by | Sep 27, 2025
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Safety Data Sheet
Issue date 17-Jun-2015 Revision date 20-May-2015 Version 1
1. Identification
Product Identifier
Product name QM 2125
Other means of identification
Recommended use of the chemical and restrictions on use
Recommended use Industrial silicone elastomer.
Application FOR INDUSTRIAL USE ONLY
Details of the Supplier of the Safety Data Sheet
Supplier Manufacturer Address
Quantum Silicones Quantum Silicones
7820 Whitepine Rd 8021 Reycan Rd
Richmond, VA 23237 Richmond, VA 23237
Emergency Telephone Number
Company Phone Number 800-852-3147 (8AM – 5PM EST)
Emergency telephone Chemtrec 1-800-424-9300
2. Hazards Identification
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements _
EMERGENCY OVERVIEW.
The product contains no substances which at their given concentration, are considered to be hazardous to health
Appearance Viscous liquid Physical State Liquid Odor Negligible}
Hazards Not Otherwise Classified (HNOC)
Not Applicable
OTHER INFORMATION
Not Applicable.
3. Composition/information on Ingredients
Substance
Not Applicable
PAGE 1/7
by | Sep 27, 2025
VuuEne LU ReyurauUH [LUy nu. yur euUU [AL Ruy, UNA Hy ao aMeHUGU Ly CUMsoIuH Neyurauun {Uy
2015/830 – United Kingdom (UK)
SAFETY DATA SHEET a
SCOTT BADER
Crestapol 1260
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : Crestapol 1260
Product code : OL170100
Product type : Liquid.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.3 Details of the supplier of the safety data sheet
Scott Bader Co Ltd, |
Wollaston.
Northants
NN297RL
United Kingdom
+44 (0)1933663100
e-mail address of person : SDS@scottbader.com
responsible for this SDS
1.4 Emergency telephone number
Telephone number : +44 1865 407333 (NCEC) 24h
(Hours of operation)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Product definition : Mixture
Classificati i ulation (EC) No. Cc
Flam. Lig. 3, H226
Acute Tox. 4, H332
Skin Irrit. 2, H315,
Eye Irrit. 2, H319
Repr. 2, H361d (Unborn child)
STOT SE 3, H335
STOT RE 1, H372
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
Physical/chemical hazards : Flammable.
Human health hazards : Possible risk of harm to the unborn child. Harmful by inhalation. Harmful: danger of
serious damage to health by prolonged exposure through inhalation. Irritating to eyes
and skin.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements
by | Sep 27, 2025
OUPON SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray Issue Date: 11/17/2024
Polyurethane Foam Kit
Print Date: 05/29/2025
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray Polyurethane Foam Kit
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
EY
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Eye irritation – Category 2A
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Simple Asphyxiant
Label elements
Hazard pictograms
Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 25
by | Sep 27, 2025
il / il
OUPON SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray Issue Date: 03/14/2024
Insulation Foam US
Print Date: 05/29/2025
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray Insulation Foam US
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Acute toxicity – Category 4 – Inhalation
Skin irritation – Category 2
Eye irritation – Category 2B
Respiratory sensitisation – Category 1
Skin sensitisation – Category 1
Specific target organ toxicity – single exposure – Category 3
Specific target organ toxicity – repeated exposure – Category 2 – Inhalation
Simple Asphyxiant
Label elements
Hazard pictograms
Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 20
by | Sep 27, 2025
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SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Print Date: 0810212021
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is impo
the precautions identified in this
appropriate methods or actions.
rtant informationthroughout the document. We expect you to follow
document unless your use conditions would necessitate other
I. IDENTIFICATION
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray Foam Sealant
Recommended use of the chemical and restrictions on use
ldentified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. lf your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Gustomer lnformation Number: 833-338-7668
SDSQ uestion-NA@d u pont. com
EMERGENCY TELEPHONE NUMBER
Z$-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Specific target organ toxicity – repeated exposure – Category 2- Oral
Simple Asphyxiant
Label elements
Hazard pictograms
@rM Trademark of The Dow Chemical Company or an affiliate. DuPont Oval Page 1 of 23
Logo trademark of affiliates of DuPont de Nemours,lnc
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
AF t
o
Signalword: WARNING!
Hazards
Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed
May displace oxygen and cause rapid suffocation.
Preca utionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dusU fume/ gas/ misV vapours/ spray.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
lF ON SKIN: Wash with plenty of soap and water.
lF exposed or concerned: Get medical advice/ attention.
lf skin irritation or rash occurs: Get medical advice/ attention
Wash contaminated clothing before reuse.
Storage
Store locked up.
Protect from sunlight. Store in a well-ventilated place
Disposal
Dispose of contents/ container to an approved waste disposal plant’
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Gomponent CASRN Goncentration
2-Ethylhexanoic acid potassium salt
Tris(‘1 -chloro-2-propyl) phosphate
3164-85-0 >= 1.0 – <= 10.0
oh
>= 10.0 – <= 30.0 %13674-84-5
Page2 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Triethyl phosphate
tra ns- 1 -C hloro-3, 3, 3{rifluoropropene
Polyethylene glycol
Polyester polyol
Diethylene glycol
Dimethylbis((1 -oxoneodecyl)oxy)stannane
78-40-0
102687-65-0
25322-68-3
Not available
111-46-6
68928-76-7
>= ‘1.0 – <= 10.0 %
>= 10.0 – <= 30.0 %
>= 1.0 – < 10.0 %
>= 20.0 – <= 80.0 %
>= 1.0 – < 10.0 %
>= 0.25 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). lf potential for exposure exists refer to Section
B for specific personal protective equipment.
lnhalation: Move person to fresh air. lf not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). lf breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove contaminated clothing immediately. lmmediately wash skin with soap and
plenty of water. Suitable emergency safety shower facility should be available in work area.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reuse. ln the case of skin irritation or allergic reactions see a physician.
Eye contact: ln case of contact, immediately flush eye with plenty of water. Suitable emergency eye
wash facility should be available in work area.
lngestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and lndication of
immediate medical attention and specialtreatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology lnformation.
lndication of any immediate medical attention and specialtreatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. lf breathing is
difficult, oxygen should be administered by qualified personnel. Treatment of exposure should be
directed at the control of symptoms and the clinical condition of the patient.
Page 3 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray lssue Date: 0212312021
Foam Sealant
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption
may occur upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. lsolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. lmmediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological lnformation" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. lf contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. lf this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: lsolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or
poorly ventil-ated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate
area of leak or spill. Confined space entry procedures must be followed before entering the area.
Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety
equipment. For additional information, refer to Section B, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological lnformation.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
Page 4 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Gonditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
1ame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
sO'C (122"F) See Section 10 for more specific information.
Storage stability
Storage Period: 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
lf exposure limits exist, they are listed below. lf no exposure limits are displayed, then no values are
licable
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. lf there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
Component Regulation Type of listing Value
Triethvl phosphate US WEEL TWA 7.45 mg/m3
trans-1 -Ch loro-3, 3, 3-
trifluoropropene
US WEEL TWA 800 ppm
Polyethylene glycol US WEEL TWA aerosol 10 mg/m3
Diethylene glycol US WEEL TWA 10 mg/m3
Dimethylbis((1-
oxoneodecvl)oxy)sta n nane
OSHA Z-1 TWA 0.1 mg/m3 , Tin
ACGIH TWA 0.1 mg/m3 , Tin
Further information: 44: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
ACGIH STEL 0.2 ms/m3 , Tin
Further rn-rnration: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
CAL PEL PEL 0.1 mq/m3 , Tin
Further information: S: Skin
CAL PEL STEL 0.2 Tin
Further information: S: Skin
Page 5 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
lndividual protection measures
Eye/face protection: Use safety glasses (with side shields). Where contact with the liquid is likely,
chemical goggles are recommended.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove
barrier materiils include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled, physical requirements (cuUpuncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. lf there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
poiitive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. ln confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
9. PHYSICAL AND CHEMICAT PROPERTIES
Appearance
Physicalstate
Color
Odor
Odor Threshold
pH
Melting poinUrange
Freezing point
Boiling point (760 mmHg)
Flash point
Evaporation Rate (ButYl Acetate
=1)
Flammability (solid, gas)
Lower explosion limit
Upper explosion limit
Vapor Pressure
Relative Vapor Density (air = 1)
Relative Density (water = 1)
Liquefied gas
yellow
No information available
No data available
No data available
No data available
No datai available
No data available
>200’c (>392’F)
Not available
Not applicable to liquids Not expected to form explosive dust-
air mixtures.
Not applicable
Not applicable
No data available
No data available
No data available
Page 6 of 23
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Water solubility
Partition coefficient: n-
octanol/water
Auto-ignition temperatu re
Decomposition temperature
Kinematic Viscosity
Explosive properties
Oxidizing properties
Molecular weight
Not applicable
No data available
No data available
No test data available
No data available
Not applicableNot explosive
No data available
No data available
NOTE: The physical data presented above are typicalvalues and should not be construed as a
specification.
IO. STABILITY AND REACTIVITY
Reactivity: No data available
Ghemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Will not occur by itself’
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
lncompatible materiats: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
1 I. TOXTCOLOGICAT INFORMATION
Toxicological information appears in this section when such data is available
Acute toxicity
Acute oraltoxicitY
Product test data not available. Refer to component data.
Acute dermaltoxicity
Product test data not available. Refer to component data
Acute inhalation toxicity
PageT of23
Product name: FROTH-PAKTM 60gal REF 1’75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data’
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product test data not available. Refer to component data
Mutagenicity
Product test data not available. Refer to component data
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCING TOXIGOLOGY:
2-Ethvlhexanoic acid potassium salt
Acute oraltoxicitY
Based on information for a similar material
Guideline 401
1D50, Rat, female, 2,043 mg/kg OECD Test
Acute dermal toxicity
Based on information for a similar material: LD50, Rabbit, > 2,000 mg/kg OECD Test
Guideline 402 No deaths occurred at this concentration.
Acute inhalation toxicitY
At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated
material may cause respiratory irritation. Prolonged excessive exposure to mist may cause
adverse effects.
LC50, Rat, 4 Hour, vapour, > 0.14 mg/l No deaths occurred following exposure to a saturated
atmosphere.
Page B of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Skin corrosion/irritation
Brief contact may cause moderate skin irritation with local redness
Effects may be slow to heal.
Serious eye damage/eye irritation
May cause severe eye irritation.
May cause corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
For similar active ingredient(s).
ln animals, effects have been reported on the following organs:
Liver.
Carcinogenicity
No relevant data found
Teratogenicity
For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the
mother. Did not cause birth defects in laboratory animals.
Reproductive toxicity
For similar material(s): ln laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals.
Mutagenicity
For similar material(s): ln vitro genetic toxicity studies were negative. Animalgenetic toxicity
studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
Tris(1 -chloro-2-propvl) phosphate
Acute oraltoxicity
1D50, Rat, male and female, >1,000 mg/kg
Acute dermaltoxicity
1D50, Rabbit, > 5,000 mg/kg
Acute inhalation toxicity
No deaths occurred at this concentration. LC50, Rat, 4 Hour, dusVmist, > 7 mg/l
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Page 9 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
No data available.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Garcinogenicity
No relevant data found
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
No relevant data found.
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Triethvl phosphate
Acute oral toxicity
1D50, Rat, 1,131 mg/kg
Acute dermaltoxicity
1D50, Guinea pig, > 21,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dusUmist, > 2.35 mg/l No deaths occurred at this concentration
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization
Page 10 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
No relevant data found
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Triethyl phosphate is considered to be a weak cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination,
muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils,
blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found
Reproductive toxicity
ln laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
ln vitro genetic toxicity studies were predominantly negative. Animalgenetic toxicity studies
were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
tra ns-1 -Ch loro-3.3.3-trifluoropropene
Acute oraltoxicity
Single dose oral LD50 has not been determined
Acute dermaltoxicity
The dermal LD50 has not been determined
Acute inhalation toxicity
LC50, Rat,4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant
Page 11 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found
Teratogenicity
No relevant data found
Reproductive toxicity
No relevant data found
Mutagenicity
This materialwas not mutagenic in an Ames bacterial assay
Aspiration Hazard
Based on available information, aspiration hazard could not be determined
Polvethvlene qlvcol
Acute oraltoxicity
Typical for this family of materials. 1D50, Rat, > 10,000 mg/kg Estimated
Acute dermaltoxicity
Typical for this family of materials. 1D50, Rabbit, > 20,000 mg/kg
Acute inhalation toxicity
Typicalfor this family of materials. LC50, Rat, 6 Hour, dusVmist, > 2.5 mg/l No deaths
occurred at this concentration.
Skin corrosion/irritation
Prolonged exposure not likely to cause significant skin irritation.
May cause more severe response if skin is abraded (scratched or cut)
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Corneal injury is unlikely.
Sensitization
For this family of materials:
Did not cause allergic skin reactions when tested in humans.
For this family of materials, sensitization studies done in guinea pigs have been negative
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Recent findings of kidney failure and death in burn patients, as well as some studies using
animal burn models, suggest that polyethylene glycol may have been a factor.
