by | Sep 27, 2025
Safety Data Sheet
HP 8100 SERIES A SIDE
Safety Data Sheet dated: 3/9/2023 – version 3
Date of first edition: 1/16/2023
1. IDENTIFICATION
Product identifier
Mixture identification:
Trade name:HP 8100 SERIES A SIDE
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use:N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company:ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable:N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Label elements
Acute toxicity (inhalation), Category 2 Fatal if inhaled.
Skin irritation, Category 2 Causes skin irritation.
Eye irritation, Category 2A Causes serious eye irritation.
Respiratory Sensitization, Category 1 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
Skin Sensitization, Category 1 May cause an allergic skin reaction.
Carcinogenicity, Category 2 Suspected of causing cancer.
Specific target organ toxicity following single exposure,
Category 3
May cause respiratory irritation.
Specific target organ toxicity following repeated exposure,
Category 2
May cause damage to organs through prolonged or repeated
exposure.
Hazard pictograms and Signal Word
Danger
Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
Page n. of1 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Hazards not otherwise classified identified during the classification process:
None
Additional classification information
HMIS Health:3 = SERIOUS
HMIS Flammability:0 = Not Combustible
HMIS Reactivity:0 = MINIMAL
HMIS P.P.E.:Safety glasses, gloves
NFPA Health:3 = SERIOUS
NFPA Flammability:0 = Not Combustible
NFPA Reactivity:0 = MINIMAL
NFPA Special Risk:NONE
H373 May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash … Thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing must not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 [In case of inadequate ventilation] wear respiratory protection.
P302+P352 IF ON SKIN: Wash with plenty of water/
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER/doctor/
P312 Call a POISON CENTER/doctor/ if you feel unwell.
P314 Get medical advice/attention if you feel unwell.
P320 Specific treatment is urgent (see … On this label).
P321 Specific treatment (see … On this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to …
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
N.A.
Mixtures
Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:
List of components
Qty Name Ident. Numb. Classification Registration Number
Page n. of2 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Qty Name Ident. Numb. Classification Registration Number
60-80 % DIPHENYLMETHANEDIISOCYANATE CAS:9016-87-9 Skin Irrit. 2, H315; Eye Irrit. 2A,
H319; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334;
Acute Tox. 2, H330
30-70 % 4,4′-METHYLENEDIPHENYL
DIISOCYANATE
CAS:101-68-8 Acute Tox. 4, H332; Skin Irrit. 2,
H315; Eye Irrit. 2A, H319; Carc. 2,
H351; STOT SE 3, H335; STOT RE
2, H373; Resp. Sens. 1, H334;
Skin Sens. 1, H317
4. FIRST AID MEASURES
Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Remove contaminated clothing immediatley and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
In case of Inhalation:
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
See protective measures under point 7 and 8.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
Page n. of3 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Wash with plenty of water.
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Exercise the greatest care when handling or opening the container.
Do not use on extensive surface areas in premises where there are occupants.
Use localized ventilation system.
Don’t use empty container before they have been cleaned.
Before making transfer operations, assure that there aren’t any incompatible material residuals in the containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Storage temperature:N.A.
Always keep in a well ventilated place.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Cool and adequately ventilated.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Appropriate engineering controls:N.A.
Individual protection measures
Eye protection:
Use close fitting safety goggles, don’t use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Use adequate protective respiratory equipment.
No data available
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical StateN.A.
Appearance and colour:N.A.
Odour:N.A.
Odour threshold:N.A.
pH:N.A.
Melting point / freezing point:N.A.
Initial boiling point and boiling range:N.A.
Flash point:N.A.
Evaporation rate:N.A.
Upper/lower flammability or explosive limits:N.A.
Vapour density:N.A.
Vapour pressure:N.A.
Relative density:N.A.
Solubility in water:N.A.
Solubility in oil:N.A.
Partition coefficient (n-octanol/water):N.A.
Auto-ignition temperature:N.A.
Decomposition temperature: N.A.
Viscosity:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Solid/gas flammability:N.A.
Other information
Substance Groups relevant propertiesN.A.
Page n. of4 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Substance Groups relevant propertiesN.A.
Miscibility:N.A.
Fat Solubility:N.A.
Conductivity:N.A.
10. STABILITY AND REACTIVITY
Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
None.
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Toxicological Information of the Preparation
a) acute toxicity The product is classified: Acute toxicity (inhalation), Category 2(H330)
b) skin corrosion/irritation The product is classified: Skin irritation, Category 2(H315)
c) serious eye damage/irritation The product is classified: Eye irritation, Category 2A(H319)
d) respiratory or skin sensitisationThe product is classified: Respiratory Sensitization, Category 1(H334), Skin
Sensitization, Category 1(H317)
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity The product is classified: Carcinogenicity, Category 2(H351)
g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure The product is classified: Specific target organ toxicity following single exposure,
Category 3(H335)
i) STOT-repeated exposure The product is classified: Specific target organ toxicity following repeated exposure,
Category 2(H373)
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Substance(s) listed on the IARC Monographs:
None
Substance(s) listed as OSHA Carcinogen(s):
None
Substance(s) listed as NIOSH Carcinogen(s):
None
Substance(s) listed on the NTP report on Carcinogens:
None
12. ECOLOGICAL INFORMATION
Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Persistence and degradability
List of Eco-Toxicological properties of the product
Not classified for environmental hazards.
No data available for the product
Page n. of5 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Bioaccumulative potential
Mobility in soil
Other adverse effects
N.A.
N.A.
N.A.
N.A.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply with the local and
national regulations currently in force.
14. TRANSPORT INFORMATION
UN number
ADR-UN number: 3082
DOT-UN Number: UN3082
IATA-Un number: 3082
IMDG-Un number: 3082
UN proper shipping name
ADR-Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
DOT Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s.
IATA-Technical name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
IMDG-Technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport hazard class(es)
ADR-Class:9
DOT Hazard Class:9
IATA-Class:9
IMDG-Class:9
Packing group
ADR-Packing Group: III
DOT Packing Group:III
IATA-Packing group:III
IMDG-Packing group: III
Environmental hazards
Marine pollutant:No
Environmental Pollutant:N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
Special precautions
Department of Transportation (DOT):
DOT-Special Provision(s):8, 146, 173, 335, IB3, T4, TP1, TP29
DOT Label(s):9
DOT Symbol:N/A
DOT Cargo Aircraft:No limit
DOT Passenger Aircraft:No limit
DOT Bulk:241
DOT Non-Bulk:203
Road and Rail (ADR-RID):
ADR-Label:9
ADR – Hazard identification number:90
ADR-Transport category (Tunnel restriction code):3 (-)
Air (IATA):
IATA-Passenger Aircraft:964
IATA-Cargo Aircraft:964
IATA-Label:9
IATA-Subrisk:-
IATA-Erg:9L
Page n. of6 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
IATA-Erg:9L
IATA-Special Provisions:A97 A158 A197 A215
Sea (IMDG):
IMDG-Stowage Code: Category A
IMDG-Stowage Note: –
IMDG-Subrisk:-
IMDG-Special Provisions:274 335 969
IMDG-EMS: F-A, S-F
15. REGULATORY INFORMATION
USA – Federal regulations
TSCA – Toxic Substances Control Act
SARA – Superfund Amendments and Reauthorization Act
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
CAA – Clean Air Act
CWA – Clean Water Act
USA – State specific regulations
California Proposition 65
Massachusetts Right to know
Pennsylvania Right to know
New Jersey Right to know
TSCA inventory:
No substances listed
TSCA listed substances:
No substances listed
Section 302 – Extremely Hazardous Substances:
No substances listed
Section 304 – Hazardous substances:
No substances listed
Section 313 – Toxic chemical list:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under CERCLA:
No substances listed
CAA listed substances:
No substances listed
CWA listed substances:
No substances listed
Substance(s) listed under California Proposition 65:
No substances listed
Substance(s) listed under Massachusetts Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under Pennsylvania Right to know:
4,4′-METHYLENEDIPHENYL DIISOCYANATE
Substance(s) listed under New Jersey Right to know:
No substances listed
16. OTHER INFORMATION
Page n. of7 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
Safety Data Sheet dated: 3/9/2023 – version 3
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality. The information relates only to the specific material and may not be valid for such material
used in combination with any other material or in any process.
