by | Sep 27, 2025
: Page 1 of 5
SAFETY DATA SHEET
is Date issued : 06/15/2016
SDS number : M-3195 REV 1 PART A
Date revised : 11/11/2022
ENTERPRISES Revision number : 2
M-3195 REV 1 PARTA
1. Identification
Product identifier: M-3195 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Reproductive Toxicity, Category 2
Label elements
Health hazard
Signal word: WARNING
Hazard statement(s)
H361: Suspected of damaging fertility or the unbom child.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
CASNNo.
Fic ei 20- 100] _Fropiemy|
1,2-Cyclohexanedicarbox ylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
1-Isopropyl-2,2-dimethy ltrimethylene diisobutyrate 6846-50-0
Toluene diisocyanate 26471-62-5
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 06/29/2017
SDS No : M-3190 REV 1 PART A
Date Revised : 08/12/2020
Revision No : 1
M-3190 REV 1 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: M-3190 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-
containing vapor.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
Page 1 of 6
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment
(PPE) as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and
contain spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous
earth, or vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 6
M-3190 REV 1 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppmmg/m
3
Polyurethane prepolymer
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Toluene diisocyanate
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA 0.005 -
STEL0.02 -
NIOSH REL
TWA - -
STEL - -
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of
Chemical Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale yellow
Page 3 of 6
M-3190 REV 1 PART A
pH: No data available
FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slightly with water
SPECIFIC GRAVITY: 1.067 (water=1) at 25 C (77 F)
VISCOSITY #1: 4450 Centipoise at 25 C (77 F)
(VOC): < 1.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-
containing vapor.
INCOMPATIBLE MATERIALS: Water, alcohols, and oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and
linear
> 5000 mg/kg Rat> 2000 mg/kg Rat No data available
Toluene diisocyanate
3360 mg/kg Rat 10000 mg/kg
Rabbit
0.35 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status IARC Status
Toluene diisocyanate 2 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
Page 4 of 6
M-3190 REV 1 PART A
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Toluene diisocyanate < 0.1 100 lbs.
Naphthalene < 0.001 100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene diisocyanate < 0.126471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Toluene diisocyanate < 0.1 Cancer
Naphthalene < 0.001 Cancer
Ethyl acrylate < 0.0001 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
Page 5 of 6
M-3190 REV 1 PART A
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 08/12/2020
REVISION SUMMARY: This SDS replaces the 06/29/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
M-3190 REV 1 PART A
SAFETY DATA SHEET
Date issued : 06/29/2017
SDS number : M-3190 REV 1 PART B
Date revised : 08/12/2020
Revision number : 1
M-3190 REV 1 PART B
1. Identification
Product identifier: M-3190 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Oral), Category 4
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Page 1 of 5
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyether polyol mixture 40 - 70Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 10 - 30102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 5 - 10104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear full
protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize small spills
with a decontaminant.
Large spill: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top drums or
plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
Page 2 of 5
M-3190 REV 1 PART B
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.082 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 1100 Centipoise at 25 C (77 F)
Percent volatiles: 0.05
VOC content: < 0.55 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: None Known
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Page 3 of 5
M-3190 REV 1 PART B
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Notes: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to
the environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO - air: Not Regulated
IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: This product does not contain any chemicals which are known to the State of California to cause cancer, birth
defects or other reproductive harm.
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
Page 4 of 5
M-3190 REV 1 PART B
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 08/12/2020
Revision summary: This SDS replaces the 06/29/2017 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3190 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART A
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART A
1. Identification
Product identifier: M-3180 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
Page 1 of 5
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
Page 2 of 5
M-3180 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.067 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 4450 Centipoise at 25 C (77 F)
VOC content: < 1.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
Page 3 of 5
M-3180 REV 1 PART A
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO – air: Not Regulated
IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
Naphthalene < 0.001 Cancer
Ethyl acrylate < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 4 of 5
M-3180 REV 1 PART A
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART A
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART B
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART B
1. Identification
Product identifier: M-3180 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Page 1 of 5
Chemical name % w/wCAS No.
Polyether polyol mixture 60 - 80Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 15 - 25102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 3 - 7104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Page 2 of 5
M-3180 REV 1 PART B
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.091 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 585 Centipoise at 25 C (77 F)
Percent volatiles: 0.05
VOC content: < 0.6 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Page 3 of 5
M-3180 REV 1 PART B
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the
environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO - air: Not Regulated
IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Naphthalene < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
Page 4 of 5
M-3180 REV 1 PART B
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART A
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART A
1. Identification
Product identifier: M-3180 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
Page 1 of 5
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
Page 2 of 5
M-3180 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.067 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 4450 Centipoise at 25 C (77 F)
VOC content: < 1.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
Page 3 of 5
M-3180 REV 1 PART A
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO – air: Not Regulated
IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
Naphthalene < 0.001 Cancer
Ethyl acrylate < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 4 of 5
M-3180 REV 1 PART A
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART A
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART B
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART B
1. Identification
Product identifier: M-3180 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Page 1 of 5
Chemical name % w/wCAS No.