Page 12 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
fssue Date: 0212312021
The use of topical applications containing this material may not be appropriate in severely
burned patients.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
Polyethylene glycols did not cause cancer in long-term animal studies.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
ln animal studies, did not interfere with reproduction
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
Diethvlene qlvcol
Acute oral toxicity
ln humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. lngestion of quantities (approximately65 mL(2o2.) fordiethylene
glycol or 100 mL (3 oz.) forethylene glycol) has caused death in humans. May cause nausea
and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney
failure. 1D50, Rat, male, 19,600 mg/kg
Lethal Dose, Human, adult, 2 Ounces Estimated.
Acute dermaltoxicity
1D50, Rabbit, 13,330 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dusVmist, > 4.6 mg/l The LC50 value is greater than the Maximum
Attainable Concentration. No deaths occurred at this concentration,
Skin corrosion/irritation
Prolonged contact is essentially nonirritating to skin
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Corneal injury is unlikely.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Page 13 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
The substance or mixture is not classified as specific target organ toxicant, single exposure
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to
pose a carcinogenic risk to man.
Teratogenicity
Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic,
high doses in animals. Other animal studies have not reproduced birth defects even at much
higher doses that caused severe maternal toxicity.
Reproductive toxicity
Diethylene glycol did not interfere with reproduction in animal studies except at very high
doses.
Mutagenicity
ln vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative
Aspiration Hazard
No aspiration toxicity classification
Dimethvlbis((1 -oxoneodecvlloxv)stan nane
Acute oraltoxicity
1D50, Rat, 892 mg/kg
Acute dermaltoxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact may cause skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight temporary eye irritation
Sensitization
Has caused allergic skin reactions when tested in guinea pigs
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity
Specific Target Organ Systemic Toxicity (Repeated Exposure)
No relevant data found.
Page 14 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Carcinogenicity
No relevant data found
Teratogenicity
No relevant data found
Reproductive toxicity
No relevant data found
Mutagenicity
Not mutagenic in Ames Test
Aspiration Hazard
No aspiration toxicity classification
I 2. ECOLOGICAT INFORMATION
Ecotoxicological information appears in this section when such data is available
Toxicity
2-Ethvlhexanoic acid potassium salt
Acute toxicity to fish
Based on information for a similar material:
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
Tris(1 -chloro-2-propvl) phosphate
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
‘100 mg/L in the most sensitive species tested).
1C50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/|, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mgll, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mgll, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring ,32 mgll
Triethvl phosphate
Acute toxicity to fish
Material is practically nontoxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
Page 15of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
LC50, Leuciscus idus (Golden orfe), static test, 48 Hour,2,140 mg/|, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/|, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72Hour, Growth rate inhibition, 900 mg/|,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/|, OECD 209 Test
tra ns-1 -C h loro-3.3,3-trif luoroprope ne
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/|, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mgll, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae),72Hour, Growth rate,
‘l’15 mg/l
Polvethvlene qlvcol
Acute toxicity to fish
Material is practically nontoxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), statictest,96 Hour, > 10,000 mg/|, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
1C50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Skeletonema costatum (marine diatom),72Hour, Growth rate, > 100 mg/l
Diethvlene qlvcol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 75,200 mg/|,
OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea),24 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
Based on data from similar materials
Page 16 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
EC50, Selenastrum capricornutum (green algae),96 Hour,6,500 – 13,000 mg/l
Toxicity to bacteria
EC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic toxicity to fish
Based on data from similar materials
NOEC, Pimephales promelas (fathead minnow), 7 d,
‘15,380
mgil
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea),21d, > 15,000 mg/l
Dimethvlbis((1-oxon lsfannane
Acute toxicity to aquatic invertebrates
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/|, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72Hour,7.6 mg/|, OECD Test Guideline
201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1.2 mgll, OECD Test
Guideline 201
Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mgll
Persistence and degradability
2-Ethvlhexanoic acid potassium salt
Biodegradability: Based on information for a similar material: Material is expected to be
readily biodegradable. Material is ultimately biodegradable (reaches >70o/o mineralization in
OECD test(s) for inherent biodegradability).
Tris(1 -chloro-2-propvl) phosphate
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability. Material is ultimately biodegradable
(reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
’10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Not applicable
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 3024 or Equivalent
Theoretical Oxygen Demand: 1.17 mglmg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
Page 17 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Atmospheric half-life: 0.24 d
Method: Estimated.
Triethvl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
trans-1 -Ch loro-3.3.3-trif luoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 30’1D
Polvethvlene qlvcol
Biodegradability: Material is readily biodegradable. Passes OECD test(s)for ready
biodegradability.
1O-day Window: Pass
Biodegradation: 85 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 1.67 mg/mg
Diethvlene qlvcol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
1O-day Window: Pass
Biodegradation: 90 – 100
o/o
Exposure time: 20 d
Method: OECD Test Guideline 301A or Equivalent
1O-day Window: Not applicable
Biodegradation: 82 – 98 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Theoretical Oxygen Demand: 1.51 mg/mg
Dimethvlbis((1 -oxoneodecvl)oxv)stan na ne
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 3018 or Equivalent
Bioaccumulative potential
Page 1B of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
2-Ethvlhexanoic acid potassium salt
Bioaccumulation: Based on information for a similar material: Bioconcentration potential is
low (BCF < 100 or Log Pow < 3).
Tris(1 -chloro-2-propvl) phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Pa rtition coefficient: n-octanol/water( log Pow) : 2. 59 Measu red
Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured
Triethvl ohosnhate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3)
Partition coefficient: n-octanol/water(log Pow): 0.80 Measured
trans-1-Chloro-3.3.3-f rifluoronrotrene
Bioaccumulation: No relevant data found
Polvethvlene glvcol
Partition coefficient: n-octanol/water(log Pow): -0.698 Pow: 0.2 at 30 "C
Diethvlene qlvcol
Bioaccumulation: Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 'C
Bloconcentration factor (BCF): 100 Fish Measured
Dimethvlbis((1 -oxoneodecvlloxv)stannane
Partition coefficient: n-octanol/water(log Pow): 5.503
Mobility in soil
2-Ethvlhexanoic acid potassium salt
Based on information for a similar material:
Potential for mobility in soil is very high (Koc between 0 and 50)
Tris(1 -chloro-2-propvl) phosphate
Potential for mobility in soil is slight (Koc betwebn 2000 and 5000)
Partition coefficient (Koc): 1300 Estimated.
Triethvl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): 48 Estimated.
tra ns-1 -Chloro-3.3.3-triflu oropropene
No relevant data found.
Polvethvlene qlvcol
No relevant data found
Diethvlee olvcol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Page 19 of23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Partition coefficient (Koc): < 1 Estimated
Dimethvlbis((1 -oxoneodecvl)oxv)stan nane
No relevant data found.
I 3. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED lN MSDS SECTION: Composition lnformation. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. lncinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage lnformation, MSDS Section 7 Stability & Reactivity
lnformation, MSDS Sectionl0 Regulatory lnformation, MSDS Section 15
I 4. TRANSPORT INFORMATION
DOT
Proper shipping name
UN number
Glass
Packing group
Chemical under pressure, n.o.s.(lnert Gases)
uN 3500
2.2
Classification for SEA transport (lMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S.(lnert Gases)
UN number UN 3500
Glass 2.2
Packing group
Marine pollutant No
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or ll
of MARPOL 73178 and the
IBG or IGC Gode
Classification for Al R transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(lnert Gases)
UN number UN 3500
Class 2.2
Packing group
Page20 ol 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. lt is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
I 5. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title lll(Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Reproductive toxicity
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title lll (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title lll, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
This material does not contain any components with a CERCLA RQ.
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components
Diethylene glycol
CASRN
111-46-6
Galifornia Prop.65
This product contains a chemical that is at or below California Propositions 65's "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.
United States TSCA lnventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S
Toxic Substances ControlAct (TSCA) Chemical Substance lnventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
Page 21 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
Health Flammability
Physical
Hazard
2* 1 3
*
= Chronic Effects (See Hazards ldentification)
Revision
ldentification Number: 12069399 I A749 / lssue Dale:0212312021 lVersion: 1.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
nd
Full text of other abbreviations
AllC - Australian lnventory of lndustrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German lnstitute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials ldentification System; IARC - lnternational
Agency for Research on Cancer; IATA - lnternational Air Transport Association; IBC - lnternational
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; lC50 - Half
maximal inhibitory concentration; ICAO - lnternational CivilAviation Organization; IECSC - lnventory of
Existing Chemical Substances in China; IMDG - lnternational Maritime Dangerous Goods; IMO -
lnternational Maritime Organization; ISHL - lndustrial Safety and Health Law (Japan); ISO
lnternational Organisation for Standardization; KECI - Korea Existing Chemicals lnventory; LC50 -
Lethal Concentration to 50
o/o
of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - lnternational Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand lnventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines lnventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and RecoveryAct; REACH - Regulation (EC) No 190712006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance lnventory; TSCA - Toxic Substances ControlAct (United States); UN - United Nations;
ACGIH USA. ACGIH Threshold Limit Values (TLV)
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107
USA. Occupational Exposure Limits (OSHA) - Table Z-'1 Limits for Air
Contaminants
OSHA Z-1
PEL Permissible exposure limit
Short-term exposure limitSTEL
TWA B-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Page 22 of 23
Product name: FROTH-PAKTM 60gal REF 1.75 HFO POLY Spray
Foam Sealant
lssue Date: 0212312021
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative
lnformation Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. lt is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. lf you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
Page 23 of 23
by | Sep 27, 2025
Trademark of The Dow Chemical Company or an affiliate. DuPont Oval
Logo trademark of affiliates of DuPont de Nemours,Inc
Page 1 of 23
SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Print Date: 06/29/2021
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray Foam Sealant
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Specific target organ toxicity – repeated exposure – Category 2 – Oral
Simple Asphyxiant
Label elements
Hazard pictograms
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 2 of 23
Signal word: WARNING!
Hazards
Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed.
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF exposed or concerned: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
Wash contaminated clothing before reuse.
Storage
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Component CASRN Concentration
2-Ethylhexanoic acid potassium salt 3164-85-0 >= 1.0 – <= 10.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 10.0 – <= 30.0 %
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 3 of 23
Triethyl phosphate 78-40-0 >= 1.0 – <= 10.0 %
trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >= 10.0 – <= 30.0 %
Polyethylene glycol 25322-68-3 >= 1.0 – < 10.0 %
Polyester polyol Not available >= 20.0 – <= 80.0 %
Diethylene glycol 111-46-6 >= 1.0 – < 10.0 %
Dimethylbis((1-oxoneodecyl)oxy)stannane 68928-76-7 >= 0.25 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove contaminated clothing immediately. Immediately wash skin with soap and
plenty of water. Suitable emergency safety shower facility should be available in work area.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reuse. In the case of skin irritation or allergic reactions see a physician.
Eye contact: In case of contact, immediately flush eye with plenty of water. Suitable emergency eye
wash facility should be available in work area.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. If breathing is
difficult, oxygen should be administered by qualified personnel. Treatment of exposure should be
directed at the control of symptoms and the clinical condition of the patient.
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5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption
may occur upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or
poorly ventilated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate
area of leak or spill. Confined space entry procedures must be followed before entering the area.
Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
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containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
50 C (122 F) See Section 10 for more specific information.
Storage stability
Storage Period: 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
Triethyl phosphate US WEEL TWA 7.45 mg/m3
trans-1-Chloro-3,3,3-
trifluoropropene
US WEEL TWA 800 ppm
Polyethylene glycol US WEEL TWA aerosol 10 mg/m3
Diethylene glycol US WEEL TWA 10 mg/m3
Dimethylbis((1-
oxoneodecyl)oxy)stannane
OSHA Z-1 TWA 0.1 mg/m3 , Tin
ACGIH TWA 0.1 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
ACGIH STEL 0.2 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
CAL PEL PEL 0.1 mg/m3 , Tin
Further information: S: Skin
CAL PEL STEL 0.2 mg/m3 , Tin
Further information: S: Skin
Exposure controls
Engineering controls: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
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Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields). Where contact with the liquid is likely,
chemical goggles are recommended.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove
barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Liquefied gas
Color yellow
Odor No information available.
Odor Threshold No data available
pH No data available
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) No data available
Flash point > 200 C ( > 392 F)
Evaporation Rate (Butyl Acetate
= 1)
Not available
Flammability (solid, gas) Not applicable to liquids Not expected to form explosive dust-
air mixtures.
Lower explosion limit Not applicable
Upper explosion limit Not applicable
Vapor Pressure No data available
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) No data available
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Water solubility Not applicable
Partition coefficient: n-
octanol/water
No data available
Auto-ignition temperature No data available
Decomposition temperature No test data available
Kinematic Viscosity No data available
Explosive properties Not applicableNot explosive
Oxidizing properties No data available
Molecular weight No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Will not occur by itself.
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Product test data not available. Refer to component data.
Acute dermal toxicity
Product test data not available. Refer to component data.
Acute inhalation toxicity
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Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product test data not available. Refer to component data.
Mutagenicity
Product test data not available. Refer to component data.
