by | Sep 27, 2025
, Page 1 of 9
SAFETY DATA SHEET
Date issued : 05/09/2012
SDS number : SP-45 PART A
Date revised : 03/10/2022
ENTERPRISES Revision number : 3
SP-45 PART A
1. Identification
Product identifier: SP-45 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Reproductive Toxicity, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental hazards:
Acute Hazards to the Aquatic Environment, Category |
Chronic Hazards to the Aquatic Environment, Category 1
Label elements
Health hazard Exclamation Environment !
mark
Signal word: DANGER
Hazard statement(s)
H315: Causes skin irritation. :
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H360: May damage fertility or the unborn child.
H373: May cause damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 06/19/2014
SDS No : SP-205 PART A
Date Revised : 10/06/2020
Revision No : 2
SP-205 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 7
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
4,4′-Diphenylmethane diisocyanate 40 – 70101-68-8
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 10 – 3025686-28-6
1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich 10 – 3068515-48-0
2,6-di-tert-butyl-p-cresol 0.1 – 1128-37-0
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
Page 2 of 7
SP-205 PART A
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
SP-205 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL
TWA – –
STEL – –
C 0.02 0.2
ACGIH TLV
TWA 0.005 –
STEL – –
NIOSH REL
TWA 0.0050.05
STEL – –
C 0.02
[1]
0.2
[1]
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – –
STEL – –
1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – –
STEL – –
2,6-di-tert-butyl-p-cresol
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – 10
STEL – –
Footnotes:
1. 10-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Page 4 of 7
SP-205 PART A
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Yellow
pH: No data available
FLASH POINT AND METHOD: 207.2 C (405 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.18 (water=1) at 25 C (77 F)
VISCOSITY #1: 325 Centipoise at 25 C (77 F)
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, amines, acids, bases, and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
4,4′-Diphenylmethane diisocyanate
> 2000 mg/kg Rat> 9400 mg/kg
Rabbit
2.24 mg/l Rat (1 h,
dust/mist)
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer > 5000 mg/kg Rat No data available 0.49 mg/l Rat
1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-
rich
No data available No data available No data available
2,6-di-tert-butyl-p-cresol > 2900 mg/kg Rat> 2000 mg/kg Rat No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Page 5 of 7
SP-205 PART A
Chemical Name IARC Status
4,4′-Diphenylmethane diisocyanate 3
2,6-di-tert-butyl-p-cresol 3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause respiratory irritation.
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Refer to Section 2 for hazard classification.
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 40 – 70101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
4,4′-Diphenylmethane diisocyanate 40 – 70 5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
Page 6 of 7
SP-205 PART A
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich 10 – 30 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DINP RESTRICTIONS: This product contains diisononyl phthalate (DINP), CAS# 68515-48-0 EINECS# 271-090-9. In the U.S., there is an
interim prohibition on DINP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvemnet Act of 2008]. In
the EU, DINP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and childcare articles which can be place in the mouth by children. Such toys and
childcare articles containing DINP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 10/06/2020
REVISION SUMMARY: This SDS replaces the 09/11/2017 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 7 of 7
SP-205 PART A
SAFETY DATA SHEET
Date Issued : 06/19/2014
SDS No : SP-205 PART B
Date Revised : 10/06/2020
Revision No : 2
SP-205 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Skin Sensitization, Category 1
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazard Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Page 1 of 7
P337+P313: If eye irritation persists: Get medical advice/attention.
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 – 100Proprietary
6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine; 2-methyl-4,6-bis(methylthio) phenylene-1,3-diamine 7 – 13106264-79-3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 7 – 1368515-49-1
Diethylmethylbenzenediamine 0.5 – 1.568479-98-1
Titanium dioxide (TiO2) 0.1 – 113463-67-7
Carbon black < 0.11333-86-4
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 7
SP-205 PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppmmg/m
3
Polyether polyol mixture
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine; 2-methyl-4,6-bis(methylthio) phenylene-1,3-
diamine
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Diethylmethylbenzenediamine
OSHA PEL
TWA - -
STEL - -
ACGIH TLV
TWA - -
STEL - -
NIOSH REL
TWA - -
STEL - -
Titanium dioxide (TiO2)
OSHA PEL
TWA -
[1]
15
[1]
STEL - -
Page 3 of 7
SP-205 PART B
Titanium dioxide (TiO2) ACGIH TLV
TWA - 10
STEL - -
NIOSH REL
TWA - -
STEL - -
Carbon black
OSHA PEL
TWA - 3.5
STEL - -
ACGIH TLV
TWA - 3.5
STEL - -
NIOSH REL
TWA - 3.5
STEL - -
Footnotes:
1. Total dust
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical
Protective Clothing" published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Gray
pH: No data available
PERCENT VOLATILE: 0.01
FLASH POINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.052 (water=1) at 25 C (77 F)
VISCOSITY #1: 1000 Centipoise at 25 C (77 F)
(VOC): < 1.052 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
Page 4 of 7
SP-205 PART B
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
Polyether polyol mixture
No data
available
No data
available
No data available
6-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine; 2-methyl-4,6-bis(methylthio)
phenylene-1,3-diamine
1515 mg/kg
Rat
> 2000 mg/kg
Rabbit
No data available
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
> 10 g/kg Rat> 3.16 g/kg
Rabbit
> 0.13 mg/l Rat
Diethylmethylbenzenediamine
> 500 mg/kg
Rat
> 2000 mg/kg Rat No data available
Titanium dioxide (TiO2)
> 10000 mg/kg
Rat
No data
available
> 6.82 mg/l Rat (4
h)
Carbon black
> 8000 mg/kg
Rat
No data
available
No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
Titanium dioxide (TiO2) 2B
Carbon black 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid
release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
Page 5 of 7
SP-205 PART B
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No. 68479-98-1) which is subject to TSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer and birth defects or other reproductive harm. For more information, go to
www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 7 – 13 Developmental Toxicity
Titanium dioxide (TiO2) 0.1 – 1 Cancer
Carbon black < 0.1 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child's mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In
the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
Page 6 of 7
SP-205 PART B
REASON FOR ISSUE: Revision
Date Revised: 10/06/2020
REVISION SUMMARY: This SDS replaces the 09/11/2017 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 7 of 7
SP-205 PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 06/19/2014
SDS No: SP-205 PART A
Date Revised : 10/06/2020
ENTERPRISES Revision No :2
SP-205 PART A
a
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
Dee ee ene ee ee ee nen nn ee ee
2, HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
by | Sep 27, 2025
WB
ENTERPRIS 5
SAFETY DATA SHEET
SP.2O5 PART A
Date Issued : 0611912014
SDS No : SP-205 PART A
Date Revised : 1010612020
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PART A
GENERAL USE: Polyurethane resin
MANT]FACTURER
BJB Enterprises, Inc.
