrosion to metals:
No corrosive effect of metal
Section 11: Toxicological Information
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 5/5
Section 12: Ecological Information
Considered an inert solid waste. No special precautions are needed in case of a release or spill
Section 13: Waste Disposal Considerations
Waste disposal of substance:
Dispose of in a licensed facility in accordance with all government rules and regulations
Container disposal:
Incinerate or dispose of in a licensed facility and/or reuse/recycle all packaging materials
Section 14: Transportation Information
IMDG-Marine Pollutants This products does not contain marine pollutants as classified by the international Maritime
organization
Emergency Response Guidebook (ERG) No: No information available
Mode of Transportation:
DOT-Non Bulk- non regulated
DOT-Bulk- non regulated
Canadian TDG-non regulated
ICAO/IATA-non regulated
IMO/IMDG-non regulated
Section 15: Regulatory Information
Safety Phrases:
Ingredients Listings:
Polyurethane Foam: TSCA, US released/Listed
Glass Fibers: exempt from TSCA requirements
Section 16: Other Information
Issued by Coosa Composites, LLC in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200
IMPORTANT: WHILE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PORCESSING OR APPLCATION/USE, WE RECOMMEN THAT
YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED
OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR
DESIGNS, DATA OR INFORMAITON SET FORTH, OR THAT THE PRODUCTS, DESGINS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMAITON, DATA OR DESINGS PROVIDED BE CONSIDERED A PART
OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, INFORMATION, DATA, OR
DESIGNS PROVIDED BE CONSIDRED A PART OF OUR TERMS AND CONDITIONS OF SALES. FUTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE
DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY COOSA COMPOSITES, LLC HEREUNDER ARE GIVEN GRATIS AND COOSA COMPOSITES, LLC
ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA, AND INFORMATION GIVEN OR RESULTS OBTAINED ALL SUCH BEING GIVEN
AND ACCEPTED AT YOUR RISK. COOSA COMPOSITES, LLC WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE MANUFACTURE OF
MEDICATE DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN THER PERMANENT CONTACT WITH INTERNAL
BODILY TISSUES OR FLUIDS.
by | Sep 27, 2025
INDEX
25NA
25NA150148
25NA150548
25NA151548
25NA157548
25NA202048
25NA202410
25NA202548
25NA205048
25NA207548
25NA241248
25NA241548
COOSA BLUEWATER PRODUCT LINES
COOSA NAUTICAL PRODUCT LINES
SAFETY DATA SHEET
Revision Date: 7/31/2015 Page 1/5
Section 1: Product and Company Identification
Product Identifier:
Trade Name: Bluewater 26, Bluewater 20, Nautical 24, Nautical 20, Nautical 15
Article Number:
CAS Number:
EC Number:
Index Number:
Formula:
Synonyms: Fiberglass Reinforced Polyurethane Foam
Intended Use of the Product
Use of the substance/mixture: plywood or wood replacement
Name, Address, and Telephone of the Responsible Party
Coosa Composites, LLC
105 Pardue Road
Pelham, AL 35124
205-663-3225
Emergency Telephone
205-663-3225
Section 2: Hazards Identification
Classification of the substance or mixture
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Label Elements
GHS Label elements
The substance is classified and labeled according to the Globally Harmonized Systems (GHS)
Hazard pictograms
GHS07
Signal word: Warning
Hazard-determining components of labeling: polyurethane foam/ fiberglass
Hazard Statements
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 2/5
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources – No smoking
P261 Avoid breathing dust/fume/gas/mist/vapours/mist
P262 Do not get in eyes, on skin, or on clothing
P264 Wash ..thoroughly after handling
P284 [In case of inadequate ventilation] wear respiratory protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. If present and easy to
do. Continue rinsing
P303+361+353 IF ON SKIN (or hair) take off immediately all contaminated clothing . Rinse skin with water/shower
P361 Take off immediately all contaminated clothing
Classification Systems: NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme
NFPA ratings (scale 0 -4)
Health = 1
Fire =1
Reactivity=0
HMIS ratings (scale 0 – 4)
1 Health = 1
1 Fire =1
0 Reactivity=0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable
vPvB: Not applicable
Section 3 Composition / Information on ingredients
Chemical characterization: Substances
Cas No. Description
9010-69-9 Polyurethane foam
Glass fibers (Nuisance particles. Non-Respirable
A glass fibers (continuous filament non-Respirable)
Woven fiberglass fabric (continuous filament non Respirable)
Identification numbers
EC Numbers
Index Numbers
SVHC
Section 4: First-Aid Measures
Description of first aid measures
General Advice: Remove contaminated clothing
If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention. If glass fibers
become imbedded, seek medical attention
If in eyes: In case of contact with eyes, rinse immediately for at least 15 minutes with plenty of water. If eye irritation persist
seek medical attention.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 3/5
Section 5: Fire-Fighting Measures
Suitable extinguishing media: Water, carbon dioxide, foam
Hazards during firefighting: If product is heated above decomposition temperature, toxic vapors will be released. By
products of combustion would be CO, CO2, hydrogen cyanide, carbon particulate, hydrogen, and glass fibers.
