by | Sep 27, 2025
SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute toxicity Oral – Category 5
Carcinogenicity – Category 2
Eye Irritation – Category 2A
Skin Irritation – Category 3
Specific Target Organ Toxicity – Single Exposure – Category 1
Pictograms
Signal Word
Danger
Hazardous Statements – Health
H303 – May be harmful if swallowed
H351 – Suspected of causing cancer.
H319 – Causes serious eye irritation
H316 – Causes mild skin irritation
H370 – Causes damage to organs.
Precautionary Statements – General
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P103 – Read label before use.
Precautionary Statements – Prevention
P201 – Obtain special instructions before use.
10-1404
Sep 27, 2021
SAFETY DATA SHEET
Sep 27, 2021
Polycoat Products
14722 Spring Ave, Santa Fe Springs, CA, US, 90670-5108
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER’S IDENTIFICATION
Version: 1.0
Date Printed: Sep 27, 2021
Supersedes Date: N.A.
Product ID:
Product Name:
10-14101
PC 412-65D-BLACK, B-Side
Emergency Phone:
Information Phone Number:
Chemtrec:800-424-9300 (account: CCN1217) OR International:703-527-3887 (account:CCN1217)
(562) 802-8834
Fax: (562) 921-7363
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 1 Page
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P264 – Wash thoroughly after handling.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P270 – Do not eat, drink or smoke when using this product.
Precautionary Statements – Response
P312 – Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P332 + P313 – If skin irritation occurs: Get medical advice/attention.
P308 + P311 – IF exposed or concerned: Call a POISON CENTER/doctor.
P321 – Specific treatment (see section 4 on this SDS).
Precautionary Statements – Storage
P405 – Store locked up.
Precautionary Statements – Disposal
P501 – Dispose of contents/ container to an approved waste disposal plant.
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a
POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with
plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Eye Contact
Remove source of exposure or move person to fresh air. Rinse eyes cautiously with lukewarm, gently flowing water for several minutes,
while holding the eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing for a duration of 15-20 minutes. Take
care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists: Get medical advice/attention.
Ingestion
IF exposed or concerned: Get medical advice/attention.
Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. If vomiting occurs naturally, lie on your side, in the recovery
position.
Give 1 or 2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious
person.
CAS Chemical Name % By Weight
0000107-21-1 ETHYLENE GLYCOL 10% – 18%
0005285-60-9 BENZENEAMINE, 4,4′-METHYLENEBIS[n-(1-
METHYLPROPROPYL)-
8% – 14%
0001333-86-4 CARBON BLACK 4% – 7%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 2 Page
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide water spray or fog is recommended. Water spray is recommended to cool or protect exposed
materials or structures. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous
use of foam and water on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Specific Hazards in Case of Fire
Sudden reaction and fire may result when the product is exposed to oxidizing agents.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene),
goggles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Clean up immediately.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing
appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work
area. Residues from spill cleanup may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous
waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
PC 412-65D-BLACK, B-Side 8 www.Polycoat.com of 3 Page
product is used and stored.
Store in tightly sealed containers to protect from atmospheric moisture. Store in a cool dry area. Store liquid in containers above ground
and surround by dikes to contain spills or leaks.
Ground and bond containers and receiving equipment. Avoid static electricity by grounding.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Respiratory Protection
If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker, a respiratory protection
program that meets or is equivalent to OSHA 29 CFR 1910.134 and ANSI Z88.2 should be followed. Check with respiratory protective
equipment suppliers.
When airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air
respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-container breathing apparatus.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
CARBON
BLACK
3.5 1
ETHYLENE
GLYCOL
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
CARBON
BLACK
3.5a 1 3 (I)
ETHYLENE
GLYCOL
25 (v) 50 (v) 10 (I,H)
(I) – Inhalable fraction
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Appearance Liquid
Auto Ignition Temp N.A.
Coefficient Water/Oil N.A.
Decomposition Pt N.A.
Evaporation Rate
Flammability
Slower than ether
N/A
8.77 lb/gal
1.05
Density
Specific Gravity
VOC Regulatory
0.00 lb/gal
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 4 Page
Flammability N/A
Flash Point 95 C
Flash Point Symbol N.A.
Freezing Point N.A.
High Boiling Point N.A.
Low Boiling Point 110 C
Lower Explosion Level
Melting Point
Odor Description
Odor Threshold
pH
Upper Explosion Level
Vapor Density
Vapor Pressure
N.A.
N.A.
Amine-Like
N.A.
N.A.
N.A.
Heavier than air
N.A.
Viscosity N.A.
VOC Part A & B Combined N.A.
Water Solubility N.A.
SECTION 10) STABILITY AND REACTIVITY
Stability
Material is stable at standard temperature and pressure.
Conditions to Avoid
Heat, high temperature, open flame, and moisture. Avoid contact with incompatible materials.
Hazardous Reactions/Polymerization
Will not occur.
Incompatible Materials
This product will react with any material containing isocyanate. Some reactions can be violent.
Hazardous Decomposition Products
Combustion products: organic vapors and thermal decomposition fragments.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Product may be absorbed through skin and cause nausea, headache, and general discomfort.
Causes mild skin irritation
Serious Eye Damage/Irritation
Vapors can irritate the eyes. Chemical burns may result due to overexposure. Affects of exposure may be delayed.
Causes serious eye irritation
Respiratory/Skin Sensitization
Inhalation : Severe overexposure may induce respiratory sensitization with asthma like symptoms. These symptoms may be immediate or
delayed up to several hours after exposure. Chronic exposures may result in permanent decreases in lung function.
Skin sensitization may develop after repeated and/or prolonged contact.
Based on available data, the classification criteria are not met.
Carcinogenicity
Suspected of causing cancer.
Germ Cell Mutagenicity
Based on available data, the classification criteria are not met.
Reproductive Toxicity
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 5 Page
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity – Single Exposure
Causes damage to organs.
Specific Target Organ Toxicity – Repeated Exposure
Based on available data, the classification criteria are not met.
0000107-21-1 ETHYLENE GLYCOL
The substance may cause effects on kidneys as a result of repeated ingestion.
Aspiration Hazard
Based on available data, the classification criteria are not met.
Acute Toxicity
If ingested : In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and
injury may be severe and cause death.
Repeated and prolonged exposure at low levels may result in adverse skin and eye effects, liver and kidney disorders.
May be harmful if swallowed
Likely Routes of Exposure
Inhalation, Ingestion, Skin contact, Eye contact
0000107-21-1 ETHYLENE GLYCOL
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.
Chronic Exposure
0001333-86-4 CARBON BLACK
CARCINOGENIC EFFECTS: In 1996, the IARC reevaluated Carbon Black as a Group 2B carcinogen. This evaluation is given to carbon
black for which there is inadequate human evidence, but sufficient animal evidence.
Prolonged inhalation of Carbon black can result in lung disease. Symptoms include coughing, shortness of breath, wheezing and reduced
pulmonary function.
Potential Health Effects – Miscellaneous
0001333-86-4 CARBON BLACK
Is an IARC, NTP or OSHA carcinogen. Has shown carcinogenic activity in laboratory animals at high doses. Significance to man is
unknown. The following medical conditions may be aggravated by exposure: asthma, respiratory disease. WARNING: This chemical is
known to the State of California to cause cancer.
0001333-86-4 CARBON BLACK
LC50 (rat): 6750 mg/m3 (4-hour exposure); cited as 27000 mg/m3 (27 mg/L) (1-hour exposure) (3)
0000107-21-1 ETHYLENE GLYCOL
LD50 (oral, rat): 5.89 g/kg; 8.54 g/kg; 13.0 g/kg (5)
LD50 (oral, mouse): 7.5 g/kg; 15.28 g/kg (5,6)
LD50 (oral, guinea pig): 6.6 g/kg; 11.0 g/kg (5)
LD50 (oral, rabbit): 5.0 g/kg (5)
LD50 (dermal, rabbit): 9.5 g/kg (6)
SECTION 12) ECOLOGICAL INFORMATION
Toxicity
Based on available data, the classification criteria are not met.
Mobility in Soil
0000107-21-1 ETHYLENE GLYCOL
Adsorption to solid soil phase is not expected. Ethylene glycol will preferentially be distributed into the compartment water.
Other Adverse Effects
No data available.
Bioaccumulative Potential
0000107-21-1 ETHYLENE GLYCOL
No potential for bioaccumulation.
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 6 Page
No potential for bioaccumulation.
Persistence and Degradability
0000107-21-1 ETHYLENE GLYCOL
Readily biodegradable.
0001333-86-4 CARBON BLACK
Carbon Black’s insolubility in water results in it not being biodegradable in any medium or by biota. It is considered persistent in the
natural environment.
Results of the PBT and vPvB assessment
0000107-21-1 ETHYLENE GLYCOL
The substance is not PBT/vPvB.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA
criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
Not regulated.
IATA Information
Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000107-21-1 ETHYLENE GLYCOL 10% – 18% SARA313,
DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA,CA_Prop65 –
California Proposition 65
0005285-60-9 BENZENEAMINE, 4,4′-
METHYLENEBIS[n-(1-
METHYLPROPROPYL)- 8% – 14% DSL,SARA312,TSCA
0001333-86-4 CARBON BLACK 4% – 7% DSL,SARA312,TSCA,CA_Prop65 –
California Proposition 65
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
* There are points of differences between OSHA GHS and UN GHS. In 90% of the categories, they can be used interchangeably, but for
the Skin Corrosion/Irritant Category and the Specific Target Organ Toxicity (Single and Repeated Exposure) Categories. In these cases,
our system will say UN GHS.
GLOSSARY
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California
Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical
Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC-
Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
PC 412-65D-BLACK, B-Side 8www.Polycoat.com of 7 Page
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
ACGIH – American Conference of Governmental Industrial Hygienists; CAS – Chemical Abstracts Service ; Chemtrec – Chemical
Transportation Emergency Center; DSL – Domestic Substances List; ESL- Effects screening levels; GHS – “Globally Harmonized System
of Classification and Labelling of Chemicals” developed by the United Nations; HMIS – Hazardous Material Information Service; IATA –
Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG – International Maritime Dangerous Goods Code; LC – Lethal
Concentration; LD – Lethal Dose; NFPA – National Fire Protection Association; OEL – Occupational Exposure Limits; OSHA- Occupational
Safety and Health Administration, US Department of Labor; PEL – Permissible Exposure Limit; SARA 313 – Superfund Amendments and
Reauthorization Act, Section 313; SCBA – Self Contained Breathing Apparatus; ppm – parts per million; STEL – Short-term exposure limit;
TLV – Threshold Limit Value; TSCA – Toxic Substances Control Act Public Law 94-469; TWA – Time-weighted average; US DOT- US
Department of Transportation.
Version 1.0:
Revision Date: Sep 27, 2021
Version 1.0
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the
information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product.
Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
information.
PC 412-65D-BLACK, B-Side 8 www.Polycoat.com of 8 Page
by | Sep 27, 2025
SECTION 2) HAZARDS IDENTIFICATION
Classification
Acute toxicity Oral – Category 5
Carcinogenicity – Category 2
Eye Irritation – Category 2
Respiratory Sensitizer (Solid/Liquid) – Category 1
Skin Irritation – Category 2
Skin Sensitizer – Category 1
Specific Target Organ Toxicity – Repeated Exposure – Category 2
Specific Target Organ Toxicity -Single Exposure (Respiratory Tract Irritation) – Category 3
Pictograms
Signal Word
Danger
Hazardous Statements – Health
H303 – May be harmful if swallowed
H351 – Suspected of causing cancer.
H319 – Causes serious eye irritation
H334 – May cause allergy or asthma symptoms or breathing difficulties if inhaled
H315 – Causes skin irritation
H317 – May cause an allergic skin reaction
H373 – May cause damage to organs through prolonged or repeated exposure.
H335 – May cause respiratory irritation
10-14100
Sep 27, 2021
SAFETY DATA SHEET
Sep 27, 2021
Polycoat Products
14722 Spring Ave, Santa Fe Springs, CA, US, 90670-5108
Manufacturer’s Name:
Revision Date:
Address:
SECTION 1) CHEMICAL PRODUCT AND MANUFACTURER’S IDENTIFICATION
Version: 1.0
Date Printed: Sep 27, 2021
Supersedes Date: N.A.
Product ID:
Product Name:
10-14100
PC 412-65D, A-Side
Emergency Phone:
Information Phone Number:
Chemtrec:800-424-9300 (account: CCN1217) OR International:703-527-3887 (account:CCN1217)
(562) 802-8834
Fax: (562) 921-7363
Product/Recommended Uses: For Further Information, Refer to the Product Technical Data Sheet.
PC 412-65D, A-Side 8www.Polycoat.com of 1 Page
Precautionary Statements – General
P101 – If medical advice is needed, have product container or label at hand.
P102 – Keep out of reach of children.
P103 – Read label before use.
Precautionary Statements – Prevention
P201 – Obtain special instructions before use.
P202 – Do not handle until all safety precautions have been read and understood.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P264 – Wash thoroughly after handling.
P284 – In case of inadequate ventilation, wear respiratory protection
P272 – Contaminated work clothing should not be allowed out of the workplace.
P260 – Do not breathe dust/fume/gas/mist/vapors/spray.
P271 – Use only outdoors or in a well-ventilated area.
P233 – Keep container tightly closed.
Precautionary Statements – Response
P312 – Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 – IF exposed or concerned: Get medical advice/attention.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337 + P313 – If eye irritation persists: Get medical advice/attention.
P304 + P340 – IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P342 + P311 – If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P302 + P352 – IF ON SKIN: Wash with plenty of water.
P321 – Specific treatment (see section 4 on this SDS).
P362 + P364 – Take off contaminated clothing. And wash it before reuse.
P333 + P313 – If skin irritation or a rash occurs: Get medical advice/attention.
P314 – Get Medical advice/attention if you feel unwell.
Precautionary Statements – Storage
P405 – Store locked up.
P403 + P405 – Store in a well-ventilated place. Store locked up.
Precautionary Statements – Disposal
P501 – Dispose of contents/ container to an approved waste disposal plant.
SECTION 4) FIRST-AID MEASURES
Inhalation
Remove source of exposure or move person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a
POISON CENTER/doctor. If breathing is difficult, trained personnel should administer emergency oxygen if advised to do so by the
POISON CENTER/doctor.
If exposed/feel unwell/concerned: Call a POISON CENTER/doctor.
CAS Chemical Name % By Weight
0000101-68-8 4,4′-METHYLENEDIPHENYL DIISOCYANATE 54% – 100%
0026447-40-5 MDI (MONOMER) 1.4% – 2%
Specific chemical identity and/or exact percentage (concentration) of the composition has been withheld to protect confidentiality.
SECTION 3) COMPOSITION/INFORMATION ON INGREDIENTS
PC 412-65D, A-Side 8www.Polycoat.com of 2 Page
Eliminate all ignition sources if safe to do so.
Skin Contact
Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Gently blot or brush away excess product. Wash with
plenty of lukewarm, gently flowing water for a duration of 15-20 minutes. If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before re-use or discard.
IF exposed or concerned: Get medical advice/attention.
Eye Contact
Rinse eyes cautiously with lukewarm, gently flowing water for several minutes, while holding the eyelids open. Remove contact lenses, if
present and easy to do. Continue rinsing for 15-20 minutes. Take care not to rinse contaminated water into the unaffected eye or onto the
face. If eye irritation persists: Get medical advice/attention.
Ingestion
Rinse mouth. Do NOT induce vomiting. Give 1 or 2 glasses of milk or water to drink and get medical attention/advice.
IF exposed or concerned: Get medical advice/attention.
SECTION 5) FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Dry chemical, foam, carbon dioxide is recommended. Water spray is recommended to cool or protect exposed materials or structures.
Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces. Simultaneous use of foam and water
on the same surface is to be avoided as water destroys the foam. Sand or earth may be used for small fires only.
Unsuitable Extinguishing Media
If water is used, use very large quantities of cold water. The reaction between water and hot isocyanate may be vigorous.
Specific Hazards in Case of Fire
Excessive pressure or temperature may cause explosive rupture of containers.
Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.
Fire-fighting Procedures
Isolate immediate hazard area and keep unauthorized personnel out. Stop spill/release if it can be done safely. Move undamaged
containers from immediate hazard area if it can be done safely. Water spray may be useful in minimizing or dispersing vapors and to
protect personnel. Water may be ineffective but can be used to cool containers exposed to heat or flame. Caution should be exercised
when using water or foam as frothing may occur, especially if sprayed into containers of hot, burning liquid.
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Special Protective Actions
Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene),
goggles, and full protective clothing are also required.
Care should always be exercised in dust/mist areas.