14791 FranklinAvenue
Tustin, CA92780
Emergency Phone: (714) 73+8r’50
24 HR. EMERGENCY TELEPHONE NI.]MBERS
CHEMTREC (USA & Canada): (800) 42,1-9300
or (703) 521-3887 CCN# 2820
2. HAZARDS IDENTIF’ICATION
GHS CT-ASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation , Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category I
Skin Sensitization, Category I
Cmcinogenici ty, Catngory 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS I-ABEL
Healthhazard Exclamation
mark
SIGNAL WORD: DANGER
TIAZARD STATEMENTS
H332: Harmful if inhaled.
H3 15: Causes skin irritation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms orbreathing difficulties if inhaled.
H3 l7: May cause an allergic skin reaction.
H35l : Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repealed exposure.
PRECAU TI ONARY STATEMET.{TS
Prevention:
P201 : Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood
P260: Do not breathe dust/fu melgas/mist/vapours/spray.
P27l: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
t
I
SP.2O5 PART A
P2l2: Contaminated work clothing should not be allowed out of the workplace.
P2 80 : Wear protectiv e gl oves /protective cl othi ng/eye protecti on/face protecti on.
Response:
P3M+P340: IF INHALED: Remove person to fiesh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P3A+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P33’7+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: S tore in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
WtVoChemical Name
40-704,4′-Diphenylmethane diisocyanate
10- 30B en zene, 1, l’-meth yl enebi s
[ 4-i so cyan ato -, h o mopol ymer
10- 30
1,2-B enzenedicarboxylic acid, di-C8 – I Gbranched alkyl esters, C9-rich
0.1 -l2,6-di -tert-bu tyl -p -cresol
CAS
101-68-8
25686-28-6
68515-48-0
128-31-0
4. FIRSTAIDMEAST]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attenti on.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Getmedical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
IIIIAI-ATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by rained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hows.
5. FIRE FIGHTING MEASI.]RES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQLIIPMENT: Firefighters should wear positive pressure self-contained brea*ring apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURBS : Evacuate unnecessary personnel from the spill area. Wear necess ary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Enswe adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to locaVnational regulations.
SP.2O5 PART A
ENTVIR OIM EN TAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTLS: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANIDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from fieezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80″F (1 8-27’C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)POSURE CONTROLS / PERSONAL PROTECTION
SP-205 PART A
EXPOSURE GUIDELINES
osHA HAZARDOUS COMPONENTS (29 CFRl910.1200)
EXPOSURE LIMITS
-dm’
0.2
0.05
0.Zltl
10
Footnotes:
1. l0-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing, Wem nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (MOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
Type ppmChemical Name
TWA
STEL
C 0.m
OSHA PEL
TWA 0.005
ACGIH TLV
STEL
TWA 0.005
STELNIOSH REL
c 0.02
trl
4,4′ -Diphenylmeth ane dii socyan ate
TWA
STEL
OSHA PEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
B en zene, 1, l’-meth yl enebi s [4-i so cyan alo -, homop olymer
TWA
OSHA PEL
STH,
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
1,2-B enzenedi carb oxyl ic acid, di -C8 – I Gbran ched allcyl e sters, C 9 -ri ch
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STFI
2,6-di -tert-butyl -p -cresol
SP.2O5 PART A
pROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines forthe Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIEIVC PRACTICES: Conraminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is imporlant. Follow all label precautions.
9. PITYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Yellow
pH: No data available
FLASHPOINT AND METHOD:201.2″C (4O5’F) Pensky-Martens CC
VAPORPRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLIIBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: l.l8 (water=1) at25″C (1’l”F)
USCOSITY #l: 325 Centipoise at 25″C (7 1″ n
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if *re miscibility of the
reaction partners is good or is supported by stining or by the presence of solvents. MDI is insoluble with, and heavier fhan water and sinks to the
bottom but reacts slowly at the interface. A solid water,insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, amines, acids, bases, and strong oxidizing agents.
r T. TOXICOLOGICAL INFORMATION
ACUTE TO)ilCITY
INHALATIONLCsO
2.24m{l Rat (1 h,
dust/mist)
0.49 mg/l Rat
No data available
SKIN CORROSION/IRRITATION: C auses ski n i rrit ation’
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
ORAL LDso DERMAL LDsO
Chemical Name
> 2000 mg/kg Rat > 9400 mg/kg
Rabbit
4,4-Diphenylmethane diisocyanate
> 5000 mg/kg RatNo data available
Benzene, l, 1′-methylenebis[4-isocyanato-, homopolymer
No data availableNo data available
1,2-B enzenedicarb oxylic acid, di -C8 – 1 0-branch ed alkyl esters, C9-
rich
> 2000 mg/kg Rat> 29ffi mg/kgRat2,6-di+ert-bu tyl -p-cresol
No data available
SP-205 PART A
IARC Status
3
3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause respiratory irritation.
