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VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 11/21/2019
11/21/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : VINYL ESTER FAIRING PRIMER
CAS-No. : mixture
Product code : 1799-052
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H336 – May cause drowsiness or dizziness.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, fume, mist, spray, vapours.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
styrene, inhibited
(CAS-No.) 100-42-5 <= 27 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
talc
(CAS-No.) 14807-96-6 <= 24 Carc. 2, H351
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 14 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 13 Carc. 2, H351
Aquatic Acute 3, H402
2-propanol
(CAS-No.) 67-63-0 <= 2 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 3/13
Name Product identifier % GHS-US classification
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Eliminate all ignition sources if safe to do so. Do
not breathe dust/fume/gas/mist/vapours/spray.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Grey Blue
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : No data available
Relative density : 0.9
Density : 8 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Not established. Highly flammable liquid and vapour. May form
flammable/explosive vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
VINYL ESTER FAIRING PRIMER
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation. May cause drowsiness or dizziness.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled. Based on available data, the classification criteria are not met.
Symptoms/effects : May cause genetic defects (avoid skin contact and inhalation.). May cause cancer (avoid skin
contact and inhalation.). Suspected of damaging fertility or the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled. May cause respiratory irritation.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
VINYL ESTER FAIRING PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
VINYL ESTER FAIRING PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 11/21/2019
Other information : None.
VINYL ESTER FAIRING PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
11/21/2019 EN (English) 13/13
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 2/18
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 3/18
styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 4/18
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 5/18
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 6/18
methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
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8/23/2019
EN (English US) 7/18
n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
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10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
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cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
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ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
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12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
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methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
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14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
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15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
EN (English US) 18/18
H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 2/18
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
EN (English US) 3/18
styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
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4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
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Safety Data Sheet
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methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
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n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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Safety Data Sheet
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8/23/2019
EN (English US) 8/18
8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 9/18
10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 10/18
2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 11/18
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 12/18
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 13/18
12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 14/18
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 15/18
14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 16/18
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 17/18
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
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Safety Data Sheet
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H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Revision date: 8/23/2019
8/23/2019
EN (English US) 1/18
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : GREY VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1799-006
Type of product : Coating
Formula : na
Product group : Trade product
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Industrial/Professional use spec : Industrial
For professional use only
Use of the substance/mixture : COATING
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixtures: SDS < 2015 : Show CLP information + DPD classification in
section 2.1
Flammable liquids Category 2 H225
Acute toxicity (inhalation:vapour) Category 4 H332
Skin corrosion/irritation Category 2 H315
Serious eye damage/eye irritation Category 2 H319
Germ cell mutagenicity Category 1B H340
Carcinogenicity Category 1B H350
Reproductive toxicity Category 2 H361
Specific target organ toxicity (repeated exposure) Category 1 H372
Hazardous to the aquatic environment - Chronic Hazard Category 3 H412
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
Carc.Cat.2; R45
Muta.Cat.2; R46
F; R11
Xn; R20
Xi; R36/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 2/18
2.2. Label elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS02 GHS07 GHS08
Signal word (CLP) : Danger
Hazardous ingredients : styrene, inhibited; Solvent Naptha Petroleum Aliphatic
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
P233 - Keep container tightly closed.
P240 - Ground and bond container and receiving equipment.
P241 - Use explosion-proof equipment.
P260 - Do not breathe dust, mist, vapors, fume.
P264 - Wash hands, forearms and face thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, eye protection.
P302+P352 - IF ON SKIN: Wash with plenty of water.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water .
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P312 - Call a POISON CENTRE or doctor if you feel unwell.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder, foam to
extinguish.
P403+P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
EUH phrases : EUH208 - Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic
reaction.
2.3. Other hazards
No additional information available
SECTION 3: Composition/Information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according
to Directive 67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
talc (CAS-No.) 14807-96-6
(EC-No.) 238-877-9
(REACH-no) No data
available
<= 31.5 Not classified Not classified
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styrene, inhibited (CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
<= 25 R10
Xn; R20
Xi; R36/38
Flam. Liq. 3, H226
Repr. 2, H361d
STOT RE 1, H372
Acute Tox. 4 (Inhalation),
H332
Skin Irrit. 2, H315
Eye Irrit. 2, H319
methyl ethyl ketone (CAS-No.) 78-93-3
(EC-No.) 201-159-0
(EC Index-No.) 606-002-00-3
(REACH-no) 01-2119457290-
43
<= 5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide (CAS-No.) 13463-67-7
(EC-No.) 236-675-5
(REACH-no) 01-2119489379-
17
<= 4 Not classified Not classified
Solvent Naptha Petroleum Aliphatic (CAS-No.) 64742-89-8
(REACH-no) 01-2119471306-
40
<= 2 Not classified Muta. 1B, H340
Carc. 1B, H350
Asp. Tox. 1, H304
n-butyl acetate (CAS-No.) 123-86-4
(EC-No.) 204-658-1
(EC Index-No.) 607-025-00-1
(REACH-no) 01-2119485493-
29
<= 1 R10
R66
R67
Flam. Liq. 3, H226
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate (CAS-No.) 136-52-7
(EC-No.) 205-250-6
(REACH-no) 01-2119524678-
29
<= 0.5 Repr.Cat.3; R62
R43
N; R50/53
Skin Sens. 1, H317
Repr. 2, H361f
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
2-propanol (CAS-No.) 67-63-0
(EC-No.) 200-661-7
(EC Index-No.) 603-117-00-0
(REACH-no) 01-2119457558-
25
<= 0.5 Not classified Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
isobutyl acetate (CAS-No.) 110-19-0
(EC-No.) 203-745-1
(EC Index-No.) 607-026-00-7
(REACH-no) 01-2119488971-
22
<= 0.5 Not classified Flam. Liq. 2, H225
Specific concentration limits:
Name Product identifier Specific concentration limits:
DSD/DPD
Specific concentration
limits: CLP
styrene, inhibited
(CAS-No.) 100-42-5
(EC-No.) 202-851-5
(EC Index-No.) 601-026-00-0
(REACH-no) 01-2119457861-
32
(12.5 =< C < 100) Xi;R36/38
(12.5 =< C < 100) Xn;R20
Full text of R- and H- phrases: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel
unwell.
First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing.
Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first
aid instruction on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center/doctor/physician if you feel unwell.
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4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged
exposure through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour. Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapor-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
Hazardous decomposition products in case of fire : Toxic fumes may be released.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open
flames. No smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew
with proper protection. For further information refer to section 8: "Exposure
controls/personal protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapors are flammable.
Precautions for safe handling : Wear personal protective equipment. Take precautionary measures against static
discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands and other
exposed areas with mild soap and water before eating, drinking or smoking and when
leaving work. Provide good ventilation in process area to prevent formation of vapor. No
open flames. No smoking. Use only non-sparking tools. Use only outdoors or in a well-
ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke
when using this product. Always wash hands after handling the product.
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7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical/ventilating/lighting
equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in
fireproof place. Keep container tightly closed. Store in a well-ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
7.3. Specific end use(s)
No additional information available
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
Belgium Limit value (mg/m ) 108 mg/m
Belgium Limit value (ppm) 25 ppm
Belgium Short time value (mg/m ) 216 mg/m
Belgium Short time value (ppm) 50 ppm
France VME (mg/m ) 100 mg/m
France VME (ppm) 23.3 ppm
France VLE (mg/m ) 200 mg/m
France VLE (ppm) 46.6 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 430 mg/m
United Kingdom WEL TWA (ppm) 100 ppm
United Kingdom WEL STEL (mg/m ) 1080 mg/m
United Kingdom WEL STEL (ppm) 250 ppm
USA - ACGIH ACGIH TWA (ppm) 20 ppm
USA - ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 0.1 mg/m Cobalt compounds (as Co); United Kingdom;
Time-weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
methyl ethyl ketone (78-93-3)
EU IOELV TWA (mg/m ) 600 mg/m
EU IOELV TWA (ppm) 200 ppm
EU IOELV STEL (mg/m ) 900 mg/m
EU IOELV STEL (ppm) 300 ppm
Belgium Limit value (mg/m ) 600 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 900 mg/m
Belgium Short time value (ppm) 300 ppm
France VME (mg/m ) 600 mg/m
France VME (ppm) 200 ppm
France VLE (mg/m ) 900 mg/m
France VLE (ppm) 300 ppm
Germany TRGS 910 Acceptable concentration notes
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methyl ethyl ketone (78-93-3)
Netherlands Grenswaarde TGG 8H (mg/m ) 590 mg/m
Netherlands Grenswaarde TGG 8H (ppm) 197 ppm
Netherlands Grenswaarde TGG 15MIN (mg/m ) 900 mg/m
Netherlands Grenswaarde TGG 15MIN (ppm) 300 ppm
United Kingdom WEL TWA (mg/m ) 600 mg/m
United Kingdom WEL TWA (ppm) 200 ppm
United Kingdom WEL STEL (mg/m ) 899 mg/m
United Kingdom WEL STEL (ppm) 300 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
Belgium Limit value (mg/m ) 10 mg/m
France VME (mg/m ) 10 mg/m
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 10 mg/m
4 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 10 mg/m
n-butyl acetate (123-86-4)
Belgium Limit value (mg/m ) 723 mg/m (Ac tate de n-butyle; Belgium; Time-
weighted average exposure limit 8 h)
Belgium Limit value (ppm) 150 ppm (Ac tate de n-butyle; Belgium; Time-weighted
average exposure limit 8 h)
Belgium Short time value (mg/m ) 964 mg/m (Ac tate de n-butyle; Belgium; Short time
value)
Belgium Short time value (ppm) 200 ppm (Ac tate de n-butyle; Belgium; Short time
value)
France VME (mg/m ) 710 mg/m (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VME (ppm) 150 ppm (Ac tate de n-butyle; France; Time-weighted
average exposure limit 8 h; VL: Valeur non
r glementaire indicative)
France VLE (mg/m ) 940 mg/m (Ac tate de n-butyle; France; Short time
value; VL: Valeur non r glementaire indicative)
France VLE (ppm) 200 ppm (Ac tate de n-butyle; France; Short time value;
VL: Valeur non r glementaire indicative)
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m Butyl acetate; United Kingdom; Time-
weighted average exposure limit 8 h; Workplace
exposure limit (EH40/2005)
United Kingdom WEL TWA (ppm) 150 ppm Butyl acetate; United Kingdom; Time-weighted
average exposure limit 8 h; Workplace exposure limit
(EH40/2005)
United Kingdom WEL STEL (mg/m ) 966 mg/m Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
United Kingdom WEL STEL (ppm) 200 ppm Butyl acetate; United Kingdom; Short time
value; Workplace exposure limit (EH40/2005)
USA - ACGIH ACGIH TWA (ppm) 150 ppm (n-Butyl acetate; USA; Time-weighted average
exposure limit 8 h; TLV - Adopted Value)
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n-butyl acetate (123-86-4)
USA - ACGIH ACGIH STEL (ppm) 200 ppm (n-Butyl acetate; USA; Short time value; TLV -
Adopted Value)
isobutyl acetate (110-19-0)
Belgium Limit value (mg/m ) 238 mg/m
Belgium Limit value (ppm) 50 ppm
Belgium Short time value (mg/m ) 712 mg/m
Belgium Short time value (ppm) 150 ppm
France VME (mg/m ) 710 mg/m
France VME (ppm) 150 ppm
France VLE (mg/m ) 940 mg/m
France VLE (ppm) 200 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 724 mg/m
United Kingdom WEL TWA (ppm) 150 ppm
United Kingdom WEL STEL (mg/m ) 903 mg/m
United Kingdom WEL STEL (ppm) 187 ppm
USA - ACGIH ACGIH TWA (ppm) 150 ppm
2-propanol (67-63-0)
Belgium Limit value (mg/m ) 500 mg/m
Belgium Limit value (ppm) 200 ppm
Belgium Short time value (mg/m ) 1000 mg/m
Belgium Short time value (ppm) 400 ppm
France VLE (mg/m ) 980 mg/m
France VLE (ppm) 400 ppm
Germany TRGS 910 Acceptable concentration notes
United Kingdom WEL TWA (mg/m ) 999 mg/m
United Kingdom WEL TWA (ppm) 400 ppm
United Kingdom WEL STEL (mg/m ) 1250 mg/m
United Kingdom WEL STEL (ppm) 500 ppm
USA - ACGIH ACGIH TWA (ppm) 200 ppm
USA - ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
Belgium Limit value (mg/m ) 2 mg/m
Germany TRGS 910 Acceptable concentration notes
Netherlands Grenswaarde TGG 8H (mg/m ) 0.25 mg/m (respirabel)
United Kingdom WEL TWA (mg/m ) 1 mg/m
USA - ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for particulate
matter containing no asbestos and < 1% crystalline
silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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8.2. Exposure controls
Appropriate engineering controls:
Ensure exposure is below occupational exposure limits (where available). Ensure good ventilation of the work station.
