SAFETY DATA SHEET
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
– Trade nameHALAR 902- Chemical nameCopolymer of ethylene and chlorotrifluoroethylene- SynonymsECTFE
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance / Mixture
– For industrial use only
1.3 Details of the supplier of the safety data sheet
Company
SOLVAY SPECIALTY POLYMERS USA, LLC
4500 McGINNIS FERRY ROAD
30005-3914, ALPHARETTA
USA
Tel: +1-770-7728200
Fax: +1-770-7728213
Product Information:
+1-800-2210553
1.4 Emergency telephone
FOR EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CONTACT CHEMTREC (24-Hour
Number): 800-424-9300 within the United States and Canada, or 703-527-3887 for international collect calls.
SECTION 2: Hazards identification
Although OSHA has not adopted the environmental portion of the GHS regulations, this document may include information on
environmental effects.
2.1 Classification of the substance or mixture
HCS 2012 (29 CFR 1910.1200)
Combustible dustMay form combustible dust concentrations in air.
2.2 Label elements
HCS 2012 (29 CFR 1910.1200)
Signal Word
– Warning
Hazard Statements
– May form combustible dust concentrations in air.
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2.3 Other hazards which do not result in classification
– This product as shipped is not a combustible dust, however if small particles are generated during further processing,
handling or by other means, combustible dust concentrations may form in the air.
SECTION 3: Composition/information on ingredients
3.1 Substance
– Not applicable, this product is a mixture.
3.2 Mixture
– SynonymsECTFE
Hazardous Ingredients and Impurities
– No ingredients are hazardous.
Non Hazardous Ingredients and Impurities
Chemical name
Identification number
CAS-No.
Concentration [%]
Ethene,chlorotrifluoro-,polymer with ethene25101-45-5 >= 99
SECTION 4: First aid measures
4.1 Description of first-aid measures
In case of inhalation
– Remove the subject from dusty environment and let him blow his nose.
Exposure to decomposition products
– Move to fresh air.
– Oxygen or artificial respiration if needed.
– Symptoms of poisoning may develop many hours after exposure.
– Keep under medical supervision for at least 48 hours.
In case of skin contact
– Wash off with soap and water.
Exposure to decomposition products
– Wash off with soap and water.
– If fingers/finger nails are touched, even if there is no pain, dip them in a bath of 5% calcium gluconate for 15 to 20
minutes.
– Consult a physician.
In case of eye contact
– In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Exposure to decomposition products
– Rinse immediately with plenty of water, also under the eyelids.
– Remove contact lenses.
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In case of ingestion
– If large quantities of this material are swallowed, call a physician immediately.
– Never give anything by mouth to an unconscious person.
4.2 Most important symptoms and effects, both acute and delayed
In case of inhalationEffects
– Mechanical irritation from the particulates generated by the product.
– The thermal decomposition vapors of fluorinated polymers may cause polymer fume fever with flu-like symptoms in
humans, especially when smoking contaminated tobacco.
Symptoms
– Headache
– Shortness of breath
– Cough
In case of skin contactEffects
– Mechanical irritation from the particulates generated by the product.
Symptoms
Exposure to decomposition products
– Irritation
– Redness
– Burn
In case of eye contactEffects
– Mechanical irritation from the particulates generated by the product.
Symptoms
Exposure to decomposition products
– Irritation
– Redness
– Burn
In case of ingestionEffects
– Low ingestion hazard.
4.3 Indication of any immediate medical attention and special treatment needed
– no data available
SECTION 5: Firefighting measures
Flash pointThe product is not flammable. Autoignition temperatureNo data availableFlammability / Explosive limitNo data available
5.1 Extinguishing media
Suitable extinguishing media
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– Water
– powder
– Foam
– Dry chemical
– Carbon dioxide (CO2)
Unsuitable extinguishing media
– None.
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire fighting- The product is not flammable.
– Not explosive
– In case of fire hazardous decomposition products may be produced such as:
Hazardous combustion products:
– Gaseous hydrogen fluoride (HF).
