by | Sep 27, 2025
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,
Powderchoppedstrandmat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glass
fiberwet-laidmat,Glassfilamentyarn Comtexroving Comtexfabrics Milledfiber,
PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
Issuedate:5/20/2021 Revisiondate:5/20/2021 : Version:1.0
5/20/2021(Revisiondate) EN(English) 1/6
SECTION1:Identification
1.1. GHSProductidentifier
Productform :Article
Tradename :Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,
Powderchoppedstrandmat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,
Glassfiberwet-laidmat,Glassfilamentyarn Comtexroving Comtexfabrics Milledfiber,
PultrusionBoard,CoatedTissue,VIPInsulationBoard
1.2. Othermeansofidentification
Noadditionalinformationavailable
1.3. Recommendeduseofthechemicalandrestrictionsonuse
Useofthesubstance/mixture :Noinformationavailable
Recommendeduse :Forwindingfiberglasspipe,storagetank;Suppressingcaraccessories,bathtubs;Usedin
handlay-upFRPmoldingprocess;Reinforcedplastic;Usedtoenhancethecement;Usedfor
windpowergenerationblades BuildingwallpanelsandindustrialheatinsulationEtc.
1.4. Supplier’sdetails
Manufacturer
TaishanFiberglassInc.
DawenkouIndustrialPark,Tai’anCity,ShandongProvince,China
T+86-538-8619150
ctgtixi@ctgf.com
1.5. Emergencyphonenumber
Emergencynumber :+86-538-8619150
SECTION2:Hazardidentification
2.1. Classificationofthesubstanceormixture
ClassificationaccordingtotheUnitedNationsGHS
Notclassified
Adversephysicochemical,humanhealthand
environmentaleffects
:Toourknowledge,thisproductdoesnotpresentanyparticularrisk,provideditishandled
inaccordancewithgoodoccupationalhygieneandsafetypractice
2.2. GHSLabelelements,includingprecautionarystatements
LabellingaccordingtotheUnitedNationsGHS
Hazardpictograms(GHSUN) :None
Signalword(GHSUN) :None
Hazardstatements(GHSUN) :None
Precautionarystatements(GHSUN) :None
2.3. Otherhazardswhichdonotresultinclassification
Otherhazardsnotcontributingtothe
classification
:Noinformationavailable
SECTION3:Composition/informationoningredients
3.1. Substances
Notapplicable
3.2. Mixtures
Productname glassfiber,% Size,
adhesive,
water,
Aluminumfoil
film,
Calciumcarbonate
powder,
organic
compound,
resin,
Assembledroving 97.45-99.70 0.30-2.35 / 0-0.20 / / / /
Directroving 98.7-99.88 0.12-1.1 / 0-0.20 / / / /
Drychoppedstrands 97.30-99.99 0.10-2.50 / 0-0.20 / / / /
Wetchoppedstrands 87.84-92.00 0.00-0.20 / 8.00-12.00 / / / /
Wovenroving 96.8-99.6 0.40-3 / 0-0.20 / / / /
Powderchoppedstrand 90.8-98.5 0.30-0.60 1.2-8.2 0-0.40 / / / /Reach24H
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,Powderchoppedstrand
mat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glassfiberwet-laidmat,Glassfilamentyarn
Comtexroving Comtexfabrics Milledfiber,PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
5/20/2021(Revisiondate) EN(English) 2/6
mat
Emulsionchoppedstrand
mat
87.3-98.5 0.30-0.60 1.2-11.7 0-0.40 / / / /
Glassfiberstitchedfabrics92.80-99.60 0.40-7.00 / 0-0.20 / / / /
Glassfiberwet-laidmat68.84-95.00 0-0.2 5-30 0-1 / / / /
Glassfilamentyarn 98.55-99.45 0.55-1.25 / 0-0.20 / / / /
Comtexroving,Comtex
fabrics
55-75 0.5-2.0 / 0-0.20 / / / /
Milledfiber 98.90-99.90 0.0-1.0 / 0-0.10 / / / /
PultrusionBoard 80-86 / / / / / / 14-20
CoatedTissue 10-40 / / 0-<1.0 / 0-85 8.0-60.0 /
VIPInsulationBoard / <0.005 / 0-0.002 / / / /
Glassfiber:CAS65997-17-3
Note:theaboveproductsareusedinEglass,TCRglass,ARglass,HMGglass,S-1HMglass,TLDglassandTHM-1glass.
SECTION4:First-aidmeasures
4.1. Descriptionofnecessaryfirst-aidmeasures
First-aidmeasuresafterinhalation :IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortablefor
breathing.CallaPOISONCENTERordoctor/physician.
First-aidmeasuresafterskincontact :Washimmediatelywithsoapandplentyofwater.Forminorskincontact,avoidspreadingthe
materialtotheunaffectedskin.Avoidusingwarmwater,becausewarmwaterwillcause
deeperpenetration.Ifpenetrationoccurs,useacleaningclothinsteadofrubbing.If
symptomspersist,calladoctor.
First-aidmeasuresaftereyecontact :IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,if
presentandeasytodo.Continuerinsing.Ifeyeirritationpersists,consultaspecialist.
First-aidmeasuresafteringestion :Notanexpectedrouteofexposure.Callapoisoncenteroradoctorifyoufeelunwell.Donot
inducevomiting.Nevergiveanythingbymouthtoanunconsciousperson.
4.2. Mostimportantsymptoms/effects,acuteanddelayed
Symptoms/effects :Noinformationavailable.
4.3. Indicationofimmediatemedicalattentionandspecialtreatmentneeded,ifnecessary
Treatsymptomatically.
SECTION5:Fire-fightingmeasures
5.1. Suitableextinguishingmedia
Suitableextinguishingmedia :Useextinguishingmediaappropriateforsurroundingfire.Waterspray.Drypowder.Foam.
Unsuitableextinguishingmedia :Noinformationavailable.
5.2. Specifichazardsarisingfromthechemical
Hazardousdecompositionproductsincaseoffire:Incompletecombustionandthermaldecompositionmayproducevarioustoxicgases,such
ascarbonmonoxideandcarbondioxide.Itcanbeverydangerousifinhaledinaconfined
spaceorinhighconcentration.
5.3. Specialprotectiveactionsforfire-fighters
Protectionduringfirefighting :Donotattempttotakeactionwithoutsuitableprotectiveequipment.Self-containedbreathing
apparatus.Completeprotectiveclothing.
SECTION6:Accidentalreleasemeasures
6.1. Personalprecautions,protectiveequipmentandemergencyprocedures
6.1.1.Fornon-emergencypersonnel
Emergencyprocedures :Ventilatespillagearea.Avoidcontactwithskin,eyesandclothing.Avoiddustformation.No
flames,nosparks.Eliminateallsourcesofignition.
6.1.2.Foremergencyresponders
Protectiveequipment :Donotattempttotakeactionwithoutsuitableprotectiveequipment.Forfurtherinformation
refertosection8:"Exposurecontrols/personalprotection".
6.2. Environmentalprecautions
Avoidreleasetotheenvironment.Donotallowintodrainsorwatercourses.Reach24H
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,Powderchoppedstrand
mat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glassfiberwet-laidmat,Glassfilamentyarn
Comtexroving Comtexfabrics Milledfiber,PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
5/20/2021(Revisiondate) EN(English) 3/6
6.3. Methodsandmaterialsforcontainmentandcleaningup
Methodsforcleaningup :Takeupmechanically(sweeping,shovelling)andcollectinsuitablecontainerfordisposal.
Otherinformation :Disposeofmaterialsorsolidresiduesatanauthorizedsite.
SECTION7:Handlingandstorage
7.1. Precautionsforsafehandling
Precautionsforsafehandling :Ensuregoodventilationoftheworkstation.Wearpersonalprotectiveequipment.Takeoff
contaminatedclothingandwashitbeforereuse.Avoidbreathing(dust,vapor,mist,gas).