Protective equipment for firefighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out
gear.
Section 6: Accidental Release Measures
Cleanup: Place into suitable container for disposal (see SDS Section 13- Disposal Considerations)
Section7: Handling and Storage
Handling: Wear protective clothing, gloves, and eye protection
Protection against fire and explosion: No explosion proofing necessary
Storage: Avoid deposition of dust. No special precautions necessary
Storage Stability: No data available
Section 8: Exposure Controls and Personal Protection
Advice on system design: Provide local exhaust ventilation to control dust
Personal protective equipment
Respiratory protection:
Wear NIOSH-certified 95 mask (or better) where adequate ventilation cannot be guaranteed, especially if cutting,
sanding, and/or grinding
Hand protection: Working gloves
Eye protection:
Eye protection as appropriate for method of cutting, sanding and/or grinding
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wear protective clothing, gloves, and eye protection.
Wash soiled clothing immediately.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 4/5
Section 9: Physical and Chemical Properties
Appearance:
Form: Solid
Odor: Odorless Odor threshold: not applicable
Color: Gray
pH value: not applicable
Melting Point:
Boiling Point:
Flash Point:
Flammability: If exposed directly to flame
Ignition temperature: 400 F
Auto igniting: May auto ignite in temperatures over 1,000 F
Danger of explosion: Explosion may occur in areas of high concentration of airborne dust
Miscibility with water: Not Soluble
Section 10: Stability and Reactivity
Conditions to avoid:
>300 Fahrenheit
Avoid extreme heat. Avoid all sources of ignition: heat, sparks, and open flame
Hazardous reactions:
The product is chemically stable
Decomposition products:
Polyurethane:
Hazardous decomposition products: carbon monoxide, carbon dioxide, hydrogen cyanide, ether, esters, ketones
Glass Fibers:
Fiberglass alone will not burn, but smoking of the binder/sizing content of the product may occur in temperature of the
environment exceeding +400 F. These same ingredients will release carbon monoxide and carbon dioxide in a sustained fire
situation. Additional trace ingredient releases can occur under similar circumstances but cannot be predicted as they may
vary in each situation.