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Environmental exposure controls:
Avoid release to the environment.
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Color : Gray.
Odor : characteristic.
Odor threshold : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour,Highly flammable liquid and vapour
Vapor pressure : No data available
Relative vapor density at 20 C : <
Relative density : <=
Specific gravity / density : 1.4
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Flammable liquid and vapour. Highly flammable liquid and vapour.
May form flammable/explosive vapor-air mixture.
10.3. Possibility of hazardous reactions
Not established.
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10.4. Conditions to avoid
Overheating. Heat. Sparks. Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
ATE CLP (vapors) 11 mg/l/4h
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 oral > 6000 mg/kg body weight (Hamster, Male, Weight of evidence, Oral)
LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg body weight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg body weight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg body weight (Equivalent or similar to OECD 423, Rat, Male / female, Read-
across, Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg body weight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure,
Rat, Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
n-butyl acetate (123-86-4)
LD50 oral rat 10770 mg/kg (Rat; Equivalent or similar to OECD 423; Experimental value; 12789 mg/kg;
Rat; Equivalent or similar to OECD 423; Experimental value; 10760 mg/kg bodyweight;
Rat)
LD50 dermal rabbit > 17600 mg/kg (Rabbit; Experimental value; Equivalent or similar to OECD 402; >14112
mg/kg bodyweight; Rabbit)
isobutyl acetate (110-19-0)
LD50 oral rat 13413 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental
value, Oral, 014 day(s))
LD50 dermal rabbit > 17400 mg/kg body weight (Equivalent or similar to OECD 402, 24 h, Rabbit, Male,
Experimental value, Dermal, 14 day(s))
LC50 inhalation rat (mg/l) > 30 mg/l (EPA OTS 798.6050, 6 h, Rat, Male / female, Read-across, Inhalation
(vapours), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value,
Oral, 14 day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value,
Dermal, 14 day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental
value, Inhalation (vapours), 14 day(s))
Skin corrosion/irritation : Causes skin irritation.
Additional information : Causes skin irritation
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Additional information : Based on available data, the classification criteria are not met
Germ cell mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable,2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : Not classified
Additional information : May cause respiratory irritation
Based on available data, the classification criteria are not met
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
Additional information : Causes damage to organs through prolonged or repeated exposure
Aspiration hazard : Not classified
Additional information : Based on available data, the classification criteria are not met
Potential Adverse human health effects and
symptoms
: Harmful if inhaled.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Aquatic acute : Not classified
Aquatic chronic : Harmful to aquatic life with long lasting effects.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
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EN (English US) 11/18
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-
across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella
subcapitata, Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static
system, Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
n-butyl acetate (123-86-4)
LC50 fish 1 18 mg/l (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Pimephales promelas; Flow-
through system; Fresh water; Experimental value)
isobutyl acetate (110-19-0)
LC50 fish 1 16.6 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oryzias latipes, Semi-static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 24.6 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna,
Semi-static system, Fresh water, Experimental value, GLP)
ErC50 (algae) 397 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
GREY VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD) 2.8 g O /g substance
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 12/18
ThOD 3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD) 2.03 g O /g substance
Chemical oxygen demand (COD) 2.31 g O /g substance
ThOD 2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)
n-butyl acetate (123-86-4)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Not established.
Biochemical oxygen demand (BOD) 0.15 – 0.5 g O /g substance
Chemical oxygen demand (COD) 2.32 g O /g substance
ThOD 2.21 g O /g substance
isobutyl acetate (110-19-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Photolysis in the air. Not
established.
ThOD 2.2 g O /g substance
BOD (% of ThOD) 0.6
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not
established.
Biochemical oxygen demand (BOD) 1.19 g O /g substance
Chemical oxygen demand (COD) 2.23 g O /g substance
ThOD 2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Persistence and degradability May cause long-term adverse effects in the environment.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 13/18
12.3. Bioaccumulative potential
GREY VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
40 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
n-butyl acetate (123-86-4)
BCF fish 1 14 (BCF)
Log Pow 2.3 (Experimental value; OECD 117: Partition Coefficient (n-octanol/water), HPLC method;
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
isobutyl acetate (110-19-0)
Log Pow 2.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method,
25 C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
Solvent Naptha Petroleum Aliphatic (64742-89-8)
Bioaccumulative potential Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 14/18
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
n-butyl acetate (123-86-4)
Surface tension 0.0613 N/m (20 C; 1 g/l)
Log Koc log Koc,SRC PCKOCWIN v2.0; 1.268 - 1.844; QSAR
isobutyl acetate (110-19-0)
Surface tension 62.5 mN/m (20 C, 1 g/l, OECD 115: Surface Tension of Aqueous Solutions)
Log Koc 1.193 - 1.844 (log Koc, SRC PCKOCWIN v2.0, QSAR)
Ecology - soil Highly mobile in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Results of PBT and vPvB assessment
Component
styrene, inhibited (100-42-5) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
methyl ethyl ketone (78-93-3) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
titanium(IV) oxide (13463-67-7) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
2-propanol (67-63-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
isobutyl acetate (110-19-0) This substance/mixture does not meet the PBT criteria of REACH, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH, annex XIII
12.6. Other adverse effects
Additional information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapors are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1866
UN-No. (IMDG) : UN 1866
UN-No. (IATA) : UN 1866
UN-No. (ADN) : Not applicable
UN-No. (RID) : UN 1866
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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 15/18
14.2. UN proper shipping name
Proper Shipping Name (ADR) : paint
Proper Shipping Name (IMDG) : RESIN SOLUTION
Proper Shipping Name (IATA) : Resin solution
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : UN 1866 paint, 3, II, (D/E)
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
Transport document description (IATA) : UN 1866 Resin solution, 3, II
Transport document description (RID) : UN 1866 , 3
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 3
Hazard labels (ADR) : 3
:
IMDG
Transport hazard class(es) (IMDG) : 3
Hazard labels (IMDG) : 3
:
IATA
Transport hazard class(es) (IATA) : 3
Hazard labels (IATA) : 3
:
ADN
Transport hazard class(es) (ADN) : Not applicable
RID
Transport hazard class(es) (RID) : 3
Hazard labels (RID) : 3
:
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 16/18
14.6. Special precautions for user
Overland transport
Classification code (ADR) : F1
Special provision (ADR) : 163, 640C, 650
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E2
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC : 3YE
Transport by sea
Packing instructions (IMDG) : P001
Packing provisions (IMDG) : PP1
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T4
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-E
Stowage category (IMDG) : B
Properties and observations (IMDG) : Miscibility with water depends upon the composition.
Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 353
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A3
ERG code (IATA) : 3L
Inland waterway transport
No data available
Rail transport
No data available
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.
GREY VINYL ESTER PRIMER
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
8/23/2019
EN (English US) 17/18
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : isobutyl acetate is listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen Ontwikkeling
: styrene, inhibited is listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable liquids
must be followed
Danish National Regulations : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct contact with
the product
The requirements from the Danish Working Environment Authorities regarding work with
carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No chemical safety assessment has been carried out
SECTION 16: Other information
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16
December 2008 on classification, labeling and packaging of substances and mixtures, amending and
repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Other information : None.
Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard Category 1
Asp. Tox. 1 Aspiration hazard Category 1
Carc. 1B Carcinogenicity Category 1B
Eye Irrit. 2 Serious eye damage/eye irritation Category 2
Flam. Liq. 2 Flammable liquids Category 2
Flam. Liq. 3 Flammable liquids Category 3
Muta. 1B Germ cell mutagenicity Category 1B
Repr. 2 Reproductive toxicity Category 2
Repr. 2 Reproductive toxicity Category 2
Skin Irrit. 2 Skin corrosion/irritation Category 2
Skin Sens. 1 Skin sensitization, Category 1
STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1
STOT SE 3 Specific target organ toxicity (single exposure) Category 3
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H304 May be fatal if swallowed and enters airways
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
GREY VINYL ESTER PRIMER
Safety Data Sheet
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8/23/2019
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H332 Harmful if inhaled
H336 May cause drowsiness or dizziness
H340 May cause genetic defects
H350 May cause cancer
H361 Suspected of damaging fertility or the unborn child
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H372 Causes damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H412 Harmful to aquatic life with long lasting effects
EUH208 Contains cobalt(II) 2-ethylhexanoate(136-52-7). May produce an allergic reaction
R10 Flammable
R11 Highly flammable
R20 Harmful by inhalation
R36/38 Irritating to eyes and skin
R43 May cause sensitization by skin contact
R45 May cause cancer
R46 May cause heritable genetic damage
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R62 Possible risk of impaired fertility
R66 Repeated exposure may cause skin dryness or cracking
R67 Vapors may cause drowsiness and dizziness
F Highly flammable
N Dangerous for the environment
Xi Irritant
Xn Harmful
SDS EU (REACH Annex II)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed
or implied including but not limited to any implied warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations
or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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Safety Data Sheet
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 3/13
Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
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SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
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CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
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10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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Safety Data Sheet
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 3/13
Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 4/13
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 5/13
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 6/13
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 8/13
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
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methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
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Safety Data Sheet
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titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
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CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : WHITE VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1794-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see seek medical attention. on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 35 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 26 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 6 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
titanium(IV) oxide
(CAS-No.) 13463-67-7 <= 5 Carc. 2, H351
Aquatic Acute 3, H402
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
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Name Product identifier % GHS-US classification
2-propanol
(CAS-No.) 67-63-0 <= 0.7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove person to fresh air
and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Allow
affected person to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Rinse skin with water/shower. Take off immediately all contaminated clothing. Wash with plenty
of water/ . Wash contaminated clothing before reuse. If skin irritation occurs: wash throughly
for five minutes. seek medical attention. Get medical advice/attention. Specific treatment (see
seek medical attention. on this label).
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: SEEK IMMEDIATE MEDICAL ATTENTION. Get
medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel.
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6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Wear personal protective equipment. Wash hands and other exposed areas with mild soap and
water before eating, drinking or smoking and when leaving work. Provide good ventilation in
process area to prevent formation of vapour. No open flames. No smoking. Use only non-
sparking tools. Use only outdoors or in a well-ventilated area. Avoid breathing DUST, FUMES,
MIST, OR VAPORS. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Do not breathe
dust/fume/gas/mist/vapours/spray. Eliminate all ignition sources if safe to do so.
Hygiene measures : Wash HANDS thoroughly after handling. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Ground/bond
container and receiving equipment. Use explosion-proof electrical, ventilating and lighting
equipment. equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : HEAT SPARKS
OR OPEN FLAMES. Keep in fireproof place. Keep container tightly closed. Store in a well-
ventilated place. Keep cool.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
titanium(IV) oxide (13463-67-7)
ACGIH ACGIH TWA (mg/m ) 10 mg/m
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
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Safety Data Sheet
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talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : off white
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.34
Relative density : <=
Density : 11.15 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
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Safety Data Sheet
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10/10/2019 EN (English) 6/13
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
titanium(IV) oxide (13463-67-7)
LD50 oral rat > 5000 mg/kg bodyweight (OECD 425: Acute Oral Toxicity: Up-and-Down Procedure, Rat,
Female, Experimental value, Oral, 14 day(s))
LC50 inhalation rat (mg/l) > 6.82 mg/l (Other, 4 h, Rat, Male, Experimental value, Inhalation (dust), 14 day(s))
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Safety Data Sheet
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2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
titanium(IV) oxide (13463-67-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Suspected of damaging fertility or the unborn child. Causes damage to organs through
prolonged or repeated exposure. May cause genetic defects. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 8/13
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
titanium(IV) oxide (13463-67-7)
LC50 fish 1 > 100 mg/l (Equivalent or similar to OECD 203, 96 h, Oncorhynchus mykiss, Static system,
Fresh water, Experimental value, Nominal concentration)
ErC50 (algae) 61 mg/l (EPA 600/9-78-018, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, Nominal concentration)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
WHITE VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 9/13
methyl ethyl ketone (78-93-3)
ThOD
2.44 g O /g substance
titanium(IV) oxide (13463-67-7)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD)
Not applicable (inorganic)
ThOD
Not applicable (inorganic)
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
12.3. Bioaccumulative potential
WHITE VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
titanium(IV) oxide (13463-67-7)
Bioaccumulative potential Not bioaccumulative.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 10/13
titanium(IV) oxide (13463-67-7)
Ecology - soil Low potential for mobility in soil.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to approved disposal site.
Additional information : Handle empty containers with care because residual vapours are flammable.
Ecology - waste materials : Avoid release to the environment.
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
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Safety Data Sheet
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10/10/2019 EN (English) 11/13
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
titanium(IV) oxide (13463-67-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
WHITE VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 12/13
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
titanium(IV) oxide (13463-67-7)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
titanium(IV) oxide (13463-67-7)
Listed on IARC (International Agency for Research on Cancer)
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
titanium(IV) oxide(13463-67-7) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
WHITE VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 13/13
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H402 Harmful to aquatic life
H411 Toxic to aquatic life with long lasting effects.
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : BLACK VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1702-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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Safety Data Sheet
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see supplemental first aid instruction on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 37 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 23 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
2-propanol
(CAS-No.) 67-63-0 <= 1 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
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Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/ . Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this
label). Rinse skin with water/shower. Take off immediately all contaminated clothing.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no
smoking.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
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6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapour. No open flames. No smoking. Use
only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapours/spray.
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Eliminate all ignition sources if safe to do so. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container
and receiving equipment. Use only non-sparking tools. Take precautionary measures against
static discharge. Flammable vapours may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof
electrical/ventilating/lighting equipment. Ground/bond container and receiving equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof
place. Store in a well-ventilated place. Keep cool. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
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8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Black
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.33
Relative density : <= 1.4
Density : 11.04 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
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SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below. Highly flammable liquid and vapour.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of
ignition.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
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Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
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cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
BLACK VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
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12.3. Bioaccumulative potential
BLACK VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable. Flammable
vapours may accumulate in the container.
Ecology - waste materials : Avoid release to the environment.
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SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Not applicable
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
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Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
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15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects.
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 13/13
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 10/10/2019
10/10/2019 EN (English) Page 1
SECTION 1: Identification
1.1. Identification
Product form : Mixture
Trade name : BLACK VINYL ESTER PRIMER
CAS-No. : mixture
Product code : 1702-006
Formula : na
1.2. Recommended use and restrictions on use
Use of the substance/mixture : COATING
1.3. Supplier
Dura Technologies, Inc.
2720 South Willow Avenue #A
Bloomington, CA 92316
909-546-1162
ChemTrec US: 800.424.9300
ChemTrec Int: +1 70 3527 3887
1.4. Emergency telephone number
Emergency number : ChemTrec US: 800.424.9300 Int: +1 70 3527 3887
CHEMTREC: 1-800-424-9300
SECTION 2: Hazard(s) identification
2.1. Classification of the substance or mixture
GHS-US classification
Flammable liquids, Category 2 H225 Highly flammable liquid and vapour.
Skin corrosion/irritation, Category 2 H315 Causes skin irritation.
Serious eye damage/eye irritation, Category 2 H319 Causes serious eye irritation.
Skin sensitisation, Category 1 H317 May cause an allergic skin reaction.
Carcinogenicity, Category 2 H351 Suspected of causing cancer.
Reproductive toxicity, Category 2 H361 Suspected of damaging fertility or the unborn child.
Specific target organ toxicity Single exposure, Category 3, Respiratory tract
irritation
H335 May cause respiratory irritation.
Specific target organ toxicity Repeated exposure, Category 1 H372 Causes damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment Acute Hazard, Category 2 H401 Toxic to aquatic life
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements
GHS US labelling
Hazard pictograms (GHS US) :
Signal word (GHS US) : Danger
Hazard statements (GHS US) : H225 – Highly flammable liquid and vapour.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H335 – May cause respiratory irritation.
H351 – Suspected of causing cancer.
H361 – Suspected of damaging fertility or the unborn child.
H372 – Causes damage to organs through prolonged or repeated exposure.
H401 – Toxic to aquatic life
Precautionary statements (GHS US) : P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
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Safety Data Sheet
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P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 – Keep container tightly closed.
P240 – Ground/Bond container and receiving equipment
P241 – Use explosion-proof electrical;lighting;ventilating equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P260 – Do not breathe dust, mist, fume, vapours, spray.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 – Wash exposed area. thoroughly after handling.
P270 – Do not eat, drink or smoke when using this product.
P271 – Use only outdoors or in a well-ventilated area.
P272 – Contaminated work clothing must not be allowed out of the workplace
P273 – Avoid release to the environment.
P280 – Wear eye protection;protective clothing.
P302+P352 – If on skin: Wash with plenty of water/
P303+P361+P353 – If on skin (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower
P304+P340 – If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P308+P313 – If exposed or concerned: Get medical advice/attention.
P312 – Call a poison center/doctor/ if you feel unwell
P314 – Get medical advice/attention if you feel unwell.
P321 – Specific treatment (see supplemental first aid instruction on this label)
P332+P313 – If skin irritation occurs: Get medical advice/attention.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 – If eye irritation persists: Get medical advice/attention.
P362+P364 – Take off contaminated clothing and wash it before reuse.
P363 – Wash contaminated clothing before reuse.
P370+P378 – In case of fire: Use carbon dioxide (CO2), dry chemical powder, foam to
extinguish.
P403+P233 – Store in a well-ventilated place. Keep container tightly closed.
P403+P235 – Store in a well-ventilated place. Keep cool.
P405 – Store locked up.
P501 – Dispose of contents/container to in accordance with local, state, and national
regulations.