SECTION 6) ACCIDENTAL RELEASE MEASURES
Emergency Procedure
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
Do not touch or walk through spilled material.
Isolate hazard area and keep unnecessary people away. Remove all possible sources of ignition in the surrounding area. Notify
authorities if any exposure to the general public or the environment occurs or is likely to occur.
If spilled material is cleaned up using a regulated solvent, the resulting waste mixture may be regulated.
Recommended Equipment
Appropriate dust or face mask to eliminate breathing foam dust particulates.
Personal Precautions
Avoid breathing vapors. Avoid contact with skin, eyes or clothing. Do not touch damaged containers or spilled materials unless wearing
appropriate protective clothing.
Environmental Precautions
Stop spill/release if it can be done safely. Prevent spilled material from entering sewers, storm drains, other unauthorized drainage
systems and natural waterways by using sand, earth, or other appropriate barriers.
Methods and Materials for Containment and Cleaning up
Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8%
PC 412-65D, A-Side 8 www.Polycoat.com of 3 Page
concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the
precautions on the supplier’s safety data sheets.
Treat the spill area with the decontamination solution, using about 10 parts of the solution for each part of the spill, and allow it to react for
at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as
described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste.
Slowly stir the isocyanate waste into the decontamination solution described above. Let stand for 48 hours, allowing the evolved carbon
dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all
relevant local, state, and federal laws and regulations regarding treatment.
SECTION 7) HANDLING AND STORAGE
General
Wash hands after use.
Do not get in eyes, on skin or on clothing.
Do not breathe vapors or mists.
Use good personal hygiene practices.
Eating, drinking and smoking in work areas is prohibited.
Remove contaminated clothing and protective equipment before entering eating areas.
Eyewash stations and showers should be available in areas where this material is used and stored.
Ventilation Requirements
Use only with adequate ventilation to control air contaminants to their exposure limits. The use of local ventilation is recommended to
control emissions near the source.
Storage Room Requirements
Keep container(s) tightly closed and properly labeled. Store in cool, dry, well-ventilated areas away from heat, direct sunlight, strong
oxidizers and any incompatibilities. Store in approved containers and protect against physical damage. Keep containers securely sealed
when not in use. Indoor storage should meet OSHA standards and appropriate fire codes. Containers that have been opened must be
carefully resealed to prevent leakage. Empty container retain residue and may be dangerous.
Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this
product is used and stored.
Keep liquid and vapors away from sparks and flame, store in containers above ground and surrounded by dikes to contain spills or leaks.
Do not cut, drill, grind, weld, or perform similar operations on or near containers.
SECTION 8) EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection
Wear eye protection with side shields or goggles. Wear indirect-vent, impact and splash resistant goggles when working with liquids. If
additional protection is needed for entire face, use in combination with a face shield.
Skin Protection
Use of gloves approved to relevant standards made from the following materials may provide suitable chemical protection: PVC,
neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact,
chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should
be replaced. Use of an apron and over- boots of chemically impervious materials such as neoprene or nitrile rubber is recommended to
avoid skin sensitization. The type of protective equipment must be selected according to the concentration and amount of the dangerous
substance at the specific workplace. Launder soiled clothes or properly disposed of contaminated material, which cannot be
decontaminated.
Respiratory Protection
If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied pressure
supplied air respiratory with a full face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing
apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.
Appropriate Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold
limit value.
Chemical
Name
OSHA TWA
(ppm)
OSHA TWA
(mg/m3)
OSHA STEL
(ppm)
OSHA STEL
(mg/m3)
OSHA Tables
(Z1, Z2, Z3)
OSHA
Carcinogen
OSHA Skin
designation
NIOSH TWA
(ppm)
4,4′-
METHYLENEDI
PHENYL
DIISOCYANAT
E
0.02 ceiling 0.2 ceiling 1 0.005
PC 412-65D, A-Side 8 www.Polycoat.com of 4 Page
Chemical
Name
NIOSH TWA
(mg/m3)
NIOSH STEL
(ppm)
NIOSH STEL
(mg/m3)
NIOSH
Carcinogen
ACGIH TWA
(ppm)
ACGIH TWA
(mg/m3)
ACGIH STEL
(ppm)
ACGIH STEL
(mg/m3)
4,4′-
METHYLENEDI
PHENYL
DIISOCYANAT
E
0.050 0.005
SECTION 9) PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Appearance Liquid
Auto Ignition Temp N.A.
Coefficient Water/Oil N.A.
Decomposition Pt N.A.
Evaporation Rate
Flammability
Flash Point
Flash Point Symbol
Freezing Point
High Boiling Point
Low Boiling Point
Lower Explosion Level
Melting Point
Odor Description
Odor Threshold
pH
Upper Explosion Level
Vapor Density
Vapor Pressure
Slower than ether
N/A
200 C
N.A.
N.A.
N.A.
220 C
N.A.
N.A.
Aromatic
N.A.
N.A.
N.A.
Heavier than air
N.A.
Viscosity N.A.
VOC Part A & B Combined N.A.
Water Solubility N.A.
9.99 lb/gal
1.20
Density
Specific Gravity
VOC Regulatory
0.00 lb/gal
SECTION 10) STABILITY AND REACTIVITY
Stability
Material is stable at standard temperature and pressure.
Conditions to Avoid
Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of
carbon dioxide and buildup of pressure.
Hazardous Reactions/Polymerization
Will not occur under normal conditions but under high temperatures above 204 C, in the presence of moistures, alkalis,tertiary amines,
and metal compounds will accelerate polymerization. Possible evolution of carbon dioxide gas may rupture closed containers.
Incompatible Materials
This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the
PC 412-65D, A-Side 8www.Polycoat.com of 5 Page
reaction with water is slow under 50 C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal
compounds. Some reactions can be violent. Material can react with strong oxidizing agents.
Hazardous Decomposition Products
Carbon dioxide, carbon monoxide, nitrogen oxides, trace amounts of hydrogen cyanide and unidentified organic compounds may be
formed during combustion.
SECTION 11) TOXICOLOGICAL INFORMATION
Skin Corrosion/Irritation
Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling,
blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a
result of contact with very small amounts of liquid material or as a result of exposure to vapor.
Causes skin irritation
Serious Eye Damage/Irritation
Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause
conjunctivitis. Any level of contact should not be left untreated.
Causes serious eye irritation
Respiratory/Skin Sensitization
May cause allergy or asthma symptoms or breathing difficulties if inhaled
May cause an allergic skin reaction
Carcinogenicity
Suspected of causing cancer.
Germ Cell Mutagenicity
Based on available data, the classification criteria are not met.
Reproductive Toxicity
Based on available data, the classification criteria are not met.
Specific Target Organ Toxicity – Single Exposure
High vapor concentrations may cause central nervous system (CNS) depression as evidenced by giddiness, headache, dizziness, and
nausea. Persons with a preexisting, nonspecific bronchial hyperactivity can respond to concentrations below the TLV with similar
symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in
lungs). As a result of previous repeated overexposures or a single large dose, certain individuals may develop isocyanate sensitization
(chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the TLV.
May cause respiratory irritation
Specific Target Organ Toxicity – Repeated Exposure
Chronic overexposure to isocyanate has also been reported to cause lung damage (including decrease in lung function) which may be
permanent.
May cause damage to organs through prolonged or repeated exposure.
Aspiration Hazard
Based on available data, the classification criteria are not met.
Acute Toxicity
May be harmful if swallowed
Likely Routes of Exposure
Inhalation, Ingestion, Skin contact, Eye contact
0000101-68-8 4,4′-METHYLENEDIPHENYL DIISOCYANATE
LC50 (rat): 369-490 mg/m3 (aerosol) (4-hour exposure) (1)
LC50 (rat): 178 mg/m3 (17.4 ppm) (duration of exposure not reported) (2)
LD50 (oral, rat): greater than 10,000 mg/kg (1,2)
LD50 (dermal, rabbit): greater than 10,000 mg/kg (1)
LD50 (oral, mouse): 2,200 mg/kg (3)
SECTION 12) ECOLOGICAL INFORMATION
PC 412-65D, A-Side 8www.Polycoat.com of 6 Page
Toxicity
Based on available data, the classification criteria are not met.
Persistence and Degradability
No data available.
Bioaccumulative Potential
No data available.
Mobility in Soil
No data available.
Other Adverse Effects
No data available.
Bioaccumulative Potential
No data available.
SECTION 13) DISPOSAL CONSIDERATIONS
Waste Disposal
Under RCRA, it is the responsibility of the user of the product, to determine a the time of disposal whether the product meets RCRA
criteria for hazardous waste. Waste management should be in full compliance with federal, state, and local laws.
Empty containers retain product residue which may exhibit hazards of material, therefore do not pressurize, cut, glaze, weld or use for any
other purposes. Return drums to reclamation centers for proper cleaning and reuse.
SECTION 14) TRANSPORT INFORMATION
U.S. DOT Information
Not regulated
IMDG Information
Not regulated.
IATA Information
Not regulated.
SECTION 15) REGULATORY INFORMATION
CAS Chemical Name % By Weight Regulation List
0000101-68-8 4,4′-METHYLENEDIPHENYL
DIISOCYANATE
54% – 100% SARA313,
DSL,CERCLA,HAPS,SARA312,VHA
PS,VOC,TSCA
0026447-40-5 MDI (MONOMER) 1.4% – 2% DSL,SARA312,VOC,TSCA
SECTION 16) OTHER INFORMATION
OTHER INFORMATION
Note: As per GHS, category 1 is the greatest level of hazard within each class.
GLOSSARY
ACGIH- American Conference of Governmental Industrial Hygienists; ANSI- American National Standards Institute; CA Prop65- California
Proposition 65; Canadian TDG- Canadian Transportation of Dangerous Goods; CAS- Chemical Abstract Service; Chemtrec- Chemical
Transportation Emergency Center (US); CHIP- Chemical Hazard Information and Packaging; DSL- Domestic Substances List; EC-
Equivalent Concentration; EH40 (UK)- HSE Guidance Note EH40 Occupational Exposure Limits; EPCRA- Emergency Planning and
Community Right-To-Know Act; ESL- Effects screening levels; HMIS- Hazardous Material Information Service; LC- Lethal Concentration;
LD- Lethal Dose; NFPA- National Fire Protection Association; OEL- Occupational Exposure Limits; OSHA- Occupational Safety and
Health Administration, US Department of Labor; PEL- Permissible Exposure Limit; SARA (Title III)- Superfund Amendments and
PC 412-65D, A-Side 8 www.Polycoat.com of 7 Page
Reauthorization Act; SARA 313- Superfund Amendments and Reauthorization Act, Section 313; SCBA- Self-Contained Breathing
Apparatus; STEL- Short Term Exposure Limit; TCEQ- Texas Commission on Environmental Quality; TLV- Threshold Limit Value; TSCA-
Toxic Substances Control Act Public Law 94-469; TWA- Time Weighted Value; US DOT- US Department of Transportation; WHMIS-
Workplace Hazardous Materials Information System.
ACGIH – American Conference of Governmental Industrial Hygienists; CAS – Chemical Abstracts Service ; Chemtrec – Chemical
Transportation Emergency Center; DSL – Domestic Substances List; ESL- Effects screening levels; GHS – “Globally Harmonized System
of Classification and Labelling of Chemicals” developed by the United Nations; HMIS – Hazardous Material Information Service; IATA –
Dangerous Goods Regulations (DGR) for the air transport (IATA); IMDG – International Maritime Dangerous Goods Code; LC – Lethal
Concentration; LD – Lethal Dose; NFPA – National Fire Protection Association; OEL – Occupational Exposure Limits; OSHA- Occupational
Safety and Health Administration, US Department of Labor; PEL – Permissible Exposure Limit; SARA 313 – Superfund Amendments and
Reauthorization Act, Section 313; SCBA – Self Contained Breathing Apparatus; ppm – parts per million; STEL – Short-term exposure limit;
TLV – Threshold Limit Value; TSCA – Toxic Substances Control Act Public Law 94-469; TWA – Time-weighted average; US DOT- US
Department of Transportation.
DISCLAIMER
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes
any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we
cannot guarantee that these are the only hazards that exist. The above information pertains to this product as currently formulated, and is based on the
information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product.
Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this
information.
PC 412-65D, A-Side 8 www.Polycoat.com of 8 Page
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 04/21/2015
SDS No : PC-10 PART A
Date Revised : 05/04/2021
Revision No : 2
PC-10 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: PC-10 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Emergency Phone: (714) 734-8450
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Carcinogenicity, Category 2
Target Organ Toxicity (Repeated exposure), Category 2
GHS LABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H351: Suspected of causing cancer.
H373: May cause damage to organs through prolonged or repeated exposure.
PRECAUTIONARY STATEMENTS
Prevention:
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Page 1 of 6
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention.
Storage:
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 40 – 7068515-49-1
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with 1,1′-methylenebis[4-isocyanatobenzene]10 – 309048-57-1
4,4′-Diphenylmethane diisocyanate 7 – 13101-68-8
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer 3 – 725686-28-6
2,4′-Diphenylmethane diisocyanate 0.1 – 15873-54-1
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK PROCEDURES: Evacuate unnecessary personnel from the spill area. Wear necessary personal protective equipment (PPE)
as specified in the SDS or the site emergency response plan. Eliminate all sources of ignition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to local/national regulations.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
Page 2 of 6
PC-10 PART A
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
Chemical Name Type ppm mg/m
3
4,4′-Diphenylmethane diisocyanate
OSHA PEL C 0.02 0.2
ACGIH TLV TWA 0.005 –
NIOSH REL
TWA 0.005 0.05
C 0.02
[1]
0.2
[1]
Footnotes:
1. 10-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: Nil
FLASH POINT AND METHOD: 212.8 C (415 F) Pensky-Martens CC
Page 3 of 6
PC-10 PART A
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.02 (water=1) at 25 C (77 F)
VISCOSITY #1: 200 Centipoise at 25 C (77 F)
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTIVITY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and ignition sources.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with water produces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stirring or by the presence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, strong bases, strong acids, strong oxidizing agents, and amines.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
Chemical Name ORAL LD50
DERMAL
LD
50
INHALATION
LC
50
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich
> 10 g/kg Rat> 3.16 g/kg
Rabbit
> 0.13 mg/l Rat
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer with
1,1′-methylenebis[4-isocyanatobenzene]
No data
available
No data
available
No data available
4,4′-Diphenylmethane diisocyanate
> 2000 mg/kg
Rat
> 9400 mg/kg
Rabbit
2.24 mg/l Rat (1 h,
dust/mist)
Benzene, 1,1′-methylenebis[4-isocyanato-, homopolymer
> 5000 mg/kg
Rat
No data
available
0.49 mg/l Rat
2,4′-Diphenylmethane diisocyanate
No data
available
> 9400 mg/kg
Rabbit
0.49 mg/l Rat (4 h)
SKIN CORROSION/IRRITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye irritation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGENICITY: No data available
CARCINOGENICITY
Chemical Name IARC Status
4,4′-Diphenylmethane diisocyanate 3
REPRODUCTIVE TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
12. ECOLOGICAL INFORMATION
Page 4 of 6
PC-10 PART A
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
CHEMICAL FATE INFORMATION: No data available
BIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and
runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
4,4′-Diphenylmethane diisocyanate 7 – 13101-68-8Diisocyanate Compounds (Category Code N120)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPE NSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).
Chemical Name Wt.% CERCLA RQ
4,4′-Diphenylmethane diisocyanate 7 – 13 5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: WARNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause birth defects or other reproductive harm. For more information, go to www.P65Warnings.ca.gov.
Chemical Name Wt.% Listed
1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich 40 – 70 Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the SDS contains all the information required by the CPR.
Page 5 of 6
PC-10 PART A
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GENERAL COMMENTS:
DIDP RESTRICTIONS: This product contains diisodecyl phthalate (DIDP), CAS# 68515-49-1 EINECS# 271-091-4. In the U.S., there is an
interim prohibition on DIDP above 0.1 percent by weight (one thousand parts per million) in toys intended for children age 12 and under that can
be placed in a child’s mouth and child care articles for children age 3 and under [H.R. 4040, The Consumer Safety Improvement Act of 2008]. In
the EU, DIDP shall not be used as substance or as constituents of preparations, at concentrations of greater than 0.1 percent by weight (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys and
child care articles containing DIDP in concentrations greater than the limit mentioned above shall not be placed on the market [Directive
2005/84/EC].
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revised: 05/04/2021
REVISION SUMMARY: This SDS replaces the 04/18/2018 SDS.