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
4,4′ -Diphenylmethane dii socyanate
2,6-di -tert-bu tyl -p -cresol
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section I 5 for regulatory reporting information.
BIOACCUMUI-ATION/A CCUMLILATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
I.JNITED STATES
SARA TITLE III (ST]PERFUND AMEI{DMENTS AND REAUTHORIZATION ACT)
3llR72 HEALTH HAZARDS: Refer to Section 2 forhazard classification.
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 3I3 TION
Comments
Diisocyanate Compounds (Category Code Nl20)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name WLVo CAS
40-10101-68-84,4′-Diphenylmethane diisocyanate
Wt.VoChemical Name
40-704,4′ -Di phenyl methane dii socyan ate
CERCLA RQ
5,0001bs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGTILATORY: This product does not contain any substances subject toTSCA Section 12(b) export notification
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCT]PATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA)
SP-205 PART A
29 CFRr91O.T 19-.-PROCFSS SAFBTY MANAGEMENT OF HIGHI,Y HAZARDOUS CHBMICALS: NONC OI’thC ChCINiCAIS iN t]TiS
product are considered highly haz;rrdous by OSHA.
CALIF’OIfNIA PROPOSITION 65: A WARNING: This product cm expose yon to chemicals including Isee table belowl, wlrich is farel
known to tlte State of California to cause cancer. For nrorc infomration, go to www.P65Wa|llilrgs.ca.gov.
V,,/t.Vo
Chemical Name
r0- 30
1,2-B enzenedicarboxyl ic acid, di -C8 – I 0-brancl.red alkyl esters, C9-rich
Listed
o Carcer
OSHA HAZARD COMM. RULE: The contenls of the SDS comply with tlre OSHA Hazud Communication Standard 29 CFR 1910.1200′
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAIf INFORMATION SYSTEM): This product hm been classified according to the
hazard criteria of the CPR and the SDS contains all the infonnation required by the CPR.
DOMFSTIC SUBSTANCE LIST (INVENTORY): All components in this product ale listed in or exempted from the Domestic Substances
List (DSL) ol the Non-Domestic Sttbstances List (NDSL).
GENERAL COMMENTS:
DINP RESTRJCTIONS: This product contains diisononyl phthalate (DINP), CAS# 68515-48-0 EINECS# 271-090-9.In the U.S., there is an
interim prohibition on DINP above 0.1 percent by weight (one thousand par ts per rnillion) in toys intended fol children age 12 and under that can
be placed in a child’s rnouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvemnet Act of 2008]. In
the EU, DINP shall not be used as substance oras consti.tuents of preparations, at concentrations of greater than 0.1 percent by weight (one
thonsand parts per million) of the plasticized material, in toys and childcare articles which can be place in the mouth by children. Such toys and
childcare articles containing DINP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
200st84tECl.
16. OfiIER INFORMATION
REASON FOR ISSUE: Revision
Date Revised : 1 0/ 0612020
RtrVISION SUMMARY: This SDS replaces theA9l1112017 SDS.
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is fumished withotrt warl”nty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
xPERSONAL PROTECTION
HEALTH
F’I,AMMABILTlY
EA
E
BTB
ENTERPRISES
SAFETY DATA SHEET
SP-205 PART B
Date Issued : 06119/2014
SDS No: SP-205 PART B
Date Revised t 10106/2020
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SP-205 PARTB
GENERAL US E: P olyureth ane curative
MANT]FACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA92780
Emergency Phone: (1 14) 73+8450
24 HR. EMERGENCY TELEPHONE I{T]MBERS
CHEMTREC (USA & Canada): (800) 42,1-9300
or (703) 527-3881 CCN# 2820
2. IIAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation , Category 2
Eye kritation, Category 2A
Skin Sensitization, Category 1
Target Organ Toxicity @epeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS I-ABEL
Healthhazard Exclamation Environment
mark
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H3 15: Causes skin irritation.
H3 19: Causes serious eye initation.
H3 17: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.
H41l: Toxic to aquatic life with long lasting effects.
PRECAUTI ONARY STATEM ENITS
Prevention:
P260: Do not breathe dust/fu me/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin initation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P35 1+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
t
a
SP.2O5 PART B
P337+P313: If eye irritation persists: Get medical advice/attention.
P3 14: Get medical advice/anention if you feel unwell.
P39l : Collect spillage.
Disposal:
P50l: Dispose of contents/containerin arcordance with local/regional/national/international regulations
3. COMPOSITION / INFORMATION ON INGREDIEITS
Wt.9o
Chemical Name
60 – 100
Polyether polyol mixture
1-136-Methyl-2,4-bis(methylthio)phenylene-1,3-diamine;2-methyl-4,6-bis(methylthio) phenylene-1,3-diamine
7 -13
1,2-B enzenedicarboxylic acid, di-C9 – I 1 -branched alkyl esters, C I 0-rich
0.5 – 1.5
Diethyl methylbenzenedi amine
0.1 -1
Titanium dioxide (Ti02)
< 0.1Carbon black
CAS
Proprietary
106264-19-3
68515-49-l
68479-98-r
13463-61:7
1333-864
4. FIRSTAIDMEASI.]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contract lenses and continue flushing for at least 15 minutes '
Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INIIALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops'
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEAST]RES
EXTINGTIISHING MEDIA: Water spray, carbon dioxide, dry chemical, orfoam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consideruse of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPLL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean wittr a liquid decontaminant. Remove and propoly
dispose of residues. Notify applicable govemment authorities if release is reportable. (See CERCLA in Section 15).