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS-US classification
talc
(CAS-No.) 14807-96-6 <= 37 Carc. 2, H351
styrene, inhibited
(CAS-No.) 100-42-5 <= 23 Flam. Liq. 3, H226
Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Inhalation:vapour), H332
Skin Irrit. 2, H315
Eye Irrit. 2A, H319
Carc. 2, H351
Repr. 2, H361
STOT SE 3, H335
STOT RE 1, H372
Aquatic Acute 2, H401
methyl ethyl ketone
(CAS-No.) 78-93-3 <= 7 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
2-propanol
(CAS-No.) 67-63-0 <= 1 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
cobalt(II) 2-ethylhexanoate
(CAS-No.) 136-52-7 <= 0.9 Eye Irrit. 2, H319
Skin Sens. 1, H317
Carc. 2, H351
Aquatic Acute 1, H400
Aquatic Chronic 2, H411
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 3/13
Full text of hazard classes and H-statements : see section 16
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. Suspected of causing cancer. IF
exposed or concerned: Get medical advice/attention.
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow affected person to
breathe fresh air. Allow the victim to rest. Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/ . Wash contaminated clothing before reuse. If skin irritation occurs:
Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this
label). Rinse skin with water/shower. Take off immediately all contaminated clothing.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison
center or a doctor if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures
5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Sand. Water spray. Dry powder. Foam. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
Reactivity in case of fire : No reactivity hazard other than the effects described in sub-sections below.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire fighting water from entering the environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do
not attempt to take action without suitable protective equipment. Self-contained breathing
apparatus. Complete protective clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No
smoking.
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective goggles. Protective clothing.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. No open flames, no sparks, and no
smoking.
6.1.2. For emergency responders
Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with
proper protection. For further information refer to section 8: "Exposure controls/personal
protection".
Emergency procedures : Ventilate area.
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 4/13
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Dam up the liquid spill. Contain released product, pump into suitable containers.
Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
Notify authorities if product enters sewers or public waters.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands and other exposed areas with
mild soap and water before eating, drinking or smoking and when leaving work. Provide good
ventilation in process area to prevent formation of vapour. No open flames. No smoking. Use
only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapours/spray.
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Eliminate all ignition sources if safe to do so. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container
and receiving equipment. Use only non-sparking tools. Take precautionary measures against
static discharge. Flammable vapours may accumulate in the container. Use explosion-proof
equipment. Wear personal protective equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling. Do not eat, drink or smoke when
using this product. Always wash hands after handling the product.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Use explosion-proof
electrical/ventilating/lighting equipment. Ground/bond container and receiving equipment.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep in fireproof
place. Store in a well-ventilated place. Keep cool. Keep container tightly closed.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight. Heat sources.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
styrene, inhibited (100-42-5)
ACGIH ACGIH TWA (ppm) 20 ppm
ACGIH ACGIH STEL (ppm) 40 ppm
cobalt(II) 2-ethylhexanoate (136-52-7)
Not applicable
methyl ethyl ketone (78-93-3)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 300 ppm
2-propanol (67-63-0)
ACGIH ACGIH TWA (ppm) 200 ppm
ACGIH ACGIH STEL (ppm) 400 ppm
talc (14807-96-6)
ACGIH ACGIH TWA (mg/m ) 2 mg/m (Respirable fraction. The value is for
particulate matter containing no asbestos and < 1%
crystalline silica)
0.1 fibers/cm (Respirable fibers: length > 5 m; aspect
ratio 3:1, as determined by the membrane filter
method at 400-450X magnification (4-mm objective),
using phase-contrast illumination)
BLACK VINYL ESTER PRIMER
Safety Data Sheet
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10/10/2019 EN (English) 5/13
8.2. Appropriate engineering controls
Appropriate engineering controls : Ensure exposure is below occupational exposure limits (where available). Ensure good
ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Personal protective equipment:
Avoid all unnecessary exposure.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses. Safety glasses
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Wear appropriate mask
Other information:
Do not eat, drink or smoke during use.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Black
Odour : characteristic
Odour threshold : No data available
pH : No data available
Melting point : Not applicable
Freezing point : No data available
Boiling point : >= 79.4 C
Flash point : 13 – 16 C
Relative evaporation rate (butylacetate=1) : No data available
Flammability (solid, gas) : Highly flammable liquid and vapour.
Vapour pressure : No data available
Relative vapour density at 20 C : 1.33
Relative density : <= 1.4
Density : 11.04 g/l
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive limits : No data available
Explosive properties : No data available
Oxidising properties : No data available
9.2. Other information
No additional information available
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 6/13
SECTION 10: Stability and reactivity
10.1. Reactivity
No reactivity hazard other than the effects described in sub-sections below. Highly flammable liquid and vapour.
10.2. Chemical stability
Polymerization can result in formation of solid deposits, even in vapour space. Highly flammable liquid and vapour. May form flammable/explosive
vapour-air mixture.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures. Open flame. Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of
ignition.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
fume. Carbon monoxide. Carbon dioxide. May release flammable gases.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
styrene, inhibited (100-42-5)
LD50 oral rat 5000 mg/kg (Rat; Literature study; >6000 mg/kg bodyweight; Rat; Weight of evidence)
LD50 dermal rat > 2000 mg/kg bodyweight (OECD 402: Acute Dermal Toxicity, 24 h, Rat, Male / female,
Experimental value, Dermal)
LD50 dermal rabbit 5010 mg/kg (Rabbit; Literature study)
LC50 inhalation rat (mg/l) 11.8 mg/l air (4 h, Rat, Inconclusive, insufficient data, Inhalation (vapours))
LC50 inhalation rat (ppm) 2770 ppm/4h (Rat; Literature study)
ATE US (oral) 5000 mg/kg bodyweight
ATE US (dermal) 5010 mg/kg bodyweight
ATE US (gases) 2770 ppmv/4h
ATE US (vapours) 11 mg/l/4h
ATE US (dust,mist) 1.5 mg/l/4h
cobalt(II) 2-ethylhexanoate (136-52-7)
LD50 oral rat 3129 mg/kg bodyweight (Rat; OECD 425: Acute Oral Toxicity: Up-and-Down Procedure;
Experimental value)
LD50 dermal rat > 2000 mg/kg bodyweight (Rat; Weight of evidence; OECD 402: Acute Dermal Toxicity)
ATE US (oral) 3129 mg/kg bodyweight
methyl ethyl ketone (78-93-3)
LD50 oral rat 2193 mg/kg bodyweight (Equivalent or similar to OECD 423, Rat, Male / female, Read-across,
Oral)
LD50 dermal rabbit > 10 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Male, Experimental value,
Dermal)
ATE US (oral) 2193 mg/kg bodyweight
2-propanol (67-63-0)
LD50 oral rat 5840 mg/kg bodyweight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14
day(s))
LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14
day(s))
LC50 inhalation rat (ppm) > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male / female, Experimental value,
Inhalation (vapours), 14 day(s))
ATE US (oral) 5840 mg/kg bodyweight
ATE US (dermal) 16400000 mg/kg bodyweight
Skin corrosion/irritation : Causes skin irritation.
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Safety Data Sheet
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Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
styrene, inhibited (100-42-5)
IARC group 2B – Possibly carcinogenic to humans
National Toxicology Program (NTP) Status Reasonably anticipated to be Human Carcinogen
cobalt(II) 2-ethylhexanoate (136-52-7)
IARC group 2B – Possibly carcinogenic to humans
2-propanol (67-63-0)
IARC group 3 – Not classifiable
talc (14807-96-6)
IARC group 3 – Not classifiable, 2B – Possibly carcinogenic to humans
Reproductive toxicity : Suspected of damaging fertility or the unborn child.
STOT-single exposure : May cause respiratory irritation.
styrene, inhibited (100-42-5)
STOT-single exposure May cause respiratory irritation.
methyl ethyl ketone (78-93-3)
STOT-single exposure May cause drowsiness or dizziness.
2-propanol (67-63-0)
STOT-single exposure May cause drowsiness or dizziness.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.
styrene, inhibited (100-42-5)
STOT-repeated exposure Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard : Not classified
Viscosity, kinematic : No data available
Potential adverse human health effects and
symptoms
: Harmful if inhaled.
Symptoms/effects : Causes damage to organs through prolonged or repeated exposure. May cause genetic
defects. Suspected of damaging fertility or the unborn child. Causes damage to organs.
Symptoms/effects after inhalation : May cause respiratory irritation. Danger of serious damage to health by prolonged exposure
through inhalation. Harmful if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
Ecology – general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
styrene, inhibited (100-42-5)
LC50 fish 1 10 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Flow-through
system, Fresh water, Experimental value, GLP)
EC50 Daphnia 1 4.7 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Flow-
through system, Fresh water, Experimental value, GLP)
ErC50 (algae) 4.9 mg/l (EPA OTS 797.1050, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh
water, Experimental value, GLP)
cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 1 46.51 mg/l (LOEC; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 1 0.212 mg/l (NOEC; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
BLACK VINYL ESTER PRIMER
Safety Data Sheet
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cobalt(II) 2-ethylhexanoate (136-52-7)
LC50 fish 2 54.1 mg/l (LC50; ASTM; 96 h; Pimephales promelas; Flow-through system; Fresh water;
Read-across)
EC50 Daphnia 2 0.605 mg/l (LC50; ASTM; 48 h; Ceriodaphnia dubia; Static system; Salt water; Read-across)
Threshold limit algae 1 144 g/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
Threshold limit algae 2 32.2 g/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella
subcapitata; Static system; Fresh water; Read-across)
methyl ethyl ketone (78-93-3)
LC50 fish 1 2993 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Pimephales promelas, Static system,
Fresh water, Experimental value, GLP)
EC50 Daphnia 1 308 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static
system, Fresh water, Experimental value, GLP)
ErC50 (algae) 1972 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata,
Static system, Fresh water, Experimental value, GLP)
2-propanol (67-63-0)
LC50 fish 1 9640 – 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow-
through system, Fresh water, Experimental value, Lethal)
talc (14807-96-6)
LC50 fish 1 > 100 g/l (24 h, Brachydanio rerio, Semi-static system)
12.2. Persistence and degradability
BLACK VINYL ESTER PRIMER (mixture)
Persistence and degradability Not established.
styrene, inhibited (100-42-5)
Persistence and degradability Biodegradable in the soil. Readily biodegradable in water.
Chemical oxygen demand (COD)
2.8 g O /g substance
ThOD
3.07 g O /g substance
BOD (% of ThOD) 0.42 (Literature study)
cobalt(II) 2-ethylhexanoate (136-52-7)
Persistence and degradability Readily biodegradable in water. No (test)data on mobility of the substance available.
methyl ethyl ketone (78-93-3)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. Not established.