HMIS RATING
HEALTH * 2
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
2 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
Page 6 of 6
PC-10 PART A
by | Sep 27, 2025
BIB
EN TE ftPRI5 E5
SAFETY DATA SHEET
PC.IO PART A
Date Issued :0N2112015
SDS No : PC-10 PART A
Date Revised : 0510412021
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: PC-l0 PART A
GENERAL USE: Polyurethane resin
MANI.JFACTURER
BJB Enterprises, lnc.
14791 Franklin Avenue
Tustin, CA92780
Emergency Phone: (714) 73+8450
24 HR. EMERGENCY TELEPHONE NI.JMBERS
CIIEMTREC (USA & Canada): (800) 42’t-9300
or(703) 521-3887 CCN# 2820
2. HA ZARDS IDENTIFICATION
GHS CI-ASSIFICATIONS
Health:
Skin Irritation, Cxegory 2
Eye kritation, Category 2A
Respiratory Sensitization, Category I
Skin Sensitization, Category 1
Carcinogenici ty, Categry 2
Target Organ Toxicity (Repeated exposure), Category 2
GHS I-ABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMEITS
H3 15: Causes skin irritation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H3 17: May cause an allergic skin reaction.
H35l: Suspected ofcausing cancer.
H373: May cause damage to organs throughprolongedor repeated exposure.
PRE CAU TI ONARY STATEM M.I TS
Prevention:
P201: Obtain special insfructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260 : Do n ot breath e du st/fu me/ gas/mist/vapours/spray’
P284: In case of inadequate ventilation wearrespiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P3M+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
I
a
PC.IO PART A
P342+P3l l: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin initation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
p305+p35
l+p338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P33’7+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention,
Storage:
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Wt.4o
Chemical Name
40-10
1,2-Benzenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C lO-rich
l0- 30
l- 1,2-efhanediyl)1, .alpha,-hydro-.omega.-hydroxy-, polymer with I ,1′-methylenebis[4-isocyanatobenzene]Poly[oxy(methy
7 -13
4,4′-Diphenylmethane diisocyanate
3-7
B en zene, 1, l’-methyl enebi s
[ 4*i so cyan ato -, h omop ol ymer
0.1 -l
2,4′ -Diphenylmethane diisocyanate
CAS
6851549-l
9U8-57-1
101-68-8
25686-28-6
5U3-54-r
4. FIRSTAIDMEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by moutlt to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrestoccurs, provide artificial respiration or
oxygen by tained personnel. Get immediate medical attention.
NOTES TO PI{YSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEAST]RES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQTIIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEAST’RES
SpLL A1tlD IIAK PROCEDURES: Evacuate unnecessarypersonnel from the spill area. Wear necessary personal protective equipment (PPE)
as specifiedin the SDS orthe site emergencyresponse plan. Eliminate all sources of igtrition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to locaVnational regulations.
ENVIR ONM EN TAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
PC.IO PART A
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIAIDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid opencontainerexposure to damp air. Avoid breathingaerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaUmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away liom excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80″F (1 8-n “C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)(POSURE CONTROLS / PERSONAL PROTECTION
Chemical Name Type ppm
OSIIA PEL c 0.az
ACGIII TLV TWA 0.005
TWA 0.005
NIOSHREL
C 0.02
trl
4,4′ -Diphenylmethane dii socyan ate
GUIDELINES
osHA HAZARDOUS COMPOTENTS (29 CFR1910.1200)
E)POSURE LIMITS
mdm3
0.2
0.05
0.2ttl
Footnotes:
1. l0-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQU IPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined wi*r polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartidge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTM CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK IfYGIEM PRACTICES: Contaminated clothing should be changed and washedbefore reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material shouldbe equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHENIICAL PROPERTMS
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: NiI
FLASH POINT AND METHOD: 212.8″C (415’F) Pensky-Martens CC
PC.IO PART A
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.02 (water=l) at25″C (71″F)
USCOSITY #l:200 Centipoise at25″C (77″n
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and igrition sourcqs.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with waterproduces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stining or by ftre prqsence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, strong bases, strong acids, strong oxidizing agents, and amines.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
INHALATION
LCso
> 0.13 mg/l Rat
No data available
2.24mgfi Rat (1 h,
dust/mist)
0.49 mgll Rat
0.49mflIRat (4 h)
SKIN COR ROSION/IR RITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye initation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGFIICITY: No data available
CARCINOGENICITY
ORAL LDso
DERMAL
LDso
Chemical Name
> l0 g/kg Rat > 3.16 {kg
Rabbit
1,2-B enzenedicarboxylic acid, di -C9- I I -branched alkyl esters, C I O-rich
No data
available
No data
available
Poly[oxy(methyl- 1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer wittr
l, l’ -methylenebis[4-isoryanatobenzene]
> 2000 mg/kg
Rat
> 9400 mg/kg
Rabbit
4,4′ -Diphenylmethane diisocyanate
> 5000 mglkg
Rat
No data
available
B en zen e, 1, 1′-methyl enebi s [4-i so cyan ato -, h omopol ymer
> 9400 mg/kg
Rabbit
2,4′ -Diphenylmethane diisocyanate
No data
available
IARC Status
REPRODUCTM TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE,: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
4,4′ -Diph enylmeth ane dii socyanate
12. ECOLOGICAL INFORMATION
3
PC-10 PART A
ECOTOXICOLOGICAI. INFORMATION: No specific ecological clara are available lbr tlris procluct. Rel’er to Section 6 for inforrlation
regzrrding acciclental releirse ancl Section l5 ior legLrlatol’y lepol’tittg inl’olmation.
CHELICAL I’ATE INFORMATION: No data available
IIIOACCUMULATION/A CCUMULATION: No d ata avai lable
BNVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may letain some
pr.odgct residues. This rnaterial and its container must be clisposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products slrotrld at all tirnes comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requircments. Avoid dispelsal of spilled material and
runoff and contact with soil, waterways, dlains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITEDSTATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
3ll3lz HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazatd
313 REPORTABLE INGREDIENTS: This product conrains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA 13 SUPPLIER NOTIFI
Comments
Diisocyanate Compounds (Category Code Nl20)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RFSPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or mole substances regulated as a hazardous substance under the Comprehensive
Environmental Response compensation and Liability Act (CERCLA) (40 CFR 302).
Wt.Vo CASChemical Name
7 -13r 0r -68-84,4′ -Diphenyl methane dii socyan ate
WtVoChemical Name
7 -13
4,4′ -Diphenylmethane dii socyan ate
CERCLA RQ
5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section l2(b) expor-t notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEA LTH A DMINISTRATION (OSHA )
29 CFR191O.1Ig…PROCFSS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICAIS: NONE Of tIrE ChCMiCAIS iN thiS
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65; A WRRNING: This product can expose you to chemicals including [see table below], which is larel
known to the State of California to cause birth clefects or other reproductive harm. For more information, go to wrvw.P65Wamings.ca.gov.
Listed
o Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of ttre SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910′ 1200
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS IM-ORMATION SYSTEM): This product has been classified according to the
hazarcl criteila of the CPR and the SDS contains all the infbnnation required by the CPR.
Wt4o
Chemical Name
40-70
1,2-Benzenedicarboxylic acid, di-C9-1 I -branched alkyl esters, C I 0-rich
PC-10 PART A
DOMFSTIC SUBSTANCE LIST (INVENTORY): All colnponents in this product are listed in or exenrptecl l’r’onr the Donrestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GBNERAL COMMENTS:
DIDP RESTRICTIONS: This product conrains diisodecyl plrthalate (DIDP), CAS# 68515-49-l EINECS# 271-091-4. In the tJ.S., there is an
interinr pr ohibition on DIDP above 0. I percent by weight (one thousand parts per million) in toys intended for chi ldren age I 2 and u ncler that can
be placed in a child’s mouth and child care articles fbr children age 3 and under [H.R. 4M0, The Consumer Safety Improvement Act of 20081. ]n
the EU, DIDP shall not be used as substance or as consti tuents of preparation s, at concentrations of greater th an 0. I percen t by weig ht (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys ancl
child care articles containing DIDP in concentrations g’eater than the limit mentioned above shall not be placed on the market [Dircctive
2W5t84tECl.
16. OTHER INFORMATION
RBASON FOR ISSUE: Revision
Date Revis ed z 0 5 I 04/ 2021
REVISION SUMMARY: This SDS replaces rhe Ml18D0l8 SDS.
HMISRATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is acculate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet rclates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEALTH
FLAMMABII,ITY
EA
n
BTB
ENTERPRISEs
SAFETY DATA SHBBT
PC-10 PART B
Date Issued : 0412112015
SDS No: PC-I0PARTB
Date Revised : 0510412021
Revision No :2
I. PRODUCT AND COMPANY IDF}ITIFICATION
PRODUCT NAME: PC-IO PART B
GENERAL US E: Polyureth ane curative
MANUFACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA9n80
Emergency Phone: (114) 13+8450
24 HR. EMERGENCY TELEPHONE NI.]MBERS
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. IIA ZARDS IDENTIFICATION
GHS CI-ASSIFICATIONS
This product does not meet the criteria for classification.
GHS I.ABEL
Not Applicable
3. COMPOSITION / INFORMATION ONINGREDIENTS
Chemical Name wt.vo
1,3-butadiene, homopolyner, hydroxy-terminated 40-70
1,2-Beruenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C lO-rich 15-40
2,6-di +ert-bu tyl -p -cresol < 0.1
Dibutyltin dilaurate < 0.04
cAs
69tU-90-5
685 l5-49-l
128-37 -0
11-58-7
4. FIRST AID MEAST]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advicdattention if initation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHAI-ATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops,
NOTES TO PHYSICIAN: Symptomatic and supponive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGIIISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers fiom the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways,
FIRE FIGHTING EQLIIPMENT: Firefighters shouldwear positive pressure self-contained breathing apparatus (SCBA) and consideruse of
unmanned hose holders or monitor nozzles for fighting large fires.
PC-10 PART B
6. ACCIDENTAL RELEASE MEASURFS
SPILL AND LEAK PROCEDURES: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel
People dealing with a major spill should wem full protective clothing including appropriate respiratory protection. Prevent product spill from
entering sewers or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use combustible
materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic bags forfurther
decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify
applicable government auttrorities if release is reportable. (See CERCLA in Section l5).
EIWIR ONMENTAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENIERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIANDLING AID STORAGE
GENERAL PROCEDTIRES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaUmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away fiom excessive heat in the original or similar container. Avoid sources of ignition and
incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAG E TEMPERATURE: 65-80"F (l 8 -n " C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
ELECTROSTATIC ACCUMLILATION HAZARD: This material can accumulate static charges which can cause an incendiary electrical
discharge.
8. E)POSURE CONTROLS / PERSONAL PROTECTION
E)(POSIJRE
osHA HAZARDOUS COMPOT{ENTS (29 CFR1910.1200)
EXPOST.]RE LIMITS
mg/m3
l0
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety gogglas or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.I or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and syn*retic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wem nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor carfidge or fresh air supplied respirator (MOSH approved) may be
necessary for certain applications. Consider ttre type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines forthe Selection of Chemical
Protective Clothing" published by ACGIH.
WORK IfYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Trainingis important. Follow all label precautions.
Chemical Nanre Type ppm
2,6-di -tert-butyl -p -cresol IIOSH REL TWA
PC.IO PART B
9. PITYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 0.09
FLASH POINT AND METHOD: > 204.4″C (400″F) COC (Cleveland Open Cup)
VAPOR PRF^SSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Negligible
SPECIFIC GRAVITY: 0.9 1 ( water= 1 ) at 2 5″ C (7 7 “F)
USCOSITY: No data available
(VOC): > 0.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures and sour@s of ignition.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carton dioxide.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
1 1. TOXICOLOGICAL IhIFORMATION
ACUTE TO)ilCITY
ORAL LDso DERMAL LDsOChemical Name
1,3-butadienq homopolymer, hydroxy-terminated No data availableNo data available
1,2-B erzenedi carb ox yl ic acid, d i -C9 – I I -bran ch ed alkyl esters, C I 0-rich> 10 g/kg Rat > 3.16 {kg Rabbit
2,6-di -tert-b utyl -p -cresol > 29C0 mg/kgRat > 2000 mg/kg Rat
Dibutyltin dilaurate > 2000 mg/kg Rat> 2000 mglkg Rabbit
Naphthalene 490mg&gRat 20000 mg/kg Rabbit
INHALATIONLCSO
No data available
> 0.13 mg/l Rat
No data available
No data available
> 0.4 mgll Rat (4 h)
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MIITAGEI.,IICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status
2,6di+errbu gl-p-cresol
Naphthalene 2
IARC Status
J
REPRODUCTM TO)ilCITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED E)POSURE: No data available
ASPIRATION HAZARD: No dara available
28
PC-10 PART I}
I2. ECOLOGICAI- INFORMATION
ITCOTOXICOf,OGICAL INFOITMATION: No specific ecological data arc available fbr this product. Ref’er to Section
(r for information
regardin-r acciclental relea.se ancl Section l5 for regulatory reporting infolniation.
CHEMICAL FATE INFORMATION: No data available
IIIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTttIItUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherevel possible. Enrpty containe$ or liners may rctain some
product rqsidues. This rlaterial and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposerl of this product, solutions and any by-products should at all tirnes cornply with the requirements of
enviror.rrneutal protections and waste disposal legislation and any regional local authority requircments. Avoid dispemal of spilled material and
runofT and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Established
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITBD STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORTZATION ACT)
3lll312 HEALTH HAZARDS: None Expected
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 ol
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Palrt 372.
CIIRCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or mor substances regulated as a hazardous substance under the Comprehensive
Environrnental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
CERCLA RQ
100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONA L SAFETY AND HEALTH ADMINISTRATION (OSHA)
29 CFR1910.rD—PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION OS: A WIRNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer and birth def’ects or other reproductive har rn. For more information, go to
www.P65 Warnin gs.ca.gov.
Chemical Name Wt.Vo
Naphthalene < 0.001
Listed
o Developmental Toxicity
o Cancer
OSHA HAZARD COMM. RIILE: The contents of the SDS comply witlr the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAI-S INFORMATION SYSTEM): This product has been classified according to the
hazard criteria of the CPR and theSDS contains all ttre information required by the CPR.
Chemical Name
'V,,lt.Vo
1,2-B errzened icarboxylic acid, d i-C9-1 I -branched erlkyl esters, C 1 Grich 15-40
Naphthalene < 0.001
PC-10 PART B
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listecl in or exenrpted frorn the Dornestic Snbstances
List (DSL) or the Non-Donrestic Substances List (NDSL).
GENERAL COMMENTS:
EXPORT RESTRICTIONS: This procluct contains polybutadiene lesin. Tlris product and the technical data related to this product are expoll
contlolled by the United States (US) Government. Exportation/intemational sl.ripnrents of this product au'e subject to licensing by the US
govemment. Export, re-expolt orotherdiversion, eitherin the original prodnct fonn orafterbeing incolporated in an interrnediate process into
ofter end-iterns, is STRICTLY PROHIBITED unless explessly atthorized by the cognizant agency of the US Government. If you plan to export
this product in some form please contact BJB Enterprises for more infonnation.
DIDPRESTRICTIONS:Thisproductcontainsdiisodecylphthalate(DIDP),CAS#68515-49-l EINECS#211-091-4.IntheU.S.,thereisan
interim prohibition on DIDP above 0. I pelcent by weight (one thousand pffts per nillion) in toys intended for children age l2 and undel that can
be placed in a child's mouth and child care articles for children age 3 and under [I{.R. 4040, The Consumer Safety Improvemnet Act of 2008|. In
the EU, DIDP shall not be used as substance or as constituents of preparations, at concerltrations of greater than 0.1 percent by weight (one
thousand pafts per nillion) of the plasticized material, in toys and childcare anicles which can be place in the mouth by children. Such toys and
childcare arlicles containing DIDP in concentrations greater than the lirnit mentioned above shall not be placed on the market [Directive
2W5t84tECl.
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revis ed z 0 5/ 04/ 2021
REVISION SUMMARY: This SDS replaces the M/18/2018 SDS
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without waranty, expressed or implied, except that is accumte to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEAI,TH
FLAMMABII,ITY
IE
n
by | Sep 27, 2025
BIB
EN TE ftPRI5 E5
SAFETY DATA SHEET
PC.IO PART A
Date Issued :0N2112015
SDS No : PC-10 PART A
Date Revised : 0510412021
Revision No :2
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: PC-l0 PART A
GENERAL USE: Polyurethane resin
MANI.JFACTURER
BJB Enterprises, lnc.