Keepawayfromheat,hotsurfaces,sparks,openflamesandotherignitionsources.No
smoking.Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Wear
personalprotectiveequipment.
Hygienemeasures :Donoteat,drinkorsmokewhenusingthisproduct.Alwayswashhandsafterhandlingthe
product.
7.2. Conditionsforsafestorage,includinganyincompatibilities
Storageconditions :Storeinawell-ventilatedplace.Keepcool.Keepawayfromheat.Keepawayfromfood,drink
andanimalfeedingstuffs.Keepcontainertightclosed.Keepoutofthereachofchildren.
SECTION8:Exposurecontrols/personalprotection
8.1. Controlparameters
Noadditionalinformationavailable
8.2. Appropriateengineeringcontrols
Appropriateengineeringcontrols :Ensuregoodventilationoftheworkstation.
Environmentalexposurecontrols :Avoidreleasetotheenvironment.
8.3. Individualprotectionmeasures,suchaspersonalprotectiveequipment(PPE)
Handprotection :Protectivegloves
Eyeprotection :Safetyglasses
Skinandbodyprotection :Wearsuitableprotectiveclothing
Respiratoryprotection :Incaseofinsufficientventilation,wearsuitablerespiratoryequipment
8.4. Exposurelimitvaluesfortheothercomponents
Noadditionalinformationavailable
SECTION9:Physicalandchemicalproperties
9.1. Basicphysicalandchemicalproperties
Physicalstate :Solid
Appearance :White
Colour :White(Individualproductshavecolordifferences)
Odour :Odourless.
Odourthreshold :Notavailable
Meltingpoint :>800 C
Freezingpoint :Notapplicable
Boilingpoint :Notavailable
Flammability(solid,gas) :Nonflammable.
Explosivelimits :Notapplicable
Lowerexplosivelimit(LEL) :Notapplicable
Upperexplosivelimit(UEL) :Notapplicable
Flashpoint :Notapplicable
Auto-ignitiontemperature :Notapplicable
Decompositiontemperature :Notavailable
pH :Notavailable
pHsolution :Notavailable
Viscosity,kinematic(calculatedvalue)(40 C) :Notapplicable
Partitioncoefficientn-octanol/water(LogKow) :Notavailable
Vapourpressure :Notavailable
Vapourpressureat50 C :NotavailableReach24H
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,Powderchoppedstrand
mat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glassfiberwet-laidmat,Glassfilamentyarn
Comtexroving Comtexfabrics Milledfiber,PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
5/20/2021(Revisiondate) EN(English) 4/6
Density :2.5 2.7g/cm
Relativedensity :2.5 2.7
Relativevapourdensityat20 C :Notapplicable
Solubility :Insoluble.
Particlesize :Notavailable
Particlesizedistribution :Notavailable
Particleshape :Notavailable
Particleaspectratio :Notavailable
Particlespecificsurfacearea :Notavailable
9.2. Datarelevantwithregardtophysicalhazardclasses(supplemental)
Noadditionalinformationavailable
SECTION10:Stabilityandreactivity
10.1.Reactivity
Theproductisnon-reactiveundernormalconditionsofuse,storageandtransport.
10.2.Chemicalstability
Stableundernormalconditions.
10.3.Possibilityofhazardousreactions
Nodangerousreactionsknownundernormalconditionsofuse.
10.4.Conditionstoavoid
Noneunderrecommendedstorageandhandlingconditions(seesection7).
10.5.Incompatiblematerials
hydrogenfluoride.fluorine.
10.6.Hazardousdecompositionproducts
Undernormalconditionsofstorageanduse,hazardousdecompositionproductsshouldnotbeproduced.
SECTION11:Toxicologicalinformation
11.1.Informationontoxicologicaleffects
Acutetoxicity(oral) :Notclassified
Acutetoxicity(dermal) :Notclassified
Acutetoxicity(inhalation) :Notclassified
Skincorrosion/irritation :Fiberglassdustmaycauseskinirritation.
Seriouseyedamage/irritation :Fiberglassdustmaycauseeyeirritation.
Respiratoryorskinsensitisation :Notclassified
Germcellmutagenicity :Notclassified
Carcinogenicity :Notclassified
Reproductivetoxicity :Notclassified
STOT-singleexposure :Notclassified
STOT-repeatedexposure :Notclassified
Aspirationhazard :Notclassified
SECTION12:Ecologicalinformation
12.1.Toxicity
Ecology-general :Theproductisnotconsideredharmfultoaquaticorganismsnortocauselong-termadverse
effectsintheenvironment.
Hazardoustotheaquaticenvironment,short-term
(acute)
:Notclassified
Hazardoustotheaquaticenvironment,long-term
(chronic)
:Notclassified
12.2.Persistenceanddegradability
Noadditionalinformationavailable
12.3.Bioaccumulativepotential
NoadditionalinformationavailableReach24H
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,Powderchoppedstrand
mat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glassfiberwet-laidmat,Glassfilamentyarn
Comtexroving Comtexfabrics Milledfiber,PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
5/20/2021(Revisiondate) EN(English) 5/6
12.4.Mobilityinsoil
Noadditionalinformationavailable
12.5.Otheradverseeffects
Ozone :Notclassified
Otheradverseeffects :Noadditionalinformationavailable
SECTION13:Disposalconsiderations
13.1.Disposalmethods
Wastetreatmentmethods :Disposeofcontents/containerinaccordancewithlicensedcollector ssortinginstructions.
Product/Packagingdisposalrecommendations :Emptycontainersshouldbetakenforrecycling,recoveryorwasteinaccordancewithlocal
regulation.
SECTION14:Transportinformation
InaccordancewithUNRTDG/IMDG/IATA
UNRTDG IMDG IATA
14.1.UNnumber
Notregulatedfortransport
14.2.UNProperShippingName
Notapplicable Notapplicable Notapplicable
14.3.Transporthazardclass(es)
Notapplicable Notapplicable Notapplicable
Notapplicable Notapplicable Notapplicable
14.4.Packinggroup
Notapplicable Notapplicable Notapplicable
14.5.Environmentalhazards
Dangerousfortheenvironment:No Dangerousfortheenvironment:No
Marinepollutant:No
Dangerousfortheenvironment:No
Nosupplementaryinformationavailable
14.6.Specialprecautionsforuser
-UNRTDG
Nodataavailable
-IMDG
Nodataavailable
-IATA
Nodataavailable
14.7.TransportinbulkaccordingtoIMOinstruments
Notapplicable
SECTION15:Regulatoryinformation
15.1.Safety,healthandenvironmentalregulationsspecificfortheproductinquestion
glassfiber(65997-17-3)
ListedontheUnitedStatesTSCA(ToxicSubstancesControlAct)inventory
ListedontheCanadianDSL(DomesticSubstancesList)
ListedontheEECinventoryEINECS(EuropeanInventoryofExistingCommercialChemicalSubstances)
ListedintroductiononAustralianIndustrialChemicalsIntroductionScheme(AICISInventory)
ListedonIECSC(InventoryofExistingChemicalSubstancesProducedorImportedinChina)
ListedontheJapaneseENCS(Existing&NewChemicalSubstances)inventory
ListedontheJapaneseISHL(IndustrialSafetyandHealthLaw)
ListedonKECL/KECI(KoreanExistingChemicalsInventory)
ListedonNZIoC(NewZealandInventoryofChemicals)Reach24H
Assembledroving,Directroving,Drychopped,strands,Wetchoppedstrands,Wovenroving,Powderchoppedstrand
mat,Emulsionchopped,strandmat,Glassfiberstitchedfabrics,Glassfiberwet-laidmat,Glassfilamentyarn
Comtexroving Comtexfabrics Milledfiber,PultrusionBoard,CoatedTissue,VIPInsulationBoard
SafetyDataSheet
accordingtotheUnitedNationsGHS(Rev.8,2019)
5/20/2021(Revisiondate) EN(English) 6/6
glassfiber(65997-17-3)
ListedonPICCS(PhilippinesInventoryofChemicalsandChemicalSubstances)
ListedontheTCSI(TaiwanChemicalSubstanceInventory)
SECTION16:Otherinformation
Issuedate :20/05/2021
Revisiondate :20/05/2021
Indicationofchanges:
Noinformationavailable.
