by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 05/15/2014
SDS No : SC-22
Date Revised : 09/08/2020
Revision No : 2
SC-22
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-22
GENERAL USE: Plasticizer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 10068515-49-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, or water fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
Page 1 of 5
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and clothing.
Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from excessive heat, in
original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination
with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – –
STEL – –
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Page 2 of 5
SC-22
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild
COLOR: Colorless
pH: No data available
FLASH POINT AND METHOD: 223.9 C (435 F) Pensky-Martens CC
VAPOR PRESSURE: < 0.08 mmHg at 20 C (68 F)
VAPOR DENSITY: > 1 (Air=1)
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Negligible
EVAPORATION RATE: < 0.01 (n-BuAc=1)
SPECIFIC GRAVITY: 0.97 (water=1) at 20 C (68 F)
VISCOSITY #1: 130 Centistokes at 20 C (68 F)
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: Heat, flames, and ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich> 10 g/kg Rat> 3.16 g/kg Rabbit> 0.13 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
NOTES: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
Page 3 of 5
SC-22
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 100Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In
Page 4 of 5
SC-22
the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 09/08/2020
REVISION SUMMARY: This SDS replaces the 08/15/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
SC-22
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 05/15/2014
SDS No : SC-22
Date Revised : 09/08/2020
Revision No : 2
SC-22
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-22
GENERAL USE: Plasticizer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 10068515-49-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, or water fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
Page 1 of 5
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and clothing.
Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from excessive heat, in
original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination
with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – –
STEL – –
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Page 2 of 5
SC-22
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild
COLOR: Colorless
pH: No data available
FLASH POINT AND METHOD: 223.9 C (435 F) Pensky-Martens CC
VAPOR PRESSURE: < 0.08 mmHg at 20 C (68 F)
VAPOR DENSITY: > 1 (Air=1)
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Negligible
EVAPORATION RATE: < 0.01 (n-BuAc=1)
SPECIFIC GRAVITY: 0.97 (water=1) at 20 C (68 F)
VISCOSITY #1: 130 Centistokes at 20 C (68 F)
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: Heat, flames, and ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich> 10 g/kg Rat> 3.16 g/kg Rabbit> 0.13 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
NOTES: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
Page 3 of 5
SC-22
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 100Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In
Page 4 of 5
SC-22
the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 09/08/2020
REVISION SUMMARY: This SDS replaces the 08/15/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
SC-22
by | Sep 27, 2025
Safety Data Sheet
RS 1400 Series A SIDE
Safety Data Sheet dated: 5/1/2023 – version 2
Date of first edition: 4/13/2023
1. IDENTIFICATION
Product identifier
Mixture identification:
Trade name:RS 1400 Series A SIDE
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use:N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company:ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable:N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Label elements
Skin irritation, Category 2 Causes skin irritation.
Eye irritation, Category 2A Causes serious eye irritation.
Respiratory Sensitization, Category 1 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Skin Sensitization, Category 1 May cause an allergic skin reaction.
Carcinogenicity, Category 2 Suspected of causing cancer.
Specific target organ toxicity following single exposure,
Category 3
May cause respiratory irritation.
Specific target organ toxicity following repeated exposure,
Category 2
May cause damage to organs through prolonged or repeated
exposure.
Hazard pictograms and Signal Word
Danger
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Page n. of1 85/1/2023 Production Name RS 1400 Series A SIDEDate
Hazards not otherwise classified identified during the classification process:
None
Additional classification information
HMIS Health:3 = SERIOUS
HMIS Flammability:0 = Not Combustible
HMIS Reactivity:0 = MINIMAL
HMIS P.P.E.:Safety glasses, gloves
NFPA Health:3 = SERIOUS
NFPA Flammability:0 = Not Combustible
NFPA Reactivity:0 = MINIMAL
NFPA Special Risk:NONE
Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … Thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302+P352 IF ON SKIN: Wash with plenty of water/
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER/doctor/ if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … On this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to …
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
N.A.
Mixtures
Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:
List of components
Qty Name Ident. Numb. Classification Registration Number
60-80 % DIPHENYLMETHANEDIISOCYANATE CAS:9016-87-9 Skin Irrit. 2, H315; Eye Irrit. 2A,
H319; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334
Page n. of2 85/1/2023 Production Name RS 1400 Series A SIDEDate
30-70 % 4,4′-METHYLENEDIPHENYL
DIISOCYANATE
CAS:101-68-8 Acute Tox. 4, H332; Skin Irrit. 2,
H315; Eye Irrit. 2A, H319; Carc. 2,
H351; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334;
Skin Sens. 1, H317
The actual concentration of the components listed above is withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Remove contaminated clothing immediatley and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
In case of Inhalation:
In case of inhalation, consult a doctor immediately and show him packing or label.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Page n. of3 85/1/2023 Production Name RS 1400 Series A SIDEDate
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Exercise the greatest care when handling or opening the container.
Do not use on extensive surface areas in premises where there are occupants.
Use localized ventilation system.
Don’t use empty container before they have been cleaned.
Before making transfer operations, assure that there aren’t any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Storage temperature:N.A.
Always keep in a well ventilated place.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Appropriate engineering controls:N.A.
Individual protection measures
Eye protection:
Use close fitting safety goggles, don’t use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment.
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical StateN.A.
Appearance and colour:N.A.
Odour:N.A.
Odour threshold:N.A.
pH:N.A.
Melting point / freezing point:N.A.
Initial boiling point and boiling range:N.A.
Flash point:N.A.
Evaporation rate:N.A.
Upper/lower flammability or explosive limits:N.A.
Vapour density:N.A.
Vapour pressure:N.A.
