by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART B
BR-25 BRUSHABLE PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
Response:
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber paste-like with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
Page 1 of 5
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 – 100Proprietary
Silica, Amorphous, Fumed 3 – 7112945-52-5
Diethyltoluenediamine (DETDA) 1 – 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 5
BR-25 BRUSHABLE PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.06
Page 3 of 5
BR-25 BRUSHABLE PART B
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
VOC (Volatile Organic Compound): Not Established
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
Page 4 of 5
BR-25 BRUSHABLE PART B
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART A
BR-25 BRUSHABLE PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
HAZARD STATEMENTS
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale amber viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher
temperatures.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated 60 – 1009057-91-4
Silica, Amorphous, Fumed 1 – 5112945-52-5
Toluene Diisocyanate < 0.09626471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
Page 1 of 5
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
BR-25 BRUSHABLE PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polypropylene glycol polymer 1,3
diisocyanatomethylbenzene terminated
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Toluene Diisocyanate
TWA NE NE 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale amber
pH: Not Applicable
PERCENT VOLATILE: Nil
FLASHPOINT AND METHOD: > 160 C (320 F)
VAPOR PRESSURE: < 1 mmHg
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Reacts slowly with water
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
Page 3 of 5
BR-25 BRUSHABLE PART A
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Moisture, oxidizing agents, and alcohols.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Toluene Diisocyanate Not Established Not Established 0.099 mg/l (4 h)
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Toluene Diisocyanate 2 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None Expected
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
Page 4 of 5
BR-25 BRUSHABLE PART A
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Toluene Diisocyanate < 0.096100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene Diisocyanate < 0.09626471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Toluene Diisocyanate < 0.096 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
1 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART A
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART A
BR-25 BRUSHABLE PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
HAZARD STATEMENTS
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale amber viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher
temperatures.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated 60 – 1009057-91-4
Silica, Amorphous, Fumed 1 – 5112945-52-5
Toluene Diisocyanate < 0.09626471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
Page 1 of 5
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
BR-25 BRUSHABLE PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polypropylene glycol polymer 1,3
diisocyanatomethylbenzene terminated
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Toluene Diisocyanate
TWA NE NE 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale amber
pH: Not Applicable
PERCENT VOLATILE: Nil
FLASHPOINT AND METHOD: > 160 C (320 F)
VAPOR PRESSURE: < 1 mmHg
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Reacts slowly with water
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
Page 3 of 5
BR-25 BRUSHABLE PART A
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Moisture, oxidizing agents, and alcohols.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Toluene Diisocyanate Not Established Not Established 0.099 mg/l (4 h)
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Toluene Diisocyanate 2 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None Expected
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
Page 4 of 5
BR-25 BRUSHABLE PART A
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Toluene Diisocyanate < 0.096100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene Diisocyanate < 0.09626471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Toluene Diisocyanate < 0.096 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
1 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART A
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART B
BR-25 BRUSHABLE PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
Response:
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber paste-like with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
Page 1 of 5
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 - 100Proprietary
Silica, Amorphous, Fumed 3 - 7112945-52-5
Diethyltoluenediamine (DETDA) 1 - 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 5
BR-25 BRUSHABLE PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.06
Page 3 of 5
BR-25 BRUSHABLE PART B
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
VOC (Volatile Organic Compound): Not Established
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
Page 4 of 5
BR-25 BRUSHABLE PART B
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART A
BR-25 BRUSHABLE PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
HAZARD STATEMENTS
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale amber viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher
temperatures.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated 60 – 1009057-91-4
Silica, Amorphous, Fumed 1 – 5112945-52-5
Toluene Diisocyanate < 0.09626471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
Page 1 of 5
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
BR-25 BRUSHABLE PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polypropylene glycol polymer 1,3
diisocyanatomethylbenzene terminated
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Toluene Diisocyanate
TWA NE NE 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale amber
pH: Not Applicable
PERCENT VOLATILE: Nil
FLASHPOINT AND METHOD: > 160 C (320 F)
VAPOR PRESSURE: < 1 mmHg
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Reacts slowly with water
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
Page 3 of 5
BR-25 BRUSHABLE PART A
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Moisture, oxidizing agents, and alcohols.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Toluene Diisocyanate Not Established Not Established 0.099 mg/l (4 h)
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Toluene Diisocyanate 2 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None Expected
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
Page 4 of 5
BR-25 BRUSHABLE PART A