Abbreviationsandacronyms :IATA-InternationalAirTransportAssociation
IMDG-InternationalMaritimeDangerousGoods
ADN-EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsby
InlandWaterways
ADR-EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsby
Road
EC50-Medianeffectiveconcentration
LC50-Medianlethalconcentration
LD50-Medianlethaldose
RID-RegulationsconcerningtheInternationalCarriageofDangerousGoodsbyRail
TimeWeightedAverage
Trainingadvice :Normaluseofthisproductshallimplyuseinaccordancewiththeinstructionsonthe
packaging.
Otherinformation :Noinformationavailable.
SafetyDataSheet(SDS),UN
Thisinformationisbasedonourcurrentknowledgeandisintendedtodescribetheproductforthepurposesofhealth,safetyandenvironmental
requirementsonly.Itshouldnotthereforebeconstruedasguaranteeinganyspecificpropertyoftheproduct.Reach24H
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: Xenon 45-20 B Black DATE: June 01, 2018
MSDS NUMBER: Xenon 45-20 B Black SUPERSEDES MSDS: June 01, 2015
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCTION IDENTIFICATION NUMBER: Xenon 45-20 B Black
CHEMICAL FAMILY: POLYETHER POLYOL BLEND
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
Physical State: Liquid
Potential Acute Heath Effects:
Eyes Corrosive to eyes.
Skin Corrosive to skin on contact. Skin contact may produce burns.
Inhalation Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking or shortness of breath.
Ingestion May cause burns to mouth, throat and stomach.
GENERAL INFORMATION: Read the entire MSDS for more thorough evaluation of the hazards.
GHS Label Elements:
Hazard Pictograms
Signal Word: Warning
Hazard statement: Causes serious eye irritation
Precautionary statements: Wear eye protection, protective clothing, protective gloves. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
SECTION 3: COMPOSITION AND INFORMATION ON INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 65-90 %
GLYCOLS Mixture 5-15 %
TRIETHYLENE DIAMINE 280-57-9 0-2%
2
*Occupational Exposure Limit(s), if available, are listed in Section 8.
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of eye contact, immediately flush eyes with
plenty of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: In case of contact, immediately wash skin with soap and plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical attention
immediately.
Inhalation: If excessive inhalation of vapor occurs, remove to fresh air. If breathing is difficult, qualified
personnel may administer oxygen. Get medical attention immediately.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Notes to Physician: Symptomatic treatment and supportive therapy as indicated. Administer oxygen if
necessary.
Following severe exposure the patient should be kept under medical review for at least 48 hours as
delayed pulmonary edema may develop.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >212 F Closed Cup
Auto Ignition Temp: Not available.
Flammable Limits: Not available.
Products of Combustion:
Thermal Decomposition products are toxic and may include oxides of carbon and nitrogen,
amines, possibly other irritating gases.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire):
Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be used to
avoid inhalation of the product.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
See Safety Data Sheet section 8 Personal Protective Equipment
Small Spill and Leak Absorb with an inert material and put the material in an appropriate waste disposal container.
Large Spill and Leak Corrosive liquid. Toxic liquid.
Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water
inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water
spray to reduce vapors. Prevent entry into sewers, basements of confined area; dike if needed. Eliminate
all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the
3
contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is
not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
SECTION 7: HANDLING AND STORAGE
Handling Do not ingest. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling. Avoid contact with eyes, skin and clothing.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Preventive Measures Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
Engineering Controls Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in case of insufficient ventilation or where operational procedures
demand it. For guidance on engineering control measures refer to publications such as the ACGIH
current edition of Industrial Ventilation, a manual of Recommended Practice.
Personal Protection
Eyes Chemical safety goggles. If there is a potential for splashing, use a full-face shield.
Body and Hands Full chemical suit. Gloves.
Respiratory Wear appropriate respirator when ventilation is inadequate.
Personal Protection in case of a Large Spill
Splash goggles. Full suit. Vapor respirator or a self-contained breathing apparatus. Boots.
Gloves.
Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product Name Exposure Limits
Ethylene Glycol ACGIH TLV (United States)
CEIL: 100mg/m
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Black Slight Odor
BOILING POINT ( F/ C) Not determined
MELTING POINT ( F/ C) Not determined
SPECIFIC GRAVITY ( WATER = 1) 1.08
BULK DENSITY 8.27 lb/gal
pH OF UNDILUTED PRODUCT Not determined
VAPOR PRESSURE (MM Hg.) Not determined
VAPOR DENSITY (AIR-1) >1
VISCOSITY 900-1300 cps @ 25 C
PERCENT (%) VOC 0
SOLUBILITY IN WATER Soluble
SECTION 10: STABILITY AND REACTIVITY
Stability and Reactivity This product is stable.
4
Conditions of Stability Avoid moisture to protect product quality.
Incompatibility with Various Substances
Slightly reactive to reactive with oxidizing agents, alkalis.
Hazardous Decomposition Products
Thermal decomposition products are toxic and may include oxides of carbon and
nitrogen, amines, possibly other irritating gases.
Hazardous Polymerization Will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
No applicable data for this section.
SECTION 12I: ECOLOGICAL INFORMATION
No applicable data for this section.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information Incinerate or landfill in a licensed facility. Do not discharge into waterways of sewer systems.
Container Disposal: Steel drums must be emptied (as defined by RCRA, Section 261.7 or state
regulations that may be more stringent) and can be sent to a licensed drum reconditoiner for reuse, a
scrap metal dealer or an approve landfill. Drums destined for scrap dealer of landfill must be punctured or
crushed to prevent reuse.
Material for disposal should be placed in appropriated sealed containers to avoid potential human and
environmental exposure. It is the responsibility of the generator to comply with all federal, state,
provincial and local laws and regulations. We recommend that you contact an appropriate waste disposal
contractor and environmental agency for relevant laws and regulations. Under the US, Resource
Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determined at
the time of disposal, whether the product meets relevant waste classification and to assure proper
disposal.
SECTION 14: TRANSPORT INFORMATION
Transportation Emergency Number 1-800-424-9300 (CHEMTREC).
DOT Classification Non Regulated
TDG Classification Non Regulated
IMO/IMDG Classification Non Regulated
ICAO/IATA Classification Non Regulated
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification
Class: Corrosive material
TSCA 8(b) inventory: All ingredients Listed.
5
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act):
Ethylene Glycol (CAS# 107-21-1) Reportable Quantity (RQ) 5000 lbs.
Any spill or release above the RC must be reported to the National Response Center (800-424-8802)
SARA 313 toxic chemical notification and release reporting: Ethylene Glycol 6%
State Regulations California prop 65: No ingredients listed.
Canadian Regulations
This product has been classified in accordance with the hazard criteria of the CPR
(Controlled Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the
information required by the CPR.
WHMIS (Canada) Class D-1B: Material causing immediate and serious toxic effects (Toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA DSL/NDSL Not all Ingredients Listed.
SECTION 16: OTHER INFORMATION
Causes respiratory tract, eye and skin burns.
Harmful if inhaled.
May be harmful if swallowed.