14791 Franklin Avenue
Tustin, CA92780
Emergency Phone: (714) 73+8450
24 HR. EMERGENCY TELEPHONE NI.JMBERS
CIIEMTREC (USA & Canada): (800) 42’t-9300
or(703) 521-3887 CCN# 2820
2. HA ZARDS IDENTIFICATION
GHS CI-ASSIFICATIONS
Health:
Skin Irritation, Cxegory 2
Eye kritation, Category 2A
Respiratory Sensitization, Category I
Skin Sensitization, Category 1
Carcinogenici ty, Categry 2
Target Organ Toxicity (Repeated exposure), Category 2
GHS I-ABEL
Health hazard Exclamation
mark
SIGNAL WORD: DANGER
HAZARD STATEMEITS
H3 15: Causes skin irritation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H3 17: May cause an allergic skin reaction.
H35l: Suspected ofcausing cancer.
H373: May cause damage to organs throughprolongedor repeated exposure.
PRE CAU TI ONARY STATEM M.I TS
Prevention:
P201: Obtain special insfructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260 : Do n ot breath e du st/fu me/ gas/mist/vapours/spray’
P284: In case of inadequate ventilation wearrespiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280 : Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P3M+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
I
a
PC.IO PART A
P342+P3l l: If experiencing respiratory symptoms: Call a POISON CENTER/doctor/physician.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin initation orrash occurs: Get medical advice/attention.
P362+P364: Take off contaminated clothing and wash it before reuse.
p305+p35
l+p338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P33’7+P313: If eye irritation persists: Get medical advice/attention.
P308+P313: IF exposed or concerned: Get medical advice/ attention,
Storage:
P405: Store locked up.
Disposal:
P501 : Dispose of contents/container in accordance with local/regional/national/international regulations.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Wt.4o
Chemical Name
40-10
1,2-Benzenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C lO-rich
l0- 30
l- 1,2-efhanediyl)1, .alpha,-hydro-.omega.-hydroxy-, polymer with I ,1′-methylenebis[4-isocyanatobenzene]Poly[oxy(methy
7 -13
4,4′-Diphenylmethane diisocyanate
3-7
B en zene, 1, l’-methyl enebi s
[ 4*i so cyan ato -, h omop ol ymer
0.1 -l
2,4′ -Diphenylmethane diisocyanate
CAS
6851549-l
9U8-57-1
101-68-8
25686-28-6
5U3-54-r
4. FIRSTAIDMEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advice/attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by moutlt to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrestoccurs, provide artificial respiration or
oxygen by tained personnel. Get immediate medical attention.
NOTES TO PI{YSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEAST]RES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQTIIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEAST’RES
SpLL A1tlD IIAK PROCEDURES: Evacuate unnecessarypersonnel from the spill area. Wear necessary personal protective equipment (PPE)
as specifiedin the SDS orthe site emergencyresponse plan. Eliminate all sources of igtrition. Ensure adequate ventilation. Dike and contain
spill. Prevent product from entering drains or waterways. Absorb with non-combustible material (such as sand, earth, diatomaceous earth, or
vermiculite) and transfer to a container for disposal according to locaVnational regulations.
ENVIR ONM EN TAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
PC.IO PART A
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIAIDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid opencontainerexposure to damp air. Avoid breathingaerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaUmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away liom excessive heat, in original or similar container. Avoid unnecessary contacl
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80″F (1 8-n “C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. E)(POSURE CONTROLS / PERSONAL PROTECTION
Chemical Name Type ppm
OSIIA PEL c 0.az
ACGIII TLV TWA 0.005
TWA 0.005
NIOSHREL
C 0.02
trl
4,4′ -Diphenylmethane dii socyan ate
GUIDELINES
osHA HAZARDOUS COMPOTENTS (29 CFR1910.1200)
E)POSURE LIMITS
mdm3
0.2
0.05
0.2ttl
Footnotes:
1. l0-minute
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQU IPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined wi*r polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartidge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTM CLOTHING: Protective clothing should be selected and used in accordance with “Guidelines for the Selection of Chemical
Protective Clothing” published by ACGIH.
WORK IfYGIEM PRACTICES: Contaminated clothing should be changed and washedbefore reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material shouldbe equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHENIICAL PROPERTMS
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Pale yellow
pH: No data available
PERCENT VOLATILE: NiI
FLASH POINT AND METHOD: 212.8″C (415’F) Pensky-Martens CC
PC.IO PART A
VAPOR PRESSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Reacts slowly with water
SPECIFIC GRAVITY: 1.02 (water=l) at25″C (71″F)
USCOSITY #l:200 Centipoise at25″C (77″n
(VOC): Nil
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures, moisture, and igrition sourcqs.
POSSIBILITY OF HAZARDOUS REACTIONS: Reaction with waterproduces carbon dioxide. Exothermic reaction with materials containing
active hydrogen groups. The reaction becomes progressively more vigorous and can be violent at higher temperatures if the miscibility of the
reaction partners is good or is supported by stining or by ftre prqsence of solvents. MDI is insoluble with, and heavier than water and sinks to the
bottom but reacts slowly at the interface. A solid water-insoluble layer of polyurea is formed at the interface by liberating carbon dioxide gas.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrogen oxides, hydrocarbons, and hydrogen cyanide.
INCOMPATIBLE MATERIALS: Water, strong bases, strong acids, strong oxidizing agents, and amines.
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY
INHALATION
LCso
> 0.13 mg/l Rat
No data available
2.24mgfi Rat (1 h,
dust/mist)
0.49 mgll Rat
0.49mflIRat (4 h)
SKIN COR ROSION/IR RITATION: Causes skin irritation.
SERIOUS EYE DAMAGE/IRRITATION: Causes serious eye initation.
RESPIRATORY OR SKIN SENSITISATION: May cause sensitization by inhalation and skin contact.
GERM CELL MUTAGFIICITY: No data available
CARCINOGENICITY
ORAL LDso
DERMAL
LDso
Chemical Name
> l0 g/kg Rat > 3.16 {kg
Rabbit
1,2-B enzenedicarboxylic acid, di -C9- I I -branched alkyl esters, C I O-rich
No data
available
No data
available
Poly[oxy(methyl- 1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, polymer wittr
l, l’ -methylenebis[4-isoryanatobenzene]
> 2000 mg/kg
Rat
> 9400 mg/kg
Rabbit
4,4′ -Diphenylmethane diisocyanate
> 5000 mglkg
Rat
No data
available
B en zen e, 1, 1′-methyl enebi s [4-i so cyan ato -, h omopol ymer
> 9400 mg/kg
Rabbit
2,4′ -Diphenylmethane diisocyanate
No data
available
IARC Status
REPRODUCTM TOXICITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED EXPOSURE,: May cause damage to organs through prolonged or repeated exposure.
ASPIRATION HAZARD: No data available
Chemical Name
4,4′ -Diph enylmeth ane dii socyanate
12. ECOLOGICAL INFORMATION
3
PC-10 PART A
ECOTOXICOLOGICAI. INFORMATION: No specific ecological clara are available lbr tlris procluct. Rel’er to Section 6 for inforrlation
regzrrding acciclental releirse ancl Section l5 ior legLrlatol’y lepol’tittg inl’olmation.
CHELICAL I’ATE INFORMATION: No data available
IIIOACCUMULATION/A CCUMULATION: No d ata avai lable
BNVIRONMENTAL DATA: No data available
DISTRIBUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may letain some
pr.odgct residues. This rnaterial and its container must be clisposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposal of this product, solutions and any by-products slrotrld at all tirnes comply with the requirements of
environmental protections and waste disposal legislation and any regional local authority requircments. Avoid dispelsal of spilled material and
runoff and contact with soil, waterways, dlains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITEDSTATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
3ll3lz HEALTH HAZARDS: Acute Health Hazard, Chronic Health Hazatd
313 REPORTABLE INGREDIENTS: This product conrains the following substances subject to the reporting requirements of Section 313
of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA 13 SUPPLIER NOTIFI
Comments
Diisocyanate Compounds (Category Code Nl20)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RFSPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or mole substances regulated as a hazardous substance under the Comprehensive
Environmental Response compensation and Liability Act (CERCLA) (40 CFR 302).
Wt.Vo CASChemical Name
7 -13r 0r -68-84,4′ -Diphenyl methane dii socyan ate
WtVoChemical Name
7 -13
4,4′ -Diphenylmethane dii socyan ate
CERCLA RQ
5,000 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section l2(b) expor-t notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEA LTH A DMINISTRATION (OSHA )
29 CFR191O.1Ig…PROCFSS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICAIS: NONE Of tIrE ChCMiCAIS iN thiS
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65; A WRRNING: This product can expose you to chemicals including [see table below], which is larel
known to the State of California to cause birth clefects or other reproductive harm. For more information, go to wrvw.P65Wamings.ca.gov.
Listed
o Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of ttre SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910′ 1200
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS IM-ORMATION SYSTEM): This product has been classified according to the
hazarcl criteila of the CPR and the SDS contains all the infbnnation required by the CPR.
Wt4o
Chemical Name
40-70
1,2-Benzenedicarboxylic acid, di-C9-1 I -branched alkyl esters, C I 0-rich
PC-10 PART A
DOMFSTIC SUBSTANCE LIST (INVENTORY): All colnponents in this product are listed in or exenrptecl l’r’onr the Donrestic Substances
List (DSL) or the Non-Domestic Substances List (NDSL).
GBNERAL COMMENTS:
DIDP RESTRICTIONS: This product conrains diisodecyl plrthalate (DIDP), CAS# 68515-49-l EINECS# 271-091-4. In the tJ.S., there is an
interinr pr ohibition on DIDP above 0. I percent by weight (one thousand parts per million) in toys intended for chi ldren age I 2 and u ncler that can
be placed in a child’s mouth and child care articles fbr children age 3 and under [H.R. 4M0, The Consumer Safety Improvement Act of 20081. ]n
the EU, DIDP shall not be used as substance or as consti tuents of preparation s, at concentrations of greater th an 0. I percen t by weig ht (one
thousand parts per million) of the plasticized material, in toys and child care articles which can be place in the mouth by children. Such toys ancl
child care articles containing DIDP in concentrations g’eater than the limit mentioned above shall not be placed on the market [Dircctive
2W5t84tECl.
16. OTHER INFORMATION
RBASON FOR ISSUE: Revision
Date Revis ed z 0 5 I 04/ 2021
REVISION SUMMARY: This SDS replaces rhe Ml18D0l8 SDS.
HMISRATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is acculate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet rclates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEALTH
FLAMMABII,ITY
EA
n
BTB
ENTERPRISEs
SAFETY DATA SHBBT
PC-10 PART B
Date Issued : 0412112015
SDS No: PC-I0PARTB
Date Revised : 0510412021
Revision No :2
I. PRODUCT AND COMPANY IDF}ITIFICATION
PRODUCT NAME: PC-IO PART B
GENERAL US E: Polyureth ane curative
MANUFACTURER
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA9n80
Emergency Phone: (114) 13+8450
24 HR. EMERGENCY TELEPHONE NI.]MBERS
CHEMTREC (USA & Canada): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. IIA ZARDS IDENTIFICATION
GHS CI-ASSIFICATIONS
This product does not meet the criteria for classification.
GHS I.ABEL
Not Applicable
3. COMPOSITION / INFORMATION ONINGREDIENTS
Chemical Name wt.vo
1,3-butadiene, homopolyner, hydroxy-terminated 40-70
1,2-Beruenedicarboxylic acid, di-C9-1 l-branched alkyl esters, C lO-rich 15-40
2,6-di +ert-bu tyl -p -cresol < 0.1
Dibutyltin dilaurate < 0.04
cAs
69tU-90-5
685 l5-49-l
128-37 -0
11-58-7
4. FIRST AID MEAST]RES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Get
medical advicdattention if initation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical advice/attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHAI-ATION: Remove to fresh air. Seek medical advice/attention if breathing becomes difficult or if respiratory irritation develops,
NOTES TO PHYSICIAN: Symptomatic and supponive therapy as needed. Following severe exposure medical follow-up should be monitored
for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGIIISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers fiom the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways,
FIRE FIGHTING EQLIIPMENT: Firefighters shouldwear positive pressure self-contained breathing apparatus (SCBA) and consideruse of
unmanned hose holders or monitor nozzles for fighting large fires.
PC-10 PART B
6. ACCIDENTAL RELEASE MEASURFS
SPILL AND LEAK PROCEDURES: Eliminate sources of ignition. Evacuate the area. Clean-up should only be performed by trained personnel
People dealing with a major spill should wem full protective clothing including appropriate respiratory protection. Prevent product spill from
entering sewers or waterways. Neutralize small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Do not use combustible
materials such as saw dust. Use only spark resistant and explosion proof recovery devices. Shovel into open-top drums or plastic bags forfurther
decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify
applicable government auttrorities if release is reportable. (See CERCLA in Section l5).
EIWIR ONMENTAL PRECA UTIONS
WATER SPILL: Do not discharge into drains, surface waters, or groundwater.
GENIERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. IIANDLING AID STORAGE
GENERAL PROCEDTIRES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over open
containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industriaUmanufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away fiom excessive heat in the original or similar container. Avoid sources of ignition and
incompatible materials. Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials. Avoid
unnecessary contact.
STORAG E TEMPERATURE: 65-80"F (l 8 -n " C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
ELECTROSTATIC ACCUMLILATION HAZARD: This material can accumulate static charges which can cause an incendiary electrical
discharge.
8. E)POSURE CONTROLS / PERSONAL PROTECTION
E)(POSIJRE
osHA HAZARDOUS COMPOT{ENTS (29 CFR1910.1200)
EXPOST.]RE LIMITS
mg/m3
l0
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airbome levels below
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety gogglas or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI 287.I or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and syn*retic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wem nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor carfidge or fresh air supplied respirator (MOSH approved) may be
necessary for certain applications. Consider ttre type of application, environmental concentrations, and other materials being used concurrently
when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910. 134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with "Guidelines forthe Selection of Chemical
Protective Clothing" published by ACGIH.
WORK IfYGIEMC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Trainingis important. Follow all label precautions.
Chemical Nanre Type ppm
2,6-di -tert-butyl -p -cresol IIOSH REL TWA
PC.IO PART B
9. PITYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Colorless
pH: No data available
PERCENT VOLATILE: 0.09
FLASH POINT AND METHOD: > 204.4″C (400″F) COC (Cleveland Open Cup)
VAPOR PRF^SSURE: No data available
VAPOR DENSITY: No data available
BOILING POINT: No data available
SOLUBILITY IN WATER: Negligible
SPECIFIC GRAVITY: 0.9 1 ( water= 1 ) at 2 5″ C (7 7 “F)
USCOSITY: No data available
(VOC): > 0.9 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
REACTMTY: Hazardous reactions will not occur under normal transport or storage conditions.
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
CONDITIONS TO AVOID: High temperatures and sour@s of ignition.
POSSIBILITY OF HAZARDOUS REACTIONS: No data available
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carton dioxide.
INCOMPATIBLE MATERIALS: Isocyanates, strong acids, strong bases, and strong oxidizing agents.
1 1. TOXICOLOGICAL IhIFORMATION
ACUTE TO)ilCITY
ORAL LDso DERMAL LDsOChemical Name
1,3-butadienq homopolymer, hydroxy-terminated No data availableNo data available
1,2-B erzenedi carb ox yl ic acid, d i -C9 – I I -bran ch ed alkyl esters, C I 0-rich> 10 g/kg Rat > 3.16 {kg Rabbit
2,6-di -tert-b utyl -p -cresol > 29C0 mg/kgRat > 2000 mg/kg Rat
Dibutyltin dilaurate > 2000 mg/kg Rat> 2000 mglkg Rabbit
Naphthalene 490mg&gRat 20000 mg/kg Rabbit
INHALATIONLCSO
No data available
> 0.13 mg/l Rat
No data available
No data available
> 0.4 mgll Rat (4 h)
SKIN CORROSION/IRRITATION: No data available
SERIOUS EYE DAMAGE/IRRITATION: No data available
RESPIRATORY OR SKIN SENSITISATION: No data available
GERM CELL MIITAGEI.,IICITY: No data available
CARCINOGENICITY
Chemical Name NTP Status
2,6di+errbu gl-p-cresol
Naphthalene 2
IARC Status
J
REPRODUCTM TO)ilCITY: No data available
STOT-SINGLE EXPOSURE: No data available
STOT-REPEATED E)POSURE: No data available
ASPIRATION HAZARD: No dara available
28
PC-10 PART I}
I2. ECOLOGICAI- INFORMATION
ITCOTOXICOf,OGICAL INFOITMATION: No specific ecological data arc available fbr this product. Ref’er to Section
(r for information
regardin-r acciclental relea.se ancl Section l5 for regulatory reporting infolniation.