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCI NG TOXICOLOGY:
2-Ethylhexanoic acid potassium salt
Acute oral toxicity
Based on information for a similar material: LD50, Rat, female, 2,043 mg/kg OECD Test
Guideline 401
Acute dermal toxicity
Based on information for a similar material: LD50, Rabbit, > 2,000 mg/kg OECD Test
Guideline 402 No deaths occurred at this concentration.
Acute inhalation toxicity
At room temperature, exposure to vapor is minimal due to low volatility; vapor from heated
material may cause respiratory irritation. Prolonged excessive exposure to mist may cause
adverse effects.
LC50, Rat, 4 Hour, vapour, > 0.14 mg/l No deaths occurred following exposure to a saturated
atmosphere.
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Skin corrosion/irritation
Brief contact may cause moderate skin irritation with local redness.
Effects may be slow to heal.
Serious eye damage/eye irritation
May cause severe eye irritation.
May cause corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
For similar active ingredient(s).
In animals, effects have been reported on the following organs:
Liver.
Carcinogenicity
No relevant data found.
Teratogenicity
For similar material(s): Has been toxic to the fetus in lab animals at doses nontoxic to the
mother. Did not cause birth defects in laboratory animals.
Reproductive toxicity
For similar material(s): In laboratory animal studies, effects on reproduction have been seen
only at doses that produced significant toxicity to the parent animals.
Mutagenicity
For similar material(s): In vitro genetic toxicity studies were negative. Animal genetic toxicity
studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Tris(1-chloro-2-propyl) phosphate
Acute oral toxicity
LD50, Rat, male and female, >1,000 mg/kg
Acute dermal toxicity
LD50, Rabbit, > 5,000 mg/kg
Acute inhalation toxicity
No deaths occurred at this concentration. LC50, Rat, 4 Hour, dust/mist, > 7 mg/l
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
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Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No data available.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
No relevant data found.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Triethyl phosphate
Acute oral toxicity
LD50, Rat, 1,131 mg/kg
Acute dermal toxicity
LD50, Guinea pig, > 21,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 2.35 mg/l No deaths occurred at this concentration.
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
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No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Triethyl phosphate is considered to be a weak cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination,
muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils,
blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
In vitro genetic toxicity studies were predominantly negative. Animal genetic toxicity studies
were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
trans-1-Chloro-3,3,3-trifluoropropene
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
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Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
This material was not mutagenic in an Ames bacterial assay.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Polyethylene glycol
Acute oral toxicity
Typical for this family of materials. LD50, Rat, > 10,000 mg/kg Estimated.
Acute dermal toxicity
Typical for this family of materials. LD50, Rabbit, > 20,000 mg/kg
Acute inhalation toxicity
Typical for this family of materials. LC50, Rat, 6 Hour, dust/mist, > 2.5 mg/l No deaths
occurred at this concentration.
Skin corrosion/irritation
Prolonged exposure not likely to cause significant skin irritation.
May cause more severe response if skin is abraded (scratched or cut).
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
For this family of materials:
Did not cause allergic skin reactions when tested in humans.
For this family of materials, sensitization studies done in guinea pigs have been negative.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Recent findings of kidney failure and death in burn patients, as well as some studies using
animal burn models, suggest that polyethylene glycol may have been a factor.
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The use of topical applications containing this material may not be appropriate in severely
burned patients.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
Polyethylene glycols did not cause cancer in long-term animal studies.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Diethylene glycol
Acute oral toxicity
In humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. Ingestion of quantities (approximately 65 mL (2 oz.) for diethylene
glycol or 100 mL (3 oz.) for ethylene glycol) has caused death in humans. May cause nausea
and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney
failure. LD50, Rat, male, 19,600 mg/kg
Lethal Dose, Human, adult, 2 Ounces Estimated.
Acute dermal toxicity
LD50, Rabbit, 13,330 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 4.6 mg/l The LC50 value is greater than the Maximum
Attainable Concentration. No deaths occurred at this concentration.
Skin corrosion/irritation
Prolonged contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
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The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to
pose a carcinogenic risk to man.
Teratogenicity
Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic,
high doses in animals. Other animal studies have not reproduced birth defects even at much
higher doses that caused severe maternal toxicity.
Reproductive toxicity
Diethylene glycol did not interfere with reproduction in animal studies except at very high
doses.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
No aspiration toxicity classification
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute oral toxicity
LD50, Rat, 892 mg/kg
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact may cause skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Has caused allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
No relevant data found.
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Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
Not mutagenic in Ames Test
Aspiration Hazard
No aspiration toxicity classification
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
2-Ethylhexanoic acid potassium salt
Acute toxicity to fish
Based on information for a similar material:
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
Tris(1-chloro-2-propyl) phosphate
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Lepomis macrochirus (Bluegill sunfish), static test, 96 Hour, 84 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Pseudokirchneriella subcapitata (green algae), static test, 96 Hour, Growth rate
inhibition, 82 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), semi-static test, 21 d, number of offspring, 32 mg/l
Triethyl phosphate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
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LC50, Leuciscus idus (Golden orfe), static test, 48 Hour, 2,140 mg/l, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/l, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 900 mg/l,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/l, OECD 209 Test
trans-1-Chloro-3,3,3-trifluoropropene
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/l, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, 115 mg/l
Polyethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), static test, 96 Hour, > 10,000 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Skeletonema costatum (marine diatom), 72 Hour, Growth rate, > 100 mg/l
Diethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 75,200 mg/l,
OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 24 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
Based on data from similar materials
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EC50, Selenastrum capricornutum (green algae), 96 Hour, 6,500 – 13,000 mg/l
Toxicity to bacteria
EC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic toxicity to fish
Based on data from similar materials
NOEC, Pimephales promelas (fathead minnow), 7 d, 15,380 mg/l
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, > 15,000 mg/l
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute toxicity to aquatic invertebrates
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 7.6 mg/l, OECD Test Guideline
201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1.2 mg/l, OECD Test
Guideline 201
Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mg/l
Persistence and degradability
2-Ethylhexanoic acid potassium salt
Biodegradability: Based on information for a similar material: Material is expected to be
readily biodegradable. Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
Tris(1-chloro-2-propyl) phosphate
Biodegradability: Material is expected to biodegrade very slowly (in the environment). Fails
to pass OECD/EEC tests for ready biodegradability. Material is ultimately biodegradable
(reaches > 70% mineralization in OECD test(s) for inherent biodegradability).
10-day Window: Fail
Biodegradation: 14 %
Exposure time: 28 d
Method: OECD Test Guideline 301E or Equivalent
10-day Window: Not applicable
Biodegradation: 95 %
Exposure time: 64 d
Method: OECD Test Guideline 302A or Equivalent
Theoretical Oxygen Demand: 1.17 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 18 of 23
Atmospheric half-life: 0.24 d
Method: Estimated.
Triethyl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
trans-1-Chloro-3,3,3-trifluoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Polyethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 85 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 1.67 mg/mg
Diethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 90 – 100 %
Exposure time: 20 d
Method: OECD Test Guideline 301A or Equivalent
10-day Window: Not applicable
Biodegradation: 82 – 98 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Theoretical Oxygen Demand: 1.51 mg/mg
Dimethylbis((1-oxoneodecyl)oxy)stannane
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301B or Equivalent
Bioaccumulative potential
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 19 of 23
2-Ethylhexanoic acid potassium salt
Bioaccumulation: Based on information for a similar material: Bioconcentration potential is
low (BCF < 100 or Log Pow < 3).
Tris(1-chloro-2-propyl) phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 2.59 Measured
Bioconcentration factor (BCF): 0.8 - 4.6 Cyprinus carpio (Carp) 42 d Measured
Triethyl phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.80 Measured
trans-1-Chloro-3,3,3-trifluoropropene
Bioaccumulation: No relevant data found.
Polyethylene glycol
Partition coefficient: n-octanol/water(log Pow): -0.698 Pow: 0.2 at 30 C
Diethylene glycol
Bioaccumulation: Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 C
Bioconcentration factor (BCF): 100 Fish Measured
Dimethylbis((1-oxoneodecyl)oxy)stannane
Partition coefficient: n-octanol/water(log Pow): 5.503
Mobility in soil
2-Ethylhexanoic acid potassium salt
Based on information for a similar material:
Potential for mobility in soil is very high (Koc between 0 and 50).
Tris(1-chloro-2-propyl) phosphate
Potential for mobility in soil is slight (Koc between 2000 and 5000).
Partition coefficient (Koc): 1300 Estimated.
Triethyl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): 48 Estimated.
trans-1-Chloro-3,3,3-trifluoropropene
No relevant data found.
Polyethylene glycol
No relevant data found.
Diethylene glycol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 20 of 23
Partition coefficient (Koc): < 1 Estimated.
Dimethylbis((1-oxoneodecyl)oxy)stannane
No relevant data found.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
Proper shipping name Chemical under pressure, n.o.s.(Inert Gases)
UN number UN 3500
Class 2.2
Packing group
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S. (Inert Gases)
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(Inert Gases)
UN number UN 3500
Class 2.2
Packing group
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 21 of 23
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Reproductive toxicity
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, a nd Liability Act of 1980 (CERCLA)
Section 103
This material does not contain any components with a CERCLA RQ.
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Diethylene glycol 111-46-6
California Prop. 65
This product contains a chemical that is at or below California Propositions 65 s "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 22 of 23
Health Flammability
Physical
Hazard
2* 1 3
* = Chronic Effects (See Hazards Identification)
Revision
Identification Number: 12069390 / A749 / Issue Date: 02/23/2021 / Version: 1.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
PEL Permissible exposure limit
STEL Short-term exposure limit
TWA 8-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
Product name: FROTH-PAK 17gal REF 1.75 HFO POLY Spray
Foam Sealant
Issue Date: 02/23/2021
Page 23 of 23
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
by | Sep 27, 2025
nnbbtqL
r oUP0Nt t
SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO
Spray Foam Sealant
lssue Date: 0212312021
Print Date: 0810212021
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
I. IDENTIFICATION
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray Foam Sealant
Recommended use of the chemical and restrictions on use
ldentified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. lf your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE
‘19805
UNITED STATES
Customer lnformation Number: 833-338-7668
S DSQuestion-NA@d u pont. com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Gontact: 1 -800-424-9300
Local Emergency Gontact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Acute toxicity – Category 4 – lnhalation
Skin irritation – Category 2
Eye irritation – Category 28
Respiratory sensitisation – Category 1
Skin sensitisation – Category 1
Specific target organ toxicity – single exposure – Category 3
Specific target organ toxicity – repeated exposure – Category 2 – lnhalation
Simple Asphyxiant
@rM Trademark of The Dow Chemical Company or an affiliate. DuPont Oval
Looo trademark of affiliates of DuPont de Nemours lnc
Page 1 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
AF T
I
Label elements
Hazard pictograms
Signalword: DANGER!
Hazards
Contains gas under pressure; may explode if heated.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention
Do not breathe dusU fume/ gas/ misV vapours/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace
Wear protective gloves.
ln case of inadequate ventilation wear respiratory protection.
Response
lF ON SKIN: Wash with plenty of soap and water.
lF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell.
lF lN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
lf skin irritation or rash occurs: Get medical advice/ attention.
lf eye irritation persists: Get medical advice/ attention.
lf experiencing respiratory symptoms: Call a POISON CENTER/doctor.
Take off contaminated clothing and wash before reuse.
Storage
Store in a well-ventilated place. Keep container tightly closed
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant
Other hazards
No data available
Page 2 ot 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
3. COMPOSTTTON/INFORMATION ON INGREDIENTS
This product is a mixture
Component CASRN Concentration
Diphenylmethane Diisocyanate, isomers and
homologues
9016-87-9 > 60.0 – <= 80.0 %
> 20.0 – <= 40.0
o/o
> 0.0 – < 20.0
o/o
4,4' -Methylenediphenyl diisocyanate 10'1-68-8
trans-1 -Ch loro-3, 3, 3trifluoropropene 1 02687-65-0
Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). lf potential for exposure exists refer to Section
8 for specific personal protective equipment.
lnhalation: Move person to fresh air. lf not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). lf breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medicalfacility. lf breathing has stopped, apply
artifical respiration.
Skin contact: Remove materialfrom skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.
Eye contact: lmmediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medicalattention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
lngestion: lf swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Most important symptoms and effects, both acute and delayed:
Page 3 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
Aside from the information found under Description of first aid measures (above) and lndication of
immediate medicalattention and specialtreatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology lnformation.
lndication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives
may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. lf you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient. Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.9. emphysema, bronchitis, reactive ainrvays dysfunction
syndrome).
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. lsocyanates. Hydrogen cyanide.
Carbon monoxide. Carbon dioxide. Hydrogen halides. Halogenated hydrocarbons.
Unusual Fire and Explosion Hazards: Some components of this product will burn in a fire situation.
Product reacts with water. Reaction may produce heat and/or gases. This reaction may be violent.
Container may rupture from gas generation in a fire situation. Blowing agent vaporizes quickly at room
temperature. Violent steam generation or eruption may occur upon application of direct water stream
to hot liquids. Dense smoke is produced when product burns.
Advice for firefighters
Fire Fighting Procedures: Keep people away. lsolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance.
Consider the use of unmanned hose holders or monitor nozzles. lmmediately withdraw all personnel
from the area in case of rising sound from venting safety device or discoloration of the container.
Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed
containers and fire-affected zone until fire is out. Contain fire water run-off if possible. Fire water run-
off, if not contained, may cause environmental damage. Review the "Accidental Release Measures"
and the "Ecological lnformation" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. lf contact is likely,
Page 4 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. lf this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAT RETEASE MEASURES
Personal precautions, protective equipment and emergency procedures: lsolate area. Keep
unnecessary and unprotected personnel from entering the area. Refer to section 7, Handling, for
additional precautionary measures. Keep personnel out of low areas. Keep personnel out of confined
or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. Confined space entry
procedures must be followed before entering the area. See Section 10 for more specific information.
Spilled material may cause a slipping hazard. Use appropriate safety equipment. For additional
information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological lnformation.
Methods and materials for containment and cleaning up: Do NOT use absorbent materials such
as: Cement powder (Note: may generate heat). Contain spilled material if possible. Absorb with
materials such as: Dirt. Vermiculite. Sand. Clay. Collect in suitable and properly labeled open
containers. lsolate area until gas has dispersed. Apply vapor suppression foams until spill can be
cleaned up. Knock down and dilute vapors with water fog or spray. See Section 13, Disposal
Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section B,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulatrons may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
50"C (122"F) See Section 10 for more specific information.
Storage stability
Storage Period: 15 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTTON
Control parameters
lf exposure limits exist, they are listed below. lf no exposure limits are displayed, then no values are
of listing Value
licable.
Page 5 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
4,4' -Methylenediphenyl Dow IHG TWA 0.005 ppm
di nate
Exposure controls
Engineering controls: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure, Lethal concentrations may exist in
areas with poor ventilation.
lndividual protection measures
Eye/face protection: Use chemical goggles.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethylvinyl alcohol
laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene.
Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. NOTICE: The
selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all relevant workplace factors such as, but not limited to: Other chemicals which may
be handled, physical requirements (cuUpuncture protection, dexterity, thermal protection), potential
body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator
equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric
levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure
air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or
for situations where the atmospheric level is unknown, use an approved positive-pressure self-
contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. ln
confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive
pressure air line with auxiliary self-contained air supply. For escape purposes, carry an approved air-
purifying respirator on person at all times.
The following should be effective types of air-purifying respirators: Organic vapor cartridge with a
particu late pre-filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
STEL 0.02 ppmDow IHG
0.005 ppmACGIH TWA
Further information sens sens
OSHA Z-1 c 0.2 mg/m3 0.02 ppm
Furtherinformation: (b): Thevalueinmgim3isapproximate.;
-:
Ceilinglimitistobe
determined from breathinq-zone air samples.
US WEEL TWA 800 ppmtrans-1 -C h loro-3, 3, 3-
trifluoropropene
Appearance
Physicalstate Liquefied gas
Page 6 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
Golor
Odor
Odor Threshold
pH
Melting point/range
Freezing point
Boiling point (760 mmHg)
Flash point
Evaporation Rate (Butyl Acetate
= 1)
Flammability (solid, gas)
Lower explosion limit
Upper explosion limit
Vapor Pressure
Relative Vapor Density (air = 1)
Relative Density (water = 1;
Water solubility
Partition coefficient: n-
octanol/water
Auto-ignition temperature
Decomposition temperature
Kinematic Viscosity
Explosive properties
Oxidizing properties
Molecular weight
brown
musty
Odor is inadequate warning of excessive exposure
No data available
No data available.
No data available.
No data available
>200’c (>392’F)
Not available
Not expected to form explosive dust-air mixtures. lVo
i nform ation avai I a ble.
Liquid.
Liquid.
Not available
No data available
1.24 at25″C (77 “F) Estimated.
insoluble
No data available
No data available
No data available
No data available
No data available
no oxidising properties
No data available
NOTE: The physical data presented above are typicalvalues and should not be construed as a
specification.
,IO.
STABITITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Can occur. Elevated temperatures can cause hazardous
polymerization. Polymerization can be catalyzed by: Strong bases. Water.
Gonditions to avoid: Exposure to elevated temperatures can cause product to decompose. Elevated
temperatures can cause pressure buildup in closed containers due to the release of blowing agents.
Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up
can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can
cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this
reaction.
PageT of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
lncompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases.
Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate
of reaction increases with temperature as well as increased contact; these reactions can become
violent. Contact is increased by stirring or if the other material mixes with the diisocyanate.
Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The
reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate
carbon dioxide and heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper.
Galvanized metals. Avoid contact with absorbent materials such as: Moist organic absorbents. Avoid
unintended contact with polyols. The reaction of polyols and isocyanates generate heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Gases are released during decomposition.
I 1 . TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Product test data not available. Refer to component data
Acute dermal toxicity
Product test data not available. Refer to component data
Acute inhalation toxicity
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols,
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosoldroplets of
MD|/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDl.
Page 8 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
Teratogenicity
ln laboratory animals, MDl/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother. Contains component(s) which did not cause birth
defects in animals, other fetal effects occurred only at doses toxic to the mother.
Reproductive toxicity
Product test data not available. Refer to component data
Mutagenicity
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other
in vitro studies were negative. Animal mutagenicity studies were predominantly negative.
Aspiration Hazard
Product test data not available. Refer to component data
COMPONENTS INFLUENCING TOXICOLOGY
Diphenvlmethane Diisocvanate. isomers and homoloques
Acute oral toxicity
Typical for this family of materials. 1D50, Rat, > 10,000 mg/kg
Acute dermaltoxicity
Typical for this family of materials. 1D50, Rabbit, > 9,400 mg/kg
Acute inhalation toxicity
1C50, Rat,4 Hour, dusVmist, 0.49 mg/l
For similar material(s): 4,4′-Methylenediphenyldiisocyanate (CAS 101-68-8). 1C50, Rat, 1
Hour, Aerosol, 2.24 mgll
For similar material(s): 2,4′-Diphenylmethane diisocyanate (CAS 5873-54-1). 1C50, Rat, 4
Hour, Aerosol, 0.387 mg/l
Skin corrosion/irtitation
Prolonged contact may cause slight skin irritation with local redness.
May stain skin.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight temporary corneal injury
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in
the chest. Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
Page 9 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
May cause respiratory irritation.
Route of Exposure: lnhalation
Target Organs: Respiratory Tract
Reproductive toxicity
No relevant data found
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
4.4′ -Methvlenediphenvl d iisocvanate
Acute oraltoxicity
LD50, Rat, > 2,000 mg/kg No deaths occurred at this concentration
trans-1 -Ch loro-3.3.3-trifluoropropene
Acute oraltoxicity
Acute dermaltoxicity
1D50, Rabbit, > 9,400 mg/kg
Acute inhalation toxicity
1C50, Rat, 1 Hour, dusUmist, 2.24 mgll
Skin corrosion/irritation
Prolonged contact may cause moderate skin irritation with local redness.
Repeated contact may cause moderate skin irritation with local redness.
May stain skin.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight temporary corneal injury
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in
the chest. Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: lnhalation
Target Organs: Respiratory Tract
Reproductive toxicity
No relevant data found
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard
Page 10 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
fssue Date: 0212312021
Single dose oral LD50 has not been determined
Acute dermaltoxicity
The dermal LD50 has not been determined
Acute inhalation toxicity
1C50, Rat,4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans
For respiratory sensitization
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Reproductive toxicity
No relevant data found
Aspiration Hazard
Based on available information, aspiration hazard could not be determined
.I
2. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
Diphenvlmethane Diisocvanate. isomers and homologues
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
1C50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/|, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/|, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Page11of17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
fssue Date: 0212312021
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72Hour, Growth rate inhibition,
1,640 mg/|, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, statictest,3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material., 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
4.4′ -Methvlenedi ldiisocvanate
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non{oxic to aquatic organisms on an acute basis
(1C50/EC50/E150/1150 >100 mgil in the most sensitive species tested).
Based on lnformation for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/|, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic inveftebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/|, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72Hour, Growth rate inhibition,
1,640 mg/|, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, statictest,3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
trans-1 -C h loro-3.3.3-trif luoroprope ne
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
Page 12 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/|, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mgll, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae),72Hour, Growth rate, 1’15 mg/l
Persistence and degradability
Diphenvlmethane Diisocvanate, isomers and homoloques
Biodegradability: ln the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. ln the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
1O-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
4.4′ -Methvlenediphenvl diisocvanate
Biodegradability: ln the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. ln the atmospheric
environment, material is expected to have a short tropospheric haltlife, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
trans-1’C h loro-3,3,3-trif luoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines
Biodegradation: 0 7o
Exposure time: 28 d
Method: OECD Test Guideline 301D
Bioaccumulative potential
Diphenvlmethane Diisocvanate. isomers and homologues
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. ln the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
4,4' -Methvlenediphenvl d iisocvanate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. ln the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
Page 13 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
trans-1 -C h loro-3,3.3-trif luoropropene
Bioaccumulation: No relevant data found
Mobility in soil
Diphenvlmethane Diisocvanate. isomers and homoloques
ln the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
4.4' -Methvlenediphenvl d iisocvanate
ln the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
trans-1 -C hloro-3,3,3-trifluoropropene
No relevant data found.
I 3. DISPOSAT CONSIDERATIONS
DiSPOSAI methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED lN MSDS SECTION: Composition lnformation. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. lncineratororotherthermaldestruction device. Foradditional
information, refer to: Handling & Storage lnformation, MSDS Section 7 Stability & Reactivity
lnformation, MSDS Sectionl0 Regulatory lnformation, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
Proper shipping name
UN number
Class
Packing group
Chemical under pressure, n.o.s.(lnert Gases)
uN 3500
2.2
Classification for SEA transport (lMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S.(tnert Gases)
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or ll
of MARPOL 73/78 and the
Page 14 ol 17
Product namer FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
IBC or IGC Gode
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(lnert Gases)
UN number UN 3500
Class 2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. lt is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
I 5. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title lll (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title lll (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title lll of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Components CASRN
Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9
4,4' -Methylenediphenyl diisocyanate 101-68-8
Comprehensive Environmental Response, Gompensation, and Liability Act of 1980 (CERCLA)
Section 103
Calculated RQ exceeds reasonably attainable upper limit.
Gomponents CASRN RQ (RCRA Code)
4,4'-Methylenediphenyldiisocyanate 101-68-8 5000 lbs RQ
Pennsylvania Worker and Gommunity Right-To-Know Act:
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
Galifornia Prop.65
Page
'15
of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
United States TSCA lnventory (TSCA)
All components of this product are in compliance with the inventory listing requirements of the U.S
Toxic Substances ControlAct (TSCA) Chemical Substance lnventory.
I6. OTHER INFORMATION
Hazard Rating System
HMIS
Health Flammability
Physical
Hazard
2* 1 3
*
= Chronic Effects (See Hazards ldentification)
Revision
ldentification Number: 12066192 I A749 / lssue Date:0212312021 lVersion: 2.1
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
nd
Full text of other abbreviations
AllC - Australian lnventory of lndustrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German lnstitute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials ldentification System; IARC - lnternational
Agency for Research on Cancer; IATA - lnternational Air Transport Association; IBC - lnternational
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; lC50 - Half
maximal inhibitory concentration; ICAO - lnternational CivilAviation Organization; IECSC - lnventory of
Existing Chemical Substances in China; IMDG - lnternational Maritime Dangerous Goods; IMO -
lnternational Maritime Organization; ISHL - lndustrial Safety and Health Law (Japan); ISO -
lnternational Organisation for Standardization; KECI - Korea Existing Chemicals lnventory; LC50 -
Lethal Concentration to 50
o/o
of a test population; LD50 - Lethal Dose to 50o/o of a test population
(Median Lethal Dose); MARPOL - lnternational Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Othenryise Specified; NFPA - National Fire
ACGIH USA. ACGIH Threshold Limit Values (TLV)
c Ceiling
Dow IHG Dow lndustrial Hvqiene Guideline
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
STEL Short term exposure limit
TWA B-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Page 16 of 17
Product name: FROTH-PAKTM AF 60gal REF1.75 HFO ISO Spray
Foam Sealant
lssue Date: 0212312021
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level, NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program, NZIoC - New Zealand lnventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines lnventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and RecoveryAct; REACH - Regulation (EC) No 190712006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance lnventory; TSCA - Toxic Substances ControlAct (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative
lnformation Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. lt is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. lf you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
Page 17 of 17
by | Sep 27, 2025
Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 20
SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Print Date: 05/29/2025
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray Insulation Foam US
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Acute toxicity – Category 4 – Inhalation
Skin irritation – Category 2
Eye irritation – Category 2B
Respiratory sensitisation – Category 1
Skin sensitisation – Category 1
Specific target organ toxicity – single exposure – Category 3
Specific target organ toxicity – repeated exposure – Category 2 – Inhalation
Simple Asphyxiant
Label elements
Hazard pictograms
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 2 of 20
Signal word: DANGER!
Hazards
Contains gas under pressure; may explode if heated.
Causes skin and eye irritation.
May cause an allergic skin reaction.
Harmful if inhaled.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause respiratory irritation.
May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention
Do not breathe mist or vapours.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves.