Relative density:N.A.
Solubility in water:N.A.
Solubility in oil:N.A.
Partition coefficient (n-octanol/water):N.A.
Auto-ignition temperature:N.A.
Decomposition temperature: N.A.
Viscosity:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Solid/gas flammability:N.A.
Other information
Substance Groups relevant propertiesN.A.
Miscibility:N.A.
Fat Solubility:N.A.
Conductivity:N.A.
Page n. of4 85/1/2023 Production Name RS 1400 Series A SIDEDate
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Toxicological Information of the Preparation
a) acute toxicity Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation The product is classified: Skin irritation, Category 2(H315)
c) serious eye damage/irritation The product is classified: Eye irritation, Category 2A(H319)
d) respiratory or skin sensitisationThe product is classified: Respiratory Sensitization, Category 1(H334), Skin
Sensitization, Category 1(H317)
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity The product is classified: Carcinogenicity, Category 2(H351)
g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure The product is classified: Specific target organ toxicity following single exposure,
Category 3(H335)
i) STOT-repeated exposure The product is classified: Specific target organ toxicity following repeated exposure,
Category 2(H373)
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Substance(s) listed on the IARC Monographs:
None
Substance(s) listed as OSHA Carcinogen(s):
None
Substance(s) listed as NIOSH Carcinogen(s):
None
Substance(s) listed on the NTP report on Carcinogens:
None
12. ECOLOGICAL INFORMATION
Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Persistence and degradability
Bioaccumulative potential
List of Eco-Toxicological properties of the product
Not classified for environmental hazards.
No data available for the product
N.A.
Page n. of5 85/1/2023 Production Name RS 1400 Series A SIDEDate
Mobility in soil
Other adverse effects
N.A.
N.A.
N.A.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.
14. TRANSPORT INFORMATION
UN number
ADR-UN number: 3082
DOT-UN Number: UN3082
IATA-Un number: 3082
IMDG-Un number: 3082
UN proper shipping name
ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
DOT Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
IATA-Technical name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport hazard class(es)
ADR-Class:9
DOT Hazard Class:9
IATA-Class:9
IMDG-Class:9
Packing group
ADR-Packing Group: III
DOT Packing Group:III
IATA-Packing group:III
IMDG-Packing group: III
Environmental hazards
Marine pollutant:No
Environmental Pollutant:N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
Special precautions
Department of Transportation (DOT):
DOT-Special Provision(s):8, 146, 173, 335, IB3, T4, TP1, TP29
DOT Label(s):9
DOT Symbol:N/A
DOT Cargo Aircraft:No limit
DOT Passenger Aircraft:No limit
DOT Bulk:241
DOT Non-Bulk:203
Road and Rail (ADR-RID):
ADR-Label:9
ADR – Hazard identification number:90
ADR-Transport category (Tunnel restriction code):3 (-)
Air (IATA):
IATA-Passenger Aircraft:964
IATA-Cargo Aircraft:964
IATA-Label:9
IATA-Subrisk:-
IATA-Erg:9L
IATA-Special Provisions:A97 A158 A197 A215
Sea (IMDG):
IMDG-Stowage Code: Category A
Page n. of6 85/1/2023 Production Name RS 1400 Series A SIDEDate
IMDG-Stowage Code: Category A
IMDG-Stowage Note: –
IMDG-Subrisk:-
IMDG-Special Provisions:274 335 969
IMDG-EMS: F-A, S-F
15. REGULATORY INFORMATION
USA – Federal regulations
TSCA – Toxic Substances Control Act
SARA – Superfund Amendments and Reauthorization Act
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
CAA – Clean Air Act
CWA – Clean Water Act
USA – State specific regulations
California Proposition 65
Massachusetts Right to know
Pennsylvania Right to know
New Jersey Right to know
TSCA inventory:
No substances listed
TSCA listed substances:
No substances listed
Section 302 – Extremely Hazardous Substances:
No substances listed
Section 304 – Hazardous substances:
No substances listed
Section 313 – Toxic chemical list:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under CERCLA:
No substances listed
CAA listed substances:
No substances listed
CWA listed substances:
No substances listed
Substance(s) listed under California Proposition 65:
No substances listed
Substance(s) listed under Massachusetts Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under Pennsylvania Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under New Jersey Right to know:
No substances listed
16. OTHER INFORMATION
Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
Page n. of7 85/1/2023 Production Name RS 1400 Series A SIDEDate
Safety Data Sheet dated: 5/1/2023 – version 2
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality. The information relates only to the specific material and may not be valid for such material
used in combination with any other material or in any process.
This document was prepared by a competent person who has received appropriate training.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID:Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG:International Maritime Code for Dangerous Goods.
IATA:International Air Transport Association.
IATA-DGR:Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO:International Civil Aviation Organization.
ICAO-TI:Technical Instructions by the “International Civil Aviation Organization” (ICAO).
GHS:Globally Harmonized System of Classification and Labeling of Chemicals.
CLP:Classification, Labeling, Packaging.
EINECS:European Inventory of Existing Commercial Chemical Substances.
INCI:International Nomenclature of Cosmetic Ingredients.
CAS:Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO:Ordinance on Hazardous Substances, Germany.
LC50:Lethal concentration, for 50 percent of test population.
LD50:Lethal dose, for 50 percent of test population.
DNEL:Derived No Effect Level.
PNEC:Predicted No Effect Concentration.
TLV:Threshold Limiting Value.
TWATLV:Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL:Short Term Exposure limit.
STOT:Specific Target Organ Toxicity.
WGK:German Water Hazard Class.
KSt:Explosion coefficient.