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Toluene Diisocyanate < 0.096100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene Diisocyanate < 0.09626471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Toluene Diisocyanate < 0.096 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
1 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART A
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART B
BR-25 BRUSHABLE PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
Response:
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber paste-like with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
Page 1 of 5
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 - 100Proprietary
Silica, Amorphous, Fumed 3 - 7112945-52-5
Diethyltoluenediamine (DETDA) 1 - 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 5
BR-25 BRUSHABLE PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.06
Page 3 of 5
BR-25 BRUSHABLE PART B
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
VOC (Volatile Organic Compound): Not Established
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
Page 4 of 5
BR-25 BRUSHABLE PART B
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART B
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART A
BR-25 BRUSHABLE PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
HAZARD STATEMENTS
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Pale amber viscous liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas. Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher
temperatures.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May be harmful if inhaled. May cause respiratory tract irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated 60 – 1009057-91-4
Silica, Amorphous, Fumed 1 – 5112945-52-5
Toluene Diisocyanate < 0.09626471-62-5
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
Page 1 of 5
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Alcohol resistant foam, carbon dioxide, dry chemical, dry sand, or limestone powder.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
BR-25 BRUSHABLE PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polypropylene glycol polymer 1,3
diisocyanatomethylbenzene terminated
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Toluene Diisocyanate
TWA NE NE 0.005 NE NE NE
STEL NE NE 0.02 NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Viscous liquid
ODOR: Slight
COLOR: Pale amber
pH: Not Applicable
PERCENT VOLATILE: Nil
FLASHPOINT AND METHOD: > 160 C (320 F)
VAPOR PRESSURE: < 1 mmHg
VAPOR DENSITY: Not Established
BOILING POINT: > 250 C (482 F)
SOLUBILITY IN WATER: Reacts slowly with water
VOC (Volatile Organic Compound): Nil Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
Page 3 of 5
BR-25 BRUSHABLE PART A
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Moisture, oxidizing agents, and alcohols.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polypropylene glycol polymer 1,3 diisocyanatomethylbenzene terminated Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Toluene Diisocyanate Not Established Not Established 0.099 mg/l (4 h)
CARCINOGENICITY
Chemical Name NTP Status
IARC
Status
Toluene Diisocyanate 2 2B
IARC: This product contains substances that are classified as possible carcinogens to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: None Expected
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
Page 4 of 5
BR-25 BRUSHABLE PART A
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Toluene Diisocyanate < 0.096100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
CLEAN AIR ACT
Chemical Name Wt.% CAS
Toluene Diisocyanate < 0.09626471-62-5
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Toluene Diisocyanate < 0.096 Cancer
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
1 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART A
SAFETY DATA SHEET
Date Issued : 12/4/2014
MSDS No : BR-25 PART B
BR-25 BRUSHABLE PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: BR-25 BRUSHABLE PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Target Organ Toxicity (Repeated exposure), Category 2
Environmental:
Chronic Hazards to the Aquatic Environment, Category 2
GHS LABEL
Health hazardEnvironment
SIGNAL WORD: WARNING
HAZARD STATEMENTS
H373: May cause damage to organs through prolonged or repeated exposure .
H411: Toxic to aquatic life with long lasting effects.
PRECAUTIONARY STATEMENT(S)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment.
Response:
P314: Get medical advice/attention if you feel unwell.
P391: Collect spillage.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Amber paste-like with a slight amine odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
Page 1 of 5
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 60 - 100Proprietary
Silica, Amorphous, Fumed 3 - 7112945-52-5
Diethyltoluenediamine (DETDA) 1 - 568479-98-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
Page 2 of 5
BR-25 BRUSHABLE PART B
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Silica, Amorphous, Fumed
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Diethyltoluenediamine (DETDA)
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with 'Guidelines for the Selection of Chemical
Protective Clothing' published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Paste-like
ODOR: Slight amine
COLOR: Amber
pH: Not Established
PERCENT VOLATILE: 0.06
Page 3 of 5
BR-25 BRUSHABLE PART B
FLASHPOINT AND METHOD: > 182.2 C (360 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
VOC (Volatile Organic Compound): Not Established
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, and nitrogen oxides.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Silica, Amorphous, Fumed 5000 mg/kg Not Established 2.08 mg/l
Diethyltoluenediamine (DETDA) 738 mg/kg > 2000 mg/kg Not Established
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: This product may cause risk of hazardous effects to the environment.
ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
Page 4 of 5
BR-25 BRUSHABLE PART B
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
None
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains diethyltoluenediamine (DETDA) (CAS No: 68479-98-1) which is subject to TSCA
12(b), Section 4 export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
None
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: New Issue
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 5 of 5
BR-25 BRUSHABLE PART B
by | Sep 27, 2025
Safety Data Sheet
218 BLACK PIGMENT
Safety Data Sheet dated: 2/14/2024 – version 1
Date of first edition: 2/14/2024
1. IDENTIFICATION
Product identifier
Identification of the substance:
Trade name:218 BLACK PIGMENT
Recommended use of the chemical and restrictions on use
Recommended use: N.A.
Restrictions on use:N.A.
Name, address, and telephone number of the chemical manufacturer, importer, or other responsible party
Company:ETECO INC.
1000 S. Linwood Ave.
Santa Ana, CA 92705
Company Phone: + 001 714-480-1370
Responsable:N.A.