Contains material, which may cause birth defects based on animal data.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 1 Health: 1
Fire Hazard: 1 Fire Hazard: 1
Reactivity: 0 Reactivity: 0
Notice to Reader
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARANTY, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONSAND THE SUITABILITY OF ANY PRIDUCT FOR ITS OWN PARTICULAR
PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZAEDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
Hazards, toxicity, and behavior of the products may differ when used with other materials and are dependent
upon the manufacturing circumstances or other processes. Such hazards, toxicity and behavior should be
determined by the user and made known to handlers, processors and end users.
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APPROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
1
SAFETY DATA SHEET
PRODUCT NAME: Xenon 45-20 A DATE: June 01,2018
MSDS NUMBER: Xenon 45-20 A SUPERSEDES MSDS: June 01, 2015
SECTION 1: MATERIAL AND MANUFACTURER IDENTIFICATION
MANUFACTURER:
Eteco, Inc.
1000 South Linwood Ave.
Santa Ana, CA 92705
Phone: 714 480 1370
TRANSPORTATION EMERGENCY CALL CHEMTREC:
800 424 9300
MEDICAL EMERGENCY INFORMATION:
800 328 8501
PRODUCT IDENTIFICATION NUMBER: Xenon 45-20 A
CHEMICAL FAMILY: AROMATIC ISOCYANATE
SECTION 2: HAZARDS IDENTIFICATION
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
Physical State and Appearance: Pale Yellow Liquid
Emergency Overview:
INHALATION OF MDI MISTS OR VAPORS MAY CAUSE RESPIRATORY IRRITATION, BREATHLESSNESS, CHEST
DISCOUMFORT AND REDUCED PULMONARY FUNCTION. OVEREXPOSURE WELL ABOVE THE PEL MAY
RESULT IN BRONCHITIS, BRONCHIAL SPASMS AND PULMONARY EDEMA. LONG-TERM EXPOSURE TO
ISOCYANATES HAS BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING REDUCED LUNG FUNCTION
WHICH MAY BE PERMANENT. ACUTE OR CHRONIC OVEREXPOSURE TO ISOCYANATES MAY CAUSE
SENSATION IN SOME INDIVIDUALS, RESULTING IN ALLERGIC RESPRATORY REACTIONS INCLUDING
WHEEZING, SHORTNESS OF BREATH AND DIFFICULTY BREATHING.
Skin: HAZARDOUS IN CASE OF SKIN CONTACT (IRRITANT, SENSITIZER). SKIN INFLAMMATION IS
IS CHARACTERIZED BY ITCHING, SCALING OR REDDENING.
Eyes: HAZARDOUS IN CASE OF EYE CONTACT (IRRITANT).
Inhalation: HAZARDOUS IN CASE OF INHALATION (LUNG IRRITANT, LUNG SENSITIZER).
Ingestion: SLIGHTLY HAZARDOUS IN CASE OF INGESTION.
Medical Conditions Aggravated by Overexposure: Preexisting conditions such as asthma, allergies, eczema,
bronchitis, and other lung and skin disorders may be aggravated by exposure to the product. Results from a lifetime
inhalation study in rats indicate that MDI aerosol was carcinogenic at 9 mg/m3, the highest dose tested. This is well above
the recommended TLV of 5ppb (0.05 mg/m3). Only irritation was noted at the lower concentration of 0.2 and 1 mg/m3. No
birth defects or teratogenic effects were reported in a teratology study with rats exposed to 1, 4, and 12 mg/m3 polymeric
MDI for 6 hr/day on days 6-15 of gestation. Embryotoxicity and fetotoxicity was reported at the top dose in the presence of
maternal toxicity. As a result of previous repeated overexposures or a single large dose, certain individuals will develop
isocyanate sensitization (chemical asthma), which will cause them to react to a later exposure to isocyanate at levels well
below the PEL/TVL. Those symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic
attack, could be immediate of delayed up to several hours after exposure. Similar to many non-specific asthmatic
responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust,
cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years.
Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung
function, which may be permanent. Sensitization may e either temporary of permanent. Prolonged contact can cause
2
reddening, swelling, rash, scaling, or blistering, in those who have developed a skin sensitization, these symptoms can
develop as a result of contact with very small amount s of liquid material, or even as a result of vapor-only exposure.
Aggravated Medical Conditions:
Individuals who are sensitized to isocyanates and those with preexisting lung diseases of conditions, including non-specific
bronchial hyper reactivity or asthma, must avoid all exposure to isocyanates.
GHS Label Elements:
Hazard pictograms
Signal Word: Danger
Hazard statement: Harmful if inhaled. Causes skin and eye irritation.
May Cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
SECTION 3: HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT CAS
NUMBER
% BY
WEIGHT
PROPRIETARY COMPONENT Mixture 25-45 %
4,4 DIPHENYLMETHANE DIISOCYANATE 101-68-8 <50%
MODIFIED MDI 26447-40-5 <10%
*Occupational Exposure Limit(s) if available, are listed in section 8.
SECTION 4: FIRST AID MEASURES
Eyes: In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes, keeping the
eyelids open. Get immediate medical attention.
Skin Contact: Remove contaminated clothing. In case of contact, immediately wash skin with soap and plenty of water.
If symptoms develop obtain medical attention. Contaminated clothing should be thoroughly cleaned. An MDI study has
demonstrated that a polyglycol-based skin cleaner or corn oil may be more effective than soap and water.
Inhalation: If excessive inhalation of vapor occurs, remove patient to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is difficult, qualified personnel may administer oxygen. Get immediate medical
attention.
Ingestion: If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if the victim
is unconscious or having convulsions. Get immediate medical attention.
NOTES TO PHYSICIANS: There is no specific antidote to counteract the effects of MDI. Symptomatic and supportive
therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.
Other First Aid Procedures: Medical supervision of all employees who handle or come into contact with MDI is
recommended. Pre-employment and periodic medical examinations with respiratory function test (PEV, PVC, as a
minimum are suggested). Persons with asthmatic conditions chronic bronchitis, other chronic respiratory diseased,
recurrent eczema or pulmonary sensitization should be excluded from working with MDI. Once a person is diagnosed as
having pulmonary sensitization (allergic asthma) to MDI, further exposure is not permissible.
SECTION 5: FIRE FIGHTING MEASURES
Flash Point: >110 C, Closed Cup.
Autoignition: >600 C.
Flammable Limits: Not available.
3
Products of Combustion: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames, sparks
and static discharge or combustible materials.
Fire Fighting Media and Instructions: Small Fire: Use DRY chemical powder.
Large Fire: Use water spray, fog or foam. Do not use water jet.
Protective Clothing (Fire): Splash goggles. Full suit. Boots. Gloves. A self-contained breathing apparatus should be
used to avoid inhalation of the product.
Special Remarks on Fire Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture closed
containers. This reaction accelerates at higher temperatures.
SECTION 6: ACCIDENTAL RELEASE MEASURES
For major spills call Chemtrec (800-424-9300)
Small Spill and Leak: Clean-up should only be performed by trained personnel. People dealing with major spillages
should wear full protective clothing including appropriate respiratory protection. Evacuate the area. Prevent further
leakage, spillage or entry into drains.
Large Spill and Leak: Contain and absorb large spillages onto an inert, non-flammable adsorbent carrier (such as earth
or sand). Shovel into open-top drums or plastic bags for further decontamination, if necessary. Wash the spillage area
with
Liquid decontaminant. Test atmosphere for MDI. Neutralize small spillages with decontaminant. Remove and properly
dispose of residues (see Section 13 for disposal considerations). Notify applicable government authorities if release is
reportable. The CERCLA RQ for 4,4-MDI is 5000 lbs (see CERCLA in Section 15).
Decontaminant: Preparation of Decontaminant Solution: Prepare a decontamination solution of 0.2-0.5% liquid detergent
and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for ammonium
hydroxide). Follow the precautions on the supplier s material safety data sheets when preparing and using solution.