– Fluorophosgene
– Gaseous hydrogen chloride (HCl).
– Other hazardous decomposition products may be formed.
5.3 Advice for firefighters
Special protective equipment for fire-fighters
– Wear self-contained breathing apparatus and protective suit.
– When intervention in close proximity wear acid resistant over suit.
Further information
– Evacuate personnel to safe areas.
– Approach from upwind.
– Protect intervention team with a water spray as they approach the fire.
– Keep containers and surroundings cool with water spray.
– Keep product and empty container away from heat and sources of ignition.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
– Prevent further leakage or spillage if safe to do so.
Advice for emergency responders
– Ensure adequate ventilation.
– Avoid dust formation.- Material can create slippery conditions.- Sweep up to prevent slipping hazard.- Keep away from open flames, hot surfaces and sources of ignition.
6.2 Environmental precautions
– Should not be released into the environment.
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– The product should not be allowed to enter drains, water courses or the soil.
– In case of accidental release or spill, immediately notify the appropriate authorities if required by Federal,
State/Provincial and local laws and regulations.
6.3 Methods and materials for containment and cleaning up
– Sweep up or vacuum up spillage and collect in suitable container for disposal.
6.4 Reference to other sections
– Refer to protective measures listed in sections 7 and 8.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
– Ensure adequate ventilation.
– Avoid dust formation.
– Use personal protective equipment.
– Do not contaminate tobacco products.
– Keep away from heat and sources of ignition.
– To avoid thermal decomposition, do not overheat.
– Take measures to prevent the build up of electrostatic charge.
– Clean and dry piping circuits and equipment before any operations.
– Ensure all equipment is electrically grounded before beginning transfer operations.
Hygiene measures
– Ensure that eyewash stations and safety showers are close to the workstation location.
– When using do not eat, drink or smoke.
– Wash hands before breaks and at the end of workday.
– Handle in accordance with good industrial hygiene and safety practice.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/Storage conditions
– Keep away from heat and sources of ignition.
– Keep in properly labeled containers.
– Keep away from combustible material.
– Keep away from heat/sparks/open flames/hot surfaces. No smoking.
– Keep away from incompatible products
– Provide tight electrical equipment well protected against corrosion.
– Refer to protective measures listed in sections 7 and 8.
Packaging material
Suitable material
– glass
– Metals
– Plastic materials.
– cardboard outer-packaging
7.3 Specific end use(s)
– Contact your supplier for additional information
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SECTION 8: Exposure controls/personal protection
Introductory Remarks: These recommendations provide general guidance for handling this product. Because specific work
environments and material handling practices vary, safety procedures should be developed for each intended application. Assistance
with selection, use and maintenance of worker protection equipment is generally available from equipment manufacturers.
8.1 Control parameters
– Contains no substances with occupational exposure limit values.
Components with workplace occupational exposure limits
ComponentsValue typeValue BasisParticles not otherwise specified (PNOS)National Institute for Occupational Safety and
Health
Includes all inert or nuisance dusts, whether mineral, inorganic, not listed specifically in
1910.1000., See Appendix D – Substances with No Established RELs
Particles not otherwise specified (PNOS)TWA15 mg/m3Occupational Safety and Health Administration
– Table Z-1 Limits for Air Contaminants
Form of exposure : total dust
All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically
by substance name are covered by the Particulates Not Otherwise Regulated (PNOR)
limit which is the same as the inert or nuisance dust limit of Table Z-3.
Particles not otherwise specified (PNOS)TWA5 mg/m3Occupational Safety and Health Administration
– Table Z-1 Limits for Air Contaminants
Form of exposure : respirable fraction
All inert or nuisance dusts, whether mineral, inorganic, or organic, not listed specifically
by substance name are covered by the Particulates Not Otherwise Regulated (PNOR)
limit which is the same as the inert or nuisance dust limit of Table Z-3.