Emergency telephone number
Transportation Emergency Call Chemtrec: 800 424 9300
Medical Emergency Information: 800 328 8501
Manufacturer Contact: 1000 S. Linwood Ave Santa Ana, CA 92705 Company Phone: + 001 714-480-1370
2. HAZARD(S) IDENTIFICATION
Classification of the chemical
Label elements
Hazards not otherwise classified identified during the classification process:
None
Additional classification information
HMIS Health:0 = MINIMAL
HMIS Flammability:0 = Not Combustible
HMIS Reactivity:0 = MINIMAL
HMIS P.P.E.:Safety glasses, gloves
NFPA Health:0 = MINIMAL
NFPA Flammability:0 = Not Combustible
NFPA Reactivity:0 = MINIMAL
NFPA Special Risk:NONE
The product is not classified as hazardous according to OSHA Hazard Communication Standard (29 CFR
1910.1200).
The product is not classified as hazardous according to OSHA Hazard Communication Standard (29 CFR 1910.1200).
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Hazard classification within the meaning of 29 CFR 1910.1200:
Mixtures
N.A.
Hazardous components within the meaning of 29 CFR 1910.1200 and related classification:
None
Page n. of1 62/14/2024 Production Name 218 BLACK PIGMENTDate
4. FIRST AID MEASURES
Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
Wash immediately with water.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and label hazardous.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Most important symptoms/effects, acute and delayed
N.A.
Indication of any immediate medical attention and special treatment needed
N.A.
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Storage temperature:N.A.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Appropriate engineering controls:N.A.
Individual protection measures
No data available
Page n. of2 62/14/2024 Production Name 218 BLACK PIGMENTDate
Individual protection measures
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
N.A.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical StateN.A.
Appearance and colour:N.A.
Odour:N.A.
Odour threshold:N.A.
pH:N.A.
Melting point / freezing point:N.A.
Initial boiling point and boiling range:N.A.
Flash point:N.A.
Evaporation rate:N.A.
Upper/lower flammability or explosive limits:N.A.
Vapour density:N.A.
Vapour pressure:N.A.
Relative density:N.A.
Solubility in water:N.A.
Solubility in oil:N.A.
Partition coefficient (n-octanol/water):N.A.
Auto-ignition temperature:N.A.
Decomposition temperature: N.A.
Viscosity:N.A.
Explosive properties:N.A.
Oxidizing properties:N.A.
Solid/gas flammability:N.A.
Other information
Substance Groups relevant propertiesN.A.
Miscibility:N.A.
Fat Solubility:N.A.
Conductivity:N.A.
10. STABILITY AND REACTIVITY
Reactivity
Data not available.
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Data not available.
Incompatible materials
Data not available.
Hazardous decomposition products
Data not available.
11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Toxicological Information of the Preparation
a) acute toxicity Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation Not classified
Page n. of3 62/14/2024 Production Name 218 BLACK PIGMENTDate
Based on available data, the classification criteria are not met
c) serious eye damage/irritation Not classified
Based on available data, the classification criteria are not met
d) respiratory or skin sensitisationNot classified
Based on available data, the classification criteria are not met
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity Not classified
Based on available data, the classification criteria are not met
g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure Not classified
Based on available data, the classification criteria are not met
i) STOT-repeated exposure Not classified
Based on available data, the classification criteria are not met
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met
Substance(s) listed on the IARC Monographs:
None
Substance(s) listed as OSHA Carcinogen(s):
None
Substance(s) listed as NIOSH Carcinogen(s):
None
Substance(s) listed on the NTP report on Carcinogens:
None
12. ECOLOGICAL INFORMATION
Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
N.A.
List of Eco-Toxicological properties of the product
Not classified for environmental hazards.
No data available for the product
N.A.
N.A.
N.A.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in force.
14. TRANSPORT INFORMATION
Not classified as dangerous in the meaning of transport regulations.
UN number
ADR-UN number: N.A.
DOT-UN Number: N.A.
IATA-Un number: N.A.
IMDG-Un number: N.A.
UN proper shipping name
Page n. of4 62/14/2024 Production Name 218 BLACK PIGMENTDate
UN proper shipping name
ADR-Shipping Name: N.A.
DOT Proper Shipping Name: N.A.
IATA-Technical name:N.A.
IMDG-Technical name: N.A.
Transport hazard class(es)
ADR-Class:N.A.
DOT Hazard Class:N.A.
IATA-Class:N.A.
IMDG-Class:N.A.
Packing group
ADR-Packing Group: N.A.
DOT Packing Group:N.A.
IATA-Packing group:N.A.
IMDG-Packing group: N.A.
Environmental hazards
Marine pollutant:No
Environmental Pollutant:N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
Special precautions
Department of Transportation (DOT):
N.A.
Road and Rail (ADR-RID):
N.A.
Air (IATA):
N.A.
Sea (IMDG):
N.A.