ET{VIR ONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater'
GEIERAL PROCEDLIRES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIAIIDLING AIID STORAGE
SP-205 PART B
GEIERAL PROCEDURES: Avoid contact witlr eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid opencontainerexposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaVmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away liom excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from freezing. Containers should be tighfly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80"F (1 8-27'C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)OOSURE CONTROLS / PERSONAL PROTECTION
osHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
mdm3Type ppm
Chemical Name
TWA
sTEL
OSIIA PBL
TWA
sTEL
ACGtrI TLV
TWA
STEL
NIOSH REL
Polyether polyol mixture
TWA
STEL
OSHA PEL
TWA
ACGIII TLV
sTEL
TWA
IYIOSHREL
STEL
6-Methyl-2,4.bis(methylthio)phenylene-1,3-diamine; 2-mahyl-4,6-bis(methylthio) phenylene-1,3-
diamine
TWA
OSHA PEL
STEL
TWA
ACGIII TLV
STEL
TWA
IIOSHREL
STEL
7,Z-Beruendicarboxylic acid, di-C9-l l-branched alkyl esters, C 10-rich
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STFI
TWA
IIIOSH REL
STEL
Di ethyl methylbenzen edi amin e
_ tllTWA
OSHA PEL
STEL
15 trl
SP.2O5 PART B
STEL
TWA
NIOSH REL
STEL
TWA
OSHA PEL
STEL
TWA
ACGIH TLV
STEL
TWA
NIOSH REL
STEL
Carbon black
TWA r0
Titanium dioxide OiO2)
ACGIH TLV
3.5
3.5
3.5
tr'ootnotes:
1. Total dust
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONA L PROTECTIVE EQU IPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor carffidge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTM CLOTHING: Protecrive clothing should be selected and used in accordance with "Guidelines forthe Selection of Chemical
Protective Clothing" published by ACGIH.
WORK IfYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEIVIICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Gray
pH: No data available
PERCENT VOLATILE: 0.01
FLASH POINT AND METHOD: > 182.2’C (360’F) Pensky-Martens CC
VAPORPRESSURE: No data available
VAPORDF ISITY: No data available
BOILING POINT: No data available
SOLLIBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.052 (water=1) at25″C (77’D
VISCOSITY #1: 1000 Crntipoise at25″C (77’D
(VOC): < 1.052gll Calculated. Theoretical VOC minus water and exempt solvents'
10. STABILITY AND REACTIYITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions
SP-205 PART B
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, and sulfur oxides.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
1 1. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
INHALATION
LCm
No data available
No data available
> 0.13 mg/l Rat
No data available
> 6.82 mg/l Rat (4
h)
No data available
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye initation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
ORAL LDso DERMAL LD5OChemical Name
No data
available
No data
available
Polyether polyol mixture
> 2000 mg/kg
Rabbit
1515 mg/kg
Rat
6-Methyl-2,i-,bis(methylthio)phenylene-1,3-diamine; Z-methyl-4,6-bis(methylthio)
phenylene-1,3-diamine
> 3.16 glkg
Rabbit
> l0 g/kg Rat
1,2-B enzenedicarboxylic acid, di -C9- I I -branched alkyl esters, C I O-rich
> 500 mg/kg
Rat
> 2000 mg/kg Rat
Di eth yl mettr ylbenzen ed i ami n e
> 10000 mg/kg
Rat
No data
available
Titanium dioxide (Ii02)
> 8000 mg/kg
Rat
No data
available
Carbon black
IARC Status
28
29
REPRODUCTM TO)ilCITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs *rrough prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
Titanium dioxide Gi02)
Carbon black
12. ECOLOGICAL INFORMATION
EIYVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTO)ilCOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid
release to the environment.
B IOA CC LIMU I-A TION/A CCUMIJLATION: No d ata available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
SP-205 PART B
waste disposal contl’acior. Disposal ol’this product. solutions and any by-products should atall times comply with the lequirenrents ol’
nrnofT and contact with soil. waterways, dlains ancl sewel.s.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITEDSTATES
SARA TITLE III (SUPERFUND AMENDMBNTS AND REAUTHORJ ZATION A CT)
3lll3l2 HEALTH HAZARDS: Acute Hetrlth Hizard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporling requirements of Section 313 o1
Title III of the Superfund Amendn.rents and Reauthorization Act of 1986 ancl 40 CFR Pan 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,ANDLIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances rcgulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains Diethylmethylbenzenediamine (CAS No.68479-98-1) which is subject toTSCA 12(b)
export notification (40 CFR part 707, subpart D).
TSCA STATUS: This product ot’its components are listed in ol’exempt fiom the TSCA inventory rcquirements.
OCCT]PATIONA L SAFETY AND HEA LTH A DMINISTRATION (OSHA
)
29 CFR1910.1I9—PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: A WARNfNG: This product can expose you to chemicals including fsee table below], which is [are]
known to the State of California to cause cancer and birth defects or other reproductive harm. For more information, go to
ww w.P65 Warni ngs.ca.gov.
Chemical Name Wt.Vo
1 ,2-Benzenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C l0-rich ‘1 -13
Titanium dioxide (TiO2)
0.1 -1
Carbon black < 0.1
Listed
o Developmental Toxiciry
o Cancer
o Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Srandard 29 CFR 1910. 1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAIf INFORMATION SYSTEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIoNS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4.In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand par ts per million) in toys intended for childlen age l2 and under that can
be placed in a child's lnouth and child care articles for children age 3 and under IH.R. 4M0, The Consumer Safety Improvement Act of 2008]. In
the EU, DIDP shall not be used as substance or as constituents of prcparations, at concentrations of greater than 0.1 percent by weight (one
thousand pafis per million) of the plasticized material, in toys and child care articles which can be place in the rnouth by children. Such toys and
child care articles containing DIDP in concentrations g eater than the limit mentioned above shall not be placed on the market [Directive
2W5/84tECl.
16. OTHER INFORMATION
SP.2O5 PART B
REASON FOR ISSLIE: Revision
Date Revised t I 0l 06/2020
REVISION SUMMARY: This SDS replaces theC9111D017 SDS.
RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This infonnation is fumished without wananty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on dris sheet lelates only to the specific material designated herein. BJB Enterprises, lnc. assulrles
no legal responsibility for use or reliance upon this data.
PERSONAL PROTECTION
HEAL'fH
FLAMMAI}ILITY
by | Sep 27, 2025
SILPAK, Tin sarery pata sneer
Tr CHEMICAL AND COMPANY IDENTIFICATION 4, FIRST AID MEASURES
Product Identifier. SP 200-4 A, SP 400-6 A, SP100-8 A, INHALATION: Remove person to fresh air. if not breathing, give mouth to
SP 400-15 A mouth resuscitation. If breathing is difficult, give oxygen. Consult a
physician immediately.
Use: Component for Polyurethane Flexible Foam; SKIN CONTACT: Remove contaminated clothing. Wash contact area
Professionalindustial use with warm water and soap. Wash contaminated clothing before reuse.
EYE CONTACT: Immediately fush eyes with plenty of water for 18
Company: SILPAK, INC. minutes, hoKing eye lids open to be sure the material is washed out.
470 EAST BONITA AVE. POMONA, CA 91767 Consult a physician immediately.
Phone Number: 909-625-0056 INGESTION: Do not induce vomiting. No adverse anticipated by this
Emergency Phone: CHEMTREC 1-(800)-424-9300 route of exposure. Get medical attention.
Email silpak@aol.com HOST IMPORTANT SYMPTOMSIEFFECTS: May cause skin and eye
compresses eee peg irritation. Vapors or mists may cause respiratory irritation. May cause
2- HAZARDS IDENTIFICATION allergic respiratory reaction in sensitized persons, resulting in wheezing,
GHS HAZARD CLASSIFICATION: shortness of breath, and difficulty breathing.
Acule Toxicty Inhalation Category 4 INDICATION OF {MMEDIATE MEDICAL ATTENTIONISPECIAL
Skin ieitation Category 2 TREATMENT: Required for asthmatic symptoms or serious inhalation
Eye Irritation Category 2 exposures. Respiratory systems, including pulmonary edema, ray be
Respiratory Sensiizaton Category 1 delayed. Persons receiving significant exposure should be observed 24-
Specific Target Organ Toxicity Category 3 48 hours for signs of respiratory distress. Persons sensitized to
{Respiratory trritation) Diisocyanates should consult a physician before working with respiratory
ititants or sensitizers
SIGNAL WORD: WARNING! peer au RAPER RTIBE:
EXTINGUISHING MEDIA: Use water fog, foam, carbon dioxide or dry
chemical, Oo not use solid water stream. Solid stream of water into hot
Contains Diphenylmethane Diisocyanate (MOI, isocyanate) product may cause il stam generation oreupfon coton dt
|AZARDS: Water contamination will produce Car le.
HAZARD STATEMENTS: Do not re-seal contaminated containers as pressure buildup may rupture.
May be harmful if inhaled; May cause respiratory irritation; Causes mild SPECIAL PROTECTIVE EQUIPMENT & PRECAUTIONS FOR
skin irritation; Causes serious eye iritafon; May cause allergy or asthma FIREFIGHTERS: Wear approved positive pressure, self-contained
symptoms or breathing difficulties if inhaled; May cause an allergic skin breathing apparatus and full body protective clothing.
reaction; May cause damage to organs through prolonged or repeated & SENT i cECEASEE EAS
exposure. . ACCIDENTAL RELEASE MEASURE
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND
PRECAUTIONARY STATEMENTS: EMERGENCY PROCEDURES: Clear non-emergency personnel from the
Do not handle until all safety precautions have been read and understood; area. Ventilate area. Wear appropriate protective clothing to prevent eye
Avoid breathing fumesimist’vaporsispray; Wash thoroughly after handling; and skin contact and respiratory protection.
Wear protective gloves! protective clothing! eye protectioface protection; METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP:
In case of inadequate ventiation, wear respiratory protection; Take off Cover with an inert absorbent material and collect into an appropriate
contaminated clothing and wash before reuse. container for disposal. Do not seat the container since COzis generated
; on contact with moisture and dangerous pressure buildup can occur.
IF ON SKIN: Wash with ptenty of soap and water. Decontaminate floor area with a mixture of water plus isopropyl alcohol
IF INEYES: Rinse cautiously with water for several minules. Remove (25%), household ammonia (15%), and detergent (5%).
contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: If breathing is difficult, remove person to fresh air and keep 7/ HANDLING AND STORAGE
| at est n a positon comfrtable for beating. HANDLING: Avoid inhatation of vapors and spray mists. Use in well- H
. ner i lated areas. Avoid contact with skin and eyes. Wash thoroughly after
Store in a well ventilated place. Keep container tightly closed. ven c
Dispose of contents and container in aocordance with loca, regional and handing, Do not eat drink or smoke in the work area. Keep container
national regulations. STORAGE: Store indoors at temperatures between 65F and 75F (18C &
24C). Recommend storage in original, unopened containers. Protect
Individuals sensitized to isocyanates should discontinue use. Long-term tofomcoe Jeading to potentially dangerous pressure buildup in sealed
overexposure to isocyanates may cause lung damage. This is one part of /
a two-component system, Read and understand the hazard information EXPOSURE CONTROL PERSONAE PROTECTION
on part B before using, }, EXPOSURE CONTROL) FEROUNAL TRUIE aN
m “3 OCCUPATIONAL EXPOSURE LIMITS:
3: COMPOSITION TINFORMATION ON INGREDIENTS [revgenatae nase | wast | atom |
CHEMICAL. CASNO. | WGT.% (PEL – OSHA Permissible Exposure Limit, TLV ACGIH Threshold Limit
4A-Diphenylmethane Diisocyanate | 101-688 25.60 Value; TWA Time Weighted Average)
Modified MOL [NE | 30-50 VENTILATION: Use with adequate general or local exhaust ventiaion to
Ingredients not precisely identified are proprietary or not hazardous. maintain exposure levels below the occupation exposure limits.