Thermal decomposition:
Will decompose to a liquid at high temperatures whilst burning
Corrosion to metals:
No corrosive effect of metal
Section 11: Toxicological Information
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 5/5
Section 12: Ecological Information
Considered an inert solid waste. No special precautions are needed in case of a release or spill
Section 13: Waste Disposal Considerations
Waste disposal of substance:
Dispose of in a licensed facility in accordance with all government rules and regulations
Container disposal:
Incinerate or dispose of in a licensed facility and/or reuse/recycle all packaging materials
Section 14: Transportation Information
IMDG-Marine Pollutants This products does not contain marine pollutants as classified by the international Maritime
organization
Emergency Response Guidebook (ERG) No: No information available
Mode of Transportation:
DOT-Non Bulk- non regulated
DOT-Bulk- non regulated
Canadian TDG-non regulated
ICAO/IATA-non regulated
IMO/IMDG-non regulated
Section 15: Regulatory Information
Safety Phrases:
Ingredients Listings:
Polyurethane Foam: TSCA, US released/Listed
Glass Fibers: exempt from TSCA requirements
Section 16: Other Information
Issued by Coosa Composites, LLC in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200
IMPORTANT: WHILE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PORCESSING OR APPLCATION/USE, WE RECOMMEN THAT
YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED
OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR
DESIGNS, DATA OR INFORMAITON SET FORTH, OR THAT THE PRODUCTS, DESGINS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMAITON, DATA OR DESINGS PROVIDED BE CONSIDERED A PART
OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, INFORMATION, DATA, OR
DESIGNS PROVIDED BE CONSIDRED A PART OF OUR TERMS AND CONDITIONS OF SALES. FUTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE
DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY COOSA COMPOSITES, LLC HEREUNDER ARE GIVEN GRATIS AND COOSA COMPOSITES, LLC
ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA, AND INFORMATION GIVEN OR RESULTS OBTAINED ALL SUCH BEING GIVEN
AND ACCEPTED AT YOUR RISK. COOSA COMPOSITES, LLC WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE MANUFACTURE OF
MEDICATE DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN THER PERMANENT CONTACT WITH INTERNAL
BODILY TISSUES OR FLUIDS.
by | Sep 27, 2025
INDEX
25NA
25NA150148
25NA150548
25NA151548
25NA157548
25NA202048
25NA202410
25NA202548
25NA205048
25NA207548
25NA241248
25NA241548
COOSA BLUEWATER PRODUCT LINES
COOSA NAUTICAL PRODUCT LINES
SAFETY DATA SHEET
Revision Date: 7/31/2015 Page 1/5
Section 1: Product and Company Identification
Product Identifier:
Trade Name: Bluewater 26, Bluewater 20, Nautical 24, Nautical 20, Nautical 15
Article Number:
CAS Number:
EC Number:
Index Number:
Formula:
Synonyms: Fiberglass Reinforced Polyurethane Foam
Intended Use of the Product
Use of the substance/mixture: plywood or wood replacement
Name, Address, and Telephone of the Responsible Party
Coosa Composites, LLC
105 Pardue Road
Pelham, AL 35124
205-663-3225
Emergency Telephone
205-663-3225
Section 2: Hazards Identification
Classification of the substance or mixture
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Label Elements
GHS Label elements
The substance is classified and labeled according to the Globally Harmonized Systems (GHS)
Hazard pictograms
GHS07
Signal word: Warning
Hazard-determining components of labeling: polyurethane foam/ fiberglass
Hazard Statements
H316 Causes mild skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 2/5
Precautionary statements
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat, hot surfaces, sparks, open flames, and other ignition sources – No smoking
P261 Avoid breathing dust/fume/gas/mist/vapours/mist
P262 Do not get in eyes, on skin, or on clothing
P264 Wash ..thoroughly after handling
P284 [In case of inadequate ventilation] wear respiratory protection
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. If present and easy to
do. Continue rinsing
P303+361+353 IF ON SKIN (or hair) take off immediately all contaminated clothing . Rinse skin with water/shower
P361 Take off immediately all contaminated clothing
Classification Systems: NFPA/HMIS Definitions: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme
NFPA ratings (scale 0 -4)
Health = 1
Fire =1
Reactivity=0
HMIS ratings (scale 0 – 4)
1 Health = 1
1 Fire =1
0 Reactivity=0
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable
vPvB: Not applicable
Section 3 Composition / Information on ingredients
Chemical characterization: Substances
Cas No. Description
9010-69-9 Polyurethane foam
Glass fibers (Nuisance particles. Non-Respirable
A glass fibers (continuous filament non-Respirable)
Woven fiberglass fabric (continuous filament non Respirable)
Identification numbers
EC Numbers
Index Numbers
SVHC
Section 4: First-Aid Measures
Description of first aid measures
General Advice: Remove contaminated clothing
If on skin: Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention. If glass fibers
become imbedded, seek medical attention
If in eyes: In case of contact with eyes, rinse immediately for at least 15 minutes with plenty of water. If eye irritation persist
seek medical attention.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 3/5
Section 5: Fire-Fighting Measures
Suitable extinguishing media: Water, carbon dioxide, foam
Hazards during firefighting: If product is heated above decomposition temperature, toxic vapors will be released. By
products of combustion would be CO, CO2, hydrogen cyanide, carbon particulate, hydrogen, and glass fibers.