15. REGULATORY INFORMATION
USA – Federal regulations
TSCA – Toxic Substances Control Act
SARA – Superfund Amendments and Reauthorization Act
CERCLA – Comprehensive Environmental Response, Compensation, and Liability Act
CAA – Clean Air Act
CWA – Clean Water Act
USA – State specific regulations
TSCA inventory:
All the components are listed on the TSCA inventory
TSCA listed substances:
No substances listed
Section 302 – Extremely Hazardous Substances:
No substances listed
Section 304 – Hazardous substances:
No substances listed
Section 313 – Toxic chemical list:
No substances listed
Substance(s) listed under CERCLA:
No substances listed
CAA listed substances:
No substances listed
CWA listed substances:
No substances listed
Page n. of5 62/14/2024 Production Name 218 BLACK PIGMENTDate
USA – State specific regulations
California Proposition 65
Massachusetts Right to know
Pennsylvania Right to know
New Jersey Right to know
Substance(s) listed under California Proposition 65:
No substances listed
Substance(s) listed under Massachusetts Right to know:
No substances listed
Substance(s) listed under Pennsylvania Right to know:
No substances listed
Substance(s) listed under New Jersey Right to know:
No substances listed
16. OTHER INFORMATION
Safety Data Sheet dated: 2/14/2024 – version 1
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality. The information relates only to the specific material and may not be valid for such material
used in combination with any other material or in any process.
This document was prepared by a competent person who has received appropriate training.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR:European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID:Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG:International Maritime Code for Dangerous Goods.
IATA:International Air Transport Association.
IATA-DGR:Dangerous Goods Regulation by the “International Air Transport Association” (IATA).
ICAO:International Civil Aviation Organization.
ICAO-TI:Technical Instructions by the “International Civil Aviation Organization” (ICAO).
GHS:Globally Harmonized System of Classification and Labeling of Chemicals.
CLP:Classification, Labeling, Packaging.
EINECS:European Inventory of Existing Commercial Chemical Substances.
INCI:International Nomenclature of Cosmetic Ingredients.
CAS:Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO:Ordinance on Hazardous Substances, Germany.
LC50:Lethal concentration, for 50 percent of test population.
LD50:Lethal dose, for 50 percent of test population.
DNEL:Derived No Effect Level.
PNEC:Predicted No Effect Concentration.
TLV:Threshold Limiting Value.
TWATLV:Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL:Short Term Exposure limit.
STOT:Specific Target Organ Toxicity.
WGK:German Water Hazard Class.
KSt:Explosion coefficient.
The information in this SDS is provided all the relevant data fully and truly. However, the information is provided without any
warranty on their absolute extensiveness and accuracy. This SDS was prepared to provide safety preventive measures for the users
who have got professional training. The personal user who obtained this SDS should make independent judgment for the
applicability of this SDS under special conditions. In these special cases, we do not assume responsibility for the damage.
Page n. of6 62/14/2024 Production Name 218 BLACK PIGMENTDate
by | Sep 27, 2025
SDS
SAFETY DATA SHEET
SDS Number:
Page 1 of 7
BD310, BD530, BD560, BD590
Acrylic Structural Bonding Adhesive – Cartridges
Revision No.: 4
Date:07/26/2018
3
Section 1 IDENTIFICATION
Product Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive Cartridges
Manufacturer: Big Dog Adhesives, LLC
615 S 4
th
Street
Elkhart, INDIANA, USA 46516-2717
Phone: 1-833-244-3644 (1-833-BIG-DOGG) Fax: 1-833-244-3649 (1-833-BIG-DOGZ)
Email: sales@bigdogadhesives.com Website: www.bigdogadhesives.com
Trade Name: BD310, BD530, BD560, BD590 Acrylic Structural Bonding Adhesive
Materials Uses: Bonding and Adhering various plastic surfaces, fiberglass surfaces, gel coat, and
various metals, including aluminum, steel, and stainless steel
In Case of Emergency Contact CHEMTREC: 800-424-9300 (USA)
703-527-3887 (INTERNATIONAL)
Section 2 HAZARD IDENTIFICATION
GHS Classification:
CATEGORY
SIGNAL
WORD
HAZARD STATEMENT(S)
Physical
Flammable Liquids, Category 2
DANGER
H225 Highly flammable liquid and vapor
Health
Acute Oral Toxicity, Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2B
Skin Sensitization, Category 1
STOT SE, Category 3
WARNING
WARNING
WARNING
WARNING
WARNING
H302 Harmful if swallowed
H316 Causes skin irritation
H320 Causes eye irritation
H317 May cause an allergic skin reaction
H335 May cause a respiratory irritation
Environmental
Acute, Category 3
Chronic, Category 4
H402 Harmful to aquatic life
H413 May cause long lasting harmful effects to aquatic life
GHS Precaution Statements:
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261 Avoid breathing dust/fume/mist/vapors/spray.
P264 Wash hands (or other affected skin surfaces) thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
SDS
SAFETY DATA SHEET
SDS Number:
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P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370/P378 In case of fire: Use dry chemical or CO2 to extinguish
P305/P351/P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P301/P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302/P352 IF ON SKIN: Wash with plenty of soap and water.
P333/P313 If skin irritation or rash occurs get medical advice/attention.
Storage:
P403 Store in a well-ventilated place .
P410 Protect from sunlight.
P411 Store at temperatures not exceeding 25
O
C (75
O
F).
Disposal:
P501 Dispose of contents/containers in accordance with local/regional/national/international regulations.
Route of Entry: Eye contact, skin contact, inhalation, and ingestion.
Target Organs: Skin, eyes, respiratory tract, digestive tract, liver, kidney, olfactory and Central Nervous System
(CNS).