In case of inadequate ventilation wear respiratory protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/ doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If skin irritation or rash occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
If experiencing respiratory symptoms: Call a POISON CENTER/ doctor.
Take off contaminated clothing and wash before reuse.
Storage
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 3 of 20
This product is a mixture.
Component CASRN Concentration
Diphenylmethane Diisocyanate, isomers and
homologues
9016-87-9 50.0 – <= 60.0 %
4,4' -Methylenediphenyl diisocyanate 101-68-8 30.0 - <= 40.0 %
trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 > 1.0 – < 5.0 %
Carbon dioxide 124-38-9 >= 1.0 – < 5.0 %
Nitrogen 7727-37-9 >= 0.1 – < 0.5 %
Note
Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9.
The specific chemical identity and/or exact percentage (concentration) of composition has been
withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility. If breathing has stopped, apply
artifical respiration.
Skin contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. An MDI skin decontamination study demonstrated that cleaning very
soon after exposure is important, and that a polyglycol-based skin cleanser or corn oil may be more
effective than soap and water. Discard items which cannot be decontaminated, including leather
articles such as shoes, belts and watchbands. Suitable emergency safety shower facility should be
available in work area.
Eye contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay,
preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately
available.
Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by
medical personnel.
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 4 of 20
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. May cause
respiratory sensitization or asthma-like symptoms. Bronchodilators, expectorants and antitussives
may be of help. Treat bronchospasm with inhaled beta2 agonist and oral or parenteral corticosteroids.
Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant
exposure should be observed 24-48 hours for signs of respiratory distress. If you are sensitized to
diisocyanates, consult your physician regarding working with other respiratory irritants or sensitizers.
Exposure may increase "myocardial irritability". Do not administer sympathomimetic drugs such as
epinephrine unless absolutely necessary. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient. Excessive exposure may aggravate preexisting
asthma and other respiratory disorders (e.g. emphysema, bronchitis, reactive airways dysfunction
syndrome).
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Nitrogen oxides. Isocyanates. Hydrogen cyanide.
Carbon monoxide. Carbon dioxide. Hydrogen halides. Halogenated hydrocarbons.
Unusual Fire and Explosion Hazards: Some components of this product will burn in a fire situation.
Product reacts with water. Reaction may produce heat and/or gases. This reaction may be violent.
Container may rupture from gas generation in a fire situation. Blowing agent vaporizes quickly at room
temperature. Violent steam generation or eruption may occur upon application of direct water stream
to hot liquids. Dense smoke is produced when product burns.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay
upwind. Keep out of low areas where gases (fumes) can accumulate. Water is not recommended, but
may be applied in large quantities as a fine spray when other extinguishing agents are not available.
Do not use direct water stream. May spread fire. Fight fire from protected location or safe distance.
Consider the use of unmanned hose holders or monitor nozzles. Immediately withdraw all personnel
from the area in case of rising sound from venting safety device or discoloration of the container.
Move container from fire area if this is possible without hazard. Use water spray to cool fire-exposed
containers and fire-affected zone until fire is out. Contain fire water run-off if possible. Fire water run-
off, if not contained, may cause environmental damage. Review the "Accidental Release Measures"
and the "Ecological Information" sections of this (M)SDS.
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Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Refer to section 7, Handling, for
additional precautionary measures. Keep personnel out of low areas. Keep personnel out of confined
or poorly ventilated areas. Keep upwind of spill. Ventilate area of leak or spill. Confined space entry
procedures must be followed before entering the area. See Section 10 for more specific information.
Spilled material may cause a slipping hazard. Use appropriate safety equipment. For additional
information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Methods and materials for containment and cleaning up: Do NOT use absorbent materials such
as: Cement powder (Note: may generate heat). Contain spilled material if possible. Absorb with
materials such as: Dirt. Vermiculite. Sand. Clay. Collect in suitable and properly labeled open
containers. Isolate area until gas has dispersed. Apply vapor suppression foams until spill can be
cleaned up. Knock down and dilute vapors with water fog or spray. See Section 13, Disposal
Considerations, for additional information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
50 C (122 F) See Section 10 for more specific information.
Storage stability
Storage Period: 24 Month
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8. EXPOSURE CONTROLS/PERSONAL PROTECTIO N
Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
4,4' -Methylenediphenyl
diisocyanate
DUPONT AEL AEL * Vapour 2.5 Parts per billion
DUPONT AEL AEL * Vapour 20 Parts per billion
DUPONT AEL AEL * particulate 0.025 mg/m3
OSHA Z-1 C 0.2 mg/m3 0.02 ppm
OSHA P0 C 0.2 mg/m3 0.02 ppm
NIOSH REL TWA 0.05 mg/m3 0.005 ppm
NIOSH REL C 0.2 mg/m3 0.02 ppm
trans-1-Chloro-3,3,3-
trifluoropropene
US WEEL TWA 800 ppm
Carbon dioxide Dow IHG TWA 5,000 ppm
Dow IHG STEL 30,000 ppm
ACGIH TWA 5,000 ppm
ACGIH STEL 30,000 ppm
OSHA Z-1 TWA 9,000 mg/m3 5,000
ppm
CAL PEL PEL 9,000 mg/m3 5,000
ppm
CAL PEL STEL 54,000 mg/m3 30,000
ppm
NIOSH REL TWA 9,000 mg/m3 5,000
ppm
NIOSH REL ST 54,000 mg/m3 30,000
ppm
Nitrogen ACGIH See Further information
Further information: Asphyxia; (): Adopted values or notations enclosed are those for
which changes are proposed in the NIC; See Notice of Intended Changes (NIC); D:
Simple asphyxiant; see discussion covering Minimal Oxygen Content found in the
'Definitions and Notations' section following the NIC tables
CAL PEL See Further information
Further information: (h): A number of gases and vapors, when present in high
concentrations, act primarily as asphyxiants without other adverse effects. A
concentration limit is not included for each material because the limiting factor is the
available oxygen. (Several of these materials present fire or explosion hazards.)
Exposure controls
Engineering measures: Use only with adequate ventilation. Local exhaust ventilation may be
necessary for some operations. Provide general and/or local exhaust ventilation to control airborne
levels below the exposure guidelines. Exhaust systems should be designed to move the air away
from the source of vapor/aerosol generation and people working at this point. The odor and irritancy
of this material are inadequate to warn of excessive exposure. Lethal concentrations may exist in
areas with poor ventilation.
Individual protection measures
Eye/face protection: Use chemical goggles.
Skin protection
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Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Butyl rubber. Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol
laminate ("EVAL"). Examples of acceptable glove barrier materials include: Neoprene.
Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. NOTICE: The
selection of a specific glove for a particular application and duration of use in a workplace should also
take into account all relevant workplace factors such as, but not limited to: Other chemicals which may
be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential
body reactions to glove materials, as well as the instructions/specifications provided by the glove
supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Atmospheric levels should be maintained below the exposure guideline.
When atmospheric levels may exceed the exposure guideline, use an approved air-purifying respirator
equipped with an organic vapor sorbent and a particle filter. For situations where the atmospheric
levels may exceed the level for which an air-purifying respirator is effective, use a positive-pressure
air-supplying respirator (air line or self-contained breathing apparatus). For emergency response or
for situations where the atmospheric level is unknown, use an approved positive-pressure self-
contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply. In
confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive
pressure air line with auxiliary self-contained air supply. For escape purposes, carry an approved air-
purifying respirator on person at all times.
The following should be effective types of air-purifying respirators: Organic vapor cartridge with a
particulate pre-filter.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Liquefied gas
Color brown
Odor musty
Odor Threshold Odor is inadequate warning of excessive exposure.
pH No data available
Melting point/range No data available.
Freezing point No data available.
Boiling point (760 mmHg) No data available
Flash point > 200 C ( > 392 F)
Evaporation Rate (Butyl Acetate
= 1)
Not available
Flammability (solid, gas) Not expected to form explosive dust-air mixtures. No
information available.
Lower explosion limit Liquid.
Upper explosion limit Liquid.
Vapor Pressure Not available
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.24 at 25 C (77 F) Estimated.
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Water solubility insoluble
Partition coefficient: n-
octanol/water
No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Kinematic Viscosity No data available
Explosive properties No data available
Oxidizing properties no oxidising properties
Molecular weight No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Possibility of hazardous reactions: Can occur. Elevated temperatures can cause hazardous
polymerization. Polymerization can be catalyzed by: Strong bases. Water.
Conditions to avoid: Exposure to elevated temperatures can cause product to decompose. Elevated
temperatures can cause pressure buildup in closed containers due to the release of blowing agents.
Generation of gas during decomposition can cause pressure in closed systems. Pressure build-up
can be rapid. Avoid moisture. Material reacts slowly with water, releasing carbon dioxide which can
cause pressure buildup and rupture of closed containers. Elevated temperatures accelerate this
reaction.
Incompatible materials: Avoid contact with: Acids. Alcohols. Amines. Water. Ammonia. Bases.
Metal compounds. Moist air. Strong oxidizers. Diisocyanates react with many materials and the rate
of reaction increases with temperature as well as increased contact; these reactions can become
violent. Contact is increased by stirring or if the other material mixes with the diisocyanate.
Diisocyanates are not soluble in water and sink to the bottom, but react slowly at the interface. The
reaction forms carbon dioxide gas and a layer of solid polyurea. Reaction with water will generate
carbon dioxide and heat. Avoid contact with metals such as: Aluminum. Zinc. Brass. Tin. Copper.
Galvanized metals. Avoid contact with absorbent materials such as: Moist organic absorbents. Avoid
unintended contact with polyols. The reaction of polyols and isocyanates generate heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Gases are released during decomposition.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
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Product test data not available. Refer to component data.
Acute dermal toxicity
Product test data not available. Refer to component data.
Acute inhalation toxicity
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Tissue injury in the upper respiratory tract and lungs has been observed in laboratory animals after
repeated excessive exposures to MDI/polymeric MDI aerosols.
Carcinogenicity
Lung tumors have been observed in laboratory animals exposed to respirable aerosol droplets of
MDI/Polymeric MDI (6 mg/m3) for their lifetime. Tumors occurred concurrently with respiratory
irritation and lung injury. Current exposure guidelines are expected to protect against these effects
reported for MDI.
Teratogenicity
In laboratory animals, MDI/polymeric MDI did not cause birth defects; other fetal effects occurred only
at high doses which were toxic to the mother. Contains component(s) which did not cause birth
defects in animals; other fetal effects occurred only at doses toxic to the mother.
Reproductive toxicity
Product test data not available. Refer to component data.
Mutagenicity
Genetic toxicity data on MDI are inconclusive. MDI was weakly positive in some in vitro studies; other
in vitro studies were negative. Animal mutagenicity studies were predominantly negative.
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCING TOXICOLOGY :
Diphenylmethane Diisocyanate, isomers and homologues
Acute oral toxicity
Typical for this family of materials. LD50, Rat, > 10,000 mg/kg
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Acute dermal toxicity
Typical for this family of materials. LD50, Rabbit, > 9,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, 0.49 mg/l
For similar material(s): 4,4′-Methylenediphenyl diisocyanate (CAS 101-68-8). LC50, Rat, 1
Hour, Aerosol, 2.24 mg/l
For similar material(s): 2,4′-Diphenylmethane diisocyanate (CAS 5873-54-1). LC50, Rat, 4
Hour, Aerosol, 0.387 mg/l
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
May stain skin.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight temporary corneal injury.
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in
the chest. Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Target Organs: Respiratory Tract
Reproductive toxicity
No relevant data found.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
4,4′ -Methylenediphenyl diisocyanate
Acute oral toxicity
LD50, Rat, > 2,000 mg/kg No deaths occurred at this concentration.
Acute dermal toxicity
LD50, Rabbit, > 9,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 1 Hour, dust/mist, 2.24 mg/l
Skin corrosion/irritation
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Prolonged contact may cause moderate skin irritation with local redness.
Repeated contact may cause moderate skin irritation with local redness.
May stain skin.
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight temporary corneal injury.
Sensitization
Skin contact may cause an allergic skin reaction.
Animal studies have shown that skin contact with isocyanates may play a role in respiratory
sensitization.
May cause allergic respiratory reaction.
MDI concentrations below the exposure guidelines may cause allergic respiratory reactions in
individuals already sensitized.
Asthma-like symptoms may include coughing, difficult breathing and a feeling of tightness in
the chest. Occasionally, breathing difficulties may be life threatening.
Specific Target Organ Systemic Toxicity (Single Exposure)
May cause respiratory irritation.
Route of Exposure: Inhalation
Target Organs: Respiratory Tract
Reproductive toxicity
No relevant data found.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
trans-1-Chloro-3,3,3-trifluoropropene
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization:
No relevant data found.
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Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Reproductive toxicity
No relevant data found.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Carbon dioxide
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 hrs, gas, 58750 ppm
Skin corrosion/irritation
No hazard from gas.
Skin contact with the solid (“dry ice”) may cause frostbite.
Liquid may cause frostbite upon skin contact.
Serious eye damage/eye irritation
No hazard from gas.
Eye contact with the solid (“dry ice”) may cause freeze burns.
Liquid may cause frostbite.
Sensitization
No relevant data found.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity.