CHEMICAL FATE INFORMATION: No data available
IIIOACCUMULATION/ACCUMULATION: No data available
ENVIRONMENTAL DATA: No data available
DISTttIItUTION: No data available
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherevel possible. Enrpty containe$ or liners may rctain some
product rqsidues. This rlaterial and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed
waste disposal contractor. Disposerl of this product, solutions and any by-products should at all tirnes cornply with the requirements of
enviror.rrneutal protections and waste disposal legislation and any regional local authority requircments. Avoid dispemal of spilled material and
runofT and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION): Not Established
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITBD STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORTZATION ACT)
3lll312 HEALTH HAZARDS: None Expected
313 REPORTABLE INGREDIENTS: This product does not contain any substances subject to the reporting requirements of Section 313 ol
Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Palrt 372.
CIIRCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY: This product contains one or mor substances regulated as a hazardous substance under the Comprehensive
Environrnental Response Compensation and Liability Act (CERCI-A) (40 CFR 302).
CERCLA RQ
100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product does not contain any substances subject to TSCA Section 12(b) export notification.
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONA L SAFETY AND HEALTH ADMINISTRATION (OSHA)
29 CFR1910.rD—PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: None of the chemicals in this
product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION OS: A WIRNING: This product can expose you to chemicals including [see table below], which is [are]
known to the State of California to cause cancer and birth def’ects or other reproductive har rn. For more information, go to
www.P65 Warnin gs.ca.gov.
Chemical Name Wt.Vo
Naphthalene < 0.001
Listed
o Developmental Toxicity
o Cancer
OSHA HAZARD COMM. RIILE: The contents of the SDS comply witlr the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIAI-S INFORMATION SYSTEM): This product has been classified according to the
hazard criteria of the CPR and theSDS contains all ttre information required by the CPR.
Chemical Name
'V,,lt.Vo
1,2-B errzened icarboxylic acid, d i-C9-1 I -branched erlkyl esters, C 1 Grich 15-40
Naphthalene < 0.001
PC-10 PART B
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listecl in or exenrpted frorn the Dornestic Snbstances
List (DSL) or the Non-Donrestic Substances List (NDSL).
GENERAL COMMENTS:
EXPORT RESTRICTIONS: This procluct contains polybutadiene lesin. Tlris product and the technical data related to this product are expoll
contlolled by the United States (US) Government. Exportation/intemational sl.ripnrents of this product au'e subject to licensing by the US
govemment. Export, re-expolt orotherdiversion, eitherin the original prodnct fonn orafterbeing incolporated in an interrnediate process into
ofter end-iterns, is STRICTLY PROHIBITED unless explessly atthorized by the cognizant agency of the US Government. If you plan to export
this product in some form please contact BJB Enterprises for more infonnation.
DIDPRESTRICTIONS:Thisproductcontainsdiisodecylphthalate(DIDP),CAS#68515-49-l EINECS#211-091-4.IntheU.S.,thereisan
interim prohibition on DIDP above 0. I pelcent by weight (one thousand pffts per nillion) in toys intended for children age l2 and undel that can
be placed in a child's mouth and child care articles for children age 3 and under [I{.R. 4040, The Consumer Safety Improvemnet Act of 2008|. In
the EU, DIDP shall not be used as substance or as constituents of preparations, at concerltrations of greater than 0.1 percent by weight (one
thousand pafts per nillion) of the plasticized material, in toys and childcare anicles which can be place in the mouth by children. Such toys and
childcare arlicles containing DIDP in concentrations greater than the lirnit mentioned above shall not be placed on the market [Directive
2W5t84tECl.
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
Date Revis ed z 0 5/ 04/ 2021
REVISION SUMMARY: This SDS replaces the M/18/2018 SDS
HMIS RATING NFPA CODES
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without waranty, expressed or implied, except that is accumte to the best
knowledge of BJB Enterprises,Inc. The dataon this sheet relates only to the specific material designated herein. BJB Enterprises, Inc. assumes
no legal responsibility for use or reliance upon this data.
XPERSONAL PROTECTION
HEAI,TH
FLAMMABII,ITY
IE
n
by | Sep 27, 2025
PB Fast Set
10/1/15
1 of 7
SAFETY DATA SHEET
PB Fast Set
Section 1. Identification
Product Identifier: PB Fast Set One Part Bonding Adhesive
Chemical family: Aeromatic isocyanates
Synonyms Diphenylmethane Disocynate
Product type: Liquid
Recommended Use: Join Precision Board Plus sheets to make them longer, wider, or
thicker.
Manufacturer s Name & Address Emergency Telephone Number (24/7)
Coastal Enterprises Company
P.O. Box 4875 Chemtrec: (800) 424-9300
Orange, CA 92863-4875
Non- Emergency phone
(800) 845-0745
Section 2. Hazards Identification
Emergency Overview
Contains dispenylmethane disocyanate (CAS No. 101-68-8) Inhalation MDI mists or vapors may
cause respiratory irritation, breathlessness, chest discomfort, and reduced pulmonary function.
Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary
edema. Long-term exposure to isocyanates has been reported to cause lung damage, including
reduced lung function, which may be permanent. Acute or chronic overexposure to isocyanates
may cause sensitization in some individuals resulting in allergic respiratory reactions including
wheezing, shortness of breath and difficulty breathing.
Potential Health Effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion, and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of
entry for liquified gases.
Acute Toxicity: Information on MDI
Inhalation of MDI vapors may cause irritation of the mucous membranes of the nose, throat or
trachea, breathlessness, chest discomfort, difficult breathing, and reduced function. Air-borne
overexposure well above the PEL may result additionally in eye irritation, headache, chemical
bronchitis, asthma-like findings or pulmonary edema. Isocyanates have also been reported to
cause hypersensitivity pneumonitis, which is characterized by flu-like symptoms, the onset of
PB Fast Set
10/1/15
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which may be delayed. Gastrointestinal symptoms include nausea, vomiting, and abdominal
pain.
Irritation: Information on Disocyanates
Eye contact with isocyanates may result in conjuctival irritation and mild corneal opacity. Skin
contact may result in dermatitis, either irritative or allergic.
Repeated Dose Toxicity: Information on MDI
Results from a lifetime inhalation study of rats indicate that MDI aerosol was carcinogenic at
6mg/m3, the highest dose tested. This is well above the recommended TLV of 5 ppb
(0.05 6mg/m3) Only irritation was noted at the lower concentration of 0.2 and 1mg/m3. No birth
defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12
mg/m3 polymeric MDI for 6 hr/day on days 6-15 gestation. Embryotoxicity was reported at the
top dose in the presence of maternity toxicity.
Information of Isocyanates
As a result of previous repeated overexposures or a single large dose, certain individuals will
develop isocyanate sensitization. (chemical asthma) which will cause them to react to a later
exposure of isocyanate at levels well below the PEL/TLV. These symptoms, which include chest
tightness, wheezing, coughing, shortness of breath, or asthmatic attack could be immediate or
delayed up to several hours after exposure. Similar to many non-specific asthmatic responses,
there are reports that once sensitized, an individual can experience these symptoms upon
exposure to dust, cold air, or other irritants. The increased lung sensitivity can persist for weeks
and in severe cases for several years. Chronic overexposure to isocyanates has been reported
to cause lung damage, including a decrease in lung function, which may be permanent.
Sensitization may be either temporary or permanent. Prolonged contact can cause reddening,
swelling, rash, scaling, or blistering. In those who have developed a skin sensitization, these
symptoms can develop as a result of contact with very small amounts of liquid material, or even
as a result of vapor-only exposure.
Medical Conditions Aggravated by Overexposure
The isocyanate component is a respiratory sensitizer. It may cause an allergic reaction leading to
asthma like spasms of the bronchial tubes and difficulty in breathing. Person with history with
respiratory disease or hypersensitivity should not be expose to the product. An animal study
indicated that MDI may induce respiratory hypersensitivity following dermal exposure. Medical
supervision of all employees who handle or come into contact with isocyanates is recommended.
Pre-employment and periodic medical examinations with respiratory function tests (FEV,FVC as a
minimum) are suggested. Persons with asthmatic conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent eczema or pulmonary sensitization should be excluded from
working with isocyanates, further exposure is not recommended. Contact may aggravate
pulmonary disorders.
Section 3. Composition / Information on Ingredients
CAS Number Content (W/W) Chemical Name
<60.0 % Isocyanate Polymer
9016-87-9 <30.0 % P-MDI
101-68-8 <17.0 % Diphenylmethane-4,4' disocyanate
disocyanate (MDI)
26447-40-5 <3.0 % MDI
PB Fast Set
10/1/15
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Section 4. First-Aid Measures
Description of Necessary First Aid Measures
General advice: Remove contaminated clothing
Eye Contact: Immediately flush eyes with water for 15 minutes, lift upper and
lower eyelids. Remove contact lenses. Get medical attention if
irritation persists.
Inhalation: Move to an area that has plenty of fresh air. Rest in a position
comfortable for breathing. Get medical attention if symptoms
occur.
Skin Contact: Flush contaminated skin with soap water. Remove
contaminated clothing and shoes. Get medical attention if
symptoms occur.
Ingestion: Wash out mouth with water. Seek fresh air and rest in a
comfortable position for breathing. If material has been
swallowed, drink small quantities of water. Do not induce
vomiting. Get medical attention if symptoms occur.
Note to Physician:
Hazards: Symptoms can appear later
Antidote: Specific antidotes or neutralizers to isocyanate do not exist
Treatment: Treatment should be supportive and based on the judgement of
the physician in response to the reaction of the patient.
Section 5. Fire-Fighting Measures
Flash point: 228 oc. Closed cup
Auto-ignition: Unspecified
Self-ignition temperature: not self-igniting
Suitable extinguishing media: water, dry extinguishing media, carbon dioxide, foam
Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapor
Protective equipment for Firefighters should be equipped with self-contained breathing
fire-fighting: apparatus and turn-out gear.
Section 6. Accidental Release Measures
Personal Precautions:
Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and
equipment.
PB Fast Set
10/1/15
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Environmental Precautions:
Do not discharge into drains/surface or waters/ground water.
Cleanup:
Dike spillage
For small amounts: Absorb isocyanate with suitable absorbent material (use 40 CFR, sections
260, 204, and 265 for further information). Shovel into open container. Do not make container
pressure tight. Move container to a well-ventilated area (outside) Spill area can be
decontaminated with the following recommended decontamination solution. Mixture of 90%
water, 8% concentrated ammonia, 2% detergent. Add at a 10 to 1 ratio. Allow it to stand for at
least 48 hours to allow escape of evolved carbon dioxide. For large amounts: If temporary
control of isocyanate vapor is required, a blanket of protein foam or other suitable foam (available
from most fire departments) may be placed over the spill. Transfer as much liquid as possible via
pump or vacuum device into closed but not sealed containers for disposal. For residues: The
following measures should be taken for final cleanup: Wash down spill area with
decontamination solution. Allow solution to stand for at least 10 minutes.
Section 7. Handling and Storage
Handling
General Advice:
Mix thoroughly before use. If bulging of drum occurs, transfer to well ventilated area, puncture to
relieve pressure, open vent and let stand for 48 hours before resealing.
Protection against fire and explosion:
No explosion proofing necessary
Storage:
General Advice:
Formation of CO2 and build up of pressure possible. Keep container tightly closed and in a well-
ventilated place. Outage of containers should be filled with dry inert gas at atmospheric pressure
to avoid reaction with moisture.
Storage incompatibility:
General: Segregate from bases.
Storage Stability:
Storage temperature 60-80 oF. Protect against moisture
Section 8. Exposure Controls / Personal Protection
Components with Workplace Control Parameters
Diphenylmethane-4,4'-diisocya OSHA CLY 0.02ppm 0.2 mg/m3
nate (MDI) ACGIH TWA Valve 0.005 ppm
PB Fast Set
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Advice on System Design:
Provide local exhaust ventilation to maintain recommended P.E.L
Personal Protective Equipment
Respiratory Protection
For situations where the airborne concentrations may exceed the level for which an air purifying
respirator is effective, or where the levels are unknown or Immediately Dangerous to Life and
Health (IDLH), use NOISH-certified full face piece pressure demand self-contained breathing
apparatus (SUBA) or a full face piece pressure demand supplied--air respirator (SAR) with
escape provisions. When atmospheric levels may exceed the occupational exposure limit (PEL
or TLV) NOISH-certified or air purifying respirators equipped with an organic vapor sorbent and
particulate filter can be used as long as appropriate precautions and change out schedules are in
place.
Hand Protection
Chemical resistant protective gloves. Suitable materials, chloroprene rubber (Neoprene), nitrile
rubber (Buna N), chlorinated polyethylene, polyvinylchloride (Pylox), butyl rubber, fluoroelastomer
(Viton)
Eye Protection
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body Protection
Suitable materials, saran contact material
General Safety and Hygiene Measures
Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety
showers must be easily accessible. Observe the appropriate PEL valve. Wash soiled clothing
immediately. Contaminated equipment or clothing should be cleaned after each use or disposed
of.
Section 9. Physical and Chemical Properties
Appearance
Physical state Liquid Vapor pressure 0.00001 mmHg
Color Amber Vapor density N/A
Odor faintly aromatic Density 10.16 lb
Odor threshold N/A Solubility in water N/A
pH N/A Partition coefficient N/A
Melting point/Freezing N/A Auto-Ignition temp. N/A
Boiling/condensation point >200oC Decomposition temp N/A
Flash point N/A Viscosity 4,350 mPa.s
Evaporation rate N/A
Flammability (solid, gas) N/A
Lower and upper explosive
(flammable) limits N/A
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Section 10. Stability and Reactivity
Conditions to Avoid:
Avoid moisture
Substances to Avoid:
Water, alcohols, strong bases, substances/products that react with isocyanates.
Hazardous Reactions:
This product is chemically stable:
Reacts with water, with formation of carbon dioxide. Risk of bursting. Reacts with alcohols. Reacts with acids. Reacts
with alkalis. Reacts with amines. Risk of exothermic reaction. Risk of violent reaction. Risk of polymerization. Contact
with rubbers and plastics can cause brittleness of the substance/product with subsequent loss in strength.
Decomposition Products:
Hazardous decomposition products: carbon monoxide, hydrogen cyanide, nitrogen oxides, aeromatic isocyanates,
gases/vapors.
Corrosion to Metals:
No corrosive effect on metal.
Oxidizing Properties:
Not an oxidizer
Section 11. Toxicological Information
Section 12. Ecological Information
Information on: Diphenylmethane-4,4′ diisocyanate (MDI)
Acute and prolonged toxicity to fish
OECD Guideline 203 static
zebra fish/LC0 (96 h): > 1,000mg/l
Information on: Diphenylmethane-4,4′ diisocyanate (MDI)
Acute toxicity to aquatic invertebrates:
OECD Guideline 202 part 1 static
Daphnia magna/EC50 (24 h): > 1,000mg/l
Section 13. Disposal Considerations
Waste Disposal of Substance:
Incinerate or dispose of in a licensed facility.
Do not discharge substance/product into the sewer system.
Container Disposal
Drums:
Steel drums must be emptied and can be sent to a licensed drum re-conditioner for reuse, a
scrap metal dealer, or an approved landfill. Refer to 40 CFR 261.7 (residues of hazardous waste
in empty containers). Check with re-conditioner to determine if decontamination is required.
Decontaminate containers prior to disposal. Recommend crushing, puncturing, or other means to
prevent unauthorized use of used containers.
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Section 14. Transport Information
Reference Bill of Lading
Section 15. Regulatory Information
Safety, health and environmental regulations specific for this product:
United States Regulations
TSCA 8(b) Inventory Released / Listed
OSHA Hazard Category Chronic target organ effects reported, ACGIH TLV established
CERCLA RQ CAS Number Chemical Name
5000 lbs. 101-68-8 Diphenylmethane-4,4′ diisocyanate (MDI)
State Regulations
State RTK
CAS Number Chemical Name State RTK
9016-87-9 P-MDI NJ
101-68-8 Diphenylmethane-4,4′ diisocyanate MA, NJ, PA
Section 16. Other Information
Hazardous Material Information System (USA):
Health: 2 Flammability: 1 Physical Hazard: 1
HMIS uses a numbering scale ranging from 0 to 4to indicate the degree of hazard. A value of
zero means that the substance possesses essentially no hazard, a rating of 4 indicates a hight
hazard.
Date of Printing: 10/1/15
Date of Issue: 10/1/15
Date of previous Issue 1/19/15
Notice to Reader
The information contained herein is based on data believed by Coastal Enterprises Company to
be accurate, but we do not assume any liability for the accuracy of this information. We neither
suggest nor guarantee that any hazards mentioned are the only ones which exist. Anyone
intending to rely on any recommendation or to use any equipment technique or material
mentioned should also satisfy himself that he can meet all applicable safety and health standards.