Skin Contact: May cause irritation of the skin. Prolonged exposure may cause sensitization. Preexisting skin
conditions may be aggravated by exposure to this material.
Eye Contact: May cause irritation and/or sensitization.
Respiratory Contact: Respiratory tract irritant. Prolonged exposure may result in dizziness, nausea, headache,
and anesthetic effects. May cause sensitization. Preexisting respiratory conditions may be aggravated by
exposure to this product. May cause CNS depression.
Ingestion: Not an expected route of entry. If ingested it may cause irritation to the gastrointestinal tract.
ADHESIVE:
HMIS (United States) NFPA (United States) WHMIS (Canada): B2, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
ACTIVATOR:
HMIS (United States) NFPA (United States) WHMIS (Canada): C, D2B
Health 2
Flammability 3
3
Reactivity 2
PPE B
2
2
SDS
SAFETY DATA SHEET
SDS Number:
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Section 3 COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS # % by Weight
Adhesive: Methyl Methacrylate Monomer 80-62-6 40 70%
Maleic Acid Powder 110-16-7 1 5%
Non Hazardous Ingredients Not Applicable 15 35%
Activator: Methyl Methacrylate Monomer 80-62-6 40 70%
Non Hazardous Ingredients Not Applicable 15 35%
Section 4 FIRST-AID MEASURES
Skin: Remove contaminated clothing. Flush skin with water, then wash affected areas with soap and water. If
irritation develops, seek medical attention. Wash or dispose of clothing before reuse.
Eye: Flush eyes with water for 15 minutes. Remove contact lenses prior to water flush if possible. Seek
immediate medical attention.
Respiratory: Remove patient to fresh air. If patient is having difficulty breathing, seek immediate medical
attention. If not breathing, clear airway and start mouth-to-mouth artificial respiration (or use bag-mask
respirator). Seek immediate medical attention.
Ingestion: Give patient water to dilute material in stomach. DO NOT induce vomiting. Seek immediate medical
attention. If vomiting occurs naturally, have person lean forward to reduce risk of aspiration. DO NOT give
anything by mouth to an unconscious person.
Section 5 FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: In case of fire, use dry chemical or CO2. Water spray may cause frothing.
Specific Hazards Arising from the Chemical: Sealed containers of adhesive may rupture violently at elevated
temperatures due to polymerization. Organic peroxides can decompose violently if heated while confined.
Special Protective Equipment and Precautions for Firefighters: Use self-contained breathing apparatus
(SCBA) and protective clothing.
Flash Point and Method: 50
o
F (10
o
C). Fine mists may be explosive below the flash point. Tag Closed Cup.
Flammability Classification: Class 1B.
Risk of Explosion due to Mechanical Impact: Not Applicable.
Risk of Explosion due to Static Discharge: Not Applicable.
Hazardous Products of Combustion: Carbon Oxides (CO and CO2), Methyl Methacrylate, and various
Hydrocarbons.
Autoignition Temp.: 790
o
F (421
o
C).
LEL: 1.7%.
UEL: 12.5%.
Section 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures: For large spill or leak wear self-
contained breathing apparatus (SCBA) and appropriate PPE.
Environmental Precautions: Keep out of sewers and drains.
Clean-Up Methods and Materials: Absorb with an inert material and place in an appropriate container for
disposal.
Section 7 HANDLING AND STORAGE
SDS
SAFETY DATA SHEET
SDS Number:
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Handling Precautions: Avoid breathing vapors. Use in a well-ventilated area. Wear rubber gloves (nitrile or
butyl) and chemical resistant apron. Wear chemical splash goggles. Do not reuse empty containers.
Storage Precautions: Store in a cool, dry, well-ventilated area at temperatures less than 75
o
F (25
o
C). Storage
above 212
o
F (100
o
C) may cause explosive decomposition. Avoid storage in direct sunlight. Keep containers
closed when not in use. Keep away from heat sources, sparks, and open flames.
Section 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control Parameters and Exposures:
Material Name: Exposure Limits:
Maleic Acid Powder (CAS 110-16-7): ACGIH TLV: TWA 20 ppm
Methyl Methacrylate (CAS 80-62-6): OSHA PEL: TWA 100 ppm
ACGIH TLV: TWA 50 ppm
STEL 100 ppm
Engineering Controls: Provide adequate explosion proof ventilation (general or local exhaust). Ensure that a
working eyewash and safety shower are in the work area.
Individual Protection Measures and PPE:
Eye / Face Protection: Wear safety glasses with side shields or splash goggles.
Skin Protection: Chemical resistant gloves (nitrile or butyl) and chemical resistant apron are recommended.
Respiratory Protection In case of insufficient ventilation, wear an approved (NIOSH) respirator with organic
vapor cartridge and dust/mist pre-filter.