This document was prepared by a competent person who has received appropriate training.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID:Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG:International Maritime Code for Dangerous Goods.
IATA:International Air Transport Association.
IATA-DGR:Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO:International Civil Aviation Organization.
ICAO-TI:Technical Instructions by the “International Civil Aviation Organization” (ICAO).
GHS:Globally Harmonized System of Classification and Labeling of Chemicals.
CLP:Classification, Labeling, Packaging.
EINECS:European Inventory of Existing Commercial Chemical Substances.
INCI:International Nomenclature of Cosmetic Ingredients.
CAS:Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO:Ordinance on Hazardous Substances, Germany.
LC50:Lethal concentration, for 50 percent of test population.
LD50:Lethal dose, for 50 percent of test population.
DNEL:Derived No Effect Level.
PNEC:Predicted No Effect Concentration.
TLV:Threshold Limiting Value.
TWATLV:Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL:Short Term Exposure limit.
STOT:Specific Target Organ Toxicity.
WGK:German Water Hazard Class.
KSt:Explosion coefficient.
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided without any
warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety preventive measures for the users
who have got professional training. The personal user who obtained this SDS should make independent judgment for the
applicability of this SDS under special conditions. In these special cases, we do not assume responsibility for the damage.
Paragraphs modified from the previous revision:
– 3. COMPOSITION/INFORMATION ON INGREDIENTS
Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
Code Hazard class and hazard category Description
A.1/2/Inhal Acute Tox. 2 Acute toxicity (inhalation), Category 2
A.1/4/Inhal Acute Tox. 4 Acute toxicity (inhalation), Category 4
A.2/2 Skin Irrit. 2 Skin irritation, Category 2
A.3/2A Eye Irrit. 2A Eye irritation, Category 2A
A.4.1/1 Resp. Sens. 1 Respiratory Sensitization, Category 1
A.4.2/1 Skin Sens. 1 Skin Sensitization, Category 1
A.6/2 Carc. 2 Carcinogenicity, Category 2
A.8/3 STOT SE 3 Specific target organ toxicity following single exposure, Category 3
A.9/2 STOT RE 2 Specific target organ toxicity following repeated exposure, Category 2
Page n. of8 83/9/2023 Production Name HP 8100 SERIES A SIDEDate
by | Sep 27, 2025
Page 1 of 6
SAFETY DATA SHEET
Date issued : 04/08/2016
SDS number : FP-90 REV 1 PART A
Date revised : 04/08/2022
ENTERPRISES Revision number : 2
FP-90 REV 1 PART A
1. Identification
Product identifier: FP-90 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
H332: Harmful if inhaled.
H315: Causes skin irritation.
319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 04/08/2016
SDS number : FP-90 REV 1 PART A
Date revised : 04/08/2022
Revision number : 2
FP-90 REV 1 PART A
1. Identification
Product identifier: FP-90 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
Page 1 of 6
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1′-methylenebis[4-isocyanatobenzene]40 – 709048-57-1
4,4′-Diphenylmethane diisocyanate 15 – 40101-68-8
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 10 – 3025686-28-6
2,4′-Diphenylmethane diisocyanate 0.1 – 15873-54-1
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Get immediate medical attention.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Page 2 of 6
FP-90 REV 1 PART A
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 6 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Liquid
Color: Pale yellow
Odor: Slightly musty
Page 3 of 6
FP-90 REV 1 PART A
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 110 C (230 F) Closed Cup
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.12 (water=1) at 25 C (77 F)
Solubility: Reacts with water
Dynamic viscosity: 1350 Centipoise at 25 C (77 F)
VOC content: Nil
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures, moisture, and freezing conditions.
Possibility of hazardous reactions: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing active hydrogen
groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the reaction partners is
good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the bottom but reacts
slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
Incompatible materials: Water, alcohols, amines, bases, and acids.
11. Toxicological information
Acute toxicity
Chemical name
LD50 (oral)
mg/kg(rat)
LD50 (dermal)
mg/kg(rabbit)
LC50 (inhalation)
mg/l
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-,
polymer with 1,1′-methylenebis[4-isocyanatobenzene]
No data
available
No data available No data available
4,4′-Diphenylmethane diisocyanate
> 2000 mg/kg Rat> 9400 mg/kg Rabbit 2.24 mg/l Rat (1 h,
dust/mist)
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer > 5000 mg/kg Rat No data available 0.49 mg/l Rat
2,4′-Diphenylmethane diisocyanate
No data
available
> 9400 mg/kg Rabbit 0.49 mg/l Rat (4 h)
Skin corrosion / irritation: Causes skin irritation.
Serious eye damage / irritation: Causes serious eye irritation.
Respiratory or skin sensitization: May cause sensitization by inhalation and skin contact.
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name IARC
4,4′-Diphenylmethane diisocyanate 3
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: May cause respiratory irritation.
Specific Target Organ Toxicity – repeated exposure: May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard: No data available
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
Page 4 of 6
FP-90 REV 1 PART A
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Other adverse effects: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA Section 313 Toxic Chemicals
Chemical name % w/wCAS No. Comments
4,4′-Diphenylmethane diisocyanate 15 – 40101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical name % w/w CERCLA rq
4,4′-Diphenylmethane diisocyanate 15 – 40 5,000 lbs.
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: This product does not contain any chemicals which are known to the State of California to cause cancer, birth
defects or other reproductive harm.
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
Page 5 of 6
FP-90 REV 1 PART A
16. Other information
Reason for issue: Revision
Date revised: 04/08/2022
Revision summary: This SDS replaces the 04/08/2019 SDS.
HMIS rating
Health * 2
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
2 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 6 of 6
FP-90 REV 1 PART A
by | Sep 27, 2025
e
Pile SHORE A POLYURETHANES
ri 3) Dedicated to QUALITY, SERVICE, SAFETY, and INNOVATION
ENTERPRISES
An ISO-9001 Certified company
FP-90 REV 1 A/B JS
90 SHORE A POLYURETHANE ELASTOMER
RoHS
BIB s FP (Fast Production) Series of products range from a 15 to 90 Shore A. You’ll find their 4 to 5 minute work time can easily be
demolded, tack free and tough in under an hour. The 1:2 ratio and low viscosity makes these translucent materials easy to mix, pour
and pigment. FP-90 REV 1 is ideal for hand casting or dispensed with our CPE equipment.
* RoHS/REACH Compliant Demold in under an hour Translucent and easy to pigment
4.5 minute work time Low viscosity and easy to mix arti ideal for dispense
PHYSICAL PROPERTIES ELEVATED TEMPERATURE CURE*
Hardness, Shore A 9025
Density (g/cc) 1.097
Cubic Inches per Pound 26.03
Color/Appearance Clear Amber
Tensile Strength (psi) 2,250
Tensile Modulus (psi) 4,000
Elongation (%) 430
Tear Strength i 240
Shrinkage (in/in) linear 0.0046″
Dielectric Constant, 1 MHz 4.704
Dissipation Factor, 1 MHz 0.0435
*Note: Reported physical properties are based on test specimens cured 2 hours at room temperature then 16 hours at 160 F (71 C).
*Shrink test specimens are cured for 24 hours at room temperature and then 16 hours at 160 F (71 C).
HANDLING PROPERTIES eectuce Pato Part B
Mix Ratio by weight 100
Mix Ratio by volume ae es 100
Specific Gravity @ 77 F (25 C) 1.039
Color Amber
Viscosity (cps) @ 77 F (25 C) Brookfield 870
Mixed Viscosity (cps) @ 77 F (25 C) Brookfield 1,500
Work Time, 100g mass @ 77 F (25 C) 4-4.5 minutes
Gel Time 5-5.5 minutes
Demold Time @ 77 F (25 C) 60 90 minutes
Properties above are typical and not for specifications.
FP-90 A/B REV | Page | of 2 Date: 07/15/2022
For more information call BJB Enterprises, Inc. (714) 734-8450 Fax (714) 734-8929
www.bjbenterprises.com
by | Sep 27, 2025
SAFETY DATA SHEET
ww
9,0, @ Date issued : 03/08/2016:
Os. SDS number ; FP-60 REV | PART A
6 Date revised : 03/11/2022
ENTERPRISES Revision number : 2
FP-60 REV 1 PART A
} 1, Identification : 2 razr th FERS aS Fe EG AE
Product identifier: FP-60 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA92780
Emergency Phone: (714) 734-8450
2. Hazard identification : * i {
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A.