Use of Decontamination Solution: Allow deactivated material to stand for at least 30 minutes before shoveling into drums.
Do not tighten the bungs. Mixing with wet earth is also effective, but slower.
SECTION 7: HANDLING AND STORAGE
Handling: Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that
the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly
because of the possibility of blockage. Avoid breathing aerosols, mists and vapors. (See Section 8 Exposure Control for
details.)
Storage: Keep containers properly sealed and when stored indoors, in a well ventilated area. Keep contents away from
moisture. Due to reaction with water, producing CO2-gas, a hazardous build-up of pressure could result if contaminated
containers are re-sealed. Do not reseal contaminated containers. Uncontaminated containers, free of moisture, may be
resealed only after placing under a nitrogen blanket. Do not store in containers made of cooper, cooper alloys or
galvanized surfaces.
Ideal storage temperature is 16-38 C (60-100 F).
Keep stocks of decontaminant (see Section 6) readily available.
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Preventive Measures: Conditions of use, adequacy of engineering or other control measures, and actual exposures will
dictate the need for specific protective devices at your workplace.
4
Engineering Controls: Use local exhaust ventilation to maintain airborne concentrations bellow the TLV. Suitable
respiratory equipment should be used in cases of insufficient ventilation or where operational procedures demand it. For
guidance on engineering control measures refer to publications such as the ACGIH current edition of Industrial
Ventilation, a manual of Recommended Practice .
Personal Protection
Eyes: Chemical safety goggles. If there is a potential for splashing, use a full face shield.
Body and Hands: The following protective materials are recommended: Gloves-neoprene, nitrile rubber, butyl
rubber. Thin latex disposable gloves should be avoided for repeated or long term use. Protective clothing should be
selected and used in accordance with Guidelines for the Selection of Chemical Protective Clothing published by ACGIH.
Respiratory: When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH
positive-pressure, supplied-air respirator may be required. Air purifying respirators equipped with organic vapor cartridges
and a HEPA (P100) particulate filter may be used under certain conditions when a cartridge change-out schedule has
been developed in accordance with the OSHA respiratory protection standard (29 C.F.R. 1910.134).
Personal Protection in Case of a Large Spills: Splash goggles. Full suit. Vapor respirator or a self-contained breathing
apparatus. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling
this product.
Product Name Exposure Limits
4,4-Diphenylmethane Diisocyanate ACGIH TLV 0.05 mg/m3 (8-hour, 40 hours/week) OSHA PEL Ceiling Limit 0.20 mg/m3
NIOSH REL/TWA 0.05 mg/m3 (10-hour, 40 hours/week)
NIOSH REL/CEILING 0.20 mg/m3 (10-minutes)
Exposure control/ personal protection: Medical supervision of all employees who handle or come in contact with
respiratory sensitizers is recommended. Persons with respiratory problems including asthmatic-type conditions, chronic
Bronchitis, other chronic respiratory diseases or recurrent skin eczema or skin allergies should be evaluated for their
suitability of working with this product. Once a person is diagnosed as sensitized, no further exposure to the material that
caused the sensitization should be permitted. The Occupational Exposure limits do not apply to previously sensitized
individuals.
SECTION 9: PHYSICAL AHD CHEMICAL PROPERTIES
APPEARANCE AND ODOR Pale Yellow Liquid Slightly Musty
BOILING POINT ( C) >300 C
MELTING POINT ( F/ C) Not available
SPECIFIC GRAVITY ( WATER = 1) 1.09 gr/ml
BULK DENSITY 9.0 lb/gal
pH Not applicable
VAPOR PRESSURE (MM Hg.) 0.000004 mmHg @ 25 C
VAPOR DENSITY (AIR-1) 8.5
VISCOSITY 700-900 cps @ 25 C
PERCENT (%) VOC 0%
FLASH POINTS >110 C (230 F) Closed Cup
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable at room temperature.
Incompatibility with various Substances: Reactive with moisture.
Conditions of Instability: Avoid high temperatures. Avoid freezing.
Hazardous Decomposition Products: Carbon Monoxide, Carbon Dioxide, Nitrous Oxide and HCN.
5
Hazardous Polymerization: Polymerization may occur at elevated temperatures in the presence of alkalies, tertiary
amines and metal compounds.
SECTION 11: TOXICOLOGICAL INFORMATION
Toxicity to Animals: LD50 Rat Oral: >5000mg/kg
LD50 Rabbit Dermal: >5000 mg/kg
Inhalation: This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapor or
aerosol at levels above the occupational exposure limit could cause respiratory sensitization. Symptoms may include
irritation to the eyes, nose, throat and lungs, possibly combined with dryness of the throat, tightness of chest and difficulty
in breathing. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive
response to even minimal concentrations of MDI may develop in sensitized persons.
Skin Contact: Moderate irritant. Repeated and/or prolonged contact may cause skin sensitization. There is limited
evidence from animal studies that skin contact may play a role in respiratory sensitization. These results emphasize the
need for protective clothing including gloves to be worn at all times when handling these chemicals or in maintenance
work.
Eye Contact: The vapor, aerosol, and liquid are irritant.
Ingestion: Ingestion may cause irritation of the gastrointestinal tract. Based on the acute oral LD50 this product is
considered practically non-toxic by ingestion.
Remarks: Short term test have shown that it is unlikely to be genotoxic. (BUTYLATEDHYDROXYTOLUENE)
Carcinogenic Effects: The ingredients of this product are not classified as carcinogenic by ACGIH or IARC, not
regulated as carcinogens by OSHA, and not listed as carcinogens by NTP.
Mutagenic Effects: There is no substantial evidence of mutagenic potential.
Reproductive Effects: No adverse reproductive effects are anticipated.
Teratogenic Effects: No birth defects were seen in two independent animal (rat) studies. Fetotoxicity was observed at
doses that were extremely toxic (including lethal) to the mother. Fetotoxicity was not observed at doses that were not
maternally toxic. The doses used in these studies were maximal respirable concentrations well in excess of the defined
limits.
Remark: A study was conducted where groups of rats were exposed for 6 hours/day, 5 days/week for a lifetime to
atmosphere of respirable polymeric MDI aerosol at concentrations of 0, 0.2, 1 or 6 mg/m3. No adverse effects were
observed at 0.2 mg/m3. At the 1mg/m3 concentration, minimal nasal and lung irritant effect were seen. Only at the top
concentration (6.0 mg/m3) was there an increased incidence of a benign tumor of the lung (adenoma). One malignant
pulmonary tumor (adenocarcinoma) was seen in the 6.0 mg/m3 group. MDI administration to rats in this study did not
change the distribution and incidence of tumors from those seen in control animals. The increased incidence of lung
tumors is associated with prolonged respiratory irritation and the concurrent accumulation of yellow material in the lung. In
the absence of prolonged exposure to high concentration leading to chronic irritation and lung damage, it is highly unlikely
that tumor formation will occur.
There are reports that excessive chronic exposure to diisocyanates may result in permanent decrease in lung function.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: Polymeric MDI. LC50 (Zebra Fish) >1000 ml/l. EC50 (Daphnia magna) (24 hours) >1000 mg/l EC50 (E. Coli)
> 100ml/l.
Environmental Fate and Distribution: It is unlikely that significant environmental exposure in the air or water will arise
based on consideration of the production and use of the substance.
6
Persistence and Degradation: Immiscible with water, but will react with water to produce inert and non-biodegradable
solids.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Information: The generation of waste should be avoided or minimized wherever possible.
Disposal should be in accordance with local, state, provincial or national regulations, This material is not hazardous waste
under RCRA 40 CFR 261. Small quantities should be treated with a decontaminant solution (see Section 6). The treated
waste is not a hazardous material under RCRA 40 CFR 261. Chemical waste, even small quantities, should never be
poured down drains, sewers or waterways.