Particles not otherwise specified (PNOS)TWA10 mg/m3American Conference of Governmental
Industrial Hygienists
Form of exposure : Inhalable fraction
Particles not otherwise specified (PNOS)TWA3 mg/m3American Conference of Governmental
Industrial Hygienists
Form of exposure : Respirable fraction
Threshold limit values of by-products from thermal decomposition:
Components with workplace occupational exposure limits
ComponentsValue typeValue BasisHydrofluoric acidTWA3 ppm
2.5 mg/m3
National Institute for Occupational Safety and
Health
Hydrofluoric acidC6 ppm
5 mg/m3
National Institute for Occupational Safety and
Health
15 minute ceiling value
Hydrofluoric acidTWA3 ppmOccupational Safety and Health Administration
– Table Z-2
Z37.28-1969
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Hydrofluoric acidTWA0.5 ppmAmerican Conference of Governmental
Industrial Hygienists
Danger of cutaneous absorption
Expressed as :Fluorine
Hydrofluoric acidC2 ppmAmerican Conference of Governmental
Industrial Hygienists
Danger of cutaneous absorption
Expressed as :Fluorine
Hydrofluoric acidOccupational Safety and Health Administration
– Table Z-1 Limits for Air Contaminants
See Table Z-2Expressed as :Fluorine
Hydrofluoric acidPEL0.4 ppm
0.33 mg/m3
SkinExpressed as :Fluorine
Hydrofluoric acidSTEL1 ppm
0.83 mg/m3
SkinExpressed as :Fluorine
Carbonyl difluorideTWA2 ppmAmerican Conference of Governmental
Industrial Hygienists
Carbonyl difluorideSTEL5 ppmAmerican Conference of Governmental
Industrial Hygienists
Carbonyl difluorideTWA2 ppm
5 mg/m3
National Institute for Occupational Safety and
Health
Carbonyl difluorideST5 ppm
15 mg/m3
National Institute for Occupational Safety and
Health
Carbonyl difluoridePEL2 ppm
5 mg/m3
Carbonyl difluorideSTEL5 ppm
15 mg/m3
hydrogen chloride (gas)C2 ppmAmerican Conference of Governmental
Industrial Hygienists
hydrogen chloride (gas)C5 ppm
7 mg/m3
National Institute for Occupational Safety and
Health
Often used in an aqueous solution.
hydrogen chloride (gas)C5 ppm
7 mg/m3
Occupational Safety and Health Administration
– Table Z-1 Limits for Air Contaminants
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The value in mg/m3 is approximate., Ceiling limit is to be determined from breathing-
zone air samples.
hydrogen chloride (gas)PEL0.3 ppm
0.45 mg/m3
hydrogen chloride (gas)C2 ppm
Biological Exposure Indices
ComponentsValue typeValue BasisHydrofluoric acidBEI2 mg/l
Fluoride
Urine
Prior to shift (16 hours
after exposure ceases)
American Conference of Governmental
Industrial Hygienists
Hydrofluoric acidBEI3 mg/l
Fluoride
Urine
End of shift (As soon as
possible after exposure
ceases)
American Conference of Governmental
Industrial Hygienists
8.2 Exposure controls
Control measures
Engineering measures
– Provide appropriate exhaust ventilation at machinery and at places where dust can be generated.
– Provide local ventilation appropriate to the product decomposition risk (see section 10).
– Refer to protective measures listed in sections 7 and 8.
– Apply technical measures to comply with the occupational exposure limits.
– For additional information, consult the current edition of The Guide to the Safe Handling of Fluoropolymers
published by the Society of Plastics Industry, Inc. (SPI) Fluoropolymer Division.
Individual protection measures
Respiratory protection
– When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
– Use respirator when performing operations involving potential exposure to vapor of the product.
– When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne
concentrations and in accordance with the appropriate regulatory standards and/or industrial recommendations.
– Comply with OSHA respiratory protection requirements.