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided without any
warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety preventive measures for the users
who have got professional training. The personal user who obtained this SDS should make independent judgment for the
applicability of this SDS under special conditions. In these special cases, we do not assume responsibility for the damage.
Paragraphs modified from the previous revision:
– 3. COMPOSITION/INFORMATION ON INGREDIENTS
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Code Hazard class and hazard category Description
A.1/4/Inhal Acute Tox. 4 Acute toxicity (inhalation), Category 4
A.2/2 Skin Irrit. 2 Skin irritation, Category 2
A.3/2A Eye Irrit. 2A Eye irritation, Category 2A
A.4.1/1 Resp. Sens. 1 Respiratory Sensitization, Category 1
A.4.2/1 Skin Sens. 1 Skin Sensitization, Category 1
A.6/2 Carc. 2 Carcinogenicity, Category 2
A.8/3 STOT SE 3 Specific target organ toxicity following single exposure, Category 3
A.9/2 STOT RE 2 Specific target organ toxicity following repeated exposure, Category 2
Page n. of8 85/1/2023 Production Name RS 1400 Series A SIDEDate
by | Sep 27, 2025
Safety Data Sheet
RS 1400 Series B-Side
Safety Data Sheet dated: 5/1/2023 – version 4
Date of first edition: 2/2/2023
1. IDENTIFICATION
Product identifier
Mixture identification:
Trade name:RS 1400 Series B-Side
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use:N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company:ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable:N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Label elements
Skin irritation, Category 2 Causes skin irritation.
Serious eye damage, Category 1 Causes serious eye damage.
Reproductive toxicity, Category 2 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity following repeated exposure,
Category 2
May cause damage to organs through prolonged or repeated
exposure.
Hazard pictograms and Signal Word
Danger
Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash … Thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water/
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
Page n. of1 85/1/2023 Production Name RS 1400 Series B-SideDate
Hazards not otherwise classified identified during the classification process:
None
Additional classification information
HMIS Health:0 = MINIMAL
HMIS Flammability:0 = Not Combustible
HMIS Reactivity:0 = MINIMAL
HMIS P.P.E.:Safety glasses, gloves
NFPA Health:0 = MINIMAL
NFPA Flammability:0 = Not Combustible
NFPA Reactivity:0 = MINIMAL
NFPA Special Risk:NONE
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER/doctor/
P314 Get medical advice/attention if you feel unwell.
P321 Specific treatment (see … On this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P501 Dispose of contents/container to …
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
N.A.
Mixtures
Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:
List of components
Qty Name Ident. Numb. Classification Registration Number
10-30 % TRIS(2-CHLORO-1-METHYLETHYL)
PHOSPHATE
CAS:13674-84-5 Acute Tox. 4, H302
< 10 % Diethylene glycol CAS:111-46-6 Acute Tox. 4, H302; STOT RE 2,
H373
< 5 % 2-DIMETHYLAMINOETHANOL CAS:108-01-0 Flam. Liq. 3, H226; Acute Tox. 4,
H302; Acute Tox. 4, H312; Acute
Tox. 3, H331; STOT SE 3, H335;
Aquatic Acute 3, H402; Skin Corr.
1B, H314
< 1% POTASSIUM 2-ETHYLHEXANOATE CAS:3164-85-0 Flam. Liq. 3, H226; Repr. 2, H361;
STOT RE 2, H373
The actual concentration of the components listed above is withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
Remove contaminated clothing immediatley and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
Page n. of2 85/1/2023 Production Name RS 1400 Series B-SideDate
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Exercise the greatest care when handling or opening the container.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Storage temperature:N.A.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Appropriate engineering controls:N.A.
Individual protection measures
Eye protection:
No data available
Page n. of3 85/1/2023 Production Name RS 1400 Series B-SideDate
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical StateN.A.
Appearance and colour:N.A.
Odour:N.A.
Odour threshold:N.A.
pH:N.A.
Melting point / freezing point:N.A.
Initial boiling point and boiling range:N.A.
Flash point:N.A.
Evaporation rate:N.A.
Upper/lower flammability or explosive limits:N.A.
Vapour density:N.A.
Vapour pressure:N.A.
Relative density:N.A.
Solubility in water:N.A.
Solubility in oil:N.A.
Partition coefficient (n-octanol/water):N.A.
Auto-ignition temperature:N.A.
Decomposition temperature: N.A.
Viscosity:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Solid/gas flammability:N.A.
Other information
Substance Groups relevant propertiesN.A.
Miscibility:N.A.
Fat Solubility:N.A.
Conductivity:N.A.
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Toxicological Information of the Preparation
a) acute toxicity Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation The product is classified: Skin irritation, Category 2(H315)
c) serious eye damage/irritation The product is classified: Serious eye damage, Category 1(H318)
d) respiratory or skin sensitisationNot classified
Page n. of4 85/1/2023 Production Name RS 1400 Series B-SideDate
Based on available data, the classification criteria are not met
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity Not classified
Based on available data, the classification criteria are not met
g) reproductive toxicity The product is classified: Reproductive toxicity, Category 2(H361)
h) STOT-single exposure Not classified
Based on available data, the classification criteria are not met
i) STOT-repeated exposure The product is classified: Specific target organ toxicity following repeated exposure,
Category 2(H373)
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Toxicological information on main components of the mixture:
TRIS(2-CHLORO-1-
METHYLETHYL)
PHOSPHATE
a) acute toxicity LD50 Oral Rat = 1101 mg/kg
LC50 Inhalation Rat > 7 mg/l 4h
LD50 Skin Rabbit > 2000 mg/kg
2-
DIMETHYLAMINOETHANO
L
a) acute toxicity LD50 Oral Rat = 1182 mg/kg
LC50 Inhalation Rat = 6 mg/l 4h
LD50 Skin Rabbit = 1220 mg/kg
Substance(s) listed on the IARC Monographs:
None
Substance(s) listed as OSHA Carcinogen(s):
None
Substance(s) listed as NIOSH Carcinogen(s):
None
Substance(s) listed on the NTP report on Carcinogens:
None
12. ECOLOGICAL INFORMATION
Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
N.A.