Thermal Hazards: None.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Adhesive Activator
Appearance: Colored (various) Paste Colored (various) Liquid
Odor: Mild Sweet Mild Sweet
Odor Threshold: Not Available Not Available
pH: 4.0 6.0 4.0 6.0
Melting Point / Freezing Point: -54
o
F (-48
o
C) -54
o
F (-48
o
C)
Initial Boiling Point and Boiling Range: 212
o
F (100
o
C) 212
o
F (100
o
C)
Flash Point and Method: 50
o
F (10
o
C) Tag Closed Cup 50
o
F (10
o
C) Tag Closed Cup
Evaporation Rate: 3 3
Flammability: Class 1B Class 1B.
Lower Explosion Limit: 1.7% 1.7%
Upper Explosion Limit: 12.5% 12.5%
Vapor Pressure: 28 mm Hg @ 68
o
F (20
o
C) 28 mm Hg @ 68
o
F (20
o
C)
Vapor Density: 3.5 3.5
Relative Density: 7.7 8.8 lbs./gallon 7.7 8.8 lbs./gallon
Solubility(ies): Not Available Not Available
Partition Coefficient (n-Octanol in Water): Not Applicable Not Applicable
Auto-Ignition Temperature: 790
o
F (421
o
C) 790
o
F (421
o
C)
Decomposition Temperature: Not Available Not Available
Viscosity (Dynamic CPS/mPA-s): 40k to 120k 60k to 150k
Percent Volatile: Not Available Not Available
Specific Gravity: 0.93 1.05 0.93 1.05
VOC: < 50 g/L of mixed product < 50 g/L of mixed product
SDS
SAFETY DATA SHEET
SDS Number:
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Section 10 STABILITY AND REACTIVITY
Reactivity: Product is stable as supplied and when used as intended. Product can become unstable under
certain conditions or in contact with incompatible materials.
Chemical Stability: Not Available.
Possibility of Hazardous Reactions: Polymerization may occur under certain conditions.
Conditions to Avoid: Avoid extreme temperatures, open flames, sparks, and direct sunlight.
Materials to Avoid (Incompatibility): Oxidizing agents and conditions, strong acids and alkalies, oxygen-free
atmospheres, inert gas blanketing, and free radical initiators.
Hazardous Decomposition Products: Carbon Oxides (CO, CO2), Methyl Methacrylate, and various
Hydrocarbons.
Section 11 TOXICOLOGICAL INFORMATION
Acute Toxicity to Animals:
Adhesive: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Maleic Acid Powder (CAS 110-16-7): LC50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
LD50 = Not Determined
Activator: Methyl Methacrylate (CAS 80-62-6): LC50 = 7093 ppm (4 hour inhalation, rat)
LD50 = 7940 mg/kg (oral, rat)
LD50 > 7550 mg/kg (dermal, rabbit)
Acute Toxicity to Humans: This product has not been tested for human effects. No additional information.
Chronic Toxicity to Animals: This product has not been tested for animal effects. No additional information.
Chronic Toxicity to Humans: This product has not been tested for human effects. No additional information.
Skin Corrosion / Irritation: Not Available.
Eye Damage / Irritation: Not Available.
Respiratory Sensitization: Not Available.
Skin Sensitization: Not Available.
Mutagenicity: Classifiable as none for human.
Carcinogenicity: Not classifiable for human or animal.
Reproductive Toxicity: Not Available.
Teratogenic Effects: Classifiable as none for human.
STOST- Single Exposure: Not Available.
STOST Repeated Exposure: Not Available.
Aspiration Hazard: Not Available.
Section 12 ECOLOGICAL INFORMATION
Ecotoxicity: This product contains components that may be harmful to aquatic organisms and may cause long
term adverse effects in an aquatic environment. Do not empty into drains.
Persistence and Degradability: Not Available.
Bioaccumulative Potential: This product contains components with the potential to bio-accumulate.
SDS
SAFETY DATA SHEET
SDS Number:
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Mobility in Soil: Not Available.
Other Adverse Effects: Not Available.
Section 13 DISPOSAL CONSIDERATIONS
Disposal Methods:
Adhesive: Adhesive is considered Hazardous Waste Product per RCRA 40 CFR 261 and is classed as D001.
Spilled, contaminated, or waste material should be put into a suitable container and handled according to
Federal, State, and local regulations. Contact a qualified waste management company for assistance.
Activator: Not a hazardous waste product (RCRA 50 CFR 261). May be disposed of in landfill or by
incineration. Dispose of in accordance with Federal, State, and local regulations.
DANGER! Rags, steel wool, and waste soaked with this product may spontaneously catch fire if improperly
discarded or stored. Waste should be immediately placed in a sealed water filled container.
Section 14 TRANSPORT INFORMATION
UN Number: UN1133.
UN Proper Shipping Name: Adhesives (DOT), Flammable Liquid.
Transport Hazard Class: 3.
Packing Group: II.
DOT Classification: UN1133, Adhesives, Flammable Liquid, Hazard Class 3, Packing Group II, Limited
Quantity.
Special Provision for Transport: 1 Liter (0.3 gallon) or less may use Limited Quantity exceptions (49 CFR
172.102 & 49 CFR 173.150 (a) (2)).
ADR / RID Classification: Class 3 Flammable Liquid.
ICAO/IATA Classification: Class 3 Flammable Liquid.
IMO/IMDG Classification: Class 3 Flammable Liquid.