Respiratory Sensitization, Category 1
Skin Sensitization, Category |
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
1332: Harmful if inhaled.
315: Causes skin irritation.
H319: Causes serious eye irritation.
334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
335: May cause respiratory irritation.
11373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
by | Sep 27, 2025
SAFETY DATA SHEET
@
e,.,@ Date issued : 05/13/2016
@’. oe SDS number : FP-80 REV | PART A
Date revised : 08/15/2022
ENTERPRISES Revision number : 2
FP-80 REV 1 PART A
| 1. Identification a peak i ob EET :
Product identifier; FP-80 REV 1 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc, CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification : ; ;
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2 .
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
Label elements
Health hazard Exclamation
mark
Signal word: DANGER
Hazard statement(s)
1332: Harmful if inhaled.
H315: Causes skin irritation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
335: May cause respiratory irritation.
373: May cause damage to organs through prolonged or repeated exposure.
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
by | Sep 27, 2025
SAFETY DATA SHEET
Date Prepared : 3/13/2015
SDS No : FP-40 PART A
FP-40 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: FP-40 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazardExclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer .
H335: May cause respiratory irritation.
H373: May cause damage to organs through prolonged or repeated exposure .
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
Page 1 of 7
P285: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE: Pale yellow liquid with a slight musty odor.
IMMEDIATE CONCERNS: Harmful by inhalation. Use in well ventilated areas. Irritating to eyes, skin, and respiratory system. May cause
sensitization by inhalation and skin contact. This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of
vapour or aerosol at levels above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even
minimal concentrations of diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for
several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: Harmful if inhaled. Inhalation at levels above the occupational exposure limit could cause respiratory sensitization and risk
of serious damage to the respiratory system.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGAN STATEMENT: Contains material which causes damage to the following organs: upper respiratory tract.
SENSITIZATION: May cause allergic skin and respiratory reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 6068515-49-1
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1′-methylenebis[4-
isocyanatobenzene]
15 – 409048-57-1
4,4′-Diphenylmethane diisocyanate 10 – 30101-68-8
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 5 – 1025686-28-6
4. FIRST AID MEASURES
Page 2 of 7
FP-40 PART A
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons and HCN.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
FP-40 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl
esters, C10-rich
TWA NE NE NE NE NE 5
STEL NE NE NE NE NE NE
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-
hydroxy-, polymer with 1,1′-methylenebis[4-
isocyanatobenzene]
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
4,4′-Diphenylmethane diisocyanate
TWA 0.02 0.2 0.005 0.05 0.005
[1]
0.05
[1]
STEL NE NE NE NE NE NE
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Footnotes:
1. NIOSH REL
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slightly musty
COLOR: Pale yellow
pH: Not Applicable
PERCENT VOLATILE: 0.02
FLASH POINT AND METHOD: > 160 C (320 F) Pensky-Martens CC
AUTOIGNITION TEMPERATURE: > 600 C (1112 F)
VAPOR PRESSURE: Not Established
VAPOR DENSITY: 8.5
BOILING POINT: > 300 C (572 F) Decomposes
SOLUBILITY IN WATER: Reacts with water
Page 4 of 7
FP-40 PART A
SPECIFIC GRAVITY: 1.058 (water=1) at 25 C (77 F)
VISCOSITY #1: 420 Centipoise at 25 C (77 F)
(VOC): < 0.220 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water (moisture) produces CO2-gas. Exothermic reaction with materials
containing active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the
miscibility of the reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than
water and sinks to the bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by
liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbon and HCN.
INCOMPATIBLE MATERIALS: Water, alcohols, amines, bases, and acids.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich > 10 g/kg > 3.16 g/kg > 0.13 mg/l
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer
with 1,1′-methylenebis[4-isocyanatobenzene]
Not Established Not Established Not Established
4,4′-Diphenylmethane diisocyanate > 10000 mg/kg > 9400 mg/kg 0.49 mg/l (4 h)
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer Not Established Not Established Not Established
CHRONIC: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when subsequently
exposed to very low levels.
CARCINOGENICITY
Chemical Name
IARC
Status
4,4′-Diphenylmethane diisocyanate 3
IARC: This product contains substances that are not classifiable as carcinogens to humans.
IRRITATION: Causes eye, skin, and respiratory irritation.
SENSITIZATION: May cause sensitization by inhalation and skin contact.
TARGET ORGANS: Contains material which causes damage to the following organs: upper respiratory tract.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
Page 5 of 7
FP-40 PART A
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
COMMENTS: Not dangerous according to transport regulations.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 10 – 30101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
4,4′-Diphenylmethane diisocyanate 10 – 305,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 30 – 60Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Page 6 of 7
FP-40 PART A
D1A – Very
Toxic
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D1A: Poisonous and infectious material (Very toxic).
Class D2A: Poisonous and infectious material (Very toxic).
Class D2B: Poisonous and infectious material (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D1A – Acute lethality
D2A – Respiratory tract sensitization
D2B – Eye irritation
D2B – Skin irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: The D1A classification applies for this material in aerosol or mist form.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that
can be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of
2008]. In the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by
weight (one thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children.
Such toys and child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market
[Directive 2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
Date Prepared: 3/13/2015
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
2 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 7 of 7
FP-40 PART A
SAFETY DATA SHEET
Date Prepared : 3/13/2015
SDS No : FP-40 PART B
FP-40 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: FP-40 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Sensitization, Category 1
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Exclamation
mark
Environment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENTS
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
Response:
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
Page 1 of 6
PHYSICAL APPEARANCE: Amber liquid with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. May cause
sensitization by skin contact. Use in well ventilated areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation. May cause an allergic skin reaction.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing skin conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
SENSITIZATION: May cause allergic skin reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 – 100Proprietary
Di-(methylthio)toluenediamine 3 – 7106264-79-3
Hydroxy terminated poly(oxyalkylated) polyol 1 – 5 102-60-3
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, silicon dioxide, and
formaldehyde.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
Page 2 of 6
FP-40 PART B
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV Supplier OEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Di-(methylthio)toluenediamine
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Hydroxy terminated poly(oxyalkylated) polyol
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Page 3 of 6
FP-40 PART B
PHYSICAL STATE: Liquid
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.1
FLASH POINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.026 (water=1) at 25 C (77 F)
VISCOSITY #1: 920 Centipoise at 25 C (77 F)
(VOC): < 1.030 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, silicon dioxide, and
formaldehyde.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, and strong oxidizers.
11. TOXICOLOGICAL INFORMATION
ACUTE
Chemical Name ORAL LD50 DERMAL LD50
INHALATION
LC
50
Polyether polyol mixture Not Established Not Established Not Established
Di-(methylthio)toluenediamine 1515 mg/kg > 2000 mg/kg Not Established
Hydroxy terminated poly(oxyalkylated) polyol 3280 mg/kg > 2000 mg/kg Not Established
SENSITIZATION: May cause sensitization by skin contact.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available
DISTRIBUTION: No data available
CHEMICAL FATE INFORMATION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
Page 4 of 6
FP-40 PART B
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
COMMENTS: Not dangerous according to transport regulations.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS: No data available
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
Date Prepared: 3/13/2015
Page 5 of 6
FP-40 PART B
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 6 of 6
FP-40 PART B
by | Sep 27, 2025
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 1/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
1. Identification
Product identifier used on the label
HSF 118-N-2-30S-NAT RESIN
Recommended use of the chemical and restriction on use
Recommended use*: polyurethane component; industrial chemicals
Suitable for use in industrial sector: Polymers industry; chemical industry
* The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not
part of the seller’s published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty,
express or implied, including by incorporation into or reference in the seller’s sales agreement.
Details of the supplier of the safety data sheet
Company:
BASF CORPORATION
100 Park Avenue
Florham Park, NJ 07932, USA
Telephone: +1 973 245-6000
Emergency telephone number
CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)
Other means of identification
Chemical family: resin
Synonyms: Urethane System Resin Component
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Classification of the product
STOT RE 2 Specific target organ toxicity repeated
exposure
Label elements
Pictogram:
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 2/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
Signal Word:
Warning
Hazard Statement:
H373 May cause damage to organs (Kidney) through prolonged or repeated
exposure.