List of Eco-Toxicological properties of the product
Not classified for environmental hazards.
No data available for the product
N.A.
N.A.
N.A.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.
Page n. of5 85/1/2023 Production Name RS 1400 Series B-SideDate
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.
14. TRANSPORT INFORMATION
Not classified as dangerous in the meaning of transport regulations.
UN number
ADR-UN number: N.A.
DOT-UN Number: N.A.
IATA-Un number: N.A.
IMDG-Un number: N.A.
UN proper shipping name
ADR-Shipping Name: N.A.
DOT Proper Shipping Name: N.A.
IATA-Technical name:N.A.
IMDG-Technical name: N.A.
Transport hazard class(es)
ADR-Class:N.A.
DOT Hazard Class:N.A.
IATA-Class:N.A.
IMDG-Class:N.A.
Packing group
ADR-Packing Group: N.A.
DOT Packing Group:N.A.
IATA-Packing group:N.A.
IMDG-Packing group: N.A.
Environmental hazards
Marine pollutant:No
Environmental Pollutant:N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
Special precautions
Department of Transportation (DOT):
N.A.
Road and Rail (ADR-RID):
N.A.
Air (IATA):
N.A.
Sea (IMDG):
N.A.
15. REGULATORY INFORMATION
USA – Federal regulations
TSCA – Toxic Substances Control Act
SARA – Superfund Amendments and Reauthorization Act
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
TSCA inventory:
No substances listed
TSCA listed substances:
No substances listed
Section 302 – Extremely Hazardous Substances:
No substances listed
Section 304 – Hazardous substances:
No substances listed
Section 313 – Toxic chemical list:
No substances listed
Substance(s) listed under CERCLA:
No substances listed
Page n. of6 85/1/2023 Production Name RS 1400 Series B-SideDate
CAA – Clean Air Act
CWA – Clean Water Act
USA – State specific regulations
California Proposition 65
Massachusetts Right to know
Pennsylvania Right to know
New Jersey Right to know
CAA listed substances:
No substances listed
CWA listed substances:
No substances listed
Substance(s) listed under California Proposition 65:
No substances listed
Substance(s) listed under Massachusetts Right to know:
No substances listed
Substance(s) listed under Pennsylvania Right to know:
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE
2-DIMETHYLAMINOETHANOL
Substance(s) listed under New Jersey Right to know:
TRIS(2-CHLORO-1-METHYLETHYL) PHOSPHATE
2-DIMETHYLAMINOETHANOL
16. OTHER INFORMATION
Safety Data Sheet dated: 5/1/2023 – version 4
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality. The information relates only to the specific material and may not be valid for such material
used in combination with any other material or in any process.
This document was prepared by a competent person who has received appropriate training.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road.
Code Description
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H402 Harmful to aquatic life
Code Hazard class and hazard category Description
A.1/3/Inhal Acute Tox. 3 Acute toxicity (inhalation), Category 3
A.1/4/Dermal Acute Tox. 4 Acute toxicity (dermal), Category 4
A.1/4/Oral Acute Tox. 4 Acute toxicity (oral), Category 4
A.2/1B Skin Corr. 1B Skin corrosion, Category 1B
A.7/2 Repr. 2 Reproductive toxicity, Category 2
A.8/3 STOT SE 3 Specific target organ toxicity following single exposure, Category 3
A.9/2 STOT RE 2 Specific target organ toxicity following repeated exposure, Category 2
B.6/3 Flam. Liq. 3 Flammable Liquids Category 3
US-HAE/A3 Aquatic Acute 3 Acute aquatic hazard, category 3
Page n. of7 85/1/2023 Production Name RS 1400 Series B-SideDate
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID:Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG:International Maritime Code for Dangerous Goods.
IATA:International Air Transport Association.
IATA-DGR:Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO:International Civil Aviation Organization.
ICAO-TI:Technical Instructions by the “International Civil Aviation Organization” (ICAO).
GHS:Globally Harmonized System of Classification and Labeling of Chemicals.
CLP:Classification, Labeling, Packaging.
EINECS:European Inventory of Existing Commercial Chemical Substances.
INCI:International Nomenclature of Cosmetic Ingredients.
CAS:Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO:Ordinance on Hazardous Substances, Germany.
LC50:Lethal concentration, for 50 percent of test population.
LD50:Lethal dose, for 50 percent of test population.
DNEL:Derived No Effect Level.
PNEC:Predicted No Effect Concentration.
TLV:Threshold Limiting Value.
TWATLV:Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL:Short Term Exposure limit.
STOT:Specific Target Organ Toxicity.
WGK:German Water Hazard Class.
KSt:Explosion coefficient.
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided without any
warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety preventive measures for the users
who have got professional training. The personal user who obtained this SDS should make independent judgment for the
applicability of this SDS under special conditions. In these special cases, we do not assume responsibility for the damage.
Paragraphs modified from the previous revision:
– 3. COMPOSITION/INFORMATION ON INGREDIENTS
Page n. of8 85/1/2023 Production Name RS 1400 Series B-SideDate
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: RS 1402 B REVISED DATE: Jan 26, 2022
SDS NUMBER: RS 1402 B SUPERSEDES SDS: N/A
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCTION IDENTIFICATION NUMBER: RS 1402 B
CHEMICAL FAMILY: POLYETHER POLYOL BLEND
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical State: Liquid
Potential Acute Heath Effects:
Eyes Corrosive to eyes.