Reproductive toxicity
Available data are inadequate to determine effects on reproduction.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Nitrogen
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
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No adverse effects are anticipated from inhalation. In confined or poorly ventilated areas,
vapor can easily accumulate and can cause unconsciousness and death due to displacement
of oxygen.
As product: The LC50 has not been determined.
Skin corrosion/irritation
Essentially nonirritating to skin.
Liquid may cause frostbite upon skin contact.
Serious eye damage/eye irritation
Essentially nonirritating to eyes.
Liquid may cause frostbite.
Liquid may cause severe eye irritation with corneal injury. Corneal burns may occur.
Sensitization
For skin sensitization:
No relevant data found.
For respiratory sensitization:
No relevant data found.
Reproductive toxicity
No relevant data found.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
Diphenylmethane Diisocyanate, isomers and homologues
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
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NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
4,4′ -Methylenediphenyl diisocyanate
Acute toxicity to fish
The measured ecotoxicity is that of the hydrolyzed product, generally under conditions
maximizing production of soluble species.
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
Based on information for a similar material:
LC50, Danio rerio (zebra fish), static test, 96 Hour, > 1,000 mg/l, OECD Test Guideline 203 or
Equivalent
Acute toxicity to aquatic invertebrates
Based on information for a similar material:
EC50, Daphnia magna (Water flea), static test, 24 Hour, > 1,000 mg/l, OECD Test Guideline
202 or Equivalent
Acute toxicity to algae/aquatic plants
Based on information for a similar material:
NOEC, Desmodesmus subspicatus (green algae), static test, 72 Hour, Growth rate inhibition,
1,640 mg/l, OECD Test Guideline 201 or Equivalent
Toxicity to bacteria
Based on information for a similar material:
EC50, activated sludge, static test, 3 Hour, Respiration rates., > 100 mg/l
Toxicity to soil-dwelling organisms
EC50, Eisenia fetida (earthworms), Based on information for a similar material:, 14 d, > 1,000
mg/kg
Toxicity to terrestrial plants
EC50, Avena sativa (oats), Growth inhibition, 1,000 mg/l
EC50, Lactuca sativa (lettuce), Growth inhibition, 1,000 mg/l
trans-1-Chloro-3,3,3-trifluoropropene
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/l, OECD Test Guideline
203
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Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, 115 mg/l
Carbon dioxide
Acute toxicity to fish
May decrease pH of aquatic systems to < pH 5 which may be toxic to aquatic organisms.
LC0, Oncorhynchus mykiss (rainbow trout), 1 Hour, 240 mg/l, Method Not Specified.
Acute toxicity to aquatic invertebrates
Based on data from similar materials
NOEC, Daphnia magna (Water flea), 48 Hour, > 100 mg/l
Nitrogen
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.
Persistence and degradability
Diphenylmethane Diisocyanate, isomers and homologues
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
4,4′ -Methylenediphenyl diisocyanate
Biodegradability: In the aquatic and terrestrial environment, material reacts with water
forming predominantly insoluble polyureas which appear to be stable. In the atmospheric
environment, material is expected to have a short tropospheric half-life, based on calculations
and by analogy with related diisocyanates.
10-day Window: Not applicable
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
trans-1-Chloro-3,3,3-trifluoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Carbon dioxide
Biodegradability: Biodegradation is not applicable.
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Nitrogen
Biodegradability: Biodegradation is not applicable. May decrease the dissolved oxygen
(DO) content of natural waters.
Bioaccumulative potential
Diphenylmethane Diisocyanate, isomers and homologues
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Reacts with
water. In the aquatic and terrestrial environment, movement is expected to be limited by its
reaction with water forming predominantly insoluble polyureas.
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
4,4' -Methylenediphenyl diisocyanate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 4.51 at 22 C
Bioconcentration factor (BCF): 92 Cyprinus carpio (Carp) 28 d
trans-1-Chloro-3,3,3-trifluoropropene
Bioaccumulation: No relevant data found.
Carbon dioxide
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.83 Measured
Nitrogen
Bioaccumulation: Partitioning from water to n-octanol is not applicable.
Mobility in soil
Diphenylmethane Diisocyanate, isomers and homologues
In the aquatic and terrestrial environment, movement is expected to be limited by its reaction
with water forming predominantly insoluble polyureas.
trans-1-Chloro-3,3,3-trifluoropropene
No relevant data found.
Carbon dioxide
No relevant data found.
Nitrogen
No data available.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
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MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section 10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
Proper shipping name Chemical under pressure, n.o.s.(Carbon dioxide, Nitrogen)
UN number UN 3500
Class 2.2
Packing group
Reportable Quantity MDI
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S. (Carbon dioxide,
Nitrogen)
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(Carbon dioxide, Nitrogen)
UN number UN 3500
Class 2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 18 of 20
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
Gases under pressure
Simple Asphyxiant
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Specific target organ toxicity (single or repeated exposure)
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This product contains the following substances which are subject to the reporting requirements of
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are
listed in 40 CFR 372.
Components CASRN
Diphenylmethane Diisocyanate, isomers and homologues 9016-87-9
4,4' -Methylenediphenyl diisocyanate 101-68-8
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
Calculated RQ exceeds reasonably attainable upper limit.
Components CASRN RQ (RCRA Code)
4,4' -Methylenediphenyl diisocyanate 101-68-8 5000 lbs RQ
Does not contain HFC.
Compliant with Title 42 Chapter 85 Clean Air Act: Subchapter VII American Innovation and
Manufacturing Act of 2020, and Section 612 US EPA Significant New Alternatives Policy.
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Carbon dioxide 124-38-9
California Prop. 65
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the Active inventory listing requirements of the
U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 19 of 20
16. OTHER INFORMATION
Hazard Rating System
HMIS
Health Flammability
Physical
Hazard
2* 1 3
* = Chronic Effects (See Hazards Identification)
Revision
Identification Number: 12031896 / A749 / Issue Date: 03/14/2024 / Version: 3.3
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
AEL * 15 minute TWA
C Ceiling value not be exceeded at any time.
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107)
Dow IHG Dow Industrial Hygiene Guideline
DUPONT AEL DuPont AEL (Acceptable Exposure Limit)
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHA P0 USA. Table Z-1-A Limits for Air Contaminants (1989 vacated values)
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
PEL Permissible exposure limit
ST STEL - 15-minute TWA exposure that should not be exceeded at any time during
a workday
STEL Short term exposure limit
TWA 8-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
Product name: FROTH-PAK AF 650BF 1.75 HFO ISO Spray
Insulation Foam US
Issue Date: 03/14/2024
Page 20 of 20
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control
Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
by | Sep 27, 2025
Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 25
SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Print Date: 05/29/2025
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
1. IDENTIFICATION
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray Polyurethane Foam Kit
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. We recommend that you use this product in a manner consistent
with the listed use. If your intended use is not consistent with the stated use, please contact your sales
or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Gases under pressure – Liquefied gas
Eye irritation – Category 2A
Skin sensitisation – Category 1
Reproductive toxicity – Category 2
Simple Asphyxiant
Label elements
Hazard pictograms
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 2 of 25
Signal word: WARNING!
Hazards
Contains gas under pressure; may explode if heated.
May cause an allergic skin reaction.
Causes serious eye irritation.
Suspected of damaging fertility or the unborn child.
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing mist or vapours.
Wash skin thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Response
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
IF exposed or concerned: Get medical advice/ attention.
If skin irritation or rash occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Wash contaminated clothing before reuse.
Storage
Store locked up.
Protect from sunlight. Store in a well-ventilated place.
Disposal
Dispose of contents/ container to an approved waste disposal plant.
Other hazards
No data available
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Component CASRN Concentration
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 3 of 25
trans-1-Chloro-3,3,3-trifluoropropene 102687-65-0 >= 20.0 – < 30.0 %
Tris(1-chloro-2-propyl) phosphate 13674-84-5 >= 10.0 – < 20.0 %
Triethyl phosphate 78-40-0 >= 5.0 – < 10.0 %
Polyethylene glycol 25322-68-3 >= 1.0 – < 5.0 %
2-Ethylhexanoic acid potassium salt 3164-85-0 >= 1.0 – < 5.0 %
Carbon dioxide 124-38-9 >= 1.0 – < 5.0 %
Diethylene glycol 111-46-6 >= 1.0 – < 5.0 %
Dimethylbis((1-oxoneodecyl)oxy)stannane 68928-76-7 >= 0.1 – < 1.0 %
4. FIRST AID MEASURES
Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.
Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth
use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by
qualified personnel. Call a physician or transport to a medical facility.
Skin contact: Remove contaminated clothing immediately. Immediately wash skin with soap and
plenty of water. Suitable emergency safety shower facility should be available in work area.
Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing
before reuse. In the case of skin irritation or allergic reactions see a physician.
Eye contact: In case of contact, immediately flush eye with plenty of water. Suitable emergency eye
wash facility should be available in work area.
Ingestion: Do not induce vomiting. Call a physician and/or transport to emergency facility
immediately.
Most important symptoms and effects, both acute and delayed:
Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.
Indication of any immediate medical attention and special treatment needed
Notes to physician: Maintain adequate ventilation and oxygenation of the patient. If breathing is
difficult, oxygen should be administered by qualified personnel. Treatment of exposure should be
directed at the control of symptoms and the clinical condition of the patient.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 4 of 25
5. FIREFIGHTING MEASURES
Suitable extinguishing media: Water fog or fine spray. Dry chemical fire extinguishers. Carbon
dioxide fire extinguishers. Foam. Alcohol resistant foams (ATC type) are preferred. General purpose
synthetic foams (including AFFF) or protein foams may function, but will be less effective.
Unsuitable extinguishing media: Do not use direct water stream. May spread fire.
Special hazards arising from the substance or mixture
Hazardous combustion products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and/or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide. Hydrogen halides.
Unusual Fire and Explosion Hazards: Container may rupture from gas generation in a fire
situation. Blowing agent vaporizes quickly at room temperature. Violent steam generation or eruption
may occur upon application of direct water stream to hot liquids.
Advice for firefighters
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Use water
spray to cool fire exposed containers and fire affected zone until fire is out and danger of reignition has
passed. Fight fire from protected location or safe distance. Consider the use of unmanned hose
holders or monitor nozzles. Immediately withdraw all personnel from the area in case of rising sound
from venting safety device or discoloration of the container. Do not use direct water stream. May
spread fire. Move container from fire area if this is possible without hazard. Burning liquids may be
moved by flushing with water to protect personnel and minimize property damage. Contain fire water
run-off if possible. Fire water run-off, if not contained, may cause environmental damage. Review the
"Accidental Release Measures" and the "Ecological Information" sections of this (M)SDS.
Special protective equipment for firefighters: Wear positive-pressure self-contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). Avoid contact with this material during fire fighting operations. If contact is likely,
change to full chemical resistant fire fighting clothing with self-contained breathing apparatus. If this is
not available, wear full chemical resistant clothing with self-contained breathing apparatus and fight
fire from a remote location. For protective equipment in post-fire or non-fire clean-up situations, refer
to the relevant sections.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures: Isolate area. Keep
unnecessary and unprotected personnel from entering the area. Keep personnel out of confined or
poorly ventilated areas. Keep upwind of spill. Spilled material may cause a slipping hazard. Ventilate
area of leak or spill. Confined space entry procedures must be followed before entering the area.
Refer to section 7, Handling, for additional precautionary measures. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or
groundwater. See Section 12, Ecological Information.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 5 of 25
Methods and materials for containment and cleaning up: Contain spilled material if possible.
Absorb with materials such as: Dirt. Sand. Sawdust. Collect in suitable and properly labeled
containers. Wash the spill site with water. See Section 13, Disposal Considerations, for additional
information.
7. HANDLING AND STORAGE
Precautions for safe handling: Avoid contact with eyes. Avoid breathing vapor. Do not enter
confined spaces unless adequately ventilated. Wash thoroughly after handling. Keep container
closed. Use with adequate ventilation. This material is hygroscopic in nature. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition
temperatures possibly resulting in spontaneous combustion.
Advice on general occupational hygiene
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage: Minimize sources of ignition, such as static build-up, heat, spark or
flame. Flammable vapors may accumulate in some storage situations. Protect from atmospheric
moisture. Store in a dry place. Avoid prolonged exposure to heat and air. Avoid temperatures above
50 C (122 F) See Section 10 for more specific information.
Storage stability
Storage Period: 24 Month
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.
Component Regulation Type of listing Value
trans-1-Chloro-3,3,3-
trifluoropropene
US WEEL TWA 800 ppm
Triethyl phosphate US WEEL TWA 7.45 mg/m3
Polyethylene glycol US WEEL TWA aerosol 10 mg/m3
Carbon dioxide Dow IHG TWA 5,000 ppm
Dow IHG STEL 30,000 ppm
ACGIH TWA 5,000 ppm
ACGIH STEL 30,000 ppm
OSHA Z-1 TWA 9,000 mg/m3 5,000
ppm
CAL PEL PEL 9,000 mg/m3 5,000
ppm
CAL PEL STEL 54,000 mg/m3 30,000
ppm
NIOSH REL TWA 9,000 mg/m3 5,000
ppm
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 6 of 25
NIOSH REL ST 54,000 mg/m3 30,000
ppm
Diethylene glycol DUPONT AEL AEL * Vapour 100 ppm
US WEEL TWA 10 mg/m3
Dimethylbis((1-
oxoneodecyl)oxy)stannane
OSHA Z-1 TWA 0.1 mg/m3 , Tin
ACGIH TWA 0.1 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
ACGIH STEL 0.2 mg/m3 , Tin
Further information: A4: Not classifiable as a human carcinogen; Skin: Danger of
cutaneous absorption
CAL PEL PEL 0.1 mg/m3 , Tin
Further information: S: Skin
CAL PEL STEL 0.2 mg/m3 , Tin
Further information: S: Skin
Exposure controls
Engineering measures: Use engineering controls to maintain airborne level below exposure limit
requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use
only in enclosed systems or with local exhaust ventilation. Exhaust systems should be designed to
move the air away from the source of vapor/aerosol generation and people working at this point.