NE-Non Existent.
|
: |
by | Sep 27, 2025
SILPAK, Tin sarery pata sneer
Tr CHEMICAL AND COMPANY IDENTIFICATION 4, FIRST AID MEASURES
Product Identifier. SP 200-4 A, SP 400-6 A, SP100-8 A, INHALATION: Remove person to fresh air. if not breathing, give mouth to
SP 400-15 A mouth resuscitation. If breathing is difficult, give oxygen. Consult a
physician immediately.
Use: Component for Polyurethane Flexible Foam; SKIN CONTACT: Remove contaminated clothing. Wash contact area
Professionalindustial use with warm water and soap. Wash contaminated clothing before reuse.
EYE CONTACT: Immediately fush eyes with plenty of water for 18
Company: SILPAK, INC. minutes, hoKing eye lids open to be sure the material is washed out.
470 EAST BONITA AVE. POMONA, CA 91767 Consult a physician immediately.
Phone Number: 909-625-0056 INGESTION: Do not induce vomiting. No adverse anticipated by this
Emergency Phone: CHEMTREC 1-(800)-424-9300 route of exposure. Get medical attention.
Email silpak@aol.com HOST IMPORTANT SYMPTOMSIEFFECTS: May cause skin and eye
compresses eee peg irritation. Vapors or mists may cause respiratory irritation. May cause
2- HAZARDS IDENTIFICATION allergic respiratory reaction in sensitized persons, resulting in wheezing,
GHS HAZARD CLASSIFICATION: shortness of breath, and difficulty breathing.
Acule Toxicty Inhalation Category 4 INDICATION OF {MMEDIATE MEDICAL ATTENTIONISPECIAL
Skin ieitation Category 2 TREATMENT: Required for asthmatic symptoms or serious inhalation
Eye Irritation Category 2 exposures. Respiratory systems, including pulmonary edema, ray be
Respiratory Sensiizaton Category 1 delayed. Persons receiving significant exposure should be observed 24-
Specific Target Organ Toxicity Category 3 48 hours for signs of respiratory distress. Persons sensitized to
{Respiratory trritation) Diisocyanates should consult a physician before working with respiratory
ititants or sensitizers
SIGNAL WORD: WARNING! peer au RAPER RTIBE:
EXTINGUISHING MEDIA: Use water fog, foam, carbon dioxide or dry
chemical, Oo not use solid water stream. Solid stream of water into hot
Contains Diphenylmethane Diisocyanate (MOI, isocyanate) product may cause il stam generation oreupfon coton dt
|AZARDS: Water contamination will produce Car le.
HAZARD STATEMENTS: Do not re-seal contaminated containers as pressure buildup may rupture.
May be harmful if inhaled; May cause respiratory irritation; Causes mild SPECIAL PROTECTIVE EQUIPMENT & PRECAUTIONS FOR
skin irritation; Causes serious eye iritafon; May cause allergy or asthma FIREFIGHTERS: Wear approved positive pressure, self-contained
symptoms or breathing difficulties if inhaled; May cause an allergic skin breathing apparatus and full body protective clothing.
reaction; May cause damage to organs through prolonged or repeated & SENT i cECEASEE EAS
exposure. . ACCIDENTAL RELEASE MEASURE
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND
PRECAUTIONARY STATEMENTS: EMERGENCY PROCEDURES: Clear non-emergency personnel from the
Do not handle until all safety precautions have been read and understood; area. Ventilate area. Wear appropriate protective clothing to prevent eye
Avoid breathing fumesimist’vaporsispray; Wash thoroughly after handling; and skin contact and respiratory protection.
Wear protective gloves! protective clothing! eye protectioface protection; METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP:
In case of inadequate ventiation, wear respiratory protection; Take off Cover with an inert absorbent material and collect into an appropriate
contaminated clothing and wash before reuse. container for disposal. Do not seat the container since COzis generated
; on contact with moisture and dangerous pressure buildup can occur.
IF ON SKIN: Wash with ptenty of soap and water. Decontaminate floor area with a mixture of water plus isopropyl alcohol
IF INEYES: Rinse cautiously with water for several minules. Remove (25%), household ammonia (15%), and detergent (5%).
contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: If breathing is difficult, remove person to fresh air and keep 7/ HANDLING AND STORAGE
| at est n a positon comfrtable for beating. HANDLING: Avoid inhatation of vapors and spray mists. Use in well- H
. ner i lated areas. Avoid contact with skin and eyes. Wash thoroughly after
Store in a well ventilated place. Keep container tightly closed. ven c
Dispose of contents and container in aocordance with loca, regional and handing, Do not eat drink or smoke in the work area. Keep container
national regulations. STORAGE: Store indoors at temperatures between 65F and 75F (18C &
24C). Recommend storage in original, unopened containers. Protect
Individuals sensitized to isocyanates should discontinue use. Long-term tofomcoe Jeading to potentially dangerous pressure buildup in sealed
overexposure to isocyanates may cause lung damage. This is one part of /
a two-component system, Read and understand the hazard information EXPOSURE CONTROL PERSONAE PROTECTION
on part B before using, }, EXPOSURE CONTROL) FEROUNAL TRUIE aN
m “3 OCCUPATIONAL EXPOSURE LIMITS:
3: COMPOSITION TINFORMATION ON INGREDIENTS [revgenatae nase | wast | atom |
CHEMICAL. CASNO. | WGT.% (PEL – OSHA Permissible Exposure Limit, TLV ACGIH Threshold Limit
4A-Diphenylmethane Diisocyanate | 101-688 25.60 Value; TWA Time Weighted Average)
Modified MOL [NE | 30-50 VENTILATION: Use with adequate general or local exhaust ventiaion to
Ingredients not precisely identified are proprietary or not hazardous. maintain exposure levels below the occupation exposure limits.