Skin Corrosive to skin on contact. Skin contact may produce burns.
Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking or shortness of breath.
Ingestion May cause burns to mouth, throat and stomach.
GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards.
GHS Label Elements:
Hazard pictograms
SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 55-90 %
GLYCOLS Mixture 0-10 %
*Occupational Exposure Limit(s), if available, are listed in Section 8.
2
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention
immediately.
Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified
personnel may administer oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if
necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours as
delayed pulmonary edema may develop.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >212 F Closed Cup
Auto Ignition Temp: Not available.
Flammable Limits: Not available.
Products of Combustion:
Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen,
amines, possibly other irritating gases.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire):
Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
See Safety Data Sheet section 8 Personal Protective Equipment
Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container.
Large Spill and Leak Corrosive liquid. Toxic liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water
spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate
all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
3
SECTION 7: HANDLING AND STORAGE
Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in case of insufficient ventilation or where operational procedures
demand it. For guidance on engineering control measures refer to publications such as the ACGIH
current edition of Industrial Ventilation, a manual of Recommended Practice.
Personal Protection
Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield.
Body and Hands Full chemical suit. Gloves.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Personal Protection in case of a Large Spill
Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots.
Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Clear Slight Odor
BOILING POINT ( F/ C) Not determined
MELTING POINT ( F/ C) Not determined
SPECIFIC GRAVITY ( WATER = 1) 1.12 kg/l
BULK DENSITY 8.8 lb/gal
pH OF UNDILUTED PRODUCT Not determined
VAPOR PRESSURE (MM Hg.) Not determined
VAPOR DENSITY (AIR-1) >1
VISCOSITY 800 to 1400 cps @ 25 C
PERCENT (%) VOC 0
SOLUBILITY IN WATER Soluble
SECTION 10: STABILITY AND REACTIVITY
Stability and Reactivity This product is stable.
Conditions of Stability Avoid moisture to protect product quality.
Incompatibility with Various Substances
Slightly reactive to reactive with oxidizing agents, alkalis.
Hazardous Decomposition Products
Thermal decomposition products are toxic and may include oxides of carbon and
nitrogen, amines, possibly other irritating gases.
4
Hazardous Polymerization Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
No applicable data for this section.
SECTION 12I: ECOLOGICAL INFORMATION
No applicable data for this section.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems.
Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a
scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or
crushed to prevent reuse.
Material for disposal should be placed in appropriated sealed containers to avoid potential human and
environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal
contractor and environmental agency for relevant laws and regulations. Under the US, Resource
Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at
the time of disposal, whether the product meets relevant waste classification and to assure proper
disposal.
SECTION 14: TRANSPORT INFORMATION
Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
DOT Classification Non Regulated
TDG Classification Non Regulated
IMO/IMDG Classification Non Regulated
ICAO/IATA Classification Non Regulated
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification
Class: Corrosive material
TSCA 8(b) inventory: All ingredients Listed.
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
Any spill or release above the RC must be reported to the National Response Center (800-424-8802)
SARA 313 toxic chemical notification and release reporting: None
State Regulations California prop 65: No ingredients listed.
5
Canadian Regulations
This product has been classified in accordance with the hazard criteria of the CPR
(Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL/NDSL Not all Ingredients Listed.
SECTION 16: OTHER INFORMATION
Causes respiratory tract, eye and skin burns.
Harmful if inhaled.
May be harmful if swallowed.
Contains material, which may cause birth defects based on animal data.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 1 Health: 1
Fire Hazard: 1 Fire Hazard: 1
Reactivity: 0 Reactivity: 0
Notice to Reader
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANTY, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be
determined by the user and made known to handlers, processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APPROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: RS 1402 A DATE: Jan 26, 2022
SDS NUMBER: RS 1402 A SUPERSEDES SDS: N/A
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCT IDENTIFICATION NUMBER: RS 1402 A
CHEMICAL FAMILY: POLYMERIC ISOCYANATE
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Brown Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m3, the highest dose tested. This is well above
the recommended TLV of 5ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
2
Aggravated Medical Conditions:
Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-
specific bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates.
GHS Label Elements:
Hazard pictograms
SECTION 3: HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 100%
*Occupational Exposure Limit(s) if available, are listed in section 8.
SECTION 4: FIRST AID MEASURES
Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get immediate medical attention.
Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water.
If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has
demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water.
Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical
attention.
Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim
is unconscious or having convulsions. Get immediate medical attention.
NOTES TO PHYSICIANS: There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive
therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.
Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is
recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a
minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased,
recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as
having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >93.3 C, Closed Cup.
Autoignition: >600 C.
Flammable Limits: Not available.
Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks
and static discharge or combustible materials.
Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Do not use water jet.
3
Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be
used to avoid inhalation of the product.
Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed
containers. This reaction accelerates at higher temperatures.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages
should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further
leakage, spillage or entry into drains.
Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth
or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area
with
Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly
dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is
reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15).
Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium
hydroxide). Follow the precautions on the supplier s material safety data sheets when preparing and using solution.
Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums.
Do not tighten the bungs. Mixing with wet earth is also effective, but slower.
SECTION 7: HANDLING AND STORAGE
Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that
the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly
because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for
details.)
Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from
moisture. Due to reaction with water, producing CO2-gas, a hazardous build-up of pressure could result if contaminated
containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be
resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or
galvanized surfaces.
Ideal storage temperature is 16-38 C (60-100 F).
Keep stocks of decontaminant (see Section 6) readily available.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For
guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial
Ventilation, a manual of Recommended Practice .