Determination of the suitability of any information or product for the use contemplated by any
user, the manner of that use and whether there is any infringement of patents, is the sole
responsibility of the user.
by | Sep 27, 2025
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SAFETY DATA SHEET
PB Bond -240
Section 1. ldentification
Product ldentifier:
Chemicalfamily:
Synonyms
Product type:
Recommended Use
PB Bond-240, One Part Bonding Adhesive
Liquid
Join Precision Board Plus sheets to make them longer, wider, or
thicker.
Aeromatic isocyanates
Diphenylmethane Disocynate
Manufacturer’s Name & Address
Coastal Enterprises CompanY
1925 W. Collins Ave
Orange, CA 92867
Non- Emergency phone
(800) 845-0745
Emergency Telephone Number (241l)
Chemtrec: (800) 424-9300
Section 2. Hazards ldentification
Emeroencv Overview
Contains dispenylmethane disocyanate (CAS No. 101-68-8) lnhalation MDI mists or vapors may
cause respiratory irritation, breathlessness, chest discomfort, and reduced pulmonary function.
Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary
edema. Long-term exposure to isocyanates has been reported to cause lung damage, including
reduced lung function, which may be permanent. Acute or chronic overexposure to isocyanates
may cause iensitization in some individuals resulting in allergic respiratory reactions including
wheezing, shortness of breath and difficulty breathing.
Potential Health Effects
Primary routes of exPosure
Routes of entry for solids and liquids include eye and skin contact, ingestion, and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of
entry for liquified gases.
1 of10
PB Bond-240
911119
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Acute Toxicity: lnformation on MDI
Of moderate toxicity afier short-term inhalation. Virtually non-toxic after a single ingestion.
Virtually non-toxic after a single skin contact. lnhalation of vapors may cause irritation of mucous
membranes of the nose, throat, trachea, chest discomfort, difficult breathing, and reduced
pulmonary function. lnhalation exposure well above the PEL may result additionally to eye
irritation, headache, chemical bronchitis, asthma-like findings, or pulmonary edema. lsocyanates
have also been reported to cause hypersensitivity pneumonitis, which is characterized by flu-like
symptoms, the onset of which may delayed. Gastrointestinal symptoms include nausea,
vomiting, and abdominal pain.
lrritation:
lnitating to eyes, respiratory system and skin.
Assessment Other Acute Effects:
Causes temporary initation of the respiratory tract.
Sensitization:
The substance may cause sensitization of the respiratory tract. Sensitization after skin contact
possible. Studies in animals suggest that dermal exposure may lead to pulmonary sensitization.
As a result of repeated overexposure of a single dose, certain individuals will develop isocyanate
sensitization (chemical asthma), which will cause them to react to a later exposure at levels below
PEL/TLV. Symptoms which include chest tightness, wheezing, cough, shortness of breath, or
asthmatic attack, could be immediate or delayed up to several hours after exposure. Similar to
many non-specific asthmatic responses, there are reports that once sensitized an individual can
experience these symptoms upon exposure to dust, cold air, and other irritants. This increase
lung sensitivity can persist for weeks and in severe cases for several years. Chronic
overexposure of isocyanates has also been reported to cause lung damage, including a decrease
in lung function, which may be permanent. Prolonged contact can cause reddening, swelling,
rash, scaling, or blistering. ln those who have developed a skin sensitization, these symptoms
can develop as a result of contact with very small amounts ol liquid material. or even as a result
of vapor only exposure.
Chronic Toxicity:
Carcinogenicity: A carcinogenic potential cannot be excluded after long exposure to severely
irritating concentrations. The effects are not relevant to humans at occupational levels of
exposure.
Repeated Dose Toxicity: The substance may cause damage to the olfactory epithelium after
repeated inhalation. These effects are not relevant to humans at occupational levels of exposure.
Reproductive Toxicity: Repeated inhalation does not cause damage to reproductive organs.
Teratogenicity: No malformations in animal studies found, however high doses was toxic in the
development of parental animals.
Genotoxicity: The substance was mutagenic in various bacterial test systems, however, these
results could not be confirmed in tests with mammals.
2ol1O
PB Bond-240
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Aquatic Toxicity: The product may hydrolyse. The test result maybe partially due degradation
products. The product has not been tested. The statement has been derived from products of a
similar structure or composition.
lnformation of lsocyanates
As a result of previous repeated overexposures or a single large dose, certain individuals will
develop isocyanate sensitization. (chemical asthma) which will cause them to react to a later
exposure of isocyanate at levels well below the PEUTLV. These symptoms, which include chest
tightness, wheezing, coughing, shortness of breath, or asthmatic attack could be immediate or
delayed up to several hours after exposure. Similar to many non-specific asthmatic responses,
there are reports that once sensitized, an individual can experience these symptoms upon
exposure to dust, cold air, or other irritants. The increased lung sensitivity can persist for weeks
and in severe cases for several years. Chronic overexposure to isocyanates has been reported
to cause lung damage, including a decrease in lung function, which may be permanent.
Sensitization may be either temporary or permanent. Prolonged contact can cause reddening,
swelling, rash, scaling, or blistering. ln those who have developed a skin sensitization, these
symptoms can develop as a result of contact with very small amounts of liquid material, or even
as a result of vapor-only exposure.
Medical Conditions Aggravated by Overexposure
The isocyanate component is a respiratory sensitizer. ll may cause an allergic reaction leading to
asthma like spasms of the bronchial tubes and difficulty in breathing. Person with history with
respiratory disease or hypersensitivity should not be expose to the product. An animal study
indicated that MDI may induce respiratory hypersensitivity following dermal exposure. Medical
supervision of all employees who handle or come into contact with isocyanates is recommended.
Pre-employment and periodic medicalexaminations with respiratory function tests (FEV,FVC as a
minimum) are suggested. Persons with asthmatic conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent eczema or pulmonary sensitization should be excluded from
working with isocyanates, further exposure is not recommended. Contact may aggravate
pulmonary disorders.
Section 3. ition / lnformation on Iredients
CAS Number
9016-87-9
101-68-8
26447-40-5
Content (W/VV)
<75.0 %
<10.0 %
<16.0 %
<1 .O "/"
ChemicalName
lsocyanate Polymer
P-MDI
Diphenylmethane- 4,4' disocyanate
disocyanate (MDl)
MDI
3of10
PB Bond-240
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Section 4. First-Aid Measures
Description of Necessary First Aid Measures
Generaladvice Remove contaminated clothing
lmmediately flush eyes with water lor 15 minutes, lift upper and
lower eyelids. Remove contact lenses. Get medical attention if
irritation persists.
Eye Contact:
lnhalation Move to an area that has plenty of fresh air. Rest in a position
comfortable for breathing. Get medical attention if symptoms
occur.
Skin Contact: Flush contaminated skin with soap water. Remove
contaminated clothing and shoes. Get medical attention if
symptoms occur.
lngestion: Wash out mouth with water. Seek fresh air and rest in a
comfortable position for breathing. lf material has been
swallowed, drink small quantities of water. Do not induce
vomiting. Get medical attention if symptoms occur.
Note to Physician:
Hazards:
Antidote:
Treatment:
Symptoms can appear later
Specific antidotes or neutralizers to isocyanate do not exist
Treatment should be supportive and based on the judgement of
the physician in response to the reaction of the patient.
Section 5. Fire-htinMeasures
Flash point:
Auto-ignition:
Self-ignition temperature:
Protective equipment for
lire-fighting:
Suitable extinguishing media: water, dry extinguishing media, carbon dioxide, foam
Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapor
2OOoc. open cup
>470
oc
not self-igniting
Firefighters should be equipped with self-contained breathing
apparatus and turn-out gear.
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Section 6. Accidental Release Measures
Personal Precautions:
Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and
equipment.
Environmental Precautions :
Do not discharge into drains/surface or waters/ground water
Cleanup:
Dike spillage
For small amounts: Absorb isocyanate with suitable absorbent material (use 40 CFR, sections
260,2O4, and 265 for further information). Shovel into open container. Do not make container
pressure tight. Move container to a well-ventilated area (outside) Spill area can be
decontaminated with the following recommended decontamination solution. Mixture ol90%
water, 87o concentrated ammonia,2o/o detergent. Add at a 10 to 1 ratio. Allow it to stand for at
least 48 hours to allow escape of evolved carbon dioxide. For large amounts: lf temporary
control of isocyanate vapor is required, a blanket of protein foam or other suitable loam (available
from most fire departments) may be placed over the spill. Transfer as much liquid as possible via
pump or vacuum device into closed but not sealed containers for disposal. For residues: The
following measures should be taken for final cleanup: Wash down spill area with
decontamination solution. Allow solution to stand for at least 10 minutes.
Section 7. Handling and Storage
Handling
GeneralAdvice:
Mix thoroughly before use. lf bulging of drum occurs, transfer to well ventilated area, puncture to
relieve pressure, open vent and let stand for 48 hours before resealing.
Protection against fire and explosion:
No explosion proofing necessary
Storage:
GeneralAdvice:
Formation of COz and build up of pressure possible. Keep container tightly closed and in a well-
ventilated place. Outage of containers should be filled with dry inert gas at atmospheric pressure
to avoid reaction with moisture.
Storage incompatibility:
General: Segregate from bases.
Storage Stability:
Storage temperature 60-80 0F. Protect against moisture
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IIIIIRPAISIS
Section 8. Exposure Controls / Personal Protection
Components with Workplace Control Parameters
Diphenylmethane-4,4′-diisocya OSHA CLY0.02ppm 0.2 mg/m3
Nate (MDl) ACGIH TWA Valve 0.005 ppm
Advice on System Design:
Provide local exhaust ventilation to maintain recommended P.E.L
Personal Protective Equipment
Respiratory Protection
For situations where the airborne concentrations may exceed the level for which an air purifying
respirator is effective, or where the levels are unknown or lmmediately Dangerous to Life and
Health (IDLH), use NO|SH-certified fullface piece pressure demand self-contained breathing
apparatus (SUBA) or a full face piece pressure demand supplied–air respirator (SAR) with
escape provisions. When atmospheric levels may exceed the occupational exposure limit (PEL
or TLV) NO|SH-certified or air purifying respirators equipped with an organic vapor sorbent and
particulate filter can be used as long as appropriate precautions and change out schedules are in
place.
Hand Protection
Chemical resistant protective gloves. Suitable materials, chloroprene rubber (Neoprene), nitrile
rubber (Buna N), chlorinated polyethylene, polyvinylchloride (Pylox), butyl rubber, fluoroelastomer
(Viton)
Eye Protection
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body Protection
Suitable materials, saran contact material
General Safety and Hygiene Measures
Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety
showers must be easily accessible. Observe the appropriate PEL valve. Wash soiled clothing
immediately. Contaminated equipment or clothing should be cleaned after each use or disposed
of.
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Section 9. Physical and Ghemical Properties
Appearance
Physical state
Color
Odor
Odor threshold
pH
Melting poinUFreezing
Boiling/condensation point
Flash point
Evaporation rate
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Liquid
Amber
faintly aromatic
N/A
NiA
<-200c
>2000c
N/A
N/A
N/A
N/A
Vapor pressure
Vapor density
Density
Solubility in water
Partition coefficient
Auto-lgnition temp.
Decomposition temp
Viscosity
0.00001 mmHg
N/A
9.4|b
React with water
N/A
N/A
N/A
5,600 mPa.s
Section 10. Stabilitv and Reactivitv
Conditions to Avoid
Avoid moisture
Substances to Avoid:
Water, alcohols, strong bases, substances/products that react with isocyanates.
Hazardous Reactions:
This product is chemically stable:
Reacts with water, with formation of carbon dioxide. Risk ol bursting. Reacts with alcohols. Reacts with acids. Reacts
with alkalis. Reacts with amines. Risk of exothermic reaction. Risk of violent reaction. Risk of polymerization. Contact
with rubbers and plastics can cause brittleness ol the substance/product with subsequent loss in strength.
Decomposition Products:
Hazardous decomposition products: carbon monoxide, hydrogen cyanide, nitrogen oxides, aeromatic isocyanates,
gasesfuapors.
Corrosion to Metals:
No corrosive etfect on metal.
Thermal Decomposition:
>260 0C. No data available
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Oxidizing Properties: N/A
r0flsTflt
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Section 11. Toxi ical lnformation
Acute Toxicity
Oral:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rat (malelfemale)
Value: >2.000 mgikg (Directive 84/449/EEC, 8.1)
lnhalation:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD10
Species: rat (malelfemale)
V alue i >2.24 m g/f (D irective 84 I 449 IEEC, 8.1′)
Exposure time: t hr. An aerosol was tested
Dermal:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rabbit (male/female)
Value: >9.400 mg/kg
lrrilation / Corrosionr Skin / Eye
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rabbit (male/female)
Result: lnitating
Method: Draize test
Sensitization:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: guinea pig/mouse/
Result: sensitizing
Method: Buehler test
Repeated Dose Toxlcity:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rat (malellemale)
NOAEL: 0.2 mg/m3
LOAEL: 1 mg/m3
This substance may cause damage to olfactory epithelium atter repeated inhalation. Not relevant to humans at
occupational levels ol exposure.
Genetic Toxlcityl
lnlormation on: Diphenylmethane-4,4′ diisocyanate (MDl)
OECD Guideline 471 Ames-test.
No clastogenic ettect reported.
Carcinogenicityr
Experimental data
OECD Guideline 471 tal inhalation 0, 2, 1, mg/mm3
Result: Lung tumors A carcinogenic potential cannot be excluded. Not relevant to humans.
Development:
OECD Guideline 414 ral inhalation 0, ‘l,4, 12 mg/mm3
NOAEL Mat: 4mglm3
NOAEL Teratog:4mg/m3
Result: This substance did not cause mallormations in animal studies. Not relevant to humans.
Aspiration Hazardt
No hazard expected
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Section 12. Ecolical lnformation
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute and prolonged toxicity to fish
OECD Guideline 203 static
zebra fish/LCO (96 h):> 1,000mgil
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute toxicity to aquatic invertebrates:
OECD Guideline 202 part I static
Daphnia magna/ECso (24 h):> 1,000m9/l
Degradability / Persistence
Biological / Degradation
Test Method: OECD Guideline 302 (aerobic),activated sludge
Results: Poorly biodegradable. Unstable in water.
Section 13. Dis Considerations
Waste Disposal of Substance:
lncinerate or dispose of in a licensed facility.
Do not discharge substance/product into the sewer system
Container Disposal
Drums:
Steel drums must be emptied and can be sent to a licensed drum re-conditioner for reuse, a
scrap metal dealer, or an approved landfill. Refer to 40 CFR 261.7 (residues of hazardous waste
in empty containers). Check with re-conditioner to determine if decontamination is required.
Decontaminate containers prior to disposal. Recommend crushing, puncturing, or other means to
prevent unauthorized use of used containers.
Reference Bill of Lading
Section 14. lnformation
Section 15. ulatolnformation
Safety. health and environmental regulations specific for this product:
United States Regulations
TSCA 8(b) lnventory Released / Listed
OSHA Hazard Category Chronic target organ etlects reported, ACGIH TLV established
CERCLA RO
5000 lbs.
State Regulations
RTK
CAS Number
901 6-87-9
101-68-8
Chemical Name
P.MDI
Diphenylmethane-4,4′ diisocyanate
CAS Number Chemical Name
101 -68-8 Diphenylmethane-4,4’ diisocyanate (MDl)
State RTK
NJ
MA, NJ, PA
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Section 16. Other lnformation
Hazardous Material lnformation System (USA):
Health: 2 Flammability: 1 PhysicalHazard: 1
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of
zero means that the substance possesses essentially no hazard, a rating of 4 indicates a high
hazard.
Date of Printing:
Date of lssue:
Date of previous lssue
9t1119
9t1t1g
1t19t18
Notice to Reader
The information contained herein is based on data believed by Coastal Enterprises Company to
be accurate, but we do not assume any liability for the accuracy of this information. We neither
suggest nor guarantee that any hazards mentioned are the only ones which exist. Anyone
intending to rely on any recommendation or to use any equipment technique or material
mentioned should also satisfy himself that he can meet all applicable safety and health standards.
Determination of the suitability of any information or product for the use contemplated by any
user, the manner of that use and whether there is any infringement of patents, is the sole
responsibility of the user.
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SAFETY DATA SHEET
PB Bond -240
Section 1. ldentification
Product ldentifier:
Chemicalfamily:
Synonyms
Product type:
Recommended Use
PB Bond-240, One Part Bonding Adhesive
Liquid
Join Precision Board Plus sheets to make them longer, wider, or
thicker.