Precautionary Statements (Prevention):
P260 Do not breathe dust/gas/mist/vapours.
Precautionary Statements (Response):
P311 Call a POISON CENTER or doctor/physician.
Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazards not otherwise classified
No specific dangers known, if the regulations/notes for storage and handling are considered.
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Emergency overview
CAUTION:
CAN CAUSE KIDNEY DAMAGE.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
CAS Number Content (W/W) Chemical name
111-46-6 >= 1.0 – < 5.0 % diethylene glycol
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
CAS Number Content (W/W) Chemical name
< 85.0 % Polyol
460-73-1 < 15.0 % Propane, 1,1,1,3,3-pentafluoro-
13674-84-5 < 10.0 % tris(2-chloro-1-methylethyl)phosphate
The product contains:
CAS Number
Content (W/W) Chemical name
460-73-1 < 15.0 % Propane, 1,1,1,3,3-pentafluoro-
13674-84-5 < 10.0 % tris(2-chloro-1-methylethyl)phosphate
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 3/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
4. First-Aid Measures
Description of first aid measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if
necessary. Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water.
Immediate medical attention required.
If swallowed:
Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give
anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention
required.
Most important symptoms and effects, both acute and delayed
Information on: diethylene glycol
Symptoms: Overexposure may cause:, vomiting, coma, abdominal cramps, lethargy, nausea,
diarrhea, headache
----------------------------------
Indication of any immediate medical attention and special treatment needed
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote.
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide, foam
Special hazards arising from the substance or mixture
Hazards during fire-fighting:
No particular hazards known.
Advice for fire-fighters
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 4/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
6. Accidental release measures
Further accidental release measures:
High risk of slipping due to leakage/spillage of product.
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing.
Environmental precautions
Do not empty into drains. Do not discharge into the subsoil/soil.
Methods and material for containment and cleaning up
Spills should be contained, solidified, and placed in suitable containers for disposal.
7. Handling and Storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Protect against moisture. Product should not
be mixed with air above atmospheric pressure for leak testing or any other purpose. Use dry nitrogen
to transfer or leak test equipment pressurized with product.
Protection against fire and explosion:
No explosion proofing necessary.
Conditions for safe storage, including any incompatibilities
Segregate from foods and animal feeds. Segregate from acids. Segregate from oxidants.
Suitable materials for containers: carbon steel (iron), High density polyethylene (HDPE), Low density
polyethylene (LDPE), Stainless steel 1.4301 (V2)
Further information on storage conditions: No special precautions necessary. Avoid extreme heat.
Store protected against freezing.
Storage stability:
Storage temperature: 16 - 27 C
8. Exposure Controls/Personal Protection
Advice on system design:
Provide local exhaust ventilation to control vapours/mists.
Personal protective equipment
Respiratory protection:
Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator as needed.
Hand protection:
Chemical resistant protective gloves
Eye protection:
Wear face shield or tightly fitting safety goggles (chemical goggles) if splashing hazard exists.
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 5/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
Body protection:
Standard work clothes and shoes.
General safety and hygiene measures:
Avoid contact with skin. Handle in accordance with good industrial hygiene and safety practice. Wear
protective clothing as necessary to prevent contact. Avoid inhalation of vapours/mists. Wash soiled
clothing immediately.
9. Physical and Chemical Properties
Form: liquid
Odour: amine-like, mild
Odour threshold: not applicable
Colour: amber
pH value: > 7.0
melting range: < -5.00 C
Boiling point: 100.00 C ( 760.000000 mmHg)
Sublimation point: No applicable information available.
Flash point: > 94.00 C (open cup)
Flammability: not flammable
Lower explosion limit: For liquids not relevant for classification
and labelling. The lower explosion point
may be 5 – 15 C below the flash point.
Upper explosion limit: For liquids not relevant for classification
and labelling.
Autoignition: > 200.00 C
Vapour pressure: 0.10 mmHg ( 20.00 C)
Density: 8.8000 lb/USg ( 25.00 C)
Relative density: No applicable information available.
Vapour density: not applicable
Partitioning coefficient n-
octanol/water (log Pow):
Unspecified
Self-ignition
temperature:
No self ignition was observed up to the
specified temperature.
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: 560.000 mPa.s ( 23.00 C)
Viscosity, kinematic: No applicable information available.
Solubility in water: soluble
Miscibility with water: slightly soluble
Solubility (quantitative): No applicable information available.
Solubility (qualitative): No applicable information available.
Evaporation rate: Value can be approximated from Henry’s
Law Constant or vapor pressure.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal.
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 6/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
Oxidizing properties:
Not an oxidizer.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions if stored and handled as prescribed/indicated.
Conditions to avoid
Temperature: < 0 degrees Celsius
Incompatible materials
acids, oxidizing agents, isocyanates
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: carbon monoxide, carbon dioxide
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: No known acute effects.
Assessment other acute effects
Assessment of STOT single:
Based on the available information there is no specific target organ toxicity to be expected after a
single exposure.
Origin of data: expert judgement
Irritation / corrosion
Assessment of irritating effects: No irritation is expected under intended use and appropriate
handling.
Sensitization
Assessment of sensitization: The chemical structure does not suggest a sensitizing effect.
Aspiration Hazard
No aspiration hazard expected.
Chronic Toxicity/Effects
Repeated dose toxicity
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 7/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
Assessment of repeated dose toxicity: Repeated oral uptake of the substance did not cause
substance-related effects. Repeated inhalative uptake of the substance did not cause substance-
related effects. Repeated dermal uptake of the substance did not cause substance-related effects.
Genetic toxicity
Assessment of mutagenicity: The chemical structure does not suggest a specific alert for such an
effect.
Carcinogenicity
Assessment of carcinogenicity: The chemical structure does not suggest a specific alert for such an
effect.
Reproductive toxicity
Assessment of reproduction toxicity: The chemical structure does not suggest a specific alert for
such an effect.
Teratogenicity
Assessment of teratogenicity: The chemical structure does not suggest a specific alert for such an
effect.
Other Information
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Symptoms of Exposure
Medical conditions aggravated by overexposure
Data available do not indicate that there are medical conditions that are generally recognized as
being aggravated by exposure to this substance/product.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms.
Persistence and degradability
Assessment biodegradation and elimination (H2O)
Poorly biodegradable.
Elimination information
Poorly biodegradable.
Bioaccumulative potential
Assessment bioaccumulation potential
Does not significantly accumulate in organisms.
Mobility in soil
Assessment transport between environmental compartments
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 8/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
Adsorption to solid soil phase is not expected.
Additional information
Adsorbable organically-bound halogen (AOX):
This product contains no organically-bound halogen.
Other ecotoxicological advice:
The product has not been tested. Do not discharge product into the environment without control.
13. Disposal considerations
Waste disposal of substance:
Incinerate in a licensed facility. Dispose of in a licensed facility. Do not discharge substance/product
into sewer system.
Container disposal:
Steel drums must be emptied and can be sent to a licensed drum reconditioner for reuse, a scrap
metal dealer or an approved landfill. Do not attempt to refill or clean containers since residue is
difficult to remove. Under no circumstances should empty drums be burned or cut open with gas or
electric torch as toxic decomposition products may be liberated. Do not reuse empty containers.
14. Transport Information
Land transport USDOT
Classified as combustible liquid in containers greater than 119
gallons.
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
15. Regulatory Information
Federal Regulations
Registration status:
Chemical TSCA, US released / listed
EPCRA 311/312 (Hazard categories): Not hazardous;
CERCLA RQ CAS Number Chemical name
1000 LBS 75-07-0 acetaldehyde
100 LBS 123-91-1 1,4-dioxane
Safety Data Sheet
HSF 118-N-2-30S-NAT RESIN
Revision date : 2014/07/25 Page: 9/9
Version: 3.0 (30576836/SDS_GEN_US/EN)
State regulations
CA Prop. 65:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
NFPA Hazard codes:
Health : 1 Fire: 1 Reactivity: 1 Special:
HMIS III rating
Health: 1 Flammability: 1 Physical hazard: 1
16. Other Information
SDS Prepared by:
BASF NA Product Regulations
SDS Prepared on: 2014/07/25
We support worldwide Responsible Care initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED
HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITN ESS FOR A PARTICULAR PURPOSE, ARE
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED
WITHOUT INFRINGING THE INTELLECTUAL PR OPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED
A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIO NS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OUR COMPANY HEREUNDER AR E GIVEN GRATIS AND WE ASSUME NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION
GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
BASF CORPORATION WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR
USE IN THE MANUFACTURE OF MEDICAL DEVICES WHICH ARE INTENDED FOR
PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN PERMANENT CONTACT WITH
INTERNAL BODILY TISSUES OR FLUIDS.