Personal Protection
Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield.
4
Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl
rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be
selected and used in accordance with Guidelines for the Selection of Chemical Protective Clothing published by ACGIH.
Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH
positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges
and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has
been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134).
Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing
apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Product Name Exposure Limits
4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m3 (8-hour, 40 hours/week) OSHA PEL Ceiling Limit 0.20 mg/m3
NIOSH REL/TWA 0.05 mg/m3 (10-hour, 40 hours/week)
NIOSH REL/CEILING 0.20 mg/m3 (10-minutes)
Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with
respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic
Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their
suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that
caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized
individuals.
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Brown Liquid Slightly Musty
BOILING POINT ( C) >300 C
MELTING POINT ( F/ C) Not available
SPECIFIC GRAVITY ( WATER = 1) 1.23 gr/ml
BULK DENSITY 9.0 lb/gal
pH Not applicable
VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25 C
VAPOR DENSITY (AIR-1) 8.5
VISCOSITY 200-500 cps @ 25 C
PERCENT (%) VOC 0%
FLASH POINTS >93.3 C (230 F) Closed Cup
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at room temperature.
Incompatibility with various Substances: Reactive with moisture.
Conditions of Instability: Avoid high temperatures. Avoid freezing.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary
amines and metal compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity to Animals: LD50 Rat Oral: >5000mg/kg
LD50 Rabbit Dermal: >5000 mg/kg
5
Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or
aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include
irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty
in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive
response to even minimal concentrations of MDI may develop in sensitized persons.
Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited
evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the
need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance
work.
Eye Contact: The vapor, aerosol, and liquid are irritant.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is
considered practically non-toxic by ingestion.
Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE)
Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not
regulated as carcinogens by OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects: There is no substantial evidence of mutagenic potential.
Reproductive Effects: No adverse reproductive effects are anticipated.
Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at
doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not
maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined
limits.
Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to
atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m3. No adverse effects were
observed at 0.2 mg/m3. At the 1mg/m3 concentration, minimal nasal and lung irritant effect were seen. Only at the top
concentration (6.0 mg/m3) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant
pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m3 group. MDI administration to rats in this study did not
change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung
tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In
the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely
that tumor formation will occur.
There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli)
> 100ml/l.
Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise
based on consideration of the production and use of the substance.
Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable
solids.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information: The generation of waste should be avoided or minimized wherever possible.
Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous waste
under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The treated
6
waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never be
poured down drains, sewers or waterways.
Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed.
SECTION 14: TRANSPORT INFORMATION
For major spills call Chemtrec (800-424-9300).
DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of
4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl
Diisocyanate), 9, NA3082, PGlll, RQ.
TDG Classification: Not regulated.
IMO/IMDG Classification: Not regulated.
ICAO/IATA Classification: Not regulated.
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification: Class: Toxic
Class: Irritating substance.
Class: Sensitizing substance.
TSCA 8(b) inventory: All Ingredients Listed
EPCRA Section 313 (40 CFR 372)
Diisocyanate Compounds (Category Code N120) 100%
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
This product does not contain nor is it manufactured with ozone depleting substances.
State Regulations:
Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled
Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA: DSL/NDSL: All Ingredients Listed.
SECTION 16: OTHER INFORMATION
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE
HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity: 1
7
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date
of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND
RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS
PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing
circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers,
processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: RS 1202 B REVISED DATE: June 01, 2015
MSDS NUMBER: RS 1202 B SUPERSEDES MSDS: August 2, 2012
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCTION IDENTIFICATION NUMBER: RS 1202 B
CHEMICAL FAMILY: POLYETHER POLYOL BLEND
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical State: Liquid
Potential Acute Heath Effects:
Eyes Corrosive to eyes.
Skin Corrosive to skin on contact. Skin contact may produce burns.
Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking or shortness of breath.
Ingestion May cause burns to mouth, throat and stomach.
GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards.
GHS Label Elements:
Hazard pictograms
SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 55-90 %
GLYCOLS Mixture 0-10 %
*Occupational Exposure Limit(s), if available, are listed in Section 8.
2
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention
immediately.
Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified
personnel may administer oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if
necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours as
delayed pulmonary edema may develop.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >212 F Closed Cup
Auto Ignition Temp: Not available.
Flammable Limits: Not available.
Products of Combustion:
Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen,
amines, possibly other irritating gases.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire):
Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
See Safety Data Sheet section 8 Personal Protective Equipment
Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container.
Large Spill and Leak Corrosive liquid. Toxic liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water
spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate
all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
3
SECTION 7: HANDLING AND STORAGE
Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in case of insufficient ventilation or where operational procedures
demand it. For guidance on engineering control measures refer to publications such as the ACGIH
current edition of Industrial Ventilation, a manual of Recommended Practice.
Personal Protection
Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield.
Body and Hands Full chemical suit. Gloves.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Personal Protection in case of a Large Spill
Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots.
Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Clear Slight Odor
BOILING POINT ( F/ C) Not determined
MELTING POINT ( F/ C) Not determined
SPECIFIC GRAVITY ( WATER = 1) 1.12 kg/l
BULK DENSITY 8.8 lb/gal
pH OF UNDILUTED PRODUCT Not determined
VAPOR PRESSURE (MM Hg.) Not determined
VAPOR DENSITY (AIR-1) >1
VISCOSITY 600 to 900 cps @ 25 C
PERCENT (%) VOC 0
SOLUBILITY IN WATER Soluble
SECTION 10: STABILITY AND REACTIVITY
Stability and Reactivity This product is stable.
Conditions of Stability Avoid moisture to protect product quality.