Lethal concentrations may exist in areas with poor ventilation.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.
Individual protection measures
Eye/face protection: Use safety glasses (with side shields). Where contact with the liquid is likely,
chemical goggles are recommended.
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove
barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate
("EVAL"). Polyvinyl alcohol ("PVA"). Styrene/butadiene rubber. Viton. Examples of acceptable glove
barrier materials include: Butyl rubber. Natural rubber ("latex"). Polyvinyl chloride ("PVC" or "vinyl").
NOTICE: The selection of a specific glove for a particular application and duration of use in a
workplace should also take into account all relevant workplace factors such as, but not limited to:
Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity,
thermal protection), potential body reactions to glove materials, as well as the
instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, use an approved respirator. When respiratory protection is required, use an approved
positive-pressure self-contained breathing apparatus or positive-pressure airline with auxiliary self-
contained air supply. For emergency conditions, use an approved positive-pressure self-contained
breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing
apparatus or positive pressure air line with auxiliary self-contained air supply.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 7 of 25
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state Liquefied gas
Color yellow
Odor No information available.
Odor Threshold No data available
pH No data available
Melting point/ range No data available
Freezing point No data available
Boiling point (760 mmHg) No data available
Flash point > 200 C ( > 392 F)
Evaporation Rate (Butyl Acetate
= 1)
Not available
Flammability (solid, gas) Not applicable to liquids Not expected to form explosive dust-
air mixtures.
Lower explosion limit Not applicable
Upper explosion limit Not applicable
Vapor Pressure No data available
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) No data available
Water solubility Not applicable
Partition coefficient: n-
octanol/water
No data available
Auto-ignition temperature No data available
Decomposition temperature No test data available
Kinematic Viscosity No data available
Explosive properties Not applicableNot explosive
Oxidizing properties No data available
Molecular weight No data available
NOTE: The physical data presented above are typical values and should not be construed as a
specification.
10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability: Stable under recommended storage conditions. See Storage, Section 7.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 8 of 25
Possibility of hazardous reactions: Will not occur by itself.
Conditions to avoid: Product can oxidize at elevated temperatures. Elevated temperatures can
cause pressure buildup in closed containers due to the release of blowing agents. Generation of gas
during decomposition can cause pressure in closed systems.
Incompatible materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases. Avoid unintended contact with isocyanates. The reaction of polyols and isocyanates
generates heat.
Hazardous decomposition products: Decomposition products depend upon temperature, air supply
and the presence of other materials. Decomposition products can include and are not limited to:
Carbon dioxide. Alcohols. Ethers. Hydrocarbons. Hydrogen halides. Ketones. Polymer fragments.
11. TOXICOLOGICAL INFORMATION
Toxicological information appears in this section when such data is available.
Acute toxicity
Acute oral toxicity
Product test data not available. Refer to component data.
Acute dermal toxicity
Product test data not available. Refer to component data.
Acute inhalation toxicity
Product test data not available. Refer to component data.
Skin corrosion/irritation
Product test data not available. Refer to component data.
Serious eye damage/eye irritation
Product test data not available. Refer to component data.
Sensitization
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Single Exposure)
Product test data not available. Refer to component data.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Product test data not available. Refer to component data.
Carcinogenicity
Product test data not available. Refer to component data.
Teratogenicity
Product test data not available. Refer to component data.
Reproductive toxicity
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 9 of 25
Product test data not available. Refer to component data.
Mutagenicity
Product test data not available. Refer to component data.
Aspiration Hazard
Product test data not available. Refer to component data.
COMPONENTS INFLUENCING TOXICOLOGY :
trans-1-Chloro-3,3,3-trifluoropropene
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 Hour, gas, 120000 ppm
Skin corrosion/irritation
Brief contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
No relevant data found.
Sensitization
Did not cause allergic skin reactions when tested in humans.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
This material was not mutagenic in an Ames bacterial assay.
Aspiration Hazard
Based on available information, aspiration hazard could not be determined.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 10 of 25
Tris(1-chloro-2-propyl) phosphate
Acute oral toxicity
LD50, Rat, 1,101 mg/kg OECD Test Guideline 401
Acute dermal toxicity
LD50, Rabbit, > 2,000 mg/kg OECD Test Guideline 402
Acute inhalation toxicity
An LC50/inhalation/4h/rat could not be determined because no mortality of rats was observed
at the maximum achievable concentration. LC50, Rat, 4 Hour, dust/mist, > 5 mg/l
Skin corrosion/irritation
Brief contact may cause slight skin irritation with local redness.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Sensitization
Did not demonstrate the potential for contact allergy in mice.
Specific Target Organ Systemic Toxicity (Single Exposure)
The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
Animal genetic toxicity studies were negative. In vitro genetic toxicity studies were negative.
Aspiration Hazard
No aspiration toxicity classification
Triethyl phosphate
Acute oral toxicity
LD50, Rat, 1,131 mg/kg
Acute dermal toxicity
LD50, Guinea pig, > 21,400 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 2.35 mg/l No deaths occurred at this concentration.
Skin corrosion/irritation
Prolonged contact may cause slight skin irritation with local redness.
Product name: FROTH-PAK 650BF HFO INSUL Polyol Spray
Polyurethane Foam Kit
Issue Date: 11/17/2024
Page 11 of 25
Serious eye damage/eye irritation
May cause moderate eye irritation.
May cause slight corneal injury.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Triethyl phosphate is considered to be a weak cholinesterase inhibitor.
Excessive exposure may produce organophosphate type cholinesterase inhibition.
Signs and symptoms of excessive exposure may be headache, dizziness, incoordination,
muscle twitching, tremors, nausea, abdominal cramps, diarrhea, sweating, pinpoint pupils,
blurred vision, salivation, tearing, tightness in chest, excessive urination, convulsions.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
In laboratory animal studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
Mutagenicity
In vitro genetic toxicity studies were predominantly negative. Animal genetic toxicity studies
were predominantly negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Polyethylene glycol
Acute oral toxicity
Typical for this family of materials. LD50, Rat, > 10,000 mg/kg Estimated.
Acute dermal toxicity
Typical for this family of materials. LD50, Rabbit, > 20,000 mg/kg
Acute inhalation toxicity
Typical for this family of materials. LC50, Rat, 6 Hour, dust/mist, > 2.5 mg/l No deaths
occurred at this concentration.
Skin corrosion/irritation
Prolonged exposure not likely to cause significant skin irritation.
May cause more severe response if skin is abraded (scratched or cut).
Serious eye damage/eye irritation
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May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
For this family of materials:
Did not cause allergic skin reactions when tested in humans.
For this family of materials, sensitization studies done in guinea pigs have been negative.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Evaluation of available data suggests that this material is not an STOT-SE toxicant.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Recent findings of kidney failure and death in burn patients, as well as some studies using
animal burn models, suggest that polyethylene glycol may have been a factor.
The use of topical applications containing this material may not be appropriate in severely
burned patients.
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Carcinogenicity
Polyethylene glycols did not cause cancer in long-term animal studies.
Teratogenicity
Did not cause birth defects or any other fetal effects in laboratory animals.
Reproductive toxicity
In animal studies, did not interfere with reproduction.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
2-Ethylhexanoic acid potassium salt
Acute oral toxicity
Information given is based on data obtained from similar substances. LC50, Rat, 2,043 mg/kg
OECD Test Guideline 401
Acute dermal toxicity
Information given is based on data obtained from similar substances. LD50, Rabbit, > 2,000
mg/kg OECD Test Guideline 402
Acute inhalation toxicity
An LC50/inhalation/4h/rat could not be determined because no mortality of rats was observed
at the maximum achievable concentration. LC0, Rat, 4 Hour, dust/mist, > 0.11 mg/l OECD
Test Guideline 403
Skin corrosion/irritation
Brief contact may cause severe skin irritation with pain and local redness.
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Serious eye damage/eye irritation
May cause severe irritation with corneal injury which may result in permanent impairment of
vision, even blindness. Chemical burns may occur.
Sensitization
Did not cause allergic skin reactions when tested in guinea pigs.
Information given is based on data obtained from similar substances.
No data available
Specific Target Organ Systemic Toxicity (Single Exposure)
The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause significant adverse
effects.
Information given is based on data obtained from similar substances.
Carcinogenicity
No data available
Teratogenicity
Has caused birth defects in laboratory animals. Information given is based on data obtained
from similar substances.
Reproductive toxicity
In animal studies, has been shown to interfere with fertility. Information given is based on data
obtained from similar substances.
Mutagenicity
Animal genetic toxicity studies were negative. In vitro genetic toxicity studies were negative.
Information given is based on data obtained from similar substances.
Aspiration Hazard
No aspiration toxicity classification
Carbon dioxide
Acute oral toxicity
Single dose oral LD50 has not been determined.
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
LC50, Rat, 4 hrs, gas, 58750 ppm
Skin corrosion/irritation
No hazard from gas.
Skin contact with the solid (“dry ice”) may cause frostbite.
Liquid may cause frostbite upon skin contact.
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Serious eye damage/eye irritation
No hazard from gas.
Eye contact with the solid (“dry ice”) may cause freeze burns.
Liquid may cause frostbite.
Sensitization
No relevant data found.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Experiments with humans and animals suggest that continued exposure to 1.5% carbon
dioxide may alter physiological processes, such as acid-base and electrolyte balance in the
blood, calcium-phosphorus metabolism, and neuroendrocrine activity.
Carcinogenicity
Available data are inadequate to evaluate carcinogenicity.
Teratogenicity
Available data are inadequate for evaluation of potential to cause birth defects.
Reproductive toxicity
Available data are inadequate to determine effects on reproduction.
Mutagenicity
No relevant data found.
Aspiration Hazard
Based on physical properties, not likely to be an aspiration hazard.
Diethylene glycol
Acute oral toxicity
In humans, expected to be moderately toxic if swallowed even though oral toxicity was low
when tested in animals. Ingestion of quantities (approximately 65 mL (2 oz.) for diethylene
glycol or 100 mL (3 oz.) for ethylene glycol) has caused death in humans. May cause nausea
and vomiting. May cause abdominal discomfort or diarrhea. Excessive exposure may cause
central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney
failure. LD50, Rat, male, 19,600 mg/kg
Lethal Dose, Human, adult, 2 Ounces Estimated.
Acute dermal toxicity
LD50, Rabbit, 13,330 mg/kg
Acute inhalation toxicity
LC50, Rat, 4 Hour, dust/mist, > 4.6 mg/l The LC50 value is greater than the Maximum
Attainable Concentration. No deaths occurred at this concentration.
Skin corrosion/irritation
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Prolonged contact is essentially nonirritating to skin.
Serious eye damage/eye irritation
May cause slight temporary eye irritation.
Corneal injury is unlikely.
Sensitization
Did not cause allergic skin reactions when tested in humans.
Did not cause allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
The substance or mixture is not classified as specific target organ toxicant, single exposure.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
Based on available data, repeated exposures are not anticipated to cause additional
significant adverse effects.
Carcinogenicity
Diethylene glycol has been tested for carcinogenicity in animal studies and is not believed to
pose a carcinogenic risk to man.
Teratogenicity
Diethylene glycol has caused toxicity to the fetus and some birth defects at maternally toxic,
high doses in animals. Other animal studies have not reproduced birth defects even at much
higher doses that caused severe maternal toxicity.
Reproductive toxicity
Diethylene glycol did not interfere with reproduction in animal studies except at very high
doses.
Mutagenicity
In vitro genetic toxicity studies were negative. Animal genetic toxicity studies were negative.
Aspiration Hazard
No aspiration toxicity classification
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute oral toxicity
LD50, Rat, 892 mg/kg
Acute dermal toxicity
The dermal LD50 has not been determined.
Acute inhalation toxicity
The LC50 has not been determined.
Skin corrosion/irritation
Brief contact may cause skin irritation with local redness.
Serious eye damage/eye irritation
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May cause slight temporary eye irritation.
Sensitization
Has caused allergic skin reactions when tested in guinea pigs.
For respiratory sensitization:
No relevant data found.
Specific Target Organ Systemic Toxicity (Single Exposure)
Available data are inadequate to determine single exposure specific target organ toxicity.
Specific Target Organ Systemic Toxicity (Repeated Exposure)
No relevant data found.
Carcinogenicity
No relevant data found.
Teratogenicity
No relevant data found.
Reproductive toxicity
No relevant data found.