NE-Non Existent.
|
: |
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 04/18/2008
SDS No : SC-89 THINNER
Date Revised : 09/03/2021
Revision No : 3
SC-89 THINNER
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-89 THINNER
GENERAL USE: Paint thinner
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Oral), Category 4
Eye Irritation, Category 2A
Target Organ Toxicity (Single exposure), Category 3
Physical:
Flammable Liquids, Category 2
GHS LABEL
Flame Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H225: Highly flammable liquid and vapour.
H302: Harmful if swallowed.
H319: Causes serious eye irritation.
H336: May cause drowsiness or dizziness.
PRECAUTIONARY STATEMENTS
Prevention:
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233: Keep container tightly closed.
P240: Ground and bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/material-handling equipment.
P242: Use non-sparking tools.
P243: Take action to prevent static discharges.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
Page 1 of 8
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P370+P378: In case of fire: Use carbon dioxide, dry chemical, or alcohol-resistant foam for extinction.
P301+P312: IF SWALLOWED: Call a POISON CENTER/doctor/physician if you feel unwell.
P330: Rinse mouth.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER/doctor/physician if you feel unwell.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P235: Keep cool.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Isobutyl acetate 30 – 60110-19-0
Methyl propyl ketone 10 – 30107-87-9
Propan-2-ol 10 – 30 67-63-0
Methyl amyl ketone 7 – 13110-43-0
Methyl isobutyl ketone 1 – 5 108-10-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD: Flammable liquid and vapor.
EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, or alcohol-resistant foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Flammable liquid and vapor. Flashback along vapor trail may occur. This material may be ignited by heat, sparks,
flame, or static electricity. Closed containers may explode when exposed to extreme heat. Heating can release vapor which can be ignited.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
Page 2 of 8
SC-89 THINNER
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Keep away from sources of ignition. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation.
Avoid breathing vapor over open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition and
incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 8
SC-89 THINNER
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
Isobutyl acetate
OSHA PEL
TWA 150 700
STEL – –
ACGIH TLV
TWA 150 –
STEL – –
NIOSH REL TWA 150 700
Supplier OEL STEL – –
Methyl propyl ketone
OSHA PEL
TWA 200 700
STEL – –
ACGIH TLV
TWA 150 530
STEL – –
NIOSH REL TWA 150 530
Supplier OEL STEL – –
Propan-2-ol
OSHA PEL
TWA 400 980
STEL – –
ACGIH TLV
TWA 200 –
STEL 400 –
NIOSH REL
TWA 400 980
STEL 500 1225
Methyl amyl ketone
OSHA PEL
TWA 100 465
STEL – –
ACGIH TLV
TWA 50 –
STEL – –
NIOSH REL
TWA 100 465
STEL – –
Methyl isobutyl ketone
OSHA PEL
TWA 100 410
STEL – –
ACGIH TLV
TWA 20 –
STEL 75 –
NIOSH REL
TWA 50 205
STEL 75 300
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
Page 4 of 8
SC-89 THINNER
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Ketone
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 100
FLASH POINT AND METHOD: 7 C (44.6 F) Closed Cup
VAPOR PRESSURE: No data available
VAPOR DENSITY: Heavier than air
BOILING POINT: No data available
SOLUBILITY IN WATER: Partially soluble
SPECIFIC GRAVITY: 0.826 (water=1) at 25 C (77 F)
VISCOSITY: No data available
(VOC): 826 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under the recommended storage conditions.
CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: May form peroxides of unknown stability.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing, strong acids, strong bases, acid anhydrides, aluminum, and halogenated compounds.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
Isobutyl acetate 13413 mg/kg Rat > 17400 mg/kg Rabbit No data available
Methyl propyl ketone 1600 mg/kg Rat > 20 ml/kg Guinea Pig 25.5 mg/l Rat (4 h)
Propan-2-ol 5045 mg/kg Rat 12800 mg/kg Rabbit 37.5 mg/l Rat (4 h)
Methyl amyl ketone 1600 mg/kg Rat > 2000 mg/kg Rat > 16.7 mg/l Rat (4 h, vapor)
Methyl isobutyl ketone 2080 mg/kg Rat > 10 ml/kg Rabbit 2000 to 4000 ppm Rat (4 h)
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
Page 5 of 8
SC-89 THINNER
CARCINOGENICITY
Chemical Name IARC Status
Propan-2-ol 3
Methyl isobutyl ketone 2B
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: May cause drowsiness or dizziness.
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
EMPTY CONTAINER: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper
instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. T HEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Flammable liquids, n.o.s.
TECHNICAL NAME: (ester, ketone, alcohol blend)
PRIMARY HAZARD CLASS/DIVISION: 3
UN/NA NUMBER: UN1993
PACKING GROUP: II
NAERG: 128
LABEL: Flammable liquid
AIR (ICAO/IATA)
SHIPPING NAME: Flammable liquid, n.o.s.
TECHNICAL NAME: (ester, ketone, alcohol blend)
UN/NA NUMBER: UN1993
PRIMARY HAZARD CLASS/DIVISION: 3
PACKING GROUP: II
ERG: 3H
LABEL: Flammable liquid
VESSEL (IMO/IMDG)
SHIPPING NAME: Flammable liquid, n.o.s.
Page 6 of 8
SC-89 THINNER
TECHNICAL NAME: (ester, ketone, alcohol blend)
UN/NA NUMBER: UN1993
PRIMARY HAZARD CLASS/DIVISION: 3
PACKING GROUP: II
LABEL: Flammable liquid
SPECIAL PROVISIONS: EmS: F-E, S-E
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard, Fire Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS
Propan-2-ol 10 – 3067-63-0
Methyl isobutyl ketone 1 – 5108-10-1
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
Isobutyl acetate 30 – 60 5,000
Methyl isobutyl ketone 1 – 5 5,000
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
Methyl isobutyl ketone 1 – 5 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 09/03/2021
REVISION SUMMARY: This SDS replaces the 07/18/2018 SDS.