END OF DATA SHEET
by | Sep 27, 2025
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 1/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
1. Identification
Product identifier used on the label
ELASTOCAST* T7
Recommended use of the chemical and restriction on use
Recommended use*: polyurethane component; industrial chemicals
Suitable for use in industrial sector: Polymers industry; chemical industry
* The Recommended use identified for this product is provided solely to comply with a US Federal requirement and is not
part of the seller’s published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty,
express or implied, including by incorporation into or reference in the seller’s sales agreement.
Details of the supplier of the safety data sheet
Company:
BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA
Telephone: +1 973 245-6000
Emergency telephone number
CHEMTREC: 1-800-424-9300
BASF HOTLINE: 1-800-832-HELP (4357)
Other means of identification
Chemical family: aromatic isocyanates
Synonyms: POLYMETHYLENE POLYPHENYLISOCYANATE
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Classification of the product
Acute Tox. 4
(Inhalation – mist) Acute toxicity
Eye Dam./Irrit. 2B Serious eye damage/eye irritation Skin Corr./Irrit. 2 Skin corrosion/irritation Skin Sens. 1B Skin sensitization
Resp. Sens. 1 Respiratory sensitization
Carc. 2 Carcinogenicity
STOT SE 3
(irritating to Specific tar get organ toxicity single exposure
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 2/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
respiratory system)
STOT RE 2 (by inhalation) Specific target organ toxicity repeated
exposure
Label elements
Pictogram:
Signal Word:
Danger
Hazard Statement:
H320 Causes eye irritation.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs (Olfactory organs) through prolonged or
repeated exposure (inhalation).
Precautionary Statements (Prevention):
P280 Wear protective gloves/protective clothing/eye protection/face
protection.
P271 Use only outdoors or in a well-ventilated area.
P260 Do not breathe dust/gas/mist/vapours.
P201 Obtain special instructions before use.
P261 Avoid breathing mist.
P202 Do not handle until all safety precautions have been read and
understood.
P284 [In case of inadequate ventilation] wear respiratory protection.
P272 Contaminated work clothing should not be allowed out of the workplace.
P264 Wash with plenty of water and soap thoroughly after handling.
Precautionary Statements (Response):
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P314 Get medical advice/attention if
you feel unwell.
P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water.
P333 + P311 If skin irritation or rash occurs: Call a POISON CENTER or
doctor/physician.
P362 + P364 Take off contaminated clothing and wash before reuse.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
P337 + P311 If e
ye irritation persists: Call a POISON CENTER or doctor/physician.
Precautionary Statements (Storage):
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 3/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Precautionary Statements (Disposal):
P501 Dispose of contents/container to hazardous or special waste collection
point.
Hazards not otherwise classified
No specific dangers known, if the regulations/notes for storage and handling are considered.
Labeling of special preparations (GHS):
CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE
RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED
PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN
BRONCHITIS, BRONCHIAL SPASMS AND PULMON ARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN RE PORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED
LUNG FUNCTION WHICH MAY BE PERMANEN T. ACUTE OR CHRONIC OVEREXPOSURE TO
ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN
ALLERGIC RESPIRATORY REACTIONS INCL UDING WHEEZING, SHORTNESS OF BREATH
AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A
ROLE IN CAUSING RESPIRATORY SENSITIZATION. ANIMAL TESTS AND OTHER RESEARCH
INDICATE THAT SKIN CONTACT WITH MDI MAY PLAY A ROLE IN CAUSING RESPIRATORY
SENSITIZATION.
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Emergency overview
DANGER:
CONTAINS ISOCYANATES. INHALATION OF ISOCYANATE MISTS OR VAPORS MAY CAUSE
RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST DISCOMFORT AND REDUCED
PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY RESULT IN
BRONCHITIS, BRONCHIAL SPASMS AND PULMON ARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN RE PORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED
LUNG FUNCTION WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO
ISOCYANATES MAY CAUSE SENSITIZATION IN SOME INDIVIDUALS, RESULTING IN
ALLERGIC RESPIRATORY REACTIONS INCL UDING WHEEZING, SHORTNESS OF BREATH
AND DIFFICULTY BREATHING. ANIMAL TESTS INDICATE THAT SKIN CONTACT MAY PLAY A
ROLE IN CAUSING RESPIRATORY SENSITIZATION.
AVOID CONTACT WITH SKIN AND EYES.
SKIN OR EYE CONTACT MAY CAUSE IRRITATION.
3. Composition / Information on Ingredients
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
CAS Number Content (W/W) Chemical name
101-68-8 >= 25.0 – < 50.0 % Diphenylmethane-4,4'-diisocyanate (MDI)
17589-24-1 >= 1.0 – < 3.0 % 1,3-Diazetidine-2,4-dione, 1,3-bis[4-[(4-
isocyanatophenyl)methyl]phenyl]-
26447-40-5 >= 3.0 – < 7.0 % Methylenediphenyl diisocyanate
57636-09-6 >= 1.0 – < 3.0 % Isocyanic acid, polymethylenepolyphenylene ester,
polymer with.alpha.-hydro-.omega.-hydroxypoly(oxy-1,2-
ethanediyl)
9016-87-9 >= 50.0 – < 75.0 % P-MDI
According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 4/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
CAS Number Content (W/W) Chemical name
9016-87-9 >= 50.0 – < 75.0 % P-MDI
101-68-8 >= 25.0 – < 50.0 % Diphenylmethane-4,4'-diisocyanate (MDI)
17589-24-1 >= 1.0 – < 3.0 % 1,3-Diazetidine-2,4-dione, 1,3-bis[4-[(4-
isocyanatophenyl)methyl]phenyl]-
26447-40-5 >= 3.0 – < 7.0 % Methylenediphenyl diisocyanate
57636-09-6 >= 1.0 – < 3.0 % Isocyanic acid, polymethylenepolyphenylene ester,
polymer with.alpha.-hydro-.omega.-hydroxypoly(oxy-1,2-
ethanediyl)
4. First-Aid Measures
Description of first aid measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if
necessary. Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. If irritation develops, seek medical attention.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water.
Immediate medical attention required.
If swallowed:
Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give
anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention
required.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Eye irritation, skin irritation, allergic symptoms
Hazards: Symptoms can appear later.
Information on: Diphenylmethane-4,4'-diisocyanate (MDI)
Hazards: Respiratory sensitization may result in allergic (asthma-like) signs in the lower respiratory
tract including wheezing, shortness of breath and difficulty breathing, the onset of which may be
delayed. Repeated inhalation of high concentrations may cause lung damage, including reduced
lung function, which may be permanent. Substances eliciting lower respiratory tract irritation may
worsen the asthma-like reactions that may be produced by product exposures.
----------------------------------
Indication of any immediate medical attention and special treatment needed
Note to physician
Antidote: Specific antidotes or neutralizers to isocyanates do not exist.
Treatment: Treatment should be supportive and based on the judgement of the
physician in response to the reaction of the patient.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 5/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
5. Fire-Fighting Measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide, foam
Special hazards arising from the substance or mixture
Hazards during fire-fighting:
nitrous gases, fumes/smoke, isocyanate, vapour
Advice for fire-fighters
Protective equipment for fire-fighting:
Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.
Further information:
Keep containers cool by spraying with water if exposed to fire. Dispose of fire debris and
contaminated extinguishing water in accordance with official regulations.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and equipment.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Absorb isocyanate with suitable absorbent material (see 40 CFR, sections 260,
264 and 265 for further information). Shovel into open container. Do not make container pressure
tight. Move container to a well-ventilated area (outside). Spill area can be decontaminated with the
following recommended decontamination solution: Mixture of 90 % water, 8 % concentrated
ammonia, 2 % detergent. Add at a 10 to 1 ratio. Allow to stand for at least 48 hours to allow escape
of evolved carbon dioxide.