– For additional information, consult the current edition of The Guide to the Safe Handling of Fluoropolymers
published by the Society of Plastics Industry, Inc. (SPI) Fluoropolymer Division.
Hand protection
– Wear protective gloves.
– Protective gloves – impervious chemical resistant:
Suitable material
– Nitrile rubber
– PVC
– Neoprene gloves
– butyl-rubber
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– Take note of the information given by the producer concerning permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection
– Safety glasses with side-shields
– In case of high-temperature processing
– Tightly fitting safety goggles
Skin and body protection
– Long sleeved clothing
– Safety shoes
Hygiene measures
– Ensure that eyewash stations and safety showers are close to the workstation location.
– When using do not eat, drink or smoke.
– Wash hands before breaks and at the end of workday.
– Handle in accordance with good industrial hygiene and safety practice.
SECTION 9: Physical and chemical properties
Physical and Chemical properties here represent typical properties of this product. Contact the business area using the Product
information phone number in Section 1 for its exact specifications.
9.1 Information on basic physical and chemical properties
Appearance
Form:
pellets
Physical state:
solid
Color:
white Odorodorless Odor ThresholdNo data availablepHNo data availableMelting point/freezing pointMelting point/range: 419 – 446 F (215 – 230 C) Initial boiling point and boiling rangeBoiling point/boiling range
Not applicable
Flash pointThe product is not flammable. Evaporation rate (Butylacetate = 1)No data availableFlammability (solid, gas)The product is not flammable.May form combustible dust concentrations in air.Flammability / Explosive limitNo data availableAutoignition temperatureNo data availableVapor pressureNo data availableVapor densityNo data availableDensity1.65 – 1.71 g/cm3
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Relative densityNo data availableSolubilityWater solubility:
insoluble
Solubility in other solvents:
common organic solvents : insoluble
Partition coefficient: n-octanol/waterNo data availableDecomposition temperature> 572 F (> 300 C)ViscosityNo data availableExplosive propertiesNot explosiveOxidizing propertiesNot considered as oxidizing.
9.2 Other information
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
– No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
– Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
– Under certain conditions, small dust-particles from the product may form flammable and explosive mixtures with the
air.
10.4 Conditions to avoid
– To avoid thermal decomposition, do not overheat.
– Keep away from flames and sparks.
10.5 Incompatible materials
– Combustible material
– Flammable materials
– Alkali metals (molten form)
10.6 Hazardous decomposition products
–
–
–
–
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SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicityNo data availableAcute inhalation toxicityNo data available
Acute dermal toxicityNo data availableAcute toxicity (other routes of
administration)
No data availableSkin corrosion/irritationNo data availableSerious eye damage/eye irritationNo data availableRespiratory or skin sensitizationNo data available
Mutagenicity
Genotoxicity in vitroNo data availableGenotoxicity in vivoNo data availableCarcinogenicityNo data available
This product does not contain any ingredient designated as probable or suspected human carcinogens by:
NTP
IARC
OSHA
ACGIH
Toxicity for reproduction and development
Toxicity to reproduction / fertilityNo data availableDevelopmental Toxicity/TeratogenicityNo data available
STOT
STOT-single exposureNo data availableSTOT-repeated exposureNo data availableExperience with human exposureNo data available
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Aspiration toxicityNo data availableFurther informationDescription of possible hazardous to health effects is based on experience and/or
toxicological characteristics of several ingredients.
Product dust may be irritating to eyes, skin and respiratory system.
The thermal decomposition vapors of fluorinated polymers may cause polymer
fume fever with flu-like symptoms in humans, especially when smoking
contaminated tobacco.
Thermal decomposition can lead to release of toxic and corrosive gases.