Page 7 of 8
SC-89 THINNER
HMIS RATING
HEALTH * 2
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
3
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 8 of 8
SC-89 THINNER
by | Sep 27, 2025
SAFETY DATA SHEET
Date Prepared : 1/20/2015
SDS No : SC-24
SC-24
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-24
GENERAL USE: Polyurethane catalyst
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
Not Applicable
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Pale yellow liquid with mild odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: Low oral toxicity.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 6068515-49-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
Page 1 of 5
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, or water fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and metal oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
SENSITIVE TO STATIC DISCHARGE: This material can accumulate static charges which can cause an incendiary electrical discharge.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel. People dealing
with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers
or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use
combustible materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic
bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and
clothing. Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat in the original or similar container. Avoid sources of ignition
and incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 12 months from date of shipment under manufacturers recommended storage conditions.
ELECTROSTATIC ACCUMULATION HAZARD: This material can accumulate static charges which can cause an incendiary electrical
discharge. Use proper bonding and/or grounding procedure.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
SC-24
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: 27
FLASH POINT AND METHOD: > 110 C (230 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Negligible
SPECIFIC GRAVITY: 1.037 (water=1) at 25 C (77 F)
VISCOSITY #1: 215 Centipoise at 25 C (77 F)
(VOC): < 280.000 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: Heat, flames, and ignition sources.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and metal oxides.
Page 3 of 5
SC-24
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
EMPTY CONTAINER: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without
proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. T HEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
COMMENTS: Not dangerous according to transport regulations.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
Page 4 of 5
SC-24
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 60Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
Date Prepared: 1/20/2015
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
SC-24
by | Sep 27, 2025
INDEX
25SC22
25SC22-D
25SC22-F
25SC22-Q
SAFETY DATA SHEET
Date Issued : 5/15/2014
MSDS No : SC-22
SC-22
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-22
GENERAL USE: Plasticizer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Colorless liquid with mild odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: Low oral toxicity.
INHALATION: May result in respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 10068515-49-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
Page 1 of 5
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, or water fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
SENSITIVE TO STATIC DISCHARGE: This material can accumulate static charges which can cause an incendiary electrical discharge.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel. People dealing
with a major spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers
or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use
combustible materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic
bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of
residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and
clothing. Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from excessive heat, in
original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination
with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
ELECTROSTATIC ACCUMULATION HAZARD: This material can accumulate static charges which can cause an incendiary electrical
discharge. Use proper bonding and/or grounding procedure.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
Page 2 of 5
SC-22
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild
COLOR: Colorless
pH: Not Applicable
FLASHPOINT AND METHOD: 225 C (437 F) ASTM D93
VAPOR PRESSURE: < 0.08 mmHg at 20 C (68 F)
VAPOR DENSITY: > 1 (Air=1)
BOILING POINT: > 250 C (482 F)
FREEZING POINT: -50 C (-58 F)
SOLUBILITY IN WATER: Negligible
EVAPORATION RATE: < 0.01 (n-Butyl Acetate=1)
DENSITY: 8.06 at 20 C (68 F)
SPECIFIC GRAVITY: 0.97 (water=1) at 20 C (68 F)
VISCOSITY: 130 Centistokes at 20 C (68 F)
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: Heat, flames, and ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Page 3 of 5
SC-22
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
EMPTY CONTAINER: Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without
proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. T HEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Page 4 of 5
SC-22
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 100Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
0 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
SC-22
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 05/15/2014
SDS No : SC-22
Date Revised : 09/08/2020
Revision No : 2
SC-22
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SC-22
GENERAL USE: Plasticizer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
This product does not meet the criteria for classification.
GHS LABEL
Not Applicable
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 10068515-49-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, carbon dioxide, dry chemical, or water fog.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
Page 1 of 5
SPILL AND LEAK PROCEDURES: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major
spill should wear full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways.
Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use in a well ventilated area. Avoid heat, sparks, and open flames. Avoid breathing vapor and contact with eyes, skin, and clothing.
Use appropriate personal protective equipment as specified in Section 8. Handle and use in a manner consistent with good
industrial/manufacturing techniques and practices.
STORAGE: Keep away from heat, sparks, open flames, or other sources of ignition. Store in a cool, dry place, away from excessive heat, in
original or similar container. Avoid unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination
with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
OSHA PEL
TWA – –
STEL – –
ACGIH TLV
TWA – –
STEL – –
NIOSH REL
TWA – –
STEL – –
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Page 2 of 5
SC-22
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Mild
COLOR: Colorless
pH: No data available
FLASH POINT AND METHOD: 223.9 C (435 F) Pensky-Martens CC
VAPOR PRESSURE: < 0.08 mmHg at 20 C (68 F)
VAPOR DENSITY: > 1 (Air=1)
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Negligible
EVAPORATION RATE: < 0.01 (n-BuAc=1)
SPECIFIC GRAVITY: 0.97 (water=1) at 20 C (68 F)
VISCOSITY #1: 130 Centistokes at 20 C (68 F)
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: Heat, flames, and ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50 DERMAL LD50 INHALATION LC 50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich> 10 g/kg Rat> 3.16 g/kg Rabbit> 0.13 mg/l Rat
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
NOTES: This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: No data available
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
Page 3 of 5
SC-22
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: None Known
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 60 – 100Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In
Page 4 of 5
SC-22
the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 09/08/2020
REVISION SUMMARY: This SDS replaces the 08/15/2017 SDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 5 of 5
SC-22