Biochemical oxygen demand (BOD)
2.03 g O /g substance
Chemical oxygen demand (COD)
2.31 g O /g substance
ThOD
2.44 g O /g substance
2-propanol (67-63-0)
Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under
anaerobic conditions. No (test)data on mobility of the substance available. Not established.
Biochemical oxygen demand (BOD)
1.19 g O /g substance
Chemical oxygen demand (COD)
2.23 g O /g substance
ThOD
2.4 g O /g substance
talc (14807-96-6)
Persistence and degradability Biodegradability: not applicable.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
BOD (% of ThOD) Not applicable
BLACK VINYL ESTER PRIMER
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12.3. Bioaccumulative potential
BLACK VINYL ESTER PRIMER (mixture)
Bioaccumulative potential Not established.
styrene, inhibited (100-42-5)
BCF fish 1 35.5 (Carassius auratus, Literature study)
Log Pow 2.96 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask
Method, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4).
cobalt(II) 2-ethylhexanoate (136-52-7)
BCF fish 1 1.2 (BCF; 131 days; Seriola quinqueradiata; Static system; Salt water; Read-across)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).
methyl ethyl ketone (78-93-3)
Log Pow 0.3 (Experimental value, OECD 117: Partition Coefficient (n-octanol/water), HPLC method, 40
C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
2-propanol (67-63-0)
Log Pow 0.05 (Weight of evidence approach, 25 C)
Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Not established.
12.4. Mobility in soil
styrene, inhibited (100-42-5)
Surface tension 0.032 N/m (20 C)
Log Koc 2.55 (log Koc, Estimated value)
Ecology - soil Low potential for adsorption in soil.
cobalt(II) 2-ethylhexanoate (136-52-7)
Surface tension 0.064 N/m (20 C; 1 g/l)
methyl ethyl ketone (78-93-3)
Surface tension 0.024 N/m (20 C)
Log Koc 1.53 (log Koc, Calculated value)
Ecology - soil Highly mobile in soil. Slightly harmful to plants.
2-propanol (67-63-0)
Surface tension 0.021 N/m (25 C)
Log Koc 0.185 - 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value)
Ecology - soil Highly mobile in soil.
12.5. Other adverse effects
Other information : Avoid release to the environment.
SECTION 13: Disposal considerations
13.1. Disposal methods
Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions.
Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to hazardous or special waste collection point, in accordance with local,
regional, national and/or international regulation.
Additional information : Handle empty containers with care because residual vapours are flammable. Flammable
vapours may accumulate in the container.
Ecology - waste materials : Avoid release to the environment.
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 10/13
SECTION 14: Transport information
Department of Transportation (DOT)
In accordance with DOT
Transport document description : UN1866 Resin solution, 3, II
UN-No.(DOT) : UN1866
Proper Shipping Name (DOT) : Resin solution
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 3 - Flammable liquid
DOT Packaging Non Bulk (49 CFR 173.xxx) : 173
DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : 149 - When transported as a limited quantity or a consumer commodity, the maximum net
capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to
5 L (1.3 gallons).
383 - Packages containing toy plastic or paper caps for toy pistols described as UN0349,
Articles, explosive, n.o.s. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the
subpart E (labeling) requirements of this part when offered for transportation by motor vehicle,
rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned
in 173.62 of this subchapter, in conformance with the following conditions:
B52 - Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure
relief devices are authorized on DOT 57 portable tanks.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / (1 + a (tr - tf)) Where: tr is the maximum mean bulk
temperature during transport, and tf is the temperature in degrees celsius of the liquid during
filling.
TP8 - A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when
the flash point of the hazardous material transported is greater than 0 C (32 F).
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Quantity Limitations Passenger aircraft/rail
(49 CFR 173.27)
: 5 L
DOT Quantity Limitations Cargo aircraft only (49
CFR 175.75)
: 60 L
DOT Vessel Stowage Location : B - (i) The material may be stowed on deck or under deck on a cargo vessel and on a
passenger vessel carrying a number of passengers limited to not more than the larger of 25
passengers, or one passenger per each 3 m of overall vessel length; and (ii) On deck only on
passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this
section is exceeded.
Emergency Response Guide (ERG) Number : 127
Other information : No supplementary information available.
Transportation of Dangerous Goods
Not applicable
Transport by sea
Transport document description (IMDG) : UN 1866 RESIN SOLUTION, 3, II
UN-No. (IMDG) : 1866
Proper Shipping Name (IMDG) : RESIN SOLUTION
Class (IMDG) : 3 - Flammable liquids
Packing group (IMDG) : II - substances presenting medium danger
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 11/13
Air transport
Transport document description (IATA) : UN 1866 Resin solution, 3, II
UN-No. (IATA) : 1866
Proper Shipping Name (IATA) : Resin solution
Class (IATA) : 3 - Flammable Liquids
Packing group (IATA) : II - Medium Danger
SECTION 15: Regulatory information
15.1. US Federal regulations
styrene, inhibited (100-42-5)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 1000 lb
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Reactive hazard - No
Fire hazard
Delayed (chronic) health hazard
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
methyl ethyl ketone (78-93-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporting requirements of the United States SARA Section 313
Listed on EPA Hazardous Air Pollutant (HAPS)
CERCLA RQ 5000 lb
2-propanol (67-63-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Subject to reporting requirements of United States SARA Section 313
talc (14807-96-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
styrene, inhibited (100-42-5)
Listed on the Canadian DSL (Domestic Substances List)
cobalt(II) 2-ethylhexanoate (136-52-7)
Listed on the Canadian DSL (Domestic Substances List)
methyl ethyl ketone (78-93-3)
Listed on the Canadian DSL (Domestic Substances List)
2-propanol (67-63-0)
Listed on the Canadian DSL (Domestic Substances List)
talc (14807-96-6)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
styrene, inhibited (100-42-5)
Listed on IARC (International Agency for Research on Cancer)
Listed as carcinogen on NTP (National Toxicology Program)
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 12/13
15.3. US State regulations
styrene, inhibited (100-42-5)
U.S. -
California -
Proposition 65
- Carcinogens
List
U.S. - California -
Proposition 65 -
Developmental
Toxicity
U.S. - California -
Proposition 65 -
Reproductive
Toxicity - Female
U.S. - California -
Proposition 65 -
Reproductive Toxicity
- Male
No significant risk level
(NSRL)
Maximum allowable
dose level (MADL)
Yes No No No 27 g/day
Component State or local regulations
styrene, inhibited(100-42-5) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
methyl ethyl ketone(78-93-3) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
talc(14807-96-6) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
2-propanol(67-63-0) U.S. - Massachusetts - Right To Know List; U.S. - New Jersey - Right to Know
Hazardous Substance List; U.S. - Pennsylvania - RTK (Right to Know) List
SECTION 16: Other information
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date : 10/10/2019
Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE
COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and
mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending
Regulation (EC) No 1907/2006.
Other information : None.
Full text of H-statements:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects.
BLACK VINYL ESTER PRIMER
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
10/10/2019 EN (English) 13/13
NFPA health hazard : 2 - Materials that, under emergency conditions, can cause
temporary incapacitation or residual injury.
NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended
solids) that can be ignited under almost all ambient
temperature conditions.
NFPA reactivity : 2 - Materials that readily undergo violent chemical change
at elevated temperatures and pressures.
Hazard Rating
Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature
conditions. Includes flammable liquids with flash points below 73 F and boiling points above
100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC)
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US (GHS HazCom 2012)
To the best of our knowledge this SDS is accurate. The the extent allowed by law, this statement is made in lieu of an other warranties, expressed or implied including but not limited to any implied
warranty of merchantability or fitness for a particular purpose and is in lieu of any other obligations or liability on the part of Dura Technoligies, Inc.
by | Sep 27, 2025
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
1 / 32
SECTION 1. IDENTIFICATION
Trade name
: NOROX
MEC
Manufacturer or supplier’s details
Company name of supplier
: United Initiators, Inc.
Address
: 555 Garden Street
Elyria OH 44035 USA
Telephone
: +1-440-323-3112
Telefax
: +1-440-323-2659
Emergency telephone
: CHEMTREC US (24h): +1-800-424-9300
CHEMTREC WORLD (24h): +1-703-527-3887
E-mail address of person
responsible for the SDS
: cs-initiators.nafta@united-in.com
Recommended use of the chemical and restrictions on use
Recommended use
: polymerization initiators
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR
1910.1200)
Flammable liquids
: Category 4
Organic peroxides
: Type D
Acute toxicity (Oral)
: Category 4
Skin corrosion
: Category 1B
Serious eye damage
: Category 1
Reproductive toxicity
: Category 2
Short-term (acute) aquatic
hazard
: Category 2
GHS label elements
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
2 / 32
Hazard pictograms
:
Signal Word
: Danger
Hazard Statements
: H227 Combustible liquid.
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H361 Suspected of damaging fertility or the unborn child.
H401 Toxic to aquatic life.
Precautionary Statements
:
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/ sparks/ open flames/ hot surfaces.
No smoking.
P220 Keep/Store away from clothing/ strong acids, bases,
heavy metal salts and other reducing substances /combustible
materials.
P234 Keep only in original container.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/ doctor if you feel unwell. Rinse mouth.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P363 Wash contaminated clothing before reuse.
P370 + P378 In case of fire: Use water spray, alcohol-resistant
foam, dry chemical or carbon dioxide to extinguish.
Storage:
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
3 / 32
P405 Store locked up.
P410 Protect from sunlight.
P411 + P235 Store at temperatures not exceeding < 86 F/ <
30 C. Keep cool.
P420 Store away from other materials.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Chemical nature
: Organic Peroxide
Liquid mixture
Components
Chemical name CAS-No. Concentration (% w/w)
dimethyl phthalate 131-11-3
>= 40 – < 45
2-Butanone, peroxide 1338-23-4
>= 25 – < 30
Trimethylpentanediol isobutyrate 6846-50-0
>= 20 – < 25
cyclohexanone, peroxide 12262-58-7
>= 10 – < 15
Butanone 78-93-3
>= 1 – < 5
Hydrogen peroxide 7722-84-1
>= 1 – < 5
Actual concentration is withheld as a trade secret
SECTION 4. FIRST AID MEASURES
General advice
: Take off contaminated clothing and shoes immediately.
Call a physician immediately.
Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and seek medical
advice.
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
4 / 32
Move out of dangerous area.
Show this material safety data sheet to the doctor in
attendance.
Do not leave the victim unattended.
Symptoms of poisoning may appear several hours later.
If inhaled
: Administer oxygen if breathing is difficult or cyanosis is
observed.
Call a physician immediately.
If breathed in, move person into fresh air.
If not breathing, give artificial respiration.
Respiratory tract burning possible if aerosols are inhaled.
Call a physician or poison control center immediately.
If unconscious, place in recovery position and seek medical
advice.
Keep respiratory tract clear.
In case of skin contact
: If symptoms persist, call a physician.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
In case of contact, immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing
and shoes.
Wash contaminated clothing before re-use.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact
: Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If swallowed
: Call a physician immediately.
Rinse mouth thoroughly with water.
Keep respiratory tract clear.
Do NOT induce vomiting.
If symptoms persist, call a physician.
Most important symptoms
and effects, both acute and
delayed
: Harmful if swallowed.
Causes serious eye damage.
Suspected of damaging fertility or the unborn child.
Causes severe burns.
Protection of first-aiders
: First Aid responders should pay attention to self-protection
and use the recommended protective clothing
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
5 / 32
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during fire
fighting
: Risk of explosion if heated under confinement.
Possible emission of gaseous decomposition products may
lead to a dangerous pressure build-up.
Avoid confinement.
Contact with incompatible materials or exposure to
temperatures exceeding SADT may result in a self-
accelerating decomposition reaction with release of flammable
vapors which may auto-ignite.
The product burns violently.
Flash back possible over considerable distance.
Do not allow run-off from fire fighting to enter drains or water
courses.
Vapors may form explosive mixtures with air.
Cool closed containers exposed to fire with water spray.
Specific extinguishing meth-
ods
: Do not use a solid water stream as it may scatter and spread
fire.
Remove undamaged containers from fire area if it is safe to do
so.
Use water spray to cool unopened containers.
Further information : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Use a water spray to cool fully closed containers.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment
for fire-fighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-
tive equipment and emer-
: Follow safe handling advice and personal protective
equipment recommendations.
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
6 / 32
gency procedures
Beware of vapors accumulating to form explosive
concentrations. Vapors can accumulate in low areas.
Use personal protective equipment.
Ensure adequate ventilation.
Remove all sources of ignition.
Never return spills in original containers for re-use.
Treat recovered material as described in the section "Disposal
considerations".
Environmental precautions
: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Contact with incompatible substances can cause
decomposition at or below SADT.
Clear spills immediately.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
To clean the floor and all objects contaminated by this
material, use plenty of water.
Soak up with inert absorbent material.
Isolate waste and do not reuse.
Non-sparking tools should be used.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.
Advice on protection against
fire and explosion
: Take necessary action to avoid static electricity discharge
(which might cause ignition of organic vapors).
Keep away from heat and sources of ignition.
Use only explosion-proof equipment.
Keep away from open flames, hot surfaces and sources of
ignition.
Keep away from combustible material.
Do not spray on a naked flame or any incandescent material.
Advice on safe handling
: Open drum carefully as content may be under pressure.
Protect from contamination.
Do not swallow.
Do not breathe vapors/dust.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Avoid formation of aerosol.
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
7 / 32
Take precautionary measures against static discharges.
Never return any product to the container from which it was
originally removed.
Provide sufficient air exchange and/or exhaust in work rooms.
Avoid confinement.
Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Smoking, eating and drinking should be prohibited in the
application area.
Wash thoroughly after handling.
For personal protection see section 8.
Conditions for safe storage
: Store in original container.
Keep containers tightly closed in a cool, well-ventilated place.
Store in cool place.
Keep in a well-ventilated place.
Contamination may result in dangerous pressure increases -
closed containers may rupture.
Observe label precautions.
Store in accordance with the particular national regulations.
Avoid impurities (e.g. rust, dust, ash), risk of decomposition.
Electrical installations / working materials must comply with
the technological safety standards.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Materials to avoid
: Keep away from combustible materials.
Keep away from strong acids, bases, heavy metal salts and
other reducing substances.
Recommended storage tem-
perature
: < 86 F
< 30 C
Further information on stor-
age stability
: Stable under recommended storage conditions.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control parame-
ters / Permissible
concentration
Basis
dimethyl phthalate 131-11-3 TWA 5 mg/m3 ACGIH
TWA 5 mg/m3 NIOSH REL
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
8 / 32
TWA 5 mg/m3 OSHA Z-1
TWA 5 mg/m3 OSHA P0
2-Butanone, peroxide 1338-23-4 C 0.2 ppm ACGIH
C 0.2 ppm
1.5 mg/m3
NIOSH REL
C 0.7 ppm
5 mg/m3
OSHA P0
Butanone 78-93-3 TWA 200 ppm ACGIH
STEL 300 ppm ACGIH
TWA 200 ppm
590 mg/m3
NIOSH REL
ST 300 ppm
885 mg/m3
NIOSH REL
TWA 200 ppm
590 mg/m3
OSHA Z-1
TWA 200 ppm
590 mg/m3
OSHA P0
STEL 300 ppm
885 mg/m3
OSHA P0
Hydrogen peroxide 7722-84-1 TWA 1 ppm ACGIH
TWA 1 ppm
1.4 mg/m3
NIOSH REL
TWA 1 ppm
1.4 mg/m3
OSHA Z-1
TWA 1 ppm
1.4 mg/m3
OSHA P0
Biological occupational exposure limits
Components CAS-No. Control
parameters
Biological
specimen
Sam-
pling
time
Permissible
concentra-
tion
Basis
Butanone 78-93-3 methyl ethyl
ketone
Urine End of
shift (As
soon as
possible
after
exposure
ceases)
2 mg/l ACGIH
BEI
Engineering measures : Minimize workplace exposure concentrations.
Personal protective equipment
Respiratory protection
: In the case of dust or aerosol formation use respirator with an
approved filter.
Filter type
: ABEK-filter
Use NIOSH approved respiratory protection.
Hand protection
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
9 / 32
Material : butyl-rubber
Break through time : 480 min
Glove thickness : 0.5 mm
Material : Nitrile rubber
Break through time : < 30 min
Glove thickness : 0.4 mm
Remarks
: The data about break through time/strength of material are
standard values! The exact break through time/strength of
material has to be obtained from the producer of the
protective glove. Choose gloves to protect hands against
chemicals depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection
: Ensure that eyewash stations and safety showers are close
to the workstation location.
Please follow all applicable local/national requirements when
selecting protective measures for a specific workplace.
Always wear eye protection when the potential for inadvertent
eye contact with the product cannot be excluded.
Tightly fitting safety goggles
Please wear suitable protective goggles. Also wear face
protection if there is a splash hazard.
Skin and body protection
: Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Additional body garments should be used based upon the
task being performed (e.g., sleevelets, apron, gauntlets,
disposable suits) to avoid exposed skin surfaces.
Wear as appropriate:
Flame retardant antistatic protective clothing.
Protective measures
: The type of protective equipment must be selected according
to the concentration and amount of the dangerous substance
at the specific workplace.
Hygiene measures
: Avoid contact with skin, eyes and clothing.
Keep away from food and drink.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and immediately after handling
the product.
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SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: liquid
Color
: colorless
Odor
: very faint, mint-like
pH
: Not applicable
Melting point/range
: No data available
Boiling point/boiling range
: not determined
Flash point
: > 89 C
Evaporation rate
: No data available
Flammability (solid, gas)
: Not applicable
Self-ignition : The substance or mixture is not classified as self heating. The
substance or mixture is not classified as pyrophoric.
Upper explosion limit / Upper
flammability limit
: No data available
Lower explosion limit / Lower
flammability limit
: No data available
Vapor pressure
: No data available
Relative vapor density
: > 1
Density
: 1.13 g/cm3
Solubility(ies)
Water solubility
: soluble
Partition coefficient: n-
octanol/water
: No data available
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Self-Accelerating decomposi-
tion temperature (SADT)
: 60 C
SADT-Self Accelerating Decomposition Temperature. Lowest
temperature at which the tested package size will undergo a
self-accelerating decomposition reaction.
Viscosity
Viscosity, dynamic
: 33 – 38 mPa.s
Viscosity, kinematic
: not determined
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
Organic peroxide
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Stable under recommended storage conditions.
Heating may cause a fire or explosion.
Chemical stability
: Stable under recommended storage conditions.
No decomposition if stored normally.
Possibility of hazardous reac-
tions
: Vapors may form explosive mixture with air.
Conditions to avoid
: Protect from contamination.
Contact with incompatible substances can cause
decomposition at or below SADT.
Heat, flames and sparks.
Avoid confinement.
Incompatible materials
: Accelerators, strong acids and bases, heavy metals and
heavy metal salts, reducing agents
Hazardous decomposition
products
: Irritant, caustic, flammable, noxious/toxic gases and vapours
can develop in the case of fire and decomposition
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Harmful if swallowed.
Product:
Acute oral toxicity
: Acute toxicity estimate: 1,632 mg/kg
Method: Calculation method
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Acute inhalation toxicity
: Acute toxicity estimate: 5.77 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method
Acute dermal toxicity
: Acute toxicity estimate: > 5,000 mg/kg
Method: Calculation method
Components:
dimethyl phthalate:
Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: (Rat): > 10.4 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Remarks: No mortality observed at this dose.
Acute dermal toxicity
: LD50 (Rabbit): > 12,000 mg/kg
2-Butanone, peroxide:
Acute oral toxicity
: Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
Acute inhalation toxicity
: Acute toxicity estimate: 1.5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Expert judgment
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on data from similar materials
Acute dermal toxicity
: Acute toxicity estimate: 2,500 mg/kg
Method: Expert judgment
Trimethylpentanediol isobutyrate:
Acute oral toxicity
: LD50 (Rat): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute oral tox-
icity
Acute inhalation toxicity
: LCLo (Rat): > 0.12 mg/l
Exposure time: 6 h
Test atmosphere: vapor
Method: Expert judgment
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: No mortality observed at this dose.