Empty containers should be decontaminated and either passed to an approved drum recycler or destroyed.
SECTION 14: TRANSPORT INFORMATION
For major spills call Chemtrec (800-424-9300).
DOT Classification: Single containers less than 5000 lbs. are not regulated. Single containers with 5000 lbs. Or more of
4,4-Methylene Diphenyl Diisocyanate are regulated as: Other Regulated Substances, Liquid, N.O.S. (Methylene Diphenyl
Diisocyanate), 9, NA3082, PGlll, RQ.
TDG Classification: Not regulated.
IMO/IMDG Classification: Not regulated.
ICAO/IATA Classification: Not regulated.
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations
This material is classified as hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200).
HCS Classification: Class: Toxic
Class: Irritating substance.
Class: Sensitizing substance.
TSCA 8(b) inventory: All Ingredients Listed
EPCRA Section 313 (40 CFR 372)
Diisocyanate Compounds (Category Code N120) 73.18%
CERCLA (Comprehensive Environmental Response, Compensation and Liability Act): 4,4-
Methylene diphenyl diisocyanate (CAS 101-68-8) has 5000 lb. RQ (reportable quantity). Any spills or releases above the
RQ must be reported to the National Response Center (800-424-8802). This product does not contain nor is it
manufactured with ozone depleting substances.
State Regulations: California prop. 65: No ingredients listed.
Canadian Regulations: This material has been classified in accordance with the hazard criteria of the CPR (Controlled
Products Regulations) and this MSDS (Material Safety Data Sheet) contains all the information required by the CPR.
WHMIS (Canada): Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class D-2A: Material causing other toxic effects (VERY TOXIC).
Class D-2B: Material causing other toxic effects (TOXIC).
7
CEPA: DSL/NDSL: All Ingredients Listed.
SECTION 16: OTHER INFORMATION
CAUSES DAMAGE TO THE FOLLOWING ORGANS: LUNGS, RESPIRATORY TRACT, SKIN AND EYES. MAY BE
HARMFULL IF INHALED. MAY CAUSE RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
RESPIRATORY AND SKIN REACTION.
Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.)
Health: 2 Fire Hazard: 1 Reactivity: 1 Health: 2 Fire Hazard: 1 Reactivity: 1
While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date
of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICATION OF SUCH INFORMATION AND
RECOMMENDATIONS AND SUITABILITY OF ANY PRODUCT FOR IRS OWN PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARD AND SHOULD BE USED WITH CAUTION, WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS
PUBLICATION, NO GUARANTEE IS MADE THAT ARE THE ONLY HAZARDS THAT EXIST.
Hazards, toxicity and behavior of the products may differ when used with other materials and are dependent upon the manufacturing
circumstances or other processes. Such hazards, toxicity and behavior should be determined by the user and made known to handlers,
processors and end users.
8
We disclaim liability for damage or injury incurring directly or indirectly from the use of this product.
APROVED AND AUTHORIZED BY: Enes Torlic
by | Sep 27, 2025
Page 1 of 6
SAFETY DATA SHEET
BB Date Issued : 06/21/2021
ENTERPRISES SDS No : WC-85DM PART A
WC-85DM PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-85DM PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 3
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
Skull and Health hazard
crossbones
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H331: Toxic if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310: Immediately call a POISON CENTER/doctor/physician.
by | Sep 27, 2025
Page 1 of 7
SAFETY DATA SHEET
oe? e Date Prepared : 09/08/2009
on SDS No: WC-792 PART A
e Date Revised : 06/23/2015
ENTERPRISES :
WC-792 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-792 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION |
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 3
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
|
|
Skull and Health hazard Exclamation
crossbones mark
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H331: Toxic if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P285: In case of inadequate ventilation wear respiratory protection,
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
Response:
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 06/25/2007
SDS No: WC-783 PART A
Date Revised : 05/30/2018
ENTERPRISES Revision No : 3
WC-783 PART A
1, PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-783 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 2
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category |
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
Skull and Health hazard
crossbones
SIGNAL WORD: DANGER
HAZARD STATEMENTS
1330: Fatal if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye imitation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310: Immediately call a POISON CENTERMoctor/physician.
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 09/08/2009
SDS No : WC-792 PART A
Date Revised : 06/22/2018
ENTERPRISES Revision No : 4
WC-792 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-792 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 2
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
Skull and Health hazard
crossbones
SIGNAL WORD: DANGER
HAZARD STATEMENTS,
1330: Fatal if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENTS
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
P310: Immediately call a POISON CENTER/octor/physician.
by | Sep 27, 2025
SAFETY DATA SHEET
Date issued : 06/25/2007
SDS number : WC-783 PART A
Date revised : 03/25/2022
ENTERPRISES Revision number : 5
WC-783 PART A
1. Identification
Product identifier: WC-783 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category 1
Skin Sensitization, Category |
Target Organ Toxicity (Single exposure), Category 3
Label elements
Exclamation Health hazard
mark
Signal word: DANGER
Hazard statement(s)
H332: Harmful if inhaled.
HB 15: Causes skin imitation.
H3 19: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
335: May cause respiratory irritation.
Precautionary statement(s)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310: Immediately call a POISON CENTER/doctor/physician.
by | Sep 27, 2025
Page 1 of 6
SAFETY DATA SHEET
Date issued : 06/25/2007
SDS number : WC-783 PART A
Date revised : 03/25/2022
ENTERPRISES Revision number : 5
WC-783 PART A
1. Identification .
Product identifier: WC-783 PART A
Relevant identified uses: Polyurethane resin
Manufacturer / Supplier Emergency telephone number (24 hour)
BJB Enterprises, Inc. CHEMTREC (USA & Canada): (800) 424-9300
14791 Franklin Avenue or (703) 527-3887 CCN# 2820
Tustin, CA 92780
Emergency Phone: (714) 734-8450
2. Hazard identification
Classification of the substance or mixture
Health hazards:
Acute Toxicity (Inhalation), Category 4
Skin Irritation, Category 2
Eye Irritation, Category 2A
Respiratory Sensitization, Category |
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
Label elements
Exclamation Health hazard
mark
Signal word: DANGER
Hazard statement(s)
332: Harmful if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory imitation.
Precautionary statement(s)
Prevention:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310: Immediately call a POISON CENTER/doctor/physician.
by | Sep 27, 2025
SAFETY DATA SHEET
Date Issued : 2/6/2007
MSDS No : WC-782 PART A
Date-Revised : 8/18/2014
Revision No : 1
WC-782 PART A
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-782 PART A
GENERAL USE: Polyurethane resin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Health:
Acute Toxicity (Inhalation), Category 3
Skin Irritation, Category 2
Eye Irritation, Category 2
Respiratory Sensitization, Category 1
Skin Sensitization, Category 1
Target Organ Toxicity (Single exposure), Category 3
GHS LABEL
Skull and
crossbones
Health hazard
SIGNAL WORD: DANGER
HAZARD STATEMENTS
H331: Toxic if inhaled.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
PRECAUTIONARY STATEMENT(S)
Prevention:
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P285: In case of inadequate ventilation wear respiratory protection.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P272: Contaminated work clothing should not be allowed out of the workplace.
Page 1 of 7
Response:
P304+P340: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P311: Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331: Do NOT induce vomiting.
Storage:
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
Disposal:
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Clear colorless liquid with a slight odor.
IMMEDIATE CONCERNS: Toxic by inhalation. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and
skin contact. This product is a respiratory irritant and potential respiratory sensitizer. Repeated inhalation of vapour or aerosol at levels
above the occupational exposure limit could cause respiratory sensitization. A hyper-reactive response to even minimal concentrations of
diisocyanates may develop in sensitized persons. The onset of the respiratory symptoms may be delayed for several hours after exposure.