For large amounts: If temporary control of isocyanate vapor is required, a blanket of protein foam or
other suitable foam (available from most fire departments) may be placed over the spill. Transfer as
much liquid as possible via pump or vacuum device into closed but not sealed containers for
disposal.
For residues: The following measures should be taken for final cleanup: Wash down spill area with
decontamination solution. Allow solution to stand for at least 10 minutes.
Dike spillage.
7. Handling and Storage
Precautions for safe handling
Provide suitable exhaust ventilation at the processing machines. Ensure thorough ventilation of
stores and work areas. Avoid aerosol formation. When handling heated product, vapours of the
product should be ventilated, and respiratory protection used. Wear respiratory protection when
spraying. Danger of bursting when sealed gastight. Protect against moisture. If bulging of drum
occurs, transfer to well ventilated area, puncture to relieve pressure, open vent and let stand for 48
hours before resealing.
Protection against fire and explosion:
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 6/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
No explosion proofing necessary.
Conditions for safe storage, including any incompatibilities
Keep away from water. Segregate from foods and animal feeds. Segregate from acids and bases.
Segregate from bases.
Suitable materials for containers: Carbon steel (Iron), High density polyethylene (HDPE), Low
density polyethylene (LDPE), Stainless steel 1.4301 (V2)
Further information on storage conditions: Formation of CO2 and build up of pressure possible. Keep
container tightly closed and in a well-ventilated place. Outage of containers should be filled with dry
inert gas at atmospheric pressure to avoid reaction with moisture.
Storage stability:
Storage temperature: 32 - 110 F
Protect against moisture.
8. Exposure Controls/Personal Protection
Components with occupational exposure limits
Diphenylmethane-4,4'-
diisocyanate (MDI)
OSHA PEL CLV 0.02 ppm 0.2 mg/m3 ; CLV 0.02 ppm 0.2
mg/m3 ;
ACGIH TLV TWA value 0.005 ppm ;
P-MDI OSHA PEL CLV 0.02 ppm 0.2 mg/m3 ; CLV 0.02 ppm 0.2
mg/m3 ;
ACGIH TLV TWA value 0.005 ppm ;
Isocyanic acid,
polymethylenepolyphenylen
e ester (P-MDI)
OSHA PEL CLV 0.02 ppm 0.2 mg/m3 ; CLV 0.02 ppm 0.2
mg/m3 ;
ACGIH TLV TWA value 0.005 ppm ;
Advice on system design:
Provide local exhaust ventilation to maintain recommended P.E.L.
Personal protective equipment
Respiratory protection:
When workers are facing concentrations above the occupational exposure limits they must use
appropriate certified respirators. When atmospheric levels may exceed the occupational exposure
limit (PEL or TLV) NIOSH-certified air-purifying respirators equipped with an organic vapor sorbent
and particulate filter can be used as long as appropriate precautions and change out schedules are
in place. For emergency or non-routine, high exposure situations, including confined space entry,
use a NIOSH-certified full facepiece pressure demand self-contained breathing apparatus (SCBA) or
a full facepiece pressure demand supplied-air respirator (SAR) with escape provisions.
Hand protection:
Chemical resistant protective gloves should be worn to prevent all skin contact., Suitable materials
may include, chloroprene rubber (Neoprene), nitrile rubber (Buna N), chlorinated polyethylene,
polyvinylchloride (Pylox), butyl rubber, depending upon conditions of use.
Eye protection:
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 7/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Body protection:
Cover as much of the exposed skin as possible to prevent all skin contact., Suitable materials may
include, saran-coated material, depending upon conditions of use.
General safety and hygiene measures:
Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety showers
must be easily accessible. Observe the appropriate PEL or TLV value. Wash soiled clothing
immediately. Contaminated equipment or clothing should be cleaned after each use or disposed of.
9. Physical and Chemical Properties
Form: liquid
Odour: faint odour, aromatic
Odour threshold: not applicable
Colour: dark amber
pH value: not applicable
Freezing point: 3 C ( 1 ATM)
Boiling point: 200 C ( 5 mmHg)
Sublimation point: No applicable information available.
Flash point: 220 C
(open cup)
Flammability: not flammable
Lower explosion limit: For liquids not relevant for classification
and labelling. The lower explosion point
may be 5 - 15 C below the flash point.
Upper explosion limit: For liquids not relevant for classification
and labelling.
Autoignition: > 250 C
Vapour pressure: 0.00016 mmHg ( 20 C)
Density: 1.22 g/cm3 ( 20 C)
Relative density: 1.22 ( 25 C)
Bulk density: 10.17 lb/USg ( 25 C)
Vapour density: not applicable
Partitioning coefficient n-
octanol/water (log Pow):
not applicable
Self-ignition
temperature:
not self-igniting
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Viscosity, dynamic: 200 mPa.s ( 20 C)
Viscosity, kinematic: No applicable information available.
Solubility in water: Reacts with water.
Solubility (quantitative): No applicable information available.
Solubility (qualitative): No applicable information available.
Molar mass: 360 g/mol
Evaporation rate: Value can be approximated from Henry’s
Law Constant or vapor pressure.
Other Information: If necessary, information on other physical and chemical
parameters is indicated in this section.
10. Stability and Reactivity
Reactivity
Corrosion to metals:
No corrosive effect on metal.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 8/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Oxidizing properties:
not fire-propagating
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with water, with formation of carbon dioxide. Risk of bursting. Reacts with alcohols. Reacts
with acids. Reacts with alkalies. Reacts with amines. Risk of exothermic reaction. Risk of
polymerization. Contact with certain rubbers and plastics can cause brittleness of the
substance/product with subsequent loss in strength.
Conditions to avoid
Avoid moisture.
Incompatible materials
acids, amines, alcohols, water, Alkalines, strong bases, Substances/products that react with
isocyanates.
Hazardous decomposition products
Decomposition products:
Hazardous decomposition products: carbon monoxide, carbon dioxide, nitrogen oxide, hydrogen
cyanide, nitrogen oxides, aromatic isocyanates, gases/vapours
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
11. Toxicological information
Primary routes of exposure
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Acute toxicity
Assessment of acute toxicity: Inhalation of vapours may cause irritation of the mucous membranes of the nose, throat or trachea, breathlessness, chest discomfort, difficult breathing and reduced pulmonary function. Inhalation exposure well above the PEL may result additionally in eye irritation,
headache, chemical bronchitis, asthma-like findings or pulmonary edema. Isocyanates have also
been reported to cause hypersensitivity pneumonitis, which is characterized by flu-like symptoms,
the onset of which may be delayed.
Oral
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Type of value: LD50
Species: rat (male/female)
Value: > 2,000 mg/kg (Directive 84/449/EEC, B.1)
———————————-
Inhalation
Type of value: LC50 Species: rat (male/female)
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 9/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Value: 2.0 mg/l (OECD Guideline 403)
An aerosol was tested.
Dermal
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Type of value: LD50
Species: rabbit (male/female)
Value: > 9,400 mg/kg
———————————-
Assessment other acute effects
Assessment of STOT single: Causes temporary irritation of the respiratory tract.
Irritation / corrosion
Assessment of irritating effects: Irritating to eyes, respiratory system and skin. Skin contact may
result in dermatitis, either irritative or allergic.
Skin
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Species: rabbit
Result: Irritating.
Method: Draize test
———————————-
Eye
Information on: Diphenylmethane-4,4′-diisocyanate (MDI) Species: rabbit
Result: Irritating.
Method: Draize test
———————————-
Sensitization
Assessment of sensitization: Sensitization after skin contact possible. The substance may cause
sensitization of the respiratory tract. As a result of previous repeated overexposures or a single large
dose, certain individuals will develop isocyanate sensitization (chemical asthma) which will cause
them to react to a later exposure to isocyanate at levels well below the PEL/TLV. These symptoms,
which include chest tightness, wheezing, cough, shortness of breath, or asthmatic attack, could be
immediate or delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon
exposure to dust, cold air, or other irritants. This increased lung sensitivity can persist for weeks and
in severe cases for several years. Chronic overexposure to isocyanates has also been reported to
cause lung damage, including a decrease in lung function, which may be permanent. Prolonged
contact can cause reddening, swelling, rash, scaling, or blistering. In those who have developed a
skin sensitization, these symptoms can develop as a result of contact with very small amounts of
liquid material, or even as a result of vapour-only exposure. Animal tests indicate that skin contact
may play a role in causing respiratory sensitization.