The exposure to decomposition products causes severe irritation of eyes, skin
and mucous membranes.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic Compartment
Acute toxicity to fish No data availableAcute toxicity to daphnia and other
aquatic invertebrates
No data available
Toxicity to aquatic plantsNo data available
Toxicity to microorganismsNo data availableChronic toxicity to fishNo data availableChronic toxicity to daphnia and
other aquatic invertebrates
No data available
12.2 Persistence and degradability
Abiotic degradationNo data availablePhysical- and photo-chemical
elimination
No data availableBiodegradationNo data available
12.3 Bioaccumulative potential
Partition coefficient: n-octanol/waterNo data available
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Bioconcentration factor (BCF)No data available
12.4 Mobility in soil
Adsorption potential (Koc)No data availableKnown distribution to environmental
compartments
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
No data availableRemarksEcological injuries are not known or expected under normal use.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product Disposal
– Do not dump into any sewers, on the ground, or into any body of water. All disposal methods must be in compliance with
all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations.
– Waste characterizations and compliance with applicable laws and regulations are the responsibility of the waste
generator.
– Can be incinerated, when in compliance with local regulations.
– The incinerator must be equipped with a system for the neutralization or recovery of HF.
Advice on cleaning and disposal of packaging
– Empty containers can be landfilled, when in accordance with the local regulations.
SECTION 14: Transport information
DOT
not regulated
TDG
not regulated
NOM
not regulated
IMDG
not regulated
IATA
not regulated
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Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of
transportation regulations for hazardous materials, it would be advisable to check their validity with your sales office.
SECTION 15: Regulatory information
15.1 Notification status
Inventory InformationStatusUnited States TSCA Inventory-Canadian Domestic Substances List (DSL)-Australia Inventory of Chemical Substances (AICS)-Korea. Korean Existing Chemicals Inventory (KECI)-
imported by Solvay. Contact Solvay for
further details.
China. Inventory of Existing Chemical Substances in China (IECSC)-
imported by Solvay. Contact Solvay for
further details.
Japan. ISHL – Inventory of Chemical Substances-Japan. CSCL – Inventory of Existing and New Chemical Substances-Philippines Inventory of Chemicals and Chemical Substances (PICCS)-New Zealand. Inventory of Chemical Substances-EU. European Registration, Evaluation, Authorisation and Restriction of Chemical
(REACH)
–
Europe it is in compliance with REACH, if
not please contact the supplier.
Taiwan. Chemical Substance Inventory (TCSI)-
15.2 Federal Regulations
US. EPA EPCRA SARA Title III
Section 313 Toxic Chemicals (40 CFR 372.65)
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Section 302 Emergency Planning Extremely Hazardous Substance Threshold Planning Quantity (40 CFR 355)
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
Section 302 Emergency Planning Extremely Hazardous Substance Reportable Quantity (40 CFR 355)
This material does not contain any components with a SARA 302 RQ.
Section 304 Emergency Release Notification Reportable Quantity (40 CFR 355)
This material does not contain any components with a section 304 EHS RQ.
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US. EPA CERCLA Hazardous Substances and Reportable Quantities (40 CFR 302.4)
This material does not contain any components with a CERCLA RQ.
15.3 State Regulations
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.
SECTION 16: Other information
Further information
– Product evaluated under the US GHS format.
Date Prepared:
Key or legend to abbreviations and acronyms used in the safety data sheet
– C Ceiling limit
– PEL Permissible exposure limit
– ST STEL – 15-minute TWA exposure that should not be exceeded at any time during a workday
– STEL Short term exposure limit
– TWA 8-hour, time-weighted average
-ACGIHAmerican Conference of Governmental Industrial Hygienists-OSHAOccupational Safety and Health Administration-NTPNational Toxicology Program-IARCInternational Agency for Research on Cancer-NIOSHNational Institute for Occupational Safety and Health
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its
publication. Such information is only given as a guidance to help the user handle, use, process, store, transport, dispose, and release
the product in satisfactory safety conditions and is not to be considered as a warranty or quality specification. It should be used in
conjunction with technical sheets but do not replace them. Thus, the information only relates to the designated specific product and may
not be applicable if such product is used in combination with other materials or in any other manufacturing process, unless otherwise
specifically indicated. It does not release the user from ensuring he is in conformity with all regulations linked to its activity.