Protective equipment for firefighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out
gear.
Section 6: Accidental Release Measures
Cleanup: Place into suitable container for disposal (see SDS Section 13- Disposal Considerations)
Section7: Handling and Storage
Handling: Wear protective clothing, gloves, and eye protection
Protection against fire and explosion: No explosion proofing necessary
Storage: Avoid deposition of dust. No special precautions necessary
Storage Stability: No data available
Section 8: Exposure Controls and Personal Protection
Advice on system design: Provide local exhaust ventilation to control dust
Personal protective equipment
Respiratory protection:
Wear NIOSH-certified 95 mask (or better) where adequate ventilation cannot be guaranteed, especially if cutting,
sanding, and/or grinding
Hand protection: Working gloves
Eye protection:
Eye protection as appropriate for method of cutting, sanding and/or grinding
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wear protective clothing, gloves, and eye protection.
Wash soiled clothing immediately.
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 4/5
Section 9: Physical and Chemical Properties
Appearance:
Form: Solid
Odor: Odorless Odor threshold: not applicable
Color: Gray
pH value: not applicable
Melting Point:
Boiling Point:
Flash Point:
Flammability: If exposed directly to flame
Ignition temperature: 400 F
Auto igniting: May auto ignite in temperatures over 1,000 F
Danger of explosion: Explosion may occur in areas of high concentration of airborne dust
Miscibility with water: Not Soluble
Section 10: Stability and Reactivity
Conditions to avoid:
>300 Fahrenheit
Avoid extreme heat. Avoid all sources of ignition: heat, sparks, and open flame
Hazardous reactions:
The product is chemically stable
Decomposition products:
Polyurethane:
Hazardous decomposition products: carbon monoxide, carbon dioxide, hydrogen cyanide, ether, esters, ketones
Glass Fibers:
Fiberglass alone will not burn, but smoking of the binder/sizing content of the product may occur in temperature of the
environment exceeding +400 F. These same ingredients will release carbon monoxide and carbon dioxide in a sustained fire
situation. Additional trace ingredient releases can occur under similar circumstances but cannot be predicted as they may
vary in each situation.
Thermal decomposition:
Will decompose to a liquid at high temperatures whilst burning
Corrosion to metals:
No corrosive effect of metal
Section 11: Toxicological Information
SAFETY DATA SHEET
COOSA BLUEWATER AND COOSA NAUTICAL PRODUCT LINES
Revision Date: 7/31/2015 Page 5/5
Section 12: Ecological Information
Considered an inert solid waste. No special precautions are needed in case of a release or spill
Section 13: Waste Disposal Considerations
Waste disposal of substance:
Dispose of in a licensed facility in accordance with all government rules and regulations
Container disposal:
Incinerate or dispose of in a licensed facility and/or reuse/recycle all packaging materials
Section 14: Transportation Information
IMDG-Marine Pollutants This products does not contain marine pollutants as classified by the international Maritime
organization
Emergency Response Guidebook (ERG) No: No information available
Mode of Transportation:
DOT-Non Bulk- non regulated
DOT-Bulk- non regulated
Canadian TDG-non regulated
ICAO/IATA-non regulated
IMO/IMDG-non regulated
Section 15: Regulatory Information
Safety Phrases:
Ingredients Listings:
Polyurethane Foam: TSCA, US released/Listed
Glass Fibers: exempt from TSCA requirements
Section 16: Other Information
Issued by Coosa Composites, LLC in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200
IMPORTANT: WHILE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PORCESSING OR APPLCATION/USE, WE RECOMMEN THAT
YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED
OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR
DESIGNS, DATA OR INFORMAITON SET FORTH, OR THAT THE PRODUCTS, DESGINS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMAITON, DATA OR DESINGS PROVIDED BE CONSIDERED A PART
OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, INFORMATION, DATA, OR
DESIGNS PROVIDED BE CONSIDRED A PART OF OUR TERMS AND CONDITIONS OF SALES. FUTHER, YOU EXPRESLLY UNDERSTAND AND AGREE THAT THE
DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY COOSA COMPOSITES, LLC HEREUNDER ARE GIVEN GRATIS AND COOSA COMPOSITES, LLC
ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA, AND INFORMATION GIVEN OR RESULTS OBTAINED ALL SUCH BEING GIVEN
AND ACCEPTED AT YOUR RISK. COOSA COMPOSITES, LLC WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR USE IN THE MANUFACTURE OF
MEDICATE DEVICES WHICH ARE INTENDED FOR PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN THER PERMANENT CONTACT WITH INTERNAL
BODILY TISSUES OR FLUIDS.