Aeromatic isocyanates
Diphenylmethane Disocynate
Manufacturer’s Name & Address
Coastal Enterprises CompanY
1925 W. Collins Ave
Orange, CA 92867
Non- Emergency phone
(800) 845-0745
Emergency Telephone Number (241l)
Chemtrec: (800) 424-9300
Section 2. Hazards ldentification
Emeroencv Overview
Contains dispenylmethane disocyanate (CAS No. 101-68-8) lnhalation MDI mists or vapors may
cause respiratory irritation, breathlessness, chest discomfort, and reduced pulmonary function.
Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary
edema. Long-term exposure to isocyanates has been reported to cause lung damage, including
reduced lung function, which may be permanent. Acute or chronic overexposure to isocyanates
may cause iensitization in some individuals resulting in allergic respiratory reactions including
wheezing, shortness of breath and difficulty breathing.
Potential Health Effects
Primary routes of exPosure
Routes of entry for solids and liquids include eye and skin contact, ingestion, and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of
entry for liquified gases.
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Acute Toxicity: lnformation on MDI
Of moderate toxicity afier short-term inhalation. Virtually non-toxic after a single ingestion.
Virtually non-toxic after a single skin contact. lnhalation of vapors may cause irritation of mucous
membranes of the nose, throat, trachea, chest discomfort, difficult breathing, and reduced
pulmonary function. lnhalation exposure well above the PEL may result additionally to eye
irritation, headache, chemical bronchitis, asthma-like findings, or pulmonary edema. lsocyanates
have also been reported to cause hypersensitivity pneumonitis, which is characterized by flu-like
symptoms, the onset of which may delayed. Gastrointestinal symptoms include nausea,
vomiting, and abdominal pain.
lrritation:
lnitating to eyes, respiratory system and skin.
Assessment Other Acute Effects:
Causes temporary initation of the respiratory tract.
Sensitization:
The substance may cause sensitization of the respiratory tract. Sensitization after skin contact
possible. Studies in animals suggest that dermal exposure may lead to pulmonary sensitization.
As a result of repeated overexposure of a single dose, certain individuals will develop isocyanate
sensitization (chemical asthma), which will cause them to react to a later exposure at levels below
PEL/TLV. Symptoms which include chest tightness, wheezing, cough, shortness of breath, or
asthmatic attack, could be immediate or delayed up to several hours after exposure. Similar to
many non-specific asthmatic responses, there are reports that once sensitized an individual can
experience these symptoms upon exposure to dust, cold air, and other irritants. This increase
lung sensitivity can persist for weeks and in severe cases for several years. Chronic
overexposure of isocyanates has also been reported to cause lung damage, including a decrease
in lung function, which may be permanent. Prolonged contact can cause reddening, swelling,
rash, scaling, or blistering. ln those who have developed a skin sensitization, these symptoms
can develop as a result of contact with very small amounts ol liquid material. or even as a result
of vapor only exposure.
Chronic Toxicity:
Carcinogenicity: A carcinogenic potential cannot be excluded after long exposure to severely
irritating concentrations. The effects are not relevant to humans at occupational levels of
exposure.
Repeated Dose Toxicity: The substance may cause damage to the olfactory epithelium after
repeated inhalation. These effects are not relevant to humans at occupational levels of exposure.
Reproductive Toxicity: Repeated inhalation does not cause damage to reproductive organs.
Teratogenicity: No malformations in animal studies found, however high doses was toxic in the
development of parental animals.
Genotoxicity: The substance was mutagenic in various bacterial test systems, however, these
results could not be confirmed in tests with mammals.
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PB Bond-240
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Aquatic Toxicity: The product may hydrolyse. The test result maybe partially due degradation
products. The product has not been tested. The statement has been derived from products of a
similar structure or composition.
lnformation of lsocyanates
As a result of previous repeated overexposures or a single large dose, certain individuals will
develop isocyanate sensitization. (chemical asthma) which will cause them to react to a later
exposure of isocyanate at levels well below the PEUTLV. These symptoms, which include chest
tightness, wheezing, coughing, shortness of breath, or asthmatic attack could be immediate or
delayed up to several hours after exposure. Similar to many non-specific asthmatic responses,
there are reports that once sensitized, an individual can experience these symptoms upon
exposure to dust, cold air, or other irritants. The increased lung sensitivity can persist for weeks
and in severe cases for several years. Chronic overexposure to isocyanates has been reported
to cause lung damage, including a decrease in lung function, which may be permanent.
Sensitization may be either temporary or permanent. Prolonged contact can cause reddening,
swelling, rash, scaling, or blistering. ln those who have developed a skin sensitization, these
symptoms can develop as a result of contact with very small amounts of liquid material, or even
as a result of vapor-only exposure.
Medical Conditions Aggravated by Overexposure
The isocyanate component is a respiratory sensitizer. ll may cause an allergic reaction leading to
asthma like spasms of the bronchial tubes and difficulty in breathing. Person with history with
respiratory disease or hypersensitivity should not be expose to the product. An animal study
indicated that MDI may induce respiratory hypersensitivity following dermal exposure. Medical
supervision of all employees who handle or come into contact with isocyanates is recommended.
Pre-employment and periodic medicalexaminations with respiratory function tests (FEV,FVC as a
minimum) are suggested. Persons with asthmatic conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent eczema or pulmonary sensitization should be excluded from
working with isocyanates, further exposure is not recommended. Contact may aggravate
pulmonary disorders.
Section 3. ition / lnformation on Iredients
CAS Number
9016-87-9
101-68-8
26447-40-5
Content (W/VV)
<75.0 %
<10.0 %
<16.0 %
<1 .O "/"
ChemicalName
lsocyanate Polymer
P-MDI
Diphenylmethane- 4,4' disocyanate
disocyanate (MDl)
MDI
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Section 4. First-Aid Measures
Description of Necessary First Aid Measures
Generaladvice Remove contaminated clothing
lmmediately flush eyes with water lor 15 minutes, lift upper and
lower eyelids. Remove contact lenses. Get medical attention if
irritation persists.
Eye Contact:
lnhalation Move to an area that has plenty of fresh air. Rest in a position
comfortable for breathing. Get medical attention if symptoms
occur.
Skin Contact: Flush contaminated skin with soap water. Remove
contaminated clothing and shoes. Get medical attention if
symptoms occur.
lngestion: Wash out mouth with water. Seek fresh air and rest in a
comfortable position for breathing. lf material has been
swallowed, drink small quantities of water. Do not induce
vomiting. Get medical attention if symptoms occur.
Note to Physician:
Hazards:
Antidote:
Treatment:
Symptoms can appear later
Specific antidotes or neutralizers to isocyanate do not exist
Treatment should be supportive and based on the judgement of
the physician in response to the reaction of the patient.
Section 5. Fire-htinMeasures
Flash point:
Auto-ignition:
Self-ignition temperature:
Protective equipment for
lire-fighting:
Suitable extinguishing media: water, dry extinguishing media, carbon dioxide, foam
Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapor
2OOoc. open cup
>470
oc
not self-igniting
Firefighters should be equipped with self-contained breathing
apparatus and turn-out gear.
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Section 6. Accidental Release Measures
Personal Precautions:
Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and
equipment.
Environmental Precautions :
Do not discharge into drains/surface or waters/ground water
Cleanup:
Dike spillage
For small amounts: Absorb isocyanate with suitable absorbent material (use 40 CFR, sections
260,2O4, and 265 for further information). Shovel into open container. Do not make container
pressure tight. Move container to a well-ventilated area (outside) Spill area can be
decontaminated with the following recommended decontamination solution. Mixture ol90%
water, 87o concentrated ammonia,2o/o detergent. Add at a 10 to 1 ratio. Allow it to stand for at
least 48 hours to allow escape of evolved carbon dioxide. For large amounts: lf temporary
control of isocyanate vapor is required, a blanket of protein foam or other suitable loam (available
from most fire departments) may be placed over the spill. Transfer as much liquid as possible via
pump or vacuum device into closed but not sealed containers for disposal. For residues: The
following measures should be taken for final cleanup: Wash down spill area with
decontamination solution. Allow solution to stand for at least 10 minutes.
Section 7. Handling and Storage
Handling
GeneralAdvice:
Mix thoroughly before use. lf bulging of drum occurs, transfer to well ventilated area, puncture to
relieve pressure, open vent and let stand for 48 hours before resealing.
Protection against fire and explosion:
No explosion proofing necessary
Storage:
GeneralAdvice:
Formation of COz and build up of pressure possible. Keep container tightly closed and in a well-
ventilated place. Outage of containers should be filled with dry inert gas at atmospheric pressure
to avoid reaction with moisture.
Storage incompatibility:
General: Segregate from bases.
Storage Stability:
Storage temperature 60-80 0F. Protect against moisture
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IIIIIRPAISIS
Section 8. Exposure Controls / Personal Protection
Components with Workplace Control Parameters
Diphenylmethane-4,4′-diisocya OSHA CLY0.02ppm 0.2 mg/m3
Nate (MDl) ACGIH TWA Valve 0.005 ppm
Advice on System Design:
Provide local exhaust ventilation to maintain recommended P.E.L
Personal Protective Equipment
Respiratory Protection
For situations where the airborne concentrations may exceed the level for which an air purifying
respirator is effective, or where the levels are unknown or lmmediately Dangerous to Life and
Health (IDLH), use NO|SH-certified fullface piece pressure demand self-contained breathing
apparatus (SUBA) or a full face piece pressure demand supplied–air respirator (SAR) with
escape provisions. When atmospheric levels may exceed the occupational exposure limit (PEL
or TLV) NO|SH-certified or air purifying respirators equipped with an organic vapor sorbent and
particulate filter can be used as long as appropriate precautions and change out schedules are in
place.
Hand Protection
Chemical resistant protective gloves. Suitable materials, chloroprene rubber (Neoprene), nitrile
rubber (Buna N), chlorinated polyethylene, polyvinylchloride (Pylox), butyl rubber, fluoroelastomer
(Viton)
Eye Protection
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body Protection
Suitable materials, saran contact material
General Safety and Hygiene Measures
Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety
showers must be easily accessible. Observe the appropriate PEL valve. Wash soiled clothing
immediately. Contaminated equipment or clothing should be cleaned after each use or disposed
of.
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Section 9. Physical and Ghemical Properties
Appearance
Physical state
Color
Odor
Odor threshold
pH
Melting poinUFreezing
Boiling/condensation point
Flash point
Evaporation rate
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Liquid
Amber
faintly aromatic
N/A
NiA
<-200c
>2000c
N/A
N/A
N/A
N/A
Vapor pressure
Vapor density
Density
Solubility in water
Partition coefficient
Auto-lgnition temp.
Decomposition temp
Viscosity
0.00001 mmHg
N/A
9.4|b
React with water
N/A
N/A
N/A
5,600 mPa.s
Section 10. Stabilitv and Reactivitv
Conditions to Avoid
Avoid moisture
Substances to Avoid:
Water, alcohols, strong bases, substances/products that react with isocyanates.
Hazardous Reactions:
This product is chemically stable:
Reacts with water, with formation of carbon dioxide. Risk ol bursting. Reacts with alcohols. Reacts with acids. Reacts
with alkalis. Reacts with amines. Risk of exothermic reaction. Risk of violent reaction. Risk of polymerization. Contact
with rubbers and plastics can cause brittleness ol the substance/product with subsequent loss in strength.
Decomposition Products:
Hazardous decomposition products: carbon monoxide, hydrogen cyanide, nitrogen oxides, aeromatic isocyanates,
gasesfuapors.
Corrosion to Metals:
No corrosive etfect on metal.
Thermal Decomposition:
>260 0C. No data available
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Oxidizing Properties: N/A
r0flsTflt
7tE
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tililnpBr$rs
Section 11. Toxi ical lnformation
Acute Toxicity
Oral:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rat (malelfemale)
Value: >2.000 mgikg (Directive 84/449/EEC, 8.1)
lnhalation:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD10
Species: rat (malelfemale)
V alue i >2.24 m g/f (D irective 84 I 449 IEEC, 8.1′)
Exposure time: t hr. An aerosol was tested
Dermal:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rabbit (male/female)
Value: >9.400 mg/kg
lrrilation / Corrosionr Skin / Eye
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rabbit (male/female)
Result: lnitating
Method: Draize test
Sensitization:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: guinea pig/mouse/
Result: sensitizing
Method: Buehler test
Repeated Dose Toxlcity:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rat (malellemale)
NOAEL: 0.2 mg/m3
LOAEL: 1 mg/m3
This substance may cause damage to olfactory epithelium atter repeated inhalation. Not relevant to humans at
occupational levels ol exposure.
Genetic Toxlcityl
lnlormation on: Diphenylmethane-4,4′ diisocyanate (MDl)
OECD Guideline 471 Ames-test.
No clastogenic ettect reported.
Carcinogenicityr
Experimental data
OECD Guideline 471 tal inhalation 0, 2, 1, mg/mm3
Result: Lung tumors A carcinogenic potential cannot be excluded. Not relevant to humans.
Development:
OECD Guideline 414 ral inhalation 0, ‘l,4, 12 mg/mm3
NOAEL Mat: 4mglm3
NOAEL Teratog:4mg/m3
Result: This substance did not cause mallormations in animal studies. Not relevant to humans.
Aspiration Hazardt
No hazard expected
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Section 12. Ecolical lnformation
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute and prolonged toxicity to fish
OECD Guideline 203 static
zebra fish/LCO (96 h):> 1,000mgil
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute toxicity to aquatic invertebrates:
OECD Guideline 202 part I static
Daphnia magna/ECso (24 h):> 1,000m9/l
Degradability / Persistence
Biological / Degradation
Test Method: OECD Guideline 302 (aerobic),activated sludge
Results: Poorly biodegradable. Unstable in water.
Section 13. Dis Considerations
Waste Disposal of Substance:
lncinerate or dispose of in a licensed facility.
Do not discharge substance/product into the sewer system
Container Disposal
Drums:
Steel drums must be emptied and can be sent to a licensed drum re-conditioner for reuse, a
scrap metal dealer, or an approved landfill. Refer to 40 CFR 261.7 (residues of hazardous waste
in empty containers). Check with re-conditioner to determine if decontamination is required.
Decontaminate containers prior to disposal. Recommend crushing, puncturing, or other means to
prevent unauthorized use of used containers.
Reference Bill of Lading
Section 14. lnformation
Section 15. ulatolnformation
Safety. health and environmental regulations specific for this product:
United States Regulations
TSCA 8(b) lnventory Released / Listed
OSHA Hazard Category Chronic target organ etlects reported, ACGIH TLV established
CERCLA RO
5000 lbs.
State Regulations
RTK
CAS Number
901 6-87-9
101-68-8
Chemical Name
P.MDI
Diphenylmethane-4,4′ diisocyanate
CAS Number Chemical Name
101 -68-8 Diphenylmethane-4,4’ diisocyanate (MDl)
State RTK
NJ
MA, NJ, PA
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Section 16. Other lnformation
Hazardous Material lnformation System (USA):
Health: 2 Flammability: 1 PhysicalHazard: 1
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of
zero means that the substance possesses essentially no hazard, a rating of 4 indicates a high
hazard.
Date of Printing:
Date of lssue:
Date of previous lssue
9t1119
9t1t1g
1t19t18
Notice to Reader
The information contained herein is based on data believed by Coastal Enterprises Company to
be accurate, but we do not assume any liability for the accuracy of this information. We neither
suggest nor guarantee that any hazards mentioned are the only ones which exist. Anyone
intending to rely on any recommendation or to use any equipment technique or material
mentioned should also satisfy himself that he can meet all applicable safety and health standards.
Determination of the suitability of any information or product for the use contemplated by any
user, the manner of that use and whether there is any infringement of patents, is the sole
responsibility of the user.
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PB Bond-240
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COASTAL
‘aia.
a3
EHTERPRISES
PB Bond-240
Product Identifier: PB Bond-240, One Part Bonding Adhesive
Chemical family: Aeromatic isocyanates
Synonyms Diphenylmethane Disocynate
Product type: Liquid
Recommended Use: Join Precision Board Plus sheets to make them longer, wider, or
thicker.
Manufacturer s Name & Address Emergency Telephone Number (24/7)
Coastal Enterprises Company
1925 W. Collins Ave Chemtrec: (800) 424-9300
Orange, CA 92867
Non- Emergency phone
(800) 845-0745
[Section 2. Hazards Identification 0
Emergency Overview
Contains dispenylmethane disocyanate (CAS No. 101-68-8) Inhalation MDI mists or vapors may
cause respiratory irritation, breathlessness, chest discomfort, and reduced pulmonary function.
Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary
edema. Long-term exposure to isocyanates has been reported to cause lung damage, including
reduced lung function, which may be permanent. Acute or chronic overexposure to isocyanates
may cause sensitization in some individuals resulting in allergic respiratory reactions including
wheezing, shortness of breath and difficulty breathing.