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Buehler test
Species: guinea pig
Result: sensitizing
Mouse Local Lymph Node Assay (LLNA)
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 10/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Species: mouse
Result: sensitizing
Can cause skin sensitization
other
Species: guinea pig
Result: sensitizing
Studies in animals suggest that dermal exposure may lead to pulmonary sensitization. However, the
relevance of this result for humans is unclear.
———————————-
Chronic Toxicity/Effects
Repeated dose toxicity
Assessment of repeated dose toxicity: The substance may cause damage to the olfactory epithelium
after repeated inhalation. The substance may cause damage to the lung after repeated inhalation.
These effects are not relevant to humans at occupational levels of exposure.
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Experimental/calculated data: rat (Wistar) (male/female) Inhalation 2 yrs, 6 hr/day 0, 0.2, 1, 6 mg/m3
, olfactory epithelium
NOAEL: 0.2 mg/m3
LOAEL: 1 mg/m3
The substance may cause damage to the olfactory epithelium after repeated inhalation. These
effects are not relevant to humans at occupational levels of exposure. Repeated inhalative uptake of
the substance did not cause damage to the reproductive organs.
———————————-
Genetic toxicity
Assessment of mutagenicity: The substance was mutagenic in various bacterial test systems;
however, these results could not be confirmed in tests with mammals.
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Genetic toxicity in vitro: OECD Guideline 471 Ames-test Salmonella typhimurium:with and without
metabolic activation ambiguous
———————————-
Information on: Diphenylmethane-4,4′-diisocyanate (MDI)
Genetic toxicity in vivo: OECD Guideline 474 Micronucleus assay rat (male) Inhalation negative
No clastogenic effect reported.
———————————-
Carcinogenicity
Assessment of carcinogenicity: A carcinogenic potential cannot be excluded after prolonged exposure to severely irritating concentrations. These effects are not relevant to humans at occupational levels of exposure.
Experimental/calculated data: OECD Guideline 453 rat Inhalation 0, 0.2, 1, 6 mg/m3
Result: Lung tumors
Reproductive toxicity
Assessment of reproduction toxicity: Repeated inhalative uptake of the substance did not cause
damage to the reproductive organs.
Teratogenicity
Assessment of teratogenicity: The substance did not cause malformations in animal studies;
however, toxicity to development was observed at high doses that were toxic to the parental animals.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 11/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Development
OECD Guideline 414 rat Inhalation 0, 1, 4, 12 mg/m3
NOAEL Mat.: 4 mg/m3
NOAEL Teratog.: 4 mg/m3
The substance did not cause malformations in animal studies; however, toxicity to development was
observed at high doses that were toxic to the parental animals.
Symptoms of Exposure
The most important known symptoms and effects are described in the labelling (see section 2)
and/or in section 11., Eye irritation, skin irritation, allergic symptoms
Medical conditions aggravated by overexposure
The isocyanate component is a respiratory sensitizer. It may cause allergic reaction leading to asthma-like spasms of the bronchial tubes and difficulty in breathing. Medical supervision of all
employees who handle or come into contact with isocyanates is recommended. Contact may
aggravate pulmonary disorders. Persons with history of respiratory disease or hypersensitivity should
not be exposed to this product. Preemployment and periodic medical examinations with respiratory
function tests (FEV, FVC as a minimum) are suggested. Persons with asthmatic conditions, chronic
bronchitis, other chronic respiratory diseases, recurrent eczema or pulmonary sensitization should
be excluded from working with isocyanates. Once a person is diagnosed as having pulmonary
sensitization (allergic asthma) to isocyanates, further exposure is not recommended.
12. Ecological Information
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations. Based on long-term (chronic) toxicity study data,
the product is very likely not harmful to aquatic organisms.
The product may hydrolyse. The test result maybe partially due to degradation products. The product
has not been tested. The statement has been derived from substances/products of a similar
structure or composition.
Toxicity to fish
LC0 (96 h) > 1,000 mg/l, Brachydanio rerio (OECD Guideline 203, static)
Aquatic invertebrates
EC50 (24 h) > 1,000 mg/l, Daphnia magna (OECD Guideline 202, part 1, static)
Aquatic plants
EC0 (72 h) 1,640 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static)
Microorganisms/Effect on activated sludge
Toxicity to microorganisms
OECD Guideline 209 aquatic
aerobic bacteria from a domestic water treatment plant/EC50 (3 h): > 100 mg/l
Persistence and degradability
Assessment biodegradation and elimination (H2O)
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 12/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Poorly biodegradable. The product is unstable in water. The elimination data also refer to products of
hydrolysis.
Elimination information
0 % BOD of the ThOD (28 d) (OECD Guideline 302 C) (aerobic, activated sludge) Poorly
biodegradable.
Assessment of stability in water
In contact with water the substance will hydrolyse slowly. Information on Stability in Water (Hydrolysis)
t1/2 20 h (25 C)
Bioaccumulative potential
Assessment bioaccumulation potential Significant accumulation in organisms is not to be expected.
Bioaccumulation potential
Bioconcentration factor: 200 (28 d), Cyprinus carpio (OECD Guideline 305 E)
Mobility in soil
Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface.
Adsorption to solid soil phase is not expected.
13. Disposal considerations
Waste disposal of substance:
Incinerate or dispose of in a licensed facility. Do not discharge substance/product into sewer system.
Container disposal:
DRUMS:
Steel drums must be emptied and can be sent to a licensed drum reconditioner for reuse, a scrap
metal dealer or an approved landfill. Do not attempt to refill or clean containers since residue is
difficult to remove. Under no circumstances should empty drums be burned or cut open with gas or
electric torch as toxic decomposition products may be liberated. Do not reuse empty containers.
14. Transport Information
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Not classified as a dangerous good under transport regulations
Air transport
IATA/ICAO
Not classified as a dangerous good under transport regulations
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 13/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
Further information
DOT: This product is regulated if the amount in a single receptacle exceeds the Reportable Quantity
(RQ). Please refer to Section 15 of this MSDS for the RQ for this product.
15. Regulatory Information
Federal Regulations
Registration status:
Chemical TSCA, US released / listed
EPCRA 311/312 (Hazard categories): Acute; Chronic
EPCRA 313:
CAS Numbe
r Chemical name
101-68-8 Diphenylmethane-4,4′-diisocyanate (MDI)
9016-87-9 P-MDI
CERCLA RQ CAS Number Chemical name
5000 LBS 101-68-8; 9016-
87-9
Diphenylmethane-4,4′-diisocyanate (MDI); P-MDI
Reportable Quantity for release: 13,157.9 lb
State regulations
State RTK CAS Number Chemical name
MA, NJ, PA 9016-87-9 P-MDI
MA, NJ, PA 101-68-8 Diphenylmethane-4,4′-diisocyanate (MDI)
NJ 26447-40-5 Methylenediphenyl diisocyanate
NFPA Hazard codes:
Health : 2 Fire: 1 Reactivity: 1 Special:
HMIS III rating
Health: 2 Flammability: 1 Physical hazard: 1
16. Other Information
SDS Prepared by: BASF NA Product Regulations
SDS Prepared on: 2015/02/17
We support worldwide Responsible Care initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.
Safety Data Sheet
ELASTOCAST T7
Revision date : 2015/02/17 Page: 14/14
Version: 4.2 (30576139/SDS_GEN_US/EN)
ELASTOCAST is a registered trademark of BASF Corporation or BASF SE
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED
HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS
PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT
PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO
DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR
TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING
WARRANTIES OF MERCHANTABILITY OR FITN ESS FOR A PARTICULAR PURPOSE, ARE
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET
FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED
WITHOUT INFRINGING THE INTELLECTUAL PR OPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED
A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY
UNDERSTAND AND AGREE THAT THE DESCRIPTIO NS, DESIGNS, DATA, AND INFORMATION
FURNISHED BY OUR COMPANY HEREUNDER AR E GIVEN GRATIS AND WE ASSUME NO
OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION
GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
BASF CORPORATION WILL NOT MAKE ITS PRODUCTS AVAILABLE TO CUSTOMERS FOR
USE IN THE MANUFACTURE OF MEDICAL DEVICES WHICH ARE INTENDED FOR
PERMANENT IMPLANTATION IN THE HUMAN BODY OR IN PERMANENT CONTACT WITH
INTERNAL BODILY TISSUES OR FLUIDS.