by | Sep 27, 2025
SAFETY DATA SHEET
; Date issued : 12/16/2016
SDS number : MD-70 REV 1 PART A
– . Date revised : 05/15/2023
ajie)
)Ematerials Revision mumber: 2
MD-70 REV 1 PART A
1. Identification
Product identifier: MD-70 REV | PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Sensitization, Category 1 r
Reproductive Toxicity, Category 2
Label elements
Health hazard Exclamation
mark
Signal word: WARNING
Hazard statement(s)
332: Harmful if inhaled.
H317: May cause an allergic skin reaction,
361: Suspected of damaging fertility or the unbom child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER/doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P40S: Store locked up.
by | Sep 27, 2025
.@
@ Dedicated to QUALITY, SERVICE, SAFETY, and INNOVATION
ENTERPRISES
An ISO-9001 Certified company
MD-60 REV 1 A/B yg
60 SHORE D POLYURETHANE ELASTOMER RoHS
BJB s MD Series of semi rigid, medium work time urethane elastomers exhibit great flexibility and excellent durability. These
tough, abrasion resistant systems easily process at room temperature. The MD Series is perfect for larger or more complex parts
and offers superior performance in many applications such as rollers, foundry tooling and high impact semi rigid parts. For faster
work times consider BJB s FD Series of elastomers.
e RoHS/REACH compliant 2:1 user friendly ratio High tensile and tear strength
Molds and cast parts Cures at room temperature
PHYSICAL PROPERTIES ELEVATED TEMPERATURE CURE*
Hardness, Shore D 605
Density (g/cc) 1.147
Cubic Inches per Pound 25.09
Color/Appearance Clear Amber
Tensile Strength (psi) 4,700
Tensile Modulus (psi) 45,000
Elongation (%) 450
Tear Strenath (pli) 475
Shrinkage (in/in) linear 0.004*
Izod Impact (ft-Ib/in) notched >16
Dielectric Constant, 1 MHz 4.659
Dissipation Factor, 1 MHz 0.047
*Note: Reported physical properties are based on test specimens cured 1-3 hours at room temperature then 16 hours at 160 F (71 C).
*Shrink test specimens are cured for 24 hours at room temperature and then 16 hours at 160 F (71 C).
HANDLING PROPERTIES [eee PatAe | PartB
Mix Ratio by weight | too ( teCr 50
Mix Ratio by volume 50
Specific Gravity @ 77 F (25 C) 1.411
Color Amber
Viscosity (cps) @ 77 F (25 C) Brookfield 4,000
Mixed Viscosity (cps) @ 77 F (25 C) Brookfield 2,800
Work Time, 100g mass @ 77 F (25 C) 10-15 minutes
Gel Time 15 20 minutes
Demold Time @ 77 F (25 C) 2-3 hours _
Properties above are typical and not for specifications.
MD-60 REV I A/B Page | of 2 Date: 01/04/2023
For more information call BJB Enterprises, Inc. (714) 734-8450 Fax (714) 734-8929
www.bjbenterprises.com
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 05/27/2016
SDS number : MD-50 REV 1 PART A
Date revised : 08/22/2022
Revision number : 2
MD-50 REV 1 PART A
1. Identification
Product identifier: MD-50 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Sensitization, Category 1
Reproductive Toxicity, Category 2
Label elements
Health hazard Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H332: Harmful if inhaled.