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Acute dermal toxicity
: LD50 (Guinea pig): > 2,000 mg/kg
Method: Expert judgment
Assessment: The substance or mixture has no acute dermal
toxicity
cyclohexanone, peroxide:
Acute oral toxicity
: LD50 (Rat, male and female): 1,242 mg/kg
Method: OECD Test Guideline 401
Acute inhalation toxicity
: LC50 (Rat): > 5,000 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Acute dermal toxicity
: Remarks: No data available
Butanone:
Acute oral toxicity
: LD50 (Rat): 2,193 mg/kg
Method: OECD Test Guideline 423
Acute inhalation toxicity
: Remarks: No data available
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg
Method: OECD Test Guideline 402
Remarks: Based on available data, the classification criteria
are not met.
Hydrogen peroxide:
Acute oral toxicity
: LD50 (Rat, male and female): 431 mg/kg
Method: Expert judgment
Assessment: The component/mixture is moderately toxic after
single ingestion.
Acute inhalation toxicity
: Acute toxicity estimate: 1.5 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The component/mixture is moderately toxic after
short term inhalation.
Remarks: Based on harmonised classification in EU regulation
1272/2008, Annex VI
Acute dermal toxicity
: LD50 (Rabbit): 9,200 mg/kg
Remarks: No adverse effect has been observed in acute tox-
icity tests.
Skin corrosion/irritation
Causes severe burns.
Product:
Remarks : Extremely corrosive and destructive to tissue.
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Components:
dimethyl phthalate:
Species : Rabbit
Method : Draize Test
Result : No skin irritation
2-Butanone, peroxide:
Species : Rabbit
Result : Causes burns.
Trimethylpentanediol isobutyrate:
Species : Guinea pig
Exposure time : 24 h
Result : No skin irritation
Remarks : Based on available data, the classification criteria are not met.
cyclohexanone, peroxide:
Species : Rabbit
Result : Causes burns.
Butanone:
Species : Rabbit
Assessment : Repeated exposure may cause skin dryness or cracking.
Method : OECD Test Guideline 404
Result : No skin irritation
Hydrogen peroxide:
Result : Corrosive after 3 minutes or less of exposure
Serious eye damage/eye irritation
Causes serious eye damage.
Product:
Remarks : May cause irreversible eye damage.
Components:
dimethyl phthalate:
Species : Rabbit
Result : No eye irritation
Method : OECD Test Guideline 405
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2-Butanone, peroxide:
Result : Irreversible effects on the eye
Trimethylpentanediol isobutyrate:
Species : Rabbit
Result : No eye irritation
Exposure time : 24 h
cyclohexanone, peroxide:
Species : Rabbit
Result : Irreversible effects on the eye
Method : Draize Test
Butanone:
Species : Rabbit
Result : Eye irritation
Method : OECD Test Guideline 405
Hydrogen peroxide:
Result : Irreversible effects on the eye
Remarks : Hydrogen peroxide (H2O2), 35%
Respiratory or skin sensitization
Skin sensitization
Not classified due to lack of data.
Respiratory sensitization
Not classified due to lack of data.
Components:
dimethyl phthalate:
Species : Mouse
Method : OECD Test Guideline 429
Result : Does not cause skin sensitization.
2-Butanone, peroxide:
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.
Assessment : Harmful if swallowed., Harmful if inhaled.
Trimethylpentanediol isobutyrate:
Species : Guinea pig
Result : Does not cause skin sensitization.
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cyclohexanone, peroxide:
Test Type : Magnusson-Kligman-Test
Method : OECD Test Guideline 406
Result : Weak sensitizer
Remarks : Not classified due to data which are conclusive although insuf-
ficient for classification.
Butanone:
Routes of exposure : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Does not cause skin sensitization.
Germ cell mutagenicity
Not classified due to lack of data.
Components:
dimethyl phthalate:
Genotoxicity in vitro
: Method: OECD Test Guideline 471
Result: negative
Method: OECD Test Guideline 473
Result: negative
Method: OECD Test Guideline 476
Result: positive
Genotoxicity in vivo
: Test Type: Chromosomal aberration
Species: Rat
Application Route: Intraperitoneal
Result: negative
Test Type: Micronucleus test
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
2-Butanone, peroxide:
Genotoxicity in vitro
: Method: OECD Test Guideline 473
Result: negative
Method: OECD Test Guideline 471
Result: negative
Method: OECD Test Guideline 476
Result: negative
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Trimethylpentanediol isobutyrate:
Genotoxicity in vitro
: Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Test Type: Ames test
Method: Regulation (EC) No. 440/2008, Annex, B.13/14
(Ames test)
Result: negative
Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative
cyclohexanone, peroxide:
Genotoxicity in vitro
: Test Type: In vitro mammalian cell gene mutation test
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 476
Result: positive
Test Type: Ames test
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: positive
Genotoxicity in vivo
: Test Type: Chromosomal aberration
Species: Mouse (male and female)
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative
Butanone:
Genotoxicity in vitro
: Method: OECD Test Guideline 471
Result: negative
Method: OECD Test Guideline 476
Result: negative
Method: OECD Test Guideline 473
Result: negative
Genotoxicity in vivo
: Species: Mouse
Application Route: Intraperitoneal
Method: OECD Test Guideline 474
Result: negative
Hydrogen peroxide:
Genotoxicity in vitro
: Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
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positive
Remarks: Information taken from reference works and the
literature.
Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: positive
Remarks: Information taken from reference works and the
literature.
Genotoxicity in vivo
: Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse (male and female)
Method: OECD Test Guideline 474
Result: negative
Remarks: Hydrogen peroxide (H2O2), 35%
Germ cell mutagenicity –
Assessment
: Based on available data, the classification criteria are not met.
Carcinogenicity
Not classified due to lack of data.
Components:
dimethyl phthalate:
Species : Rat
Application Route : Skin contact
Method : OECD Test Guideline 451
Result : negative
Remarks : Based on data from similar materials
2-Butanone, peroxide:
Remarks : This information is not available.
Hydrogen peroxide:
Carcinogenicity – Assess-
ment
: Carcinogenicity classification not possible from current data.
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
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Reproductive toxicity
Suspected of damaging fertility or the unborn child.
Components:
dimethyl phthalate:
Effects on fertility
: Species: Rat
Application Route: oral (gavage)
Method: OECD Test Guideline 440
Result: negative
Effects on fetal development
: Species: Rat
Application Route: Ingestion
General Toxicity Maternal: NOAEL: 840 mg/kg body weight
Developmental Toxicity: NOAEL: 3,570 mg/kg body weight
Method: OECD Test Guideline 414
2-Butanone, peroxide:
Effects on fertility
: Species: Rat
Application Route: oral (gavage)
General Toxicity Parent: NOAEL: 50 mg/kg body weight
Method: OECD Test Guideline 421
Result: negative
Trimethylpentanediol isobutyrate:
Effects on fetal development
: Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 414
Result: negative
Reproductive toxicity – As-
sessment
: Suspected of damaging fertility or the unborn child., Some
evidence of adverse effects on sexual function and fertility,
and/or on development, based on animal experiments.
cyclohexanone, peroxide:
Effects on fetal development
: Species: Rat, male and female
Application Route: oral (gavage)
General Toxicity Maternal: NOEL: 200 mg/kg bw/day
Method: OECD Test Guideline 422
Butanone:
Effects on fertility
: Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: NOAEL: 10,000 mg/l
General Toxicity F1: NOAEL: 10,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials
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Species: Rat
Application Route: oral (drinking water)
General Toxicity Parent: LOAEL: 20,000 mg/l
Method: OECD Test Guideline 416
Remarks: Based on data from similar materials
Effects on fetal development
: Species: Rat
Application Route: Inhalation
General Toxicity Maternal: NOAEC: ca. 1,002 mg/kg body
weight
Teratogenicity: NOAEC Parent: ca. 1,002 mg/kg body weight
Method: OECD Test Guideline 414
Result: negative
Hydrogen peroxide:
Reproductive toxicity – As-
sessment
: No data available
STOT-single exposure
Not classified due to lack of data.
Components:
cyclohexanone, peroxide:
Assessment : May cause respiratory irritation.
Butanone:
Assessment : May cause drowsiness or dizziness.
Hydrogen peroxide:
Target Organs : Respiratory Tract
Assessment : May cause respiratory irritation.
STOT-repeated exposure
Not classified due to lack of data.
Components:
Hydrogen peroxide:
Remarks : No data available
Repeated dose toxicity
Components:
dimethyl phthalate:
Species : Rat
NOAEL : 770 mg/kg
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Application Route : Oral
Exposure time : 16 w
Method : OECD Test Guideline 408
2-Butanone, peroxide:
Species : Rat
NOAEL : 200 mg/kg
Application Route : oral (gavage)
Exposure time : 28 d
Method : OECD Test Guideline 407
Repeated dose toxicity –
Assessment
: Harmful if swallowed., Harmful if inhaled.
cyclohexanone, peroxide:
Species : Rat, male and female
NOAEL : 200 mg/kg bw/day
Application Route : oral (gavage)
Method : OECD Test Guideline 422
Hydrogen peroxide:
Species : Mouse, female
NOAEL : 37 mg/kg
Application Route : oral (drinking water)
Exposure time : 90 d
Remarks : Hydrogen peroxide (H2O2), 35%
Species : Mouse, males
NOAEL : 26 mg/kg
Application Route : oral (drinking water)
Exposure time : 90
Remarks : Hydrogen peroxide (H2O2), 35%
Aspiration toxicity
Not classified due to lack of data.
Components:
dimethyl phthalate:
No aspiration toxicity classification
Trimethylpentanediol isobutyrate:
Not classified due to data which are conclusive although insufficient for classification.
Hydrogen peroxide:
Based on available data, the classification criteria are not met.