Reacts slowly with water to produce carbon dioxide which may rupture closed containers. This reaction accelerates at higher temperatures.
Do not breathe vapor or mist. Do not get on skin or clothing. Avoid contact with eyes. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use. Wash thoroughly after handling.
POTENTIAL HEALTH EFFECTS
EYES: Causes serious eye irritation.
SKIN: Causes skin irritation. May cause an allergic skin reaction.
INGESTION: Harmful if swallowed. Aspiration hazard. This material can enter the lungs during swallowing or vomiting and cause lung
inflammation and damage. It may also cause irritation to the mucous membranes of the mouth, throat, and digestive tract.
INHALATION: Toxic by inhalation of aerosol or mist. If misted, irritation of mucous membranes, nose, eyes, and throat may occur.
Extremely high vapor concentrations may cause lung damage. Inhalation at levels above the occupational exposure limit could cause
respiratory sensitization and risk of damage to the respiratory system. The onset of the respiratory system may be delayed for several hours
after exposure. A hyper-reactive response to even minimal concentrations of diisocyanates may develop in sensitized persons.
MEDICAL CONDITIONS AGGRAVATED: Pre-existing eye, skin, and respiratory conditions may be aggravated by exposure.
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
TARGET ORGANS: Contains material which causes damage to the following organs: upper respiratory tract.
SENSITIZATION: May cause allergic skin and respiratory reaction.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Dicyclohexylmethane-4,4′-diisocyanate 75 – 855124-30-1
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-
propanediol (3:1), polymer with 1,1′-methylenebis[4-isocyanatocyclohexane]
15 – 2553170-03-9
N-Methylpyrrolidone 0.037 872-50-4
Phenyl mercuric acetate (60% as Hg) 0.0092 62-38-4
4. FIRST AID MEASURES
Page 2 of 7
WC-782 PART A
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get immediate medical attention.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting. Provided the patient is conscious, wash out mouth with
water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Get immediate medical attention.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or alcohol foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxide, and HCN.
EXPLOSION HAZARDS: Material will react with water which produces carbon dioxide gas, a hazardous build-up of pressure could result if
contaminated containers are re-sealed. Containers may rupture if overheated.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 3 of 7
WC-782 PART A
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Dicyclohexylmethane-4,4′-diisocyanate
TWA NE NE 0.005 0.054 0.01
[1]
0.11
[1]
STEL NE NE NE NE NE NE
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-
hydroxy-, ether with 2-ethyl-2-(hydroxymethyl)-1,3-
propanediol (3:1), polymer with 1,1′-methylenebis[4-
isocyanatocyclohexane]
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
N-Methylpyrrolidone
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Phenyl mercuric acetate (60% as Hg)
TWA NE NE NE NE NE
[1]
0.01
[1]
STEL NE NE NE NE NE
[3]
0.03
[3]
OSHA TABLE COMMENTS:
1. NIOSH REL (ceiling)
2. NIOSH REL
3. NIOSH REL (skin)
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Colorless
pH: Not Applicable
PERCENT VOLATILE: 0.1
FLASHPOINT AND METHOD: 207 C (405 F) Pensky-Martens CC
VAPOR PRESSURE: < 0.001 mmHg at 25 C (77 F)
VAPOR DENSITY: Not Established
Page 4 of 7
WC-782 PART A
BOILING POINT: Decomposes
SOLUBILITY IN WATER: Insoluble, reacts slowly with water
SPECIFIC GRAVITY: 1.08 (water=1) at 25 C (77 F)
VISCOSITY: 650 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): 1.080 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product may foam when exposed to heat and moisture.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, nitrous oxide, and HCN.
INCOMPATIBLE MATERIALS: Moisture, strong acids, amines, and metal carboxylates.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Dicyclohexylmethane-4,4'-diisocyanate
9900 mg/kg > 10000 mg/kg 0.29 to 0.30 mg/l
(4 h of aerosols)
poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy-, ether
with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (3:1), polymer with 1,1′-
methylenebis[4-isocyanatocyclohexane]
Not Established Not Established Not Established
N-Methylpyrrolidone 4990 mg/kg 8 mg/kg > 5.1 mg/l (4 h)
Phenyl mercuric acetate (60% as Hg) 41 mg/kg Not Established Not Established
CHRONIC EFFECTS: Contains material that can cause target organ damage. Once sensitized, a severe allergic reaction may occur when
subsequently exposed to very low levels.
IRRITATION: Causes eye, skin, and respiratory irritation.
SENSITIZATION: May cause sensitization by skin contact.
TARGET ORGANS: Contains material which causes damage to the following organs: upper respiratory tract.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
Page 5 of 7
WC-782 PART A
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard. Chronic health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Dicyclohexylmethane-4,4′-diisocyanate 75 – 855124-30-1Diisocyanate Compounds (Category Code N120)
Phenyl mercuric acetate (60% as Hg) 0.009262-38-4Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
Chemical Name Wt.%
CERCLA
RQ
Phenyl mercuric acetate (60% as Hg) 0.0092100 lbs.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119—PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
N-Methylpyrrolidone 0.037
Cancer
Developmental Toxicity
Phenyl mercuric acetate (60% as Hg) 0.0092Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
Page 6 of 7
WC-782 PART A
D1A – Very
Toxic
D2A – Very
Toxic
D2B – Toxic
WHMIS CLASSIFICATION
Class D1A: Material causing immediate and serious toxic effects (Very toxic).
Class D2A: Material causing other toxic effects (Very toxic).
Class D2B: Material causing other toxic effects (Toxic).
WHMIS HEALTH EFFECTS CRITERIA
D1A – Acute lethality
D2A – Respiratory tract sensitization
D2B – Eye irritation
D2B – Skin irritation
D2B – Skin Sensitization
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: The D1A classification applies for this material in aerosol or mist form.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 2/6/2007 MSDS.
HMIS RATING
HEALTH * 3
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X
NFPA CODES
1
3 1
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
Page 7 of 7
WC-782 PART A
SAFETY DATA SHEET
Date Issued : 2/6/2007
MSDS No : WC-782 PART B
Date-Revised : 8/18/2014
Revision No : 1
WC-782 PART B
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: WC-782 PART B
GENERAL USE: Polyurethane curative
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
BJB Enterprises, Inc.
14791 Franklin Avenue
Tustin, CA 92780
Customer Service Number: (714) 734-8450
Fax: (714) 734-8929
CHEMTREC (US Transportation): (800) 424-9300
or (703) 527-3887 CCN# 2820
2. HAZARDS IDENTIFICATION
GHS CLASSIFICATIONS
Not a dangerous substance according to GHS.
GHS LABEL
HAZARD STATEMENTS
EMERGENCY OVERVIEW
PHYSICAL APPEARANCE AND ODOR: Clear colorless liquid with a slight odor.
IMMEDIATE CONCERNS: Avoid eye and skin contact. Avoid breathing vapors. May cause eye and skin irritation. Use in well ventilated
areas.
POTENTIAL HEALTH EFFECTS
EYES: May cause eye irritation.
SKIN: May cause skin irritation.
INGESTION: May be harmful if swallowed.
INHALATION: May cause respiratory irritation.
MEDICAL CONDITIONS AGGRAVATED: None Known
ROUTES OF ENTRY: Eye and skin contact, inhalation of vapors, or accidental ingestion.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS
Polyether polyol mixture 95 – 100Proprietary
Phenyl mercuric neodecanoate 0.16926545-49-3
neodecanoic acid 0.04326896-20-8
4. FIRST AID MEASURES
EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Get medical attention if irritation develops.
SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if irritation or rash
Page 1 of 5
develops. Wash clothing before reuse.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting unless directed to do so by medical personnel. Provided the
patient is conscious, wash out mouth with water. Never give anything by mouth to an unconscious person.