Marine Pollutant: No additional information.
Section 15 REGULATORY INFORMATION
U.S. Federal Regulations
Chemical (& CAS Number)
SARA 302
(EHS)TPQ
SARA 304
(EHS)Rq
SARA 313
de minimis
CERCLA
Rq
CAA
112(r) TQ
RCRA
Code
Methyl Methacrylate (CAS 80-62-6) 1.0 1000 U162
Maleic Acid Powder (CAS 110-16-7)
All quantities are in pounds.
State Regulations
Chemical (& CAS Number)
CA
Prop 65
MA
RTK
MN
RTK
NJ
RTK
PA
RTK
RI
RTK
Methyl Methacrylate (CAS 80-62-6) X X X X X
Maleic Acid Powder (CAS 110-16-7) X X X
TSCA (Toxic Substances Control Act): All components of this product are on the TSCA Inventory or are
exempt from TSCA Inventory Requirements.
SDS
SAFETY DATA SHEET
SDS Number:
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International Regulations:
DSL (Canada Domestic Substance List): All components of this product are on the DSL (Canada Domestic
Substance List) or are exempt from DSL.
EINECS: Not Available.
WHMIS: B2, C, D2B.
Section 16 OTHER INFORMATION
Changes to This Revision: July 9, 2018
Prepared By: Louis J. Giovannini
Telephone: USA 520-271-7313
Internet: lou@bigdogadhesives.com
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above
named manufacturer nor any of its subsidiaries assumes any liability whatsoever for accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
END OF SDS DOCUMENT
by | Sep 27, 2025
D
Revision Date 08/Feb/2018
7. IDENTIFICATION OF THE SUBSTANC MIXTURE AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Description: ATPRIM E 2A
Other means of identification
SAP ID(s): 5582
Chemical Family Aromatic Isocyanate
Recommended use of the chemical and restrictions on use
Recommended Use Two-Component Urethane-Based Primer System
Uses advised against No information available
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Polynt Composites USA, Inc. In Canada
99 East Cottage Avenue Polynt Composites Canada Inc
Carpentersville IL 60110 29 Regan Road
Brampton, Ontario
L7A 1B2
Emergency Telephone Chemtrec: 1-800-424-9300 (in U.S. & Canada)
+1-703-741-5970 (international)
E-mail address MSDS@polynt.com
(a HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute toxicity – Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 2
Serious eye damageleye irritation Category 2
Respiratory sensitization Sub-category 1B
Skin sensitization Sub-category 1B
Carcinogenicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific target organ toxicity (repeated exposure) Category 2
Label elements
Emergency Overview
Danger
jazard statements
[Harmful if inhaled
Causes skin irritation
auses serious eye irritation
uspected of causing cancer
jay cause allergy or asthma symptoms or breathing d ifficulties if inhaled
IMay cause an allergic skin reaction
lay cause respiratory irritation
IMay cause damage to organs through prolonged or repeated exposure
Page 1/9
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 09/19/2006
SDS No : AF-4 DEFOAMER
Date Revised : 12/03/2020
ENTERPRISES Revision No : 6
AF-4 DEFOAMER
a
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: AF-4 DEFOAMER
GENERAL USE: Anti-foaming agent; defoamer
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
1479] Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
i ee
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Carcinogenicity, Category 2
Target Organ Toxicity (Single exposure), Category 3
Aspiration Hazard, Category 1
Physical:
Flammable Liquids, Category 4
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H227: Combustible liquid.
H351: Suspected of causing cancer.
336: May cause drowsiness or dizziness.
304: May be fatal if swallowed and enters airways.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P370+P378: In case of fire: Use water spray, carbon dioxide, dry chemical, or foam for extinction.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312: Call a POISON CENTER/doctor/physician if you feel unwell.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/physician.
P331: Do NOT induce vomiting.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 07/23/2024
SDS number : 6902 BLACK
6902 BLACK
1. Identification
Product identifier: 6902 BLACK
Relevant identified uses: Pigment
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. Hazard identification
Classification of the substance or mixture
This product does not meet the criteria for classification.
Label elements
Precautionary statement(s)
Prevention:
P201: Obtain special instructions before use.
P264: Wash thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P281: Use personal protective equipment as required.
Response:
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition/information on ingredients
Chemical name % w/wCAS No.
Carbon black 30 – 601333-86-4
Comments: There are no other ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment under OSHA’s 29 CFR 1910.1200.
4. First-aid measures
Eye: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention if irritation develops.
Skin: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
Ingestion: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the patient
is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops.
Indication of immediate medical attention and special treatment needed, if necessary: Symptomatic and supportive therapy as needed.
Page 1 of 5
Following severe exposure medical follow-up should be monitored for at least 48 hours.
5. Fire-fighting measures
Suitable extinguishing media: Water spray, carbon dioxide, dry chemical, or foam.
Hazardous combustion products: Carbon monoxide and carbon dioxide.
Fire fighting procedures: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not release runoff
from fire control methods to sewers or waterways.
Fire fighting equipment: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of unmanned
hose holders or monitor nozzles for fighting large fires.