Polyether polyol mixture 60 - 80Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 15 - 25102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 3 - 7104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Page 2 of 5
M-3180 REV 1 PART B
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.091 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 585 Centipoise at 25 C (77 F)
Percent volatiles: 0.05
VOC content: < 0.6 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Page 3 of 5
M-3180 REV 1 PART B
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the
environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO - air: Not Regulated
IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Naphthalene < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
Page 4 of 5
M-3180 REV 1 PART B
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART A
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART A
1. Identification
Product identifier: M-3180 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
Page 1 of 5
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
Page 2 of 5
M-3180 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.067 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 4450 Centipoise at 25 C (77 F)
VOC content: < 1.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrogen cyanide, and isocyanate-containing vapor.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
Page 3 of 5
M-3180 REV 1 PART A
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO – air: Not Regulated
IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
Naphthalene < 0.001 Cancer
Ethyl acrylate < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 4 of 5
M-3180 REV 1 PART A
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART A
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3180 REV 1 PART B
Date revised : 02/18/2022
Revision number : 2
M-3180 REV 1 PART B
1. Identification
Product identifier: M-3180 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Page 1 of 5
Chemical name % w/wCAS No.
Polyether polyol mixture 60 - 80Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 15 - 25102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 3 - 7104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Page 2 of 5
M-3180 REV 1 PART B
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.091 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 585 Centipoise at 25 C (77 F)
Percent volatiles: 0.05
VOC content: < 0.6 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Page 3 of 5
M-3180 REV 1 PART B
Germ cell mutagenicity: No data available
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the
environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO - air: Not Regulated
IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Naphthalene < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
Page 4 of 5
M-3180 REV 1 PART B
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/11/2018 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3180 REV 1 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 10/15/2015
SDS number : M-3170 REV 1 PART A
Date revised : 02/18/2022
Revision number : 2
M-3170 REV 1 PART A
1. Identification
Product identifier: M-3170 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/w CAS No.
Polyurethane prepolymer 60 – 100Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 10 – 30474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
Page 1 of 5
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
Page 2 of 5
M-3170 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.085 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 3165 Centipoise at 25 C (77 F)
VOC content: < 2 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
Toluene diisocyanate 3360 mg/kg Rat 10000 mg/kg Rabbit 0.35 mg/l Rat
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
Page 3 of 5
M-3170 REV 1 PART A
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: None Known
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
Naphthalene < 0.0001 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Page 4 of 5
M-3170 REV 1 PART A
Reason for issue: Revision
Date revised: 02/18/2022
Revision summary: This SDS replaces the 10/15/2018 SDS.
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3170 REV 1 PART A
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 04/26/2016
SDS number : M-3140 REV 1 PART B
Date revised : 07/28/2022
Revision number : 2
M-3140 REV 1 PART B
1. Identification
Product identifier: M-3140 REV 1 PART B
Relevant identified uses: Polyurethane curative
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Sensitization, Category 1
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category 2
Chronic Hazards to the Aquatic Environment, Category 3
Label elements
Exclamation
mark
Signal word: WARNING
Hazard statement(s)
H317: May cause an allergic skin reaction.
H401: Toxic to aquatic life.
H412: Harmful to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Page 1 of 5
Chemical name % w/w CAS No.
Polyether polyol mixture 80 – 100Proprietary
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- 3 – 7102093-68-5
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- 0.5 – 1.5104983-85-9
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, silicon oxides, and formaldehyde.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Page 2 of 5
M-3140 REV 1 PART B
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Amber
Odor: Slight amine
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 182.2 C (360 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.032 (water=1) at 25 C (77 F)
Solubility: Slightly soluble
Dynamic viscosity: 1350 Centipoise at 25 C (77 F)
VOC content: < 0.1 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, silicon oxides, and formaldehyde.
Incompatible materials: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Polyether polyol mixture No data available No data available No data available
1,3-Benzenediamine, 4-methyl-2,6-bis(methylthio)- No data available No data available No data available
1,3-Benzenediamine, 2-methyl-4,6-bis(methylthio)- No data available No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: May cause sensitization by skin contact.
Germ cell mutagenicity: No data available
Page 3 of 5
M-3140 REV 1 PART B
Reproductive toxicity: No data available
Specific Target Organ Toxicity - single exposure: No data available
Specific Target Organ Toxicity - repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid release to the
environment.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: This product may cause risk of hazardous effects to the environment.
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA - air: Not Regulated
IMO / IMDG - sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: This product does not contain any chemicals which are known to the State of California to cause cancer, birth
defects or other reproductive harm.
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 4 of 5
M-3140 REV 1 PART B
16. Other information
Reason for issue: Revision
Date revised: 07/28/2022
Revision summary: This SDS replaces the 04/17/2019 SDS.