INHALATION: Remove to fresh air. Seek medical attention if breathing becomes difficult or if respiratory irritation develops.
NOTES TO PHYSICIAN: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be
monitored for at least 48 hours.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Water spray, carbon dioxide, dry chemical, or foam.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and carbon dioxide.
FIRE FIGHTING PROCEDURES: Cool fire exposed containers with water spray. Remove containers from the fire area if possible. Do not
release runoff from fire control methods to sewers or waterways.
FIRE FIGHTING EQUIPMENT: Firefighters should wear positive pressure self-contained breathing apparatus (SCBA) and consider use of
unmanned hose holders or monitor nozzles for fighting large fires.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing with a major spill should wear
full protective clothing including appropriate respiratory protection. Prevent product spill from entering sewers or waterways. Neutralize
small spills with a decontaminant.
LARGE SPILL: Contain and absorb large spills onto an inert, non-flammable adsorbent carrier (such as earth or sand). Shovel into open-top
drums or plastic bags for further decontamination, if necessary. Wash the spill area clean with a liquid decontaminant. Remove and properly
dispose of residues. Notify applicable government authorities if release is reportable. (See CERCLA in Section 15).
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Do not discharge into drains or rivers.
GENERAL PROCEDURES: Refer to section 8 of SDS for personal protection details.
RELEASE NOTES: Composition and extent of any spill should be evaluated against local regulations and reported to the proper agencies, if
necessary.
7. HANDLING AND STORAGE
GENERAL PROCEDURES: Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Avoid breathing vapor over
open containers. Avoid open container exposure to damp air. Avoid breathing aerosols, mists, and vapors.
HANDLING: Use appropriate personal protective equipment as specified in Section 8. Handle in a well-ventilated area. Handle and use in a
manner consistent with good industrial/manufacturing techniques and practices.
STORAGE: Store in a dry and well-ventilated place, away from excessive heat, in original or similar container. Avoid unnecessary contact.
Protect from freezing. Containers should be tightly sealed to prevent contamination with foreign materials.
STORAGE TEMPERATURE: 65-80 F (18-27 C)
SHELF LIFE: 6 months from date of shipment under manufacturers recommended storage conditions.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Page 2 of 5
WC-782 PART B
EXPOSURE GUIDELINES
OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SupplierOEL
Chemical Name ppm mg/m
3
ppm mg/m
3
ppm mg/m
3
Polyether polyol mixture
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
Phenyl mercuric neodecanoate
TWA NE 0.1 NE 0.1 NE NE
STEL NE NE NE NE NE NE
neodecanoic acid
TWA NE NE NE NE NE NE
STEL NE NE NE NE NE NE
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Safety goggles or glasses are recommended. Plastic face shields should be used for complete face protection to protect
against possible splashing or spraying of material. ANSI Z87.1 or approved equivalent.
SKIN: Chemical-resistant gloves and chemical goggles, face-shield, and synthetic apron or coveralls should be used to prevent contact with
eyes, skin, or clothing. Wear nitrile or neoprene gloves. Chemical resistant gloves lined with polyethylene offer maximum protection.
RESPIRATORY: Exhaust ventilation recommended. An organic vapor cartridge or fresh air supplied respirator (NIOSH approved) may be
necessary for certain applications. Consider the type of application, environmental concentrations, and other materials being used
concurrently when determining respirator use and selection. Observe OSHA regulations for respirator use (29 CFR 1910.134).
PROTECTIVE CLOTHING: Protective clothing should be selected and used in accordance with ‘Guidelines for the Selection of Chemical
Protective Clothing’ published by ACGIH.
WORK HYGIENIC PRACTICES: Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited. Wash hands before eating.
OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Training is important. Follow all label precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid
ODOR: Slight
COLOR: Colorless
pH: Not Established
PERCENT VOLATILE: 0.052
FLASHPOINT AND METHOD: > 204 C (400 F) Pensky-Martens CC
VAPOR PRESSURE: Not Established
VAPOR DENSITY: Not Established
BOILING POINT: Not Established
SOLUBILITY IN WATER: Slightly soluble
SPECIFIC GRAVITY: 1.03 (water=1) at 25 C (77 F)
VISCOSITY: 550 Centipoise at 25 C (77 F)
VOC (Volatile Organic Compound): < 0.540 g/l Calculated. Theoretical VOC minus water and exempt solvents.
10. STABILITY AND REACTIVITY
Page 3 of 5
WC-782 PART B
STABILITY: This product is stable under normal ambient conditions of temperature and pressure.
POLYMERIZATION: Product will not undergo polymerization.
CONDITIONS TO AVOID: High temperatures, moisture, and freezing conditions.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous reactions will not occur under normal transport or storage conditions.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and carbon dioxide.
INCOMPATIBLE MATERIALS: Isocyanates and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
TOXICITY TO ANIMALS
Chemical Name
ORAL LD50
(rat)
DERMAL LD50
(rabbit)
INHALATION
LC
50 (rat)
Polyether polyol mixture Not Established Not Established Not Established
Phenyl mercuric neodecanoate 25 to 200 mg/kg Not Established Not Established
neodecanoic acid Not Established Not Established Not Established
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: No data available.
ECOTOXICOLOGICAL INFORMATION: No specific ecological data are available for this product. Refer to Section 6 for information
regarding accidental release and Section 15 for regulatory reporting information.
BIOACCUMULATION/ACCUMULATION: No data available.
DISTRIBUTION: No data available.
CHEMICAL FATE INFORMATION: No data available.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain
some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via
a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements
of environmental protections and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION) LAND: Not Regulated
AIR (ICAO/IATA): Not Regulated
VESSEL (IMO/IMDG): Not Regulated
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZ ATION ACT)
311/312 HAZARD CATEGORIES: Acute health hazard
313 REPORTABLE INGREDIENTS: This product contains the following substances subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name Wt.% CAS Comments
Phenyl mercuric neodecanoate 0.16926545-49-3Mercury Compounds (Category Code N458)
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND L IABILITY ACT)
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CERCLA REGULATORY: For this/these chemicals, release of more than the Reportable Quantity to the environment in a 24-hour
period requires notification to the National Response Center (800-424-8802 or 202-426-2675):
None
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product contains chemical(s) subject to TSCA Section 12(b) export notification:
None
TSCA STATUS: This product or its components are listed in or exempt from the TSCA inventory requirements.
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA )
29 CFR1910.119---PROCESS SAFETY MANAGEMENT OF HIGHL Y HAZARDOUS CHEMICALS: None of the chemicals in
this product are considered highly hazardous by OSHA.
CALIFORNIA PROPOSITION 65: This product contains chemical(s) which are known to the State of California to cause cancer, birth
defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code
Section 25249.5):
Chemical Name Wt.% Listed
Phenyl mercuric neodecanoate 0.169Developmental Toxicity
OSHA HAZARD COMM. RULE: The contents of the SDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
CANADA
WHMIS HAZARD SYMBOL AND CLASSIFICATION
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SY STEM): This product has been classified according to the
hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
WHMIS CLASS: Does not meet criteria.
DOMESTIC SUBSTANCE LIST (INVENTORY): All components in this product are listed in or exempted from the Domestic
Substances List (DSL) or the Non-Domestic Substances List (NDSL).
16. OTHER INFORMATION
REASON FOR ISSUE: Revision
REVISION SUMMARY: This MSDS replaces the 2/6/2007 MSDS.
HMIS RATING
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA CODES
1
1 0
HMIS RATINGS NOTES: Personal Protection: See Section 8
MANUFACTURER DISCLAIMER: This information is furnished without warranty, expressed or implied, except that is accurate to the best
knowledge of BJB Enterprises, Inc. The data on this sheet relates only to the specific material designated herein. BJB Enterprises, Inc.
assumes no legal responsibility for use or reliance upon this data.
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