6. Accidental release measures
Small spill: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE) as specified in the SDS or
the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain spill. Prevent product from
entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or vermiculite) and transfer to a
container for disposal according to local/national regulations.
Environmental precautions
Water spill: Do not discharge into drains, surface waters, or groundwater.
General procedures: Refer to section 8 of SDS for personal protection details.
Release notes: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if necessary.
7. Handling and storage
General procedures: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open containers.
Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
Precautions for safe handling: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle
and use in a manner consistent with good industrial/manufacturing techniques and practices.
Conditions for safe storage: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid
unnecessary contact. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
Storage temperature: 65-80 F (18-27 C)
Shelf life: 12 months from date of shipment under manufacturers recommended storage conditions.
8. Exposure controls/personal protection
Exposure controls
Control parameters
Occupational exposure limit values
Chemical name Type ppm mg/m
3
Carbon black
OSHA PEL TWA – 3.5
ACGIH TLV TWA – 3.5
NIOSH REL TWA – 3.5
Appropriate engineering controls: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
Individual protection measures, such as personal protective equipment
Eye / face protection: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
Skin protection – hand protection: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be
used to prevent contact with eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer
maximum protection.
Respiratory protection: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may
be necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
Page 2 of 5
6902 BLACK
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Skin protection – other: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
Occupational hygiene practices: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in immediate
work area should be prohibited. Wash hands before eating.
Other use precautions: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Training is
important. Follow all label precautions.
9. Physical and chemical properties
Physical state: Viscous liquid
Color: Black
Odor: Slight
pH: No data available
Initial boiling point and boiling range: No data available
Flash point: > 93.3 C (200 F)
Vapor pressure: No data available
Relative vapor density: No data available
Relative density: 1.06 (water=1) at 25 C (77 F)
Solubility: Negligible
Viscosity: No data available
VOC content: Nil
10. Stability and reactivity
Reactivity: Hazardous reactions will not occur under normal transport or storage conditions.
Chemical stability: This product is stable under normal ambient conditions of temperature and pressure.
Conditions to avoid: High temperatures and sources of ignition.
Possibility of hazardous reactions: No data available
Hazardous decomposition products: Carbon monoxide and carbon dioxide.
Incompatible materials: Strong oxidizing agents.
11. Toxicological information
Acute toxicity
Chemical name LD50 (oral) mg/kg(rat) LD50 (dermal) mg/kg(rabbit) LC50 (inhalation) mg/l
Carbon black > 8000 mg/kg Rat No data available No data available
Skin corrosion / irritation: No data available
Serious eye damage / irritation: No data available
Respiratory or skin sensitization: No data available
Germ cell mutagenicity: No data available
Carcinogenicity
Chemical name IARC
Carbon black 2B
Reproductive toxicity: No data available
Specific Target Organ Toxicity – single exposure: No data available
Specific Target Organ Toxicity – repeated exposure: No data available
Aspiration hazard: No data available
Page 3 of 5
6902 BLACK
12. Ecological information
Ecotoxicological information: No specific ecological data are available for this product. Refer to Section 6 for information regarding accidental
release and Section 15 for regulatory reporting information.
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Environmental data: No data available
Mobility in soil: No data available
13. Disposal considerations
Disposal methods: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. Transport information
USA Department of Transport Regulations (DOT): Not Regulated
ICAO / IATA – air: Not Regulated
IMO / IMDG – sea: Not Regulated
15. Regulatory information
UNITED STATES
SARA Section 311/312 Hazard Categories
311/312 Health hazards: Refer to Section 2 for hazard classification.
313 reportable ingredients: This product does not contain any substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
CERCLA Hazardous Substances and Reportable Quantities (RQ)
CERCLA regulatory: This product does not contain any substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
TSCA (The Toxic Substances Control Act)
TSCA regulatory: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA Status: This product or its components are listed in or exempt from the TSCA inventory requirements.
Occupational safety and health administration (osha)
29 cfr1910.119—process safety management of highly hazardous chemicals: None of the chemicals in this product are considered highly
hazardous by OSHA.
California Proposition 65: WARNING: This product can expose you to chemicals including [see table below], which is [are] known to the
State of California to cause cancer. For more information, go to www.P65Warnings.ca.gov.
Chemical name % w/w Listed
Carbon black 30 – 60 Cancer
USA OSHA Hazard Communication Standard (29CFR 1910.1200): The contents of the SDS comply with the OSHA Hazard
Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS Regulatory Status: This product has been classified according to the hazard criteria of the CPR and the SDS contains all the
information required by the CPR.
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL): All components in this product are listed in or exempted from the
Domestic Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. Other information
Page 4 of 5
6902 BLACK
Reason for issue: New Issue
Date Prepared: 07/23/2024
HMIS rating
Health 1
Flammability 1
Physical hazard 0
Personal protection X
NFPA codes
1
1 0
HMIS ratings notes: Personal Protection: See Section 8
Manufacturer disclaimer: This information is furnished without warranty, expressed or implied, except that is accurate to the best knowledge of
BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes no legal
responsibility for use or reliance upon this data.
Page 5 of 5
6902 BLACK