Potential Health Effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion, and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of
entry for liquified gases.
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SAFETY DATA SHEET
PB Bond -240
Section 1. ldentification
Product ldentifier:
Chemicalfamily:
Synonyms
Product type:
Recommended Use
PB Bond-240, One Part Bonding Adhesive
Liquid
Join Precision Board Plus sheets to make them longer, wider, or
thicker.
Aeromatic isocyanates
Diphenylmethane Disocynate
Manufacturer’s Name & Address
Coastal Enterprises CompanY
1925 W. Collins Ave
Orange, CA 92867
Non- Emergency phone
(800) 845-0745
Emergency Telephone Number (241l)
Chemtrec: (800) 424-9300
Section 2. Hazards ldentification
Emeroencv Overview
Contains dispenylmethane disocyanate (CAS No. 101-68-8) lnhalation MDI mists or vapors may
cause respiratory irritation, breathlessness, chest discomfort, and reduced pulmonary function.
Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary
edema. Long-term exposure to isocyanates has been reported to cause lung damage, including
reduced lung function, which may be permanent. Acute or chronic overexposure to isocyanates
may cause iensitization in some individuals resulting in allergic respiratory reactions including
wheezing, shortness of breath and difficulty breathing.
Potential Health Effects
Primary routes of exPosure
Routes of entry for solids and liquids include eye and skin contact, ingestion, and inhalation.
Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of
entry for liquified gases.
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Acute Toxicity: lnformation on MDI
Of moderate toxicity afier short-term inhalation. Virtually non-toxic after a single ingestion.
Virtually non-toxic after a single skin contact. lnhalation of vapors may cause irritation of mucous
membranes of the nose, throat, trachea, chest discomfort, difficult breathing, and reduced
pulmonary function. lnhalation exposure well above the PEL may result additionally to eye
irritation, headache, chemical bronchitis, asthma-like findings, or pulmonary edema. lsocyanates
have also been reported to cause hypersensitivity pneumonitis, which is characterized by flu-like
symptoms, the onset of which may delayed. Gastrointestinal symptoms include nausea,
vomiting, and abdominal pain.
lrritation:
lnitating to eyes, respiratory system and skin.
Assessment Other Acute Effects:
Causes temporary initation of the respiratory tract.
Sensitization:
The substance may cause sensitization of the respiratory tract. Sensitization after skin contact
possible. Studies in animals suggest that dermal exposure may lead to pulmonary sensitization.
As a result of repeated overexposure of a single dose, certain individuals will develop isocyanate
sensitization (chemical asthma), which will cause them to react to a later exposure at levels below
PEL/TLV. Symptoms which include chest tightness, wheezing, cough, shortness of breath, or
asthmatic attack, could be immediate or delayed up to several hours after exposure. Similar to
many non-specific asthmatic responses, there are reports that once sensitized an individual can
experience these symptoms upon exposure to dust, cold air, and other irritants. This increase
lung sensitivity can persist for weeks and in severe cases for several years. Chronic
overexposure of isocyanates has also been reported to cause lung damage, including a decrease
in lung function, which may be permanent. Prolonged contact can cause reddening, swelling,
rash, scaling, or blistering. ln those who have developed a skin sensitization, these symptoms
can develop as a result of contact with very small amounts ol liquid material. or even as a result
of vapor only exposure.
Chronic Toxicity:
Carcinogenicity: A carcinogenic potential cannot be excluded after long exposure to severely
irritating concentrations. The effects are not relevant to humans at occupational levels of
exposure.
Repeated Dose Toxicity: The substance may cause damage to the olfactory epithelium after
repeated inhalation. These effects are not relevant to humans at occupational levels of exposure.
Reproductive Toxicity: Repeated inhalation does not cause damage to reproductive organs.
Teratogenicity: No malformations in animal studies found, however high doses was toxic in the
development of parental animals.
Genotoxicity: The substance was mutagenic in various bacterial test systems, however, these
results could not be confirmed in tests with mammals.
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Aquatic Toxicity: The product may hydrolyse. The test result maybe partially due degradation
products. The product has not been tested. The statement has been derived from products of a
similar structure or composition.
lnformation of lsocyanates
As a result of previous repeated overexposures or a single large dose, certain individuals will
develop isocyanate sensitization. (chemical asthma) which will cause them to react to a later
exposure of isocyanate at levels well below the PEUTLV. These symptoms, which include chest
tightness, wheezing, coughing, shortness of breath, or asthmatic attack could be immediate or
delayed up to several hours after exposure. Similar to many non-specific asthmatic responses,
there are reports that once sensitized, an individual can experience these symptoms upon
exposure to dust, cold air, or other irritants. The increased lung sensitivity can persist for weeks
and in severe cases for several years. Chronic overexposure to isocyanates has been reported
to cause lung damage, including a decrease in lung function, which may be permanent.
Sensitization may be either temporary or permanent. Prolonged contact can cause reddening,
swelling, rash, scaling, or blistering. ln those who have developed a skin sensitization, these
symptoms can develop as a result of contact with very small amounts of liquid material, or even
as a result of vapor-only exposure.
Medical Conditions Aggravated by Overexposure
The isocyanate component is a respiratory sensitizer. ll may cause an allergic reaction leading to
asthma like spasms of the bronchial tubes and difficulty in breathing. Person with history with
respiratory disease or hypersensitivity should not be expose to the product. An animal study
indicated that MDI may induce respiratory hypersensitivity following dermal exposure. Medical
supervision of all employees who handle or come into contact with isocyanates is recommended.
Pre-employment and periodic medicalexaminations with respiratory function tests (FEV,FVC as a
minimum) are suggested. Persons with asthmatic conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent eczema or pulmonary sensitization should be excluded from
working with isocyanates, further exposure is not recommended. Contact may aggravate
pulmonary disorders.
Section 3. ition / lnformation on Iredients
CAS Number
9016-87-9
101-68-8
26447-40-5
Content (W/VV)
<75.0 %
<10.0 %
<16.0 %
<1 .O "/"
ChemicalName
lsocyanate Polymer
P-MDI
Diphenylmethane- 4,4' disocyanate
disocyanate (MDl)
MDI
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Section 4. First-Aid Measures
Description of Necessary First Aid Measures
Generaladvice Remove contaminated clothing
lmmediately flush eyes with water lor 15 minutes, lift upper and
lower eyelids. Remove contact lenses. Get medical attention if
irritation persists.
Eye Contact:
lnhalation Move to an area that has plenty of fresh air. Rest in a position
comfortable for breathing. Get medical attention if symptoms
occur.
Skin Contact: Flush contaminated skin with soap water. Remove
contaminated clothing and shoes. Get medical attention if
symptoms occur.
lngestion: Wash out mouth with water. Seek fresh air and rest in a
comfortable position for breathing. lf material has been
swallowed, drink small quantities of water. Do not induce
vomiting. Get medical attention if symptoms occur.
Note to Physician:
Hazards:
Antidote:
Treatment:
Symptoms can appear later
Specific antidotes or neutralizers to isocyanate do not exist
Treatment should be supportive and based on the judgement of
the physician in response to the reaction of the patient.
Section 5. Fire-htinMeasures
Flash point:
Auto-ignition:
Self-ignition temperature:
Protective equipment for
lire-fighting:
Suitable extinguishing media: water, dry extinguishing media, carbon dioxide, foam
Hazards during fire-fighting: nitrous gases, fumes/smoke, isocyanate, vapor
2OOoc. open cup
>470
oc
not self-igniting
Firefighters should be equipped with self-contained breathing
apparatus and turn-out gear.
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Section 6. Accidental Release Measures
Personal Precautions:
Clear area. Ensure adequate ventilation. Wear suitable personal protective clothing and
equipment.
Environmental Precautions :
Do not discharge into drains/surface or waters/ground water
Cleanup:
Dike spillage
For small amounts: Absorb isocyanate with suitable absorbent material (use 40 CFR, sections
260,2O4, and 265 for further information). Shovel into open container. Do not make container
pressure tight. Move container to a well-ventilated area (outside) Spill area can be
decontaminated with the following recommended decontamination solution. Mixture ol90%
water, 87o concentrated ammonia,2o/o detergent. Add at a 10 to 1 ratio. Allow it to stand for at
least 48 hours to allow escape of evolved carbon dioxide. For large amounts: lf temporary
control of isocyanate vapor is required, a blanket of protein foam or other suitable loam (available
from most fire departments) may be placed over the spill. Transfer as much liquid as possible via
pump or vacuum device into closed but not sealed containers for disposal. For residues: The
following measures should be taken for final cleanup: Wash down spill area with
decontamination solution. Allow solution to stand for at least 10 minutes.
Section 7. Handling and Storage
Handling
GeneralAdvice:
Mix thoroughly before use. lf bulging of drum occurs, transfer to well ventilated area, puncture to
relieve pressure, open vent and let stand for 48 hours before resealing.
Protection against fire and explosion:
No explosion proofing necessary
Storage:
GeneralAdvice:
Formation of COz and build up of pressure possible. Keep container tightly closed and in a well-
ventilated place. Outage of containers should be filled with dry inert gas at atmospheric pressure
to avoid reaction with moisture.
Storage incompatibility:
General: Segregate from bases.
Storage Stability:
Storage temperature 60-80 0F. Protect against moisture
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IIIIIRPAISIS
Section 8. Exposure Controls / Personal Protection
Components with Workplace Control Parameters
Diphenylmethane-4,4′-diisocya OSHA CLY0.02ppm 0.2 mg/m3
Nate (MDl) ACGIH TWA Valve 0.005 ppm
Advice on System Design:
Provide local exhaust ventilation to maintain recommended P.E.L
Personal Protective Equipment
Respiratory Protection
For situations where the airborne concentrations may exceed the level for which an air purifying
respirator is effective, or where the levels are unknown or lmmediately Dangerous to Life and
Health (IDLH), use NO|SH-certified fullface piece pressure demand self-contained breathing
apparatus (SUBA) or a full face piece pressure demand supplied–air respirator (SAR) with
escape provisions. When atmospheric levels may exceed the occupational exposure limit (PEL
or TLV) NO|SH-certified or air purifying respirators equipped with an organic vapor sorbent and
particulate filter can be used as long as appropriate precautions and change out schedules are in
place.
Hand Protection
Chemical resistant protective gloves. Suitable materials, chloroprene rubber (Neoprene), nitrile
rubber (Buna N), chlorinated polyethylene, polyvinylchloride (Pylox), butyl rubber, fluoroelastomer
(Viton)
Eye Protection
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body Protection
Suitable materials, saran contact material
General Safety and Hygiene Measures
Wear protective clothing as necessary to prevent contact. Eye wash fountains and safety
showers must be easily accessible. Observe the appropriate PEL valve. Wash soiled clothing
immediately. Contaminated equipment or clothing should be cleaned after each use or disposed
of.
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Section 9. Physical and Ghemical Properties
Appearance
Physical state
Color
Odor
Odor threshold
pH
Melting poinUFreezing
Boiling/condensation point
Flash point
Evaporation rate
Flammability (solid, gas)
Lower and upper explosive
(flammable) limits
Liquid
Amber
faintly aromatic
N/A
NiA
<-200c
>2000c
N/A
N/A
N/A
N/A
Vapor pressure
Vapor density
Density
Solubility in water
Partition coefficient
Auto-lgnition temp.
Decomposition temp
Viscosity
0.00001 mmHg
N/A
9.4|b
React with water
N/A
N/A
N/A
5,600 mPa.s
Section 10. Stabilitv and Reactivitv
Conditions to Avoid
Avoid moisture
Substances to Avoid:
Water, alcohols, strong bases, substances/products that react with isocyanates.
Hazardous Reactions:
This product is chemically stable:
Reacts with water, with formation of carbon dioxide. Risk ol bursting. Reacts with alcohols. Reacts with acids. Reacts
with alkalis. Reacts with amines. Risk of exothermic reaction. Risk of violent reaction. Risk of polymerization. Contact
with rubbers and plastics can cause brittleness ol the substance/product with subsequent loss in strength.
Decomposition Products:
Hazardous decomposition products: carbon monoxide, hydrogen cyanide, nitrogen oxides, aeromatic isocyanates,
gasesfuapors.
Corrosion to Metals:
No corrosive etfect on metal.
Thermal Decomposition:
>260 0C. No data available
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Oxidizing Properties: N/A
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Section 11. Toxi ical lnformation
Acute Toxicity
Oral:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rat (malelfemale)
Value: >2.000 mgikg (Directive 84/449/EEC, 8.1)
lnhalation:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD10
Species: rat (malelfemale)
V alue i >2.24 m g/f (D irective 84 I 449 IEEC, 8.1′)
Exposure time: t hr. An aerosol was tested
Dermal:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Type ofvalue: LD50
Species: rabbit (male/female)
Value: >9.400 mg/kg
lrrilation / Corrosionr Skin / Eye
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rabbit (male/female)
Result: lnitating
Method: Draize test
Sensitization:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: guinea pig/mouse/
Result: sensitizing
Method: Buehler test
Repeated Dose Toxlcity:
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Species: rat (malellemale)
NOAEL: 0.2 mg/m3
LOAEL: 1 mg/m3
This substance may cause damage to olfactory epithelium atter repeated inhalation. Not relevant to humans at
occupational levels ol exposure.
Genetic Toxlcityl
lnlormation on: Diphenylmethane-4,4′ diisocyanate (MDl)
OECD Guideline 471 Ames-test.
No clastogenic ettect reported.
Carcinogenicityr
Experimental data
OECD Guideline 471 tal inhalation 0, 2, 1, mg/mm3
Result: Lung tumors A carcinogenic potential cannot be excluded. Not relevant to humans.
Development:
OECD Guideline 414 ral inhalation 0, ‘l,4, 12 mg/mm3
NOAEL Mat: 4mglm3
NOAEL Teratog:4mg/m3
Result: This substance did not cause mallormations in animal studies. Not relevant to humans.
Aspiration Hazardt
No hazard expected
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Section 12. Ecolical lnformation
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute and prolonged toxicity to fish
OECD Guideline 203 static
zebra fish/LCO (96 h):> 1,000mgil
lnformation on: Diphenylmethane-4,4′ diisocyanate (MDl)
Acute toxicity to aquatic invertebrates:
OECD Guideline 202 part I static
Daphnia magna/ECso (24 h):> 1,000m9/l
Degradability / Persistence
Biological / Degradation
Test Method: OECD Guideline 302 (aerobic),activated sludge
Results: Poorly biodegradable. Unstable in water.
Section 13. Dis Considerations
Waste Disposal of Substance:
lncinerate or dispose of in a licensed facility.
Do not discharge substance/product into the sewer system
Container Disposal
Drums:
Steel drums must be emptied and can be sent to a licensed drum re-conditioner for reuse, a
scrap metal dealer, or an approved landfill. Refer to 40 CFR 261.7 (residues of hazardous waste
in empty containers). Check with re-conditioner to determine if decontamination is required.
Decontaminate containers prior to disposal. Recommend crushing, puncturing, or other means to
prevent unauthorized use of used containers.
Reference Bill of Lading
Section 14. lnformation
Section 15. ulatolnformation
Safety. health and environmental regulations specific for this product:
United States Regulations
TSCA 8(b) lnventory Released / Listed
OSHA Hazard Category Chronic target organ etlects reported, ACGIH TLV established
CERCLA RO
5000 lbs.
State Regulations
RTK
CAS Number
901 6-87-9
101-68-8
Chemical Name
P.MDI
Diphenylmethane-4,4′ diisocyanate
CAS Number Chemical Name
101 -68-8 Diphenylmethane-4,4’ diisocyanate (MDl)
State RTK
NJ
MA, NJ, PA
9of10
PB Bond-240
911119
[0flsrflt
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tilltnPntsts
Section 16. Other lnformation
Hazardous Material lnformation System (USA):
Health: 2 Flammability: 1 PhysicalHazard: 1
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of
zero means that the substance possesses essentially no hazard, a rating of 4 indicates a high
hazard.
Date of Printing:
Date of lssue:
Date of previous lssue
9t1119
9t1t1g
1t19t18
Notice to Reader
The information contained herein is based on data believed by Coastal Enterprises Company to
be accurate, but we do not assume any liability for the accuracy of this information. We neither
suggest nor guarantee that any hazards mentioned are the only ones which exist. Anyone
intending to rely on any recommendation or to use any equipment technique or material
mentioned should also satisfy himself that he can meet all applicable safety and health standards.
Determination of the suitability of any information or product for the use contemplated by any
user, the manner of that use and whether there is any infringement of patents, is the sole
responsibility of the user.
10 of 10
PB Bond-240
911119