H317: May cause an allergic skin reaction.
H361: Suspected of damaging fertility or the unborn child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER/doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Page 1 of 6
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 80 – 100Proprietary
Hexane, 1,6-diisocyanato-, homopolymer 5 – 1028182-81-2
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate 5 – 106846-50-0
Toluene diisocyanate < 0.126471-62-5
Hexamethylene-1,6-diisocyanate < 0.1 822-06-0
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Get immediate medical attention.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Page 2 of 6
MD-50 REV 1 PART A
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Hexamethylene-1,6-diisocyanate
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA 0.005 -
STEL - -
NIOSH REL
TWA 0.005 0.035
STEL - -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 104.4 C (220 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.103 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 4500 Centipoise at 25 C (77 F)
VOC content: < 0.1 g/l Calculated. Theoretical VOC minus water and exempt solvents.
Page 3 of 6
MD-50 REV 1 PART A
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, oxidizing agents, strong bases, alcohols, amines, and copper alloys.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyurethane prepolymer No data available No data available No data available
Hexane, 1,6-diisocyanato-, homopolymer > 2500 mg/kg Rat > 2000 mg/kg Rat 4600 mg/m3 Rat
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate> 2000 mg/kg Rat > 2000 mg/kg Guinea Pig > 0.12 mg/l Rat (6 h)
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Hexamethylene-1,6-diisocyanate 746 to 959 mg/kg Rat > 7000 mg/kg Rat 0.124 mg/l Rat (4 h, vapor)
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
Page 4 of 6
MD-50 REV 1 PART A
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
Hexamethylene-1,6-diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 08/22/2022
Revision summary: This SDS replaces the 05/28/2019 SDS.
Page 5 of 6
MD-50 REV 1 PART A
HMIS rating
Health * 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 6 of 6
MD-50 REV 1 PART A
SAFETY DATA SHEET
Date issued : 05/27/2016
SDS number : MD-50 REV 1 PART B
Date revised : 08/22/2022
Revision number : 2
MD-50 REV 1 PART B
1. Identification
Product identifier: MD-50 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Page 1 of 5
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyether polyol mixture 60 - 80Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 10 - 30102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 5 - 10104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
Page 2 of 5
MD-50 REV 1 PART B
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.109 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 440 Centipoise at 25 C (77 F)
VOC content: < 0.1 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Page 3 of 5
MD-50 REV 1 PART B
Carcinogenicity
Notes: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to
the environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA - air: Not Regulated
IMO / IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: This product does not contain any chemicals which are known to the State of California to cause cancer, birth
defects or other reproductive harm.
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 4 of 5
MD-50 REV 1 PART B
16. Other information
Reason for issue: Revision
Date revised: 08/22/2022
Revision summary: This SDS replaces the 05/28/2019 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
MD-50 REV 1 PART B
by | Sep 27, 2025
. Page 1 of 5
SAFETY DATA SHEET
8 Date issued : 06/15/2016
i SDS number : M3195 REV I PART B
Date revised : 11/11/2022
ENTERPRISES Revision number : 2
M-3195 REV 1PARTB
1, Identification
Product identifier: M-3195 REV | PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
302: Harmful if swallowed.
1317: May cause an allergic skin reaction.
401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+4P313: If skin imitation or rash occurs: Get medical advice/attention.