END OF DATA SHEET
by | Sep 27, 2025
Safety Data Sheet
Issue date 28-Feb-2018 Revision date 28-Sep-2018 Version 2
1. Identification
Product Identifier
Product name Flex 25
Other means of identification
Recommended use of the chemical and restrictions on use
Recommended use Industrial silicone elastomer.
Application FOR INDUSTRIAL USE ONLY
Details of the Supplier of the Safety Data Sheet
Emergency Telephone Number
Company Phone Number 800-852-3147 (8AM – 5PM EST)
Emergency telephone Chemtrec 1-800-424-9300
2. Hazards Identification
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
EMERGENCY OVERVIEW
Hazards Not Otherwise Classified (HNOC)
Not Applicable
OTHER INFORMATION
Not Applicable.
3. Composition/information on Ingredients
Substance
Not Applicable
Mixture
Chemical name CAS No weight-% Trade secret
Supplier
CHT
7820 Whitepine Rd
Richmond, VA 23237
Manufacturer Address
CHT
8021 Reycan Road
Richmond, VA 23237
The product contains no substances which at their given concentration, are considered to be hazardous to health
Appearance Viscous liquid Physical State Liquid
_____________________________________________________________________________________________
PAGE 1 / 7
Odor Negligible
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
Silica, quartz 14808-60-7 3 – 7 *
Titanium Dioxide 13463-67-7 0.1 – 1 *
4. First aid measures
Description of first aid measures
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.
Consult a physician.
Skin Contact Wash skin with soap and water.
INHALATION Remove to fresh air.
INGESTION Clean mouth with water and drink afterwards plenty of water.
Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms No information available.
Indication of Any Immediate Medical Attention and Special Treatment Needed
Note to physicians Treat symptomatically.
5. Fire-fighting measures
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing MediaCAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available.
Explosion Data
Sensitivity to Mechanical ImpactNone.
Sensitivity to Static DischargeNone.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal Precautions Ensure adequate ventilation, especially in confined areas.
Environmental Precautions
Environmental Precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth
or other non-combustible absorbent material. Take up mechanically, placing in appropriate
containers for disposal. Clean contaminated surface thoroughly.
7. Handling and Storage
_____________________________________________________________________________________________
PAGE 2 / 7
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
Precautions for Safe Handling
Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials Incompatible with strong acids and bases. Interaction with strong bases can cause
liberation of hydrogen.
8. Exposure Controls/Personal Protection
Control Parameters
Ingredients with workplace
exposure parameters
.
Chemical name ACGIH TLV OSHA PEL NIOSH IDLH
Titanium Dioxide
13463-67-7
TWA: 10 mg/m
3
TWA: 15 mg/m
3
total dust
(vacated) TWA: 10 mg/m
3
total dust
IDLH: 5000 mg/m
3
NIOSH IDLH Immediately Dangerous to Life or Health
OTHER INFORMATION Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Appropriate Engineering Controls
Engineering controls Showers
Eyewash stations
Individual protection measures, such as personal protective equipment
Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection Wear protective gloves and protective clothing.
Respiratory Protection No protective equipment is needed under normal use conditions.
General hygiene considerations Handle in accordance with good industrial hygiene and safety practice.
9. Physical and Chemical Properties
Information on basic physical and chemical properties
Physical State Liquid
Appearance Viscous liquid Odor Negligible
Color Beige Odor threshold No information available
Property VALUES Remarks Method
pH No information available
Melting point / Freezing point No information available
Boiling point / Boiling range No information available
Flash point > 140 C / > 284 F CC (closed cup)
Evaporation rate No information available
Flammability (solid, gas) No information available
Flammability limit in air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure No information available
Vapor density No information available
Relative density No information available
Water solubility No information available
_____________________________________________________________________________________________
PAGE 3 / 7
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
Explosive properties Not an explosive
Oxidizing properties This product is not an oxidizing agent
OTHER INFORMATION
Softening point No information available
Molecular weight No information available
VOC content (%) No information available
Density 1.16
Bulk density No information available
10. Stability and Reactivity
Reactivity
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
hazardous polymerization No information available.
Conditions to avoid
No information available.
Incompatible materials
Incompatible with strong acids and bases. Interaction with strong bases can cause liberation of hydrogen.
Hazardous decomposition products
None known based on information supplied.
11. Toxicological Information
Information on Likely Routes of Exposure
Product information No data available.
INHALATION No data available.
Eye Contact No data available.
Skin Contact No data available.
INGESTION No data available.
Chemical name Oral LD50 dermal LD50 Inhalation LC50
Titanium Dioxide
13463-67-7
> 10000 mg/kg ( Rat ) – –
Information on Toxicological Effects
Symptoms No information available.
Solubility in other solvents No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity 35,000 cps
No data available
_____________________________________________________________________________________________
PAGE 4 / 7
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
Delayed and immediate effects as well as chronic effects from short and long-term exposure
sensitization No information available.
Germ Cell Mutagenicity No information available.
carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
This product contains one or more substances which are classified by IARC as
carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly
carcinogenic to humans (Group 2B).
Chemical name ACGIH IARC NTP OSHA
Silica, quartz
14808-60-7
A2 Group 1 Known X
Titanium Dioxide
13463-67-7
– Group 2B – X
ACGIH (American Conference of Governmental Industrial Hygienists)
A2 – Suspected Human Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 – Carcinogenic to Humans
Group 2B – Possibly Carcinogenic to Humans
Not classifiable as a human carcinogen
NTP (National Toxicology Program)
Known – Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present
Reproductive Toxicity No information available.
STOT – Single Exposure No information available.
STOT – Repeated Exposure No information available.
Target organ effects EYES, Lungs, Respiratory System.
Aspiration Hazard No information available.
Numerical Measures of Toxicity – Product information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral) 11,687.00 mg/kg
ATEmix (dermal) 5,664.00 mg/kg
12. Ecological Information
Ecotoxicity
Chemical name Algae/aquatic plants Fish Crustacea
Octamethylcyclotetrasiloxane
556-67-2
– 500: 96 h Brachydanio rerio mg/L
LC50 1000: 96 h Lepomis
macrochirus mg/L LC50
25.2: 24 h Daphnia magna mg/L
EC50
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other Adverse Effects No information available
13. Disposal Considerations
Waste Treatment Methods
Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Do not reuse container.
_____________________________________________________________________________________________
PAGE 5 / 7
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
14. Transport Information
DOT NOT REGULATED
IATA NOT REGULATED
IMDG NOT REGULATED
15. Regulatory Information
International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Complies
IECSC Complies
KECL Complies
PICCS Complies
AICS Complies
TCSI Complies
Legend:
TSCA – United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL – Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS – European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS – Japan Existing and New Chemical Substances
IECSC – China Inventory of Existing Chemical Substances
KECL – Korean Existing and Evaluated Chemical Substances
PICCS – Philippines Inventory of Chemicals and Chemical Substances
AICS – Australian Inventory of Chemical Substances
TCSI – Taiwan Chemical Substance Inventory
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard NO
Chronic health hazard NO
Fire Hazard NO
Sudden Release of Pressure Hazard NO
Reactive Hazard NO
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material
_____________________________________________________________________________________________
PAGE 6 / 7
_____________________________________________________________________________________________
Flex 25 Revision date 28-Sep-2018
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
Chemical name California Proposition 65
Silica, quartz – 14808-60-7 Carcinogen
Titanium Dioxide – 13463-67-7 Carcinogen
U.S. State Right-to-Know Regulations
U.S. EPA Label information
EPA Pesticide registration numberNot Applicable
16. Other information, including date of preparation of the last revision
Issue date 28-Feb-2018
Revision date 28-Sep-2018
Revision note
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet
NFPA Health Hazards 0 Flammability 1 Instability 0 –
HMIS Health Hazards 0 Flammability 1 Physical Hazards 0 –
_____________________________________________________________________________________________
PAGE 7 / 7