Incompatibility with Various Substances
Slightly reactive to reactive with oxidizing agents, alkalis.
Hazardous Decomposition Products
4
Thermal decomposition products are toxic and may include oxides of carbon and
nitrogen, amines, possibly other irritating gases.
Hazardous Polymerization Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
No applicable data for this section.
SECTION 12I: ECOLOGICAL INFORMATION
No applicable data for this section.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems.
Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a
scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or
crushed to prevent reuse.
Material for disposal should be placed in appropriated sealed containers to avoid potential human and
environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal
contractor and environmental agency for relevant laws and regulations. Under the US, Resource
Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at
the time of disposal, whether the product meets relevant waste classification and to assure proper
disposal.
SECTION 14: TRANSPORT INFORMATION
Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
DOT Classification Non Regulated
TDG Classification Non Regulated
IMO/IMDG Classification Non Regulated
ICAO/IATA Classification Non Regulated
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification
Class: Corrosive material
TSCA 8(b) inventory: All ingredients Listed.
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
Any spill or release above the RC must be reported to the National Response Center (800-424-8802)
SARA 313 toxic chemical notification and release reporting: None
5
State Regulations California prop 65: No ingredients listed.
Canadian Regulations
This product has been classified in accordance with the hazard criteria of the CPR
(Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL/NDSL Not all Ingredients Listed.
SECTION 16: OTHER INFORMATION
Causes respiratory tract, eye and skin burns.
Harmful if inhaled.
May be harmful if swallowed.
Contains material, which may cause birth defects based on animal data.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 1 Health: 1
Fire Hazard: 1 Fire Hazard: 1
Reactivity: 0 Reactivity: 0
Notice to Reader
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANTY, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be
determined by the user and made known to handlers, processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APPROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: RS 1202 A DATE: June 01, 2015
MSDS NUMBER: RS 1202 A SUPERSEDES MSDS: August 02, 2012
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCT IDENTIFICATION NUMBER: RS 1202 A
CHEMICAL FAMILY: POLYMERIC ISOCYANATE
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Brown Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m3, the highest dose tested. This is well above
the recommended TLV of 5ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
2
Aggravated Medical Conditions:
Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-
specific bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates.
GHS Label Elements:
Hazard pictograms
SECTION 3: HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 100%
*Occupational Exposure Limit(s) if available, are listed in section 8.
SECTION 4: FIRST AID MEASURES
Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get immediate medical attention.
Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water.
If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has
demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water.
Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical
attention.
Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim
is unconscious or having convulsions. Get immediate medical attention.
NOTES TO PHYSICIANS: There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive
therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.
Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is
recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a
minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased,
recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as
having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >93.3 C, Closed Cup.
Autoignition: >600 C.
Flammable Limits: Not available.
Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks
and static discharge or combustible materials.
Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Do not use water jet.
3
Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be
used to avoid inhalation of the product.
Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed
containers. This reaction accelerates at higher temperatures.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages
should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further
leakage, spillage or entry into drains.
Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth
or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area
with
Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly
dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is
reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15).
Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium
hydroxide). Follow the precautions on the supplier s material safety data sheets when preparing and using solution.
Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums.
Do not tighten the bungs. Mixing with wet earth is also effective, but slower.
SECTION 7: HANDLING AND STORAGE
Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that
the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly
because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for
details.)
Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from
moisture. Due to reaction with water, producing CO2-gas, a hazardous build-up of pressure could result if contaminated
containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be
resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or
galvanized surfaces.
Ideal storage temperature is 16-38 C (60-100 F).
Keep stocks of decontaminant (see Section 6) readily available.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For
guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial
Ventilation, a manual of Recommended Practice .
Personal Protection
Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield.
4
Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl
rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be
selected and used in accordance with Guidelines for the Selection of Chemical Protective Clothing published by ACGIH.
Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH
positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges
and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has
been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134).
Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing
apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Product Name Exposure Limits
4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m3 (8-hour, 40 hours/week) OSHA PEL Ceiling Limit 0.20 mg/m3
NIOSH REL/TWA 0.05 mg/m3 (10-hour, 40 hours/week)
NIOSH REL/CEILING 0.20 mg/m3 (10-minutes)
Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with
respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic
Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their
suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that
caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized
individuals.
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Brown Liquid Slightly Musty
BOILING POINT ( C) >300 C
MELTING POINT ( F/ C) Not available
SPECIFIC GRAVITY ( WATER = 1) 1.23 gr/ml
BULK DENSITY 9.0 lb/gal
pH Not applicable
VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25 C
VAPOR DENSITY (AIR-1) 8.5
VISCOSITY 900-1300 cps @ 25 C
PERCENT (%) VOC 0%
FLASH POINTS >93.3 C (230 F) Closed Cup
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at room temperature.
Incompatibility with various Substances: Reactive with moisture.
Conditions of Instability: Avoid high temperatures. Avoid freezing.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary
amines and metal compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity to Animals: LD50 Rat Oral: >5000mg/kg
LD50 Rabbit Dermal: >5000 mg/kg
5
Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or
aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include
irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty
in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive
response to even minimal concentrations of MDI may develop in sensitized persons.
Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited
evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the
need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance
work.
Eye Contact: The vapor, aerosol, and liquid are irritant.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is
considered practically non-toxic by ingestion.
Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE)
Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not
regulated as carcinogens by OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects: There is no substantial evidence of mutagenic potential.
Reproductive Effects: No adverse reproductive effects are anticipated.
Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at
doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not
maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined
limits.
Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to
atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m3. No adverse effects were
observed at 0.2 mg/m3. At the 1mg/m3 concentration, minimal nasal and lung irritant effect were seen. Only at the top
concentration (6.0 mg/m3) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant
pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m3 group. MDI administration to rats in this study did not
change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung
tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In
the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely
that tumor formation will occur.
There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli)
> 100ml/l.
Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise
based on consideration of the production and use of the substance.
Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable
solids.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information: The generation of waste should be avoided or minimized wherever possible.
Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous waste
under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The treated
6
waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never be
poured down drains, sewers or waterways.
Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed.
SECTION 14: TRANSPORT INFORMATION
For major spills call Chemtrec (800-424-9300).
DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of
4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl
Diisocyanate), 9, NA3082, PGlll, RQ.
TDG Classification: Not regulated.
IMO/IMDG Classification: Not regulated.
ICAO/IATA Classification: Not regulated.
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification: Class: Toxic
Class: Irritating substance.
Class: Sensitizing substance.
TSCA 8(b) inventory: All Ingredients Listed
EPCRA Section 313 (40 CFR 372)
Diisocyanate Compounds (Category Code N120) 100%
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
This product does not contain nor is it manufactured with ozone depleting substances.
State Regulations:
Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled
Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
CEPA: DSL/NDSL: All Ingredients Listed.
SECTION 16: OTHER INFORMATION
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE
HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity: 1
7
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date
of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND
RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS
PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing
circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers,
processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
CHEMLINE SDS CHEMLINE CA, INC
CHEMLINE RF15.0 PART B S60 BLACK
[____ | PRopucT AND COMPANY IDENTIFICATION
Product Identifier: CHEMLINE RF15.0 PART B S60 BLACK
Common Name: POLYURETHANE POLYOL BLEND
SDS Number: RF15.0 PART B 20000 S60 CA
Product Code: |-RF15.0-B-20000-S60
Revision Date: 11/20/2017
Version: 41
Internal ID: RF15.0-B-20000-S60
Product Use: 2 part polymeric elastomers for industrial and commercial applications.
Supplier Details: CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Phone: (310)764-0820
Fax: (310)764-0822
Web: WWW.CHEMLINE.NET
Emergency: CHEMTREC 800.424.9300 (24 HOURS)
[| HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
No GHS Classifications Indicated
GHS Label Elements, Including Precautionary Statements
GHS Signal Word: NONE
GHS Hazard Pictograms:
No GHS pictograms indicated for this product
GHS Hazard Statements:
No GHS hazards statements indicated
GHS Precautionary Statements:
No GHS precautionary statements indicated
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
Route of Entry: Eyes; Ingestion; Inhalation; Skin;
Target Organs: Eyes; Skin; Respiratory system;
Inhalation: Heating, spraying, foaming or otherwise mechanically dispersing operations way generate vapor
or aerosol concentrations sufficient to cause irritation or other adverse effects. Minimal respiratory
tract irritation may occur with exposure to a large amount of material.
Skin Contact: Prolonged or repeated exposure can cause skin irritation or dermatitis in some individuals.
Eye Contact: May cause watering of the eye and irritation of the conjunctiva.
Ingestion: May cause nausea or vomiting.
[| COMPOSITION/INFORMATION ON INGREDIENTS
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SDS Number: RF15.0 PART B 20000 S60 CA Page: 1/4 Revision Date: 11/20/2017
by | Sep 27, 2025
CHEMLINE Ss D S CHEMLINE CA, INC
~~ CHEMLINE RF15.0 S60 PARTA
[| PRODUCT AND COMPANY IDENTIFICATION
Supplier Details: CHEMLINE CA, INC
19500 SOUTH ALAMEDA STREET
EAST RANCHO DOMINGUEZ, CA 90221
Phone: (310)764-0820
Fax: (310)764-0822
Web: WWW.CHEMLINE.NET
Emergency: CHEMTREC 800.424.9300 (24 HOURS)
[______ | HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS Classification in Accordance with 29 CFR 1910 (OSHA HCS):
Health, Acute toxicity, 4 Oral
Health, Skin corrosion/irritation, 2
Health, Respiratory or skin sensitization, 1 Skin
Health, Serious Eye Damage/Eye Irritation, 2A
Health, Respiratory or skin sensitization, 1 Respiratory
Health, Specific target organ toxicity – Single exposure, 3
Health, Carcinogenicity, 2
Environmental, Hazards to the aquatic environment – Acute, 3
Environmental, Hazards to the aquatic environment – Chronic, 3
GHS Label Elements, Including Precautionary Statements
GHS Signal Word: DANGER
GHS Hazard Pictograms:
GHS Hazard Statements:
H302 – Harmful if swallowed
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H319 – Causes serious eye irritation
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled
H336 – May cause drowsiness or dizziness
H351 – Suspected of causing cancer.
H402 – Harmful to aquatic life
H412 – Harmful to aquatic life with long lasting effects
GHS Precautionary Statements:
No GHS precautionary statements indicated
Hazards not Otherwise Classified (HNOC) or not Covered by GHS
Route of Entry: Eyes; Ingestion; Inhalation; Skin;
Target Organs: Respiratory system; Skin; Eyes;
Inhalation: At room temperature, MDI vapors are minimal due to low vapor pressure. May cause respiratory
sensitization with asthma-like symptoms in susceptable individuals. Impaired lung function has
been associated with overesposure to isocyanates. MDI concentrations below the exposure
guidelines may cause allergic respiratory reactions in indiviuals already sensitized. Heating,
spraying, foaming or otherwise mechanically dispersing operations way generate vapor or aerosol
nn $e
SDS Number: RF15.0 PART A 30000 S60 CA Page: 1/9 Revision Date: 11/20/2017