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART A
Date revised : 11/11/2022
Revision number : 2
M-3195 REV 1 PART A
1. Identification
Product identifier: M-3195 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Reproductive Toxicity, Category 2
Label elements
Health hazard
Signal word: WARNING
Hazard statement(s)
H361: Suspected of damaging fertility or the unborn child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 80 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 20474919-59-0
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate 1 – 56846-50-0
Toluene diisocyanate < 0.126471-62-5
Page 1 of 5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Page 2 of 5
M-3195 REV 1 PART A
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.078 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 5400 Centipoise at 25 C (77 F)
VOC content: < 0.8 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate > 2000 mg/kg Rat> 2000 mg/kg Guinea Pig> 0.12 mg/l Rat (6 h)
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Page 3 of 5
M-3195 REV 1 PART A
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
CERCLA Hazardous Substances and Reportable Quantities (RQ)
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Page 4 of 5
M-3195 REV 1 PART A
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/11/2022
Revision summary: This SDS replaces the 06/06/2019 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3195 REV 1 PART A
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART A
Date revised : 11/11/2022
Revision number : 2
M-3195 REV 1 PART A
1. Identification
Product identifier: M-3195 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Reproductive Toxicity, Category 2
Label elements
Health hazard
Signal word: WARNING
Hazard statement(s)
H361: Suspected of damaging fertility or the unborn child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 80 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 20474919-59-0
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate 1 – 56846-50-0
Toluene diisocyanate < 0.126471-62-5
Page 1 of 5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Page 2 of 5
M-3195 REV 1 PART A
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.078 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 5400 Centipoise at 25 C (77 F)
VOC content: < 0.8 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate > 2000 mg/kg Rat> 2000 mg/kg Guinea Pig> 0.12 mg/l Rat (6 h)
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Page 3 of 5
M-3195 REV 1 PART A
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
CERCLA Hazardous Substances and Reportable Quantities (RQ)
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Page 4 of 5
M-3195 REV 1 PART A
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/11/2022
Revision summary: This SDS replaces the 06/06/2019 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3195 REV 1 PART A
SAFETY DATA SHEET
Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART B
Date revised : 11/11/2022
Revision number : 2
M-3195 REV 1 PART B
1. Identification
Product identifier: M-3195 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
Page 1 of 5
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyether polyol mixture 40 - 70Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 10 - 30102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 5 - 10104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Page 2 of 5
M-3195 REV 1 PART B
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.078 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 1250 Centipoise at 25 C (77 F)
VOC content: < 0.5 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Page 3 of 5
M-3195 REV 1 PART B
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to
the environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA - air: Not Regulated
IMO / IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Page 4 of 5
M-3195 REV 1 PART B
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Naphthalene < 0.001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/11/2022
Revision summary: This SDS replaces the 06/06/2019 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3195 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART A
Date revised : 11/11/2022
Revision number : 2
M-3195 REV 1 PART A
1. Identification
Product identifier: M-3195 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Reproductive Toxicity, Category 2
Label elements
Health hazard
Signal word: WARNING
Hazard statement(s)
H361: Suspected of damaging fertility or the unborn child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 80 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 20474919-59-0
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate 1 – 56846-50-0
Toluene diisocyanate < 0.126471-62-5
Page 1 of 5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Page 2 of 5
M-3195 REV 1 PART A
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.078 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 5400 Centipoise at 25 C (77 F)
VOC content: < 0.8 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
1-Isopropyl-2,2-dimethyltrimethylene diisobutyrate > 2000 mg/kg Rat> 2000 mg/kg Guinea Pig> 0.12 mg/l Rat (6 h)
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Page 3 of 5
M-3195 REV 1 PART A
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
CERCLA Hazardous Substances and Reportable Quantities (RQ)
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Page 4 of 5
M-3195 REV 1 PART A
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/11/2022
Revision summary: This SDS replaces the 06/06/2019 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3195 REV 1 PART A
SAFETY DATA SHEET
Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART B
Date revised : 11/11/2022
Revision number : 2
M-3195 REV 1 PART B
1. Identification
Product identifier: M-3195 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
Page 1 of 5
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyether polyol mixture 40 - 70Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 10 - 30102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 5 - 10104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Page 2 of 5
M-3195 REV 1 PART B
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.078 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 1250 Centipoise at 25 C (77 F)
VOC content: < 0.5 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Page 3 of 5
M-3195 REV 1 PART B
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to
the environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA - air: Not Regulated
IMO / IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Page 4 of 5
M-3195 REV 1 PART B
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Naphthalene < 0.001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 11/11/2022
Revision summary: This SDS replaces the 06/06/2019 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
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