Mutagenicity
Not mutagenic in Ames Test
Aspiration Hazard
No aspiration toxicity classification
12. ECOLOGICAL INFORMATION
Ecotoxicological information appears in this section when such data is available.
Toxicity
trans-1-Chloro-3,3,3-trifluoropropene
Acute toxicity to fish
Material is slightly toxic to aquatic organisms on an acute basis (LC50/EC50 between 10 and
100 mg/L in the most sensitive species tested).
LC50, Oncorhynchus mykiss (rainbow trout), Static, 96 Hour, 38 mg/l, OECD Test Guideline
203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna, 48 Hour, 82 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth inhibition, 106.7 mg/l
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, Growth rate, 115 mg/l
Tris(1-chloro-2-propyl) phosphate
Acute toxicity to fish
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LC50, Pimephales promelas (fathead minnow), 96 Hour, 51 mg/l, OECD Test Guideline 203
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 48 Hour, 131 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 82 mg/l, OECD Test Guideline
201
NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 42 mg/l, OECD Test
Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 3 Hour, 784 mg/l, OECD 209 Test
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, 32 mg/l
Triethyl phosphate
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Leuciscus idus (Golden orfe), static test, 48 Hour, 2,140 mg/l, OECD Test Guideline
203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), static test, 48 Hour, 350 mg/l, OECD Test Guideline 202
or Equivalent
Acute toxicity to algae/aquatic plants
EC50, Desmodesmus subspicatus (green algae), 72 Hour, Growth rate inhibition, 900 mg/l,
OECD Test Guideline 201
Toxicity to bacteria
EC50, activated sludge, Respiration inhibition, 30 min, > 2,985 mg/l, OECD 209 Test
Polyethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), static test, 96 Hour, > 10,000 mg/l, OECD Test
Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
LC50, Daphnia magna (Water flea), 48 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
ErC50, Skeletonema costatum (marine diatom), 72 Hour, Growth rate, > 100 mg/l
2-Ethylhexanoic acid potassium salt
Acute toxicity to fish
Information given is based on data obtained from similar substances.
LC50, Oryzias latipes (Orange-red killifish), 96 Hour, > 100 mg/l, OECD Test Guideline 203
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Acute toxicity to aquatic invertebrates
Information given is based on data obtained from similar substances.
EC50, Daphnia magna (Water flea), 48 Hour, 85.4 mg/l
Acute toxicity to algae/aquatic plants
Information given is based on data obtained from similar substances.
EC50, Desmodesmus subspicatus (green algae), 96 Hour, 49.3 mg/l
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, 25 mg/l
Carbon dioxide
Acute toxicity to fish
May decrease pH of aquatic systems to < pH 5 which may be toxic to aquatic organisms.
LC0, Oncorhynchus mykiss (rainbow trout), 1 Hour, 240 mg/l, Method Not Specified.
Acute toxicity to aquatic invertebrates
Based on data from similar materials
NOEC, Daphnia magna (Water flea), 48 Hour, > 100 mg/l
Diethylene glycol
Acute toxicity to fish
Material is practically non-toxic to aquatic organisms on an acute basis
(LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested).
LC50, Pimephales promelas (fathead minnow), flow-through test, 96 Hour, 75,200 mg/l,
OECD Test Guideline 203 or Equivalent
Acute toxicity to aquatic invertebrates
EC50, Daphnia magna (Water flea), 24 Hour, > 10,000 mg/l
Acute toxicity to algae/aquatic plants
Based on data from similar materials
EC50, Selenastrum capricornutum (green algae), 96 Hour, 6,500 – 13,000 mg/l
Toxicity to bacteria
EC50, activated sludge, 3 Hour, > 1,000 mg/l, OECD 209 Test
Chronic toxicity to fish
Based on data from similar materials
NOEC, Pimephales promelas (fathead minnow), 7 d, 15,380 mg/l
Chronic toxicity to aquatic invertebrates
NOEC, Daphnia magna (Water flea), 21 d, > 15,000 mg/l
Dimethylbis((1-oxoneodecyl)oxy)stannane
Acute toxicity to aquatic invertebrates
Material is moderately toxic to aquatic organisms on an acute basis (LC50/EC50 between 1
and 10 mg/L in the most sensitive species tested).
EC50, Daphnia magna (Water flea), 48 Hour, 39 mg/l, OECD Test Guideline 202
Acute toxicity to algae/aquatic plants
EC50, Pseudokirchneriella subcapitata (green algae), 72 Hour, 7.6 mg/l, OECD Test Guideline
201
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NOEC, Pseudokirchneriella subcapitata (green algae), 72 Hour, 1.2 mg/l, OECD Test
Guideline 201
Toxicity to bacteria
For similar material(s):
EC50, Bacteria, 3 Hour, Respiration rates., 14 mg/l
Persistence and degradability
trans-1-Chloro-3,3,3-trifluoropropene
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Tris(1-chloro-2-propyl) phosphate
Biodegradability: Not readily biodegradable.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301E
Theoretical Oxygen Demand: 1.17 mg/mg
Photodegradation
Test Type: Half-life (indirect photolysis)
Sensitization: OH radicals
Atmospheric half-life: 0.24 d
Method: Estimated.
Triethyl phosphate
Biodegradability: Material is ultimately biodegradable (reaches > 70% mineralization in
OECD test(s) for inherent biodegradability).
10-day Window: Not applicable
Biodegradation: > 90 %
Exposure time: 28 d
Method: OECD Test Guideline 302B or Equivalent
Theoretical Oxygen Demand: 1.58 mg/mg
Polyethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 85 %
Exposure time: 28 d
Method: OECD Test Guideline 301F or Equivalent
Theoretical Oxygen Demand: 1.67 mg/mg
2-Ethylhexanoic acid potassium salt
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Biodegradability: Readily biodegradable. Information given is based on data obtained from
similar substances.
Biodegradation: 99 %
Exposure time: 28 d
Carbon dioxide
Biodegradability: Biodegradation is not applicable.
Diethylene glycol
Biodegradability: Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability.
10-day Window: Pass
Biodegradation: 90 – 100 %
Exposure time: 20 d
Method: OECD Test Guideline 301A or Equivalent
10-day Window: Not applicable
Biodegradation: 82 – 98 %
Exposure time: 28 d
Method: OECD Test Guideline 302C or Equivalent
Theoretical Oxygen Demand: 1.51 mg/mg
Dimethylbis((1-oxoneodecyl)oxy)stannane
Biodegradability: Material is not readily biodegradable according to OECD/EEC guidelines.
Biodegradation: 0 %
Exposure time: 28 d
Method: OECD Test Guideline 301B or Equivalent
Bioaccumulative potential
trans-1-Chloro-3,3,3-trifluoropropene
Bioaccumulation: No relevant data found.
Tris(1-chloro-2-propyl) phosphate
Bioaccumulation: Does not bioaccumulate.
Partition coefficient: n-octanol/water(log Pow): 2.68
Triethyl phosphate
Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.80 Measured
Polyethylene glycol
Partition coefficient: n-octanol/water(log Pow): -0.698 Pow: 0.2 at 30 C
2-Ethylhexanoic acid potassium salt
Bioaccumulation: Bioaccumulation is unlikely. Based on information for a similar material:
Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Carbon dioxide
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Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3).
Partition coefficient: n-octanol/water(log Pow): 0.83 Measured
Diethylene glycol
Bioaccumulation: Bioaccumulation is unlikely.
Partition coefficient: n-octanol/water(log Pow): -1.98 at 20 C
Bioconcentration factor (BCF): 100 Fish Measured
Dimethylbis((1-oxoneodecyl)oxy)stannane
Partition coefficient: n-octanol/water(log Pow): 5.503
Mobility in soil
trans-1-Chloro-3,3,3-trifluoropropene
No relevant data found.
Triethyl phosphate
Potential for mobility in soil is very high (Koc between 0 and 50).
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Partition coefficient (Koc): 48 Estimated.
Polyethylene glycol
No relevant data found.
2-Ethylhexanoic acid potassium salt
Based on information for a similar material:
Potential for mobility in soil is very high (Koc between 0 and 50).
Carbon dioxide
No relevant data found.
Diethylene glycol
Given its very low Henry's constant, volatilization from natural bodies of water or moist soil is
not expected to be an important fate process.
Potential for mobility in soil is very high (Koc between 0 and 50).
Partition coefficient (Koc): < 1 Estimated.
Dimethylbis((1-oxoneodecyl)oxy)stannane
No relevant data found.
13. DISPOSAL CONSIDERATIONS
Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
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INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Recycler. Reclaimer. Incinerator or other thermal destruction device. For additional
information, refer to: Handling & Storage Information, MSDS Section 7 Stability & Reactivity
Information, MSDS Section 10 Regulatory Information, MSDS Section 15
14. TRANSPORT INFORMATION
DOT
Proper shipping name Chemical under pressure, n.o.s.(Carbon dioxide, Nitrogen)
UN number UN 3500
Class 2.2
Packing group
Classification for SEA transport (IMO-IMDG):
Proper shipping name CHEMICAL UNDER PRESSURE, N.O.S. (Carbon dioxide,
Nitrogen)
UN number UN 3500
Class 2.2
Packing group
Marine pollutant No
Transport in bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code
Consult IMO regulations before transporting ocean bulk
Classification for AIR transport (IATA/ICAO):
Proper shipping name Chemical under pressure, n.o.s.(Carbon dioxide, Nitrogen)
UN number UN 3500
Class 2.2
Packing group
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.
15. REGULATORY INFORMATION
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
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Gases under pressure
Simple Asphyxiant
Serious eye damage or eye irritation
Respiratory or skin sensitisation
Reproductive toxicity
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
Section 103
This material does not contain any components with a CERCLA RQ.
Does not contain HFC.
Compliant with Title 42 Chapter 85 Clean Air Act: Subchapter VII American Innovation and
Manufacturing Act of 2020, and Section 612 US EPA Significant New Alternatives Policy.
This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the
U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Pennsylvania Worker and Community Right-To-Know Act:
The following chemicals are listed because of the additional requirements of Pennsylvania law:
Components CASRN
Diethylene glycol 111-46-6
Carbon dioxide 124-38-9
California Prop. 65
This product contains a chemical that is at or below California Propositions 65 s "safe harbor level" as
determined via a risk assessment. Therefore, the chemical is not required to be listed as a Prop 65
chemical on the SDS or label.
United States TSCA Inventory (TSCA)
All components of this product are in compliance with the Active inventory listing requirements of the
U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
16. OTHER INFORMATION
Hazard Rating System
HMIS
Health Flammability
Physical
Hazard
2* 1 3
* = Chronic Effects (See Hazards Identification)
Revision
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Issue Date: 11/17/2024
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Identification Number: 12031877 / A749 / Issue Date: 11/17/2024 / Version: 3.2
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
Legend
ACGIH USA. ACGIH Threshold Limit Values (TLV)
AEL * 8 & 12 hr. TWA
CAL PEL California permissible exposure limits for chemical contaminants (Title 8, Article
107)
Dow IHG Dow Industrial Hygiene Guideline
DUPONT AEL DuPont AEL (Acceptable Exposure Limit)
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Limits for Air
Contaminants
PEL Permissible exposure limit
ST STEL - 15-minute TWA exposure that should not be exceeded at any time during
a workday
STEL Short-term exposure limit
TWA 8-hr TWA
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
Full text of other abbreviations
AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control
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Issue Date: 11/17/2024
Page 25 of 25
Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative
Information Source and References
This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.
DDP Specialty Electronic Materials US, LLC urges each customer or recipient of this (M)SDS to study
it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that
his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US
by | Sep 27, 2025
OUPON ” SAFETY DATA SHEET
DDP Specialty Electronic Materials US,
LLC
Product name: FROTH-PAK 1.75 ISO 12.0 HC Polyurethane Issue Date: 09/02/2022
Foam System GUN Can
Print Date: 06/06/2023
DDP Specialty Electronic Materials US, LLC encourages and expects you to read and understand the
entire (M)SDS, as there is important information throughout the document. We expect you to follow
the precautions identified in this document unless your use conditions would necessitate other
appropriate methods or actions.
eR EES
1. IDENTIFICATION
Product name: FROTH-PAK 1.75 ISO 12.0 HC Polyurethane Foam System GUN Can
Recommended use of the chemical and restrictions on use
Identified uses: For industrial use. Component(s) for the manufacture of urethane polymers. We
recommend that you use this product in a manner consistent with the listed use. If your intended use is
not consistent with the stated use, please contact your sales or technical service representative.
COMPANY IDENTIFICATION
DDP Specialty Electronic Materials US,
LLC
974 Centre Road, Building 730,
Wilmington DE 19805
UNITED STATES
Customer Information Number: 833-338-7668
SDSQuestion-NA@dupont.com
EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 1-800-424-9300
Local Emergency Contact: 800-424-9300
2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Flammable aerosols – Category 1
Gases under pressure – Liquefied gas
Acute toxicity – Category 4 – Inhalation
Skin irritation – Category 2
Eye irritation – Category 2B
Respiratory sensitisation – Category 1
Skin sensitisation – Category 1
Specific target organ toxicity – single exposure – Category 3
Specific target organ toxicity – repeated exposure – Category 2 – Inhalation
Trademark of affiliates of DuPont de Nemours, Inc. Page 1 of 19