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Further information
Product:
Remarks : No data available
Components:
dimethyl phthalate:
Remarks : No data available
Trimethylpentanediol isobutyrate:
Remarks : No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
dimethyl phthalate:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 39 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: LC50 (Daphnia magna (Water flea)): > 52 mg/l
Exposure time: 48 h
Toxicity to algae/aquatic
plants
: EC50 (Desmodesmus subspicatus (green algae)): 260 mg/l
Exposure time: 72 h
Toxicity to fish (Chronic tox-
icity)
: NOEC (Oncorhynchus mykiss (rainbow trout)): 11 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210
LOEC (Oncorhynchus mykiss (rainbow trout)): 24 mg/l
Exposure time: 102 d
Method: OECD Test Guideline 210
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: NOEC (Daphnia magna (Water flea)): 9.6 mg/l
Exposure time: 21 d
LOEC (Daphnia magna (Water flea)): 23 mg/l
Exposure time: 21 d
Toxicity to microorganisms
: EC50: 4,100 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209
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2-Butanone, peroxide:
Toxicity to fish
: LC50 (Poecilia reticulata (guppy)): 44.2 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
NOEC (Poecilia reticulata (guppy)): 18 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 39 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
NOEC (Daphnia magna (Water flea)): 26.7 mg/l
Method: OECD Test Guideline 202
Toxicity to algae/aquatic
plants
: EC50 (Pseudokirchneriella subcapitata (green algae)): 5.6
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
NOEC (Pseudokirchneriella subcapitata (green algae)): 2.1
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to microorganisms
: EC50 (Bacteria): 48 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209
Trimethylpentanediol isobutyrate:
Toxicity to fish
: NOEC (Fish): >= 6 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia): >= 1.46 mg/l
Exposure time: 48 h
NOEC (Daphnia): 0.7 mg/l
Exposure time: 21 d
Toxicity to algae/aquatic
plants
: EC50 (Chlorella pyrenoidosa): > 7.49 mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: LOEC (Daphnia magna (Water flea)): 0.7 mg/l
Exposure time: 21 d
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Ecotoxicology Assessment
Acute aquatic toxicity
: This product has no known ecotoxicological effects.
Chronic aquatic toxicity
: Harmful to aquatic life with long lasting effects.
cyclohexanone, peroxide:
Toxicity to fish
: LC50 (Poecilia reticulata (guppy)): 47.7 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 18 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae/aquatic
plants
: ErC50 (Raphidocelis subcapitata (freshwater green alga)): 1.7
mg/l
Exposure time: 72 h
Method: OECD Test Guideline 201
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: Remarks: No data available
Toxicity to microorganisms
: EC10 (Bacteria): 11.1 mg/l
Exposure time: 0.5 h
Method: OECD Test Guideline 209
Ecotoxicology Assessment
Chronic aquatic toxicity
: This product has no known ecotoxicological effects.
Butanone:
Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 2,993 mg/l
Exposure time: 96 h
Method: OECD Test Guideline 203
Toxicity to daphnia and other
aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 308 mg/l
Exposure time: 48 h
Method: OECD Test Guideline 202
Toxicity to algae/aquatic
plants
: EC50 (Pseudokirchneriella subcapitata (green algae)): 2,029
mg/l
Exposure time: 96 h
Method: OECD Test Guideline 201
Toxicity to microorganisms
: NOEC (Pseudomonas putida): 1,150 mg/l
Exposure time: 16 h
Method: DIN 38 412 Part 8
Hydrogen peroxide:
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Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): 16.4 mg/l
Exposure time: 96 h
Toxicity to daphnia and other
aquatic invertebrates
: LC50 (Daphnia pulex (Water flea)): 2.4 mg/l
Exposure time: 48 h
Toxicity to algae/aquatic
plants
: EC50 (Skeletonema costatum (marine diatom)): 1.38 mg/l
Exposure time: 72 h
NOEC (Skeletonema costatum (marine diatom)): 0.63 mg/l
Exposure time: 72 h
Toxicity to daphnia and other
aquatic invertebrates (Chron-
ic toxicity)
: NOEC (Daphnia magna (Water flea)): 0.63 mg/l
Exposure time: 21 d
Toxicity to microorganisms
: EC50 (activated sludge): > 1,000 mg/l
Exposure time: 3 h
Method: OECD Test Guideline 209
Persistence and degradability
Components:
dimethyl phthalate:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301E
2-Butanone, peroxide:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301D
Trimethylpentanediol isobutyrate:
Biodegradability
: Result: rapidly biodegradable
Exposure time: 28 d
Method: OECD Test Guideline 301B
cyclohexanone, peroxide:
Biodegradability
: aerobic
Biochemical oxygen demand
Result: Readily biodegradable.
Biodegradation: 92 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Butanone:
Biodegradability
: Result: Readily biodegradable.
Method: OECD Test Guideline 301D
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Hydrogen peroxide:
Biodegradability
: Result: Readily biodegradable.
Bioaccumulative potential
Components:
dimethyl phthalate:
Bioaccumulation
: Bioconcentration factor (BCF): 57
Method: OECD Test Guideline 305
Partition coefficient: n-
octanol/water
: log Pow: 1.54
2-Butanone, peroxide:
Partition coefficient: n-
octanol/water
: log Pow: < 0.3 (25 C / 25 C)
Trimethylpentanediol isobutyrate:
Bioaccumulation
: Species: Fish
Bioconcentration factor (BCF): 1.95
Partition coefficient: n-
octanol/water
: log Pow: 4.91 (25 C / 25 C)
cyclohexanone, peroxide:
Partition coefficient: n-
octanol/water
: log Pow: 1.26
Butanone:
Partition coefficient: n-
octanol/water
: log Pow: 0.3 (40 C / 40 C)
Hydrogen peroxide:
Partition coefficient: n-
octanol/water
: log Pow: -1.57 (20 C / 20 C)
Remarks: Information refers to the main ingredient.
Calculation
Mobility in soil
No data available
Other adverse effects
Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
27 / 32
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological infor-
mation
: An environmental hazard cannot be excluded in the event of
unprofessional handling or disposal.
Toxic to aquatic life.
Components:
dimethyl phthalate:
Additional ecological infor-
mation
: No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of wastes in an approved waste disposal facility.
The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Contaminated packaging
: Dispose of in accordance with local regulations.
Clean container with water.
Dispose of contents/ container to an approved waste disposal
plant.
Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International Regulations
UNRTDG
UN number : UN 3105
Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID
(METHYL ETHYL KETONE PEROXIDE(S) ,
CYCLOHEXANONE PEROXIDE(S) )
Class : 5.2
Packing group : Not assigned by regulation
Labels : 5.2
Environmentally hazardous : no
IATA-DGR
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
28 / 32
UN/ID No. : UN 3105
Proper shipping name : Organic peroxide type D, liquid
(Methyl ethyl ketone peroxide(s), Cyclohexanone peroxide(s))
Class : 5.2
Packing group : Not assigned by regulation
Labels : Organic Peroxides, Keep Away From Heat
Packing instruction (cargo
aircraft)
: 570
Packing instruction (passen-
ger aircraft)
: 570
IMDG-Code
UN number : UN 3105
Proper shipping name : ORGANIC PEROXIDE TYPE D, LIQUID
(METHYL ETHYL KETONE PEROXIDE(S),
CYCLOHEXANONE PEROXIDE(S) )
Class : 5.2
Packing group : Not assigned by regulation
Labels : 5.2
EmS Code : F-J, S-R
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 3105
Proper shipping name : Organic peroxide type D, liquid
(Methyl ethyl ketone peroxide, <=25%, Cyclohexanone perox-
ide, <=10%)
Class : 5.2
Packing group : Not assigned by regulation
Labels : ORGANIC PEROXIDE
ERG Code : 145
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
SECTION 15. REGULATORY INFORMATION
CERCLA Reportable Quantity
Components CAS-No. Component RQ
(lbs)
Calculated product RQ
(lbs)
2-Butanone, peroxide 1338-23-4 10 40
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
29 / 32
Butanone 78-93-3 5000 5000 (D035)
Butanone 78-93-3 100 100 (F005)
SARA 304 Extremely Hazardous Substances Reportable Quantity
Listed substances in the product are at low enough levels to not be expected to exceed the RQ
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
Components CAS-No. Component TPQ (lbs)
Hydrogen peroxide 7722-84-1 1000
SARA 311/312 Hazards
: Flammable (gases, aerosols, liquids, or solids)
Organic peroxides
Acute toxicity (any route of exposure)
Reproductive toxicity
Skin corrosion or irritation
Serious eye damage or eye irritation
SARA 313
: The following components are subject to reporting levels
established by SARA Title III, Section 313:
dimethyl
phthalate
131-11-3
Clean Air Act
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 112 (40 CFR
61):
dimethyl phthalate 131-11-3
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).
The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermedi-
ate or Final VOC's (40 CFR 60.489):
Butanone 78-93-3
Clean Water Act
This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act,
Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section
307
dimethyl phthalate 131-11-3
This product contains the following priority pollutants related to the U.S. Clean Water Act:
dimethyl phthalate 131-11-3
International Regulations
Gefahrgruppe nach TRGS 741: Ib (German regulatory requirements)
The ingredients of this product are reported in the following inventories:
TCSI (TW)
:
On the inventory, or in compliance with the inventory
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
30 / 32
TSCA (US)
:
All substances listed as active on the TSCA inventory
AIIC (AU)
:
All components are listed on the inventory, regulatory
obligations/restrictions apply
DSL (CA)
:
All components of this product are on the Canadian DSL
ENCS (JP)
:
On the inventory, or in compliance with the inventory
ISHL (JP)
:
On the inventory, or in compliance with the inventory
KECI (KR)
:
On the inventory, or in compliance with the inventory
PICCS (PH)
:
On the inventory, or in compliance with the inventory
IECSC (CN)
:
On the inventory, or in compliance with the inventory
TECI (TH)
:
On the inventory, or in compliance with the inventory
TSCA list
No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification requirements.
SECTION 16. OTHER INFORMATION
Further information
This material safety datasheet only contains information relating to safety and does not replace
any product information or product specification.
These safety instructions also apply to empty packaging which may still contain product residues.
The hazards on the label also apply to residues in the container.
Sources of key data used to
compile the Material Safety
Data Sheet
: Internal technical data, data from raw material SDSs, OECD
eChem Portal search results and European Chemicals Agen-
cy, http://echa.europa.eu/
Revision Date : 04/22/2024
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. Table Z-1-A Limits for Air Contaminants (1989 vacated
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
31 / 32
values)
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
ACGIH / C : Ceiling limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
NIOSH REL / C : Ceiling value not be exceeded at any time.
OSHA P0 / TWA : 8-hour time weighted average
OSHA P0 / STEL : Short-term exposure limit
OSHA P0 / C : Ceiling limit
OSHA Z-1 / TWA : 8-hour time weighted average
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act
(United States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
SAFETY DATA SHEET
according to the OSHA Hazard Communication Standard
NOROX
MEC
Version
1.3
Revision Date:
04/22/2024
SDS Number:
600000000092
Date of last issue: 06/24/2022
Date of first issue: 10/19/2018
32 / 32
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
US / Z8