HMIS rating
Health 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3140 REV 1 PART B
by | Sep 27, 2025
O ” SHORE A POLYURETHANES
Dedicated to QUALITY, SERVICE, SAFETY, and INNOVATION
ENTERPRISES
An 1SO-9001 Certified cony pany
M-3140 REV 1 A/B Jf
40 SHORE A POLYURETHANE ELASTOMER RoHS
BJB s M Series with work times between 15 and 20 minutes is perfect for a variety of part and mold applications. These
flexible systems exhibit exceptional physical properties with a convenient mix ratio. For faster work time see our FP and F-1
Series. Longer work times are available in the L Series of urethane elastomers.
* RoHS/REACH Compliant * Vibration Dampening * Industrial Rollers
e Phthalate Free e Over Molding Strain Reliefs
PHYSICAL PROPERTIES [ao anee
Hardness, Shore A 4035
Dens (fc) 1035
Cubic Inches per Pound 26.92
Color/Appearance Translucent Amber
Tensile Strength (psi) 850
Tensile Modulus (psi) 170
Elongation (%) 990
Tear Strength (pli) 95
Shrinkage (in/in) linear 0.0010″
Dielectric Constant, 1 MHz 5.198
Dissipation Factor, 1 MHz 0.0512
*Note: Reported physical properties are based on test specimens cured 2 hours at room temperature then 16 hours at 160 F (71 C).
Shrink test specimens are cured for 24 hours at room temperature and then 16 hours at 160 F (71 C).
HANDLING PROPERTIES ear aes] PatB
Mix Ratio by weight 100
Mix Ratio by volume Pa bee Se | 100
Specific Gravity @ 77 F (25 C) 1.032
Color Amber
Viscosity (cps) @ 77 F (25 C) Brookfield 1,350
Mixed Viscosity (cps) @ 77 F (25 C) Brookfield 1,600
Work Time, 100g mass @ 77 F (25 C) 15 20 minutes
Gel Time 25 30 minutes
Demold Time @ 77 F (25 C) 4-6 hours
Properties above are typical and not for specifications.
M-3140 REV 1 A/B Page | of 2 Date: 08/09/2022
For more information call BJB Enterprises, Inc. (714) 734-8450 Fax (714) 734-8929
www.bjbenterprises.com
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 04/26/2016
SDS number : M-3140 REV 1 PART A
Date revised : 07/28/2022
Revision number : 2
M-3140 REV 1 PART A
1. Identification
Product identifier: M-3140 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Not Applicable
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Polyurethane prepolymer 50 – 70Proprietary
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 30 – 60474919-59-0
Toluene diisocyanate < 0.126471-62-5
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
Page 1 of 5
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Toluene diisocyanate ACGIH TLV STEL 0.005 -
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection - hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection - other: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Pale yellow
Odor: Slight
Page 2 of 5
M-3140 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 160 C (320 F) Pensky-Martens CC
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.028 (water=1) at 25 C (77 F)
Solubility: Reacts slightly with water
Dynamic viscosity: 1475 Centipoise at 25 C (77 F)
VOC content: < 3.1 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
Incompatible materials: Water, alcohols, and oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Polyurethane prepolymer No data available No data available No data available
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched
and linear
> 5000 mg/kg Rat > 2000 mg/kg Rat No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name NTP IARC
Toluene diisocyanate 2 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Page 3 of 5
M-3140 REV 1 PART A
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: None Known
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
Toluene diisocyanate < 0.1 100 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
CAA 112(b) Hazardous Air Pollutants
Chemical name % w/wCAS No.
Toluene diisocyanate < 0.126471-62-5
Occupational safety and health administration (osha)
29 cfr1910.119---process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Toluene diisocyanate < 0.1 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Reason for issue: Revision
Date revised: 07/28/2022
Revision summary: This SDS replaces the 04/17/2019 SDS.
Page 4 of 5
M-3140 REV 1 PART A
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
M-3140 REV 1 PART A
by | Sep 27, 2025
j
} |
Page 1 of 5
SAFETY DATA SHEET
o
#5, @ Date Issued : 10/31/2017
Gey SDS No: M-3130 REV 1 PART A
@ Date Revised : 12/03/2020
ENTERPRISES Revision No : 1
M-3130 REV 1 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: M-3130 REV 1 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2, HAZARDS IDENTIFICATION B
GUS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable t
3, COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
Polyurethane prepolymer 40-70
1,2-Cyclohexanedicarboxylic acid, 1,2-dinonyl ester, branched and linear 474919-59-0
Toluene diisocyanate 26471-62-5
4. FIRST AID MEASURES : ! :
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5, FIREFIGHTING MEASURES ; : ;
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES _
SPILL AND LEAK PROCEDURES: Evacuate the area, Clean-up should only be performed by trained personnel. People dealing